ES2420879T3 - Componentes catalizadores para la polimerización de olefinas - Google Patents
Componentes catalizadores para la polimerización de olefinas Download PDFInfo
- Publication number
- ES2420879T3 ES2420879T3 ES03767757T ES03767757T ES2420879T3 ES 2420879 T3 ES2420879 T3 ES 2420879T3 ES 03767757 T ES03767757 T ES 03767757T ES 03767757 T ES03767757 T ES 03767757T ES 2420879 T3 ES2420879 T3 ES 2420879T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst component
- compound
- solid catalyst
- olefins
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 36
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 20
- 239000003054 catalyst Substances 0.000 title claims description 92
- 239000010936 titanium Substances 0.000 claims abstract description 71
- 150000001875 compounds Chemical class 0.000 claims abstract description 54
- 239000011949 solid catalyst Substances 0.000 claims abstract description 25
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 12
- 150000002170 ethers Chemical class 0.000 claims abstract description 11
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 11
- 150000002367 halogens Chemical class 0.000 claims abstract description 9
- 150000002576 ketones Chemical class 0.000 claims abstract description 7
- 150000001412 amines Chemical class 0.000 claims abstract description 5
- 150000002825 nitriles Chemical class 0.000 claims abstract description 5
- 125000005843 halogen group Chemical group 0.000 claims abstract description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 88
- 238000000034 method Methods 0.000 claims description 44
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical group CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 34
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 33
- 239000005977 Ethylene Substances 0.000 claims description 32
- -1 alkylaluminum compound Chemical class 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 24
- 238000002360 preparation method Methods 0.000 claims description 24
- 229920000642 polymer Polymers 0.000 claims description 22
- 239000007789 gas Substances 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 13
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 11
- 239000000047 product Substances 0.000 claims description 11
- 150000002430 hydrocarbons Chemical group 0.000 claims description 10
- 150000004292 cyclic ethers Chemical class 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 150000003377 silicon compounds Chemical class 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- 239000003085 diluting agent Substances 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000005907 alkyl ester group Chemical group 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 150
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 54
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 49
- 239000007787 solid Substances 0.000 description 48
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 38
- 239000011777 magnesium Substances 0.000 description 37
- 238000003756 stirring Methods 0.000 description 35
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 30
- 235000011147 magnesium chloride Nutrition 0.000 description 27
- 229910001629 magnesium chloride Inorganic materials 0.000 description 24
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 22
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 20
- 239000000725 suspension Substances 0.000 description 16
- 239000012071 phase Substances 0.000 description 15
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 14
- 238000007334 copolymerization reaction Methods 0.000 description 13
- 229910003074 TiCl4 Inorganic materials 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- 239000001294 propane Substances 0.000 description 11
- 238000011282 treatment Methods 0.000 description 11
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 239000012798 spherical particle Substances 0.000 description 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- 229910000831 Steel Inorganic materials 0.000 description 8
- 238000007429 general method Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000010959 steel Substances 0.000 description 8
- 239000008096 xylene Substances 0.000 description 8
- 229920000092 linear low density polyethylene Polymers 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000004707 linear low-density polyethylene Substances 0.000 description 6
- 150000003609 titanium compounds Chemical class 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 125000005234 alkyl aluminium group Chemical group 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229920001038 ethylene copolymer Polymers 0.000 description 4
- 238000012685 gas phase polymerization Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229910003910 SiCl4 Inorganic materials 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000012512 characterization method Methods 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 230000001603 reducing effect Effects 0.000 description 3
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
- 238000001291 vacuum drying Methods 0.000 description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000002083 X-ray spectrum Methods 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 150000005840 aryl radicals Chemical group 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- 229920001866 very low density polyethylene Polymers 0.000 description 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
- 101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 description 1
- 101100378709 Arabidopsis thaliana AIR3 gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910010062 TiCl3 Inorganic materials 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000006653 Ziegler-Natta catalysis Methods 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- AENCLWKVWIIOQH-UHFFFAOYSA-K cyclopentane;trichlorotitanium Chemical compound Cl[Ti](Cl)Cl.[CH]1C=CC=C1 AENCLWKVWIIOQH-UHFFFAOYSA-K 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- UFSFYCIIKGJKSN-UHFFFAOYSA-N n,n-diethylethanamine;n-ethylethanamine Chemical compound CCNCC.CCN(CC)CC UFSFYCIIKGJKSN-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
- RFRNCCDBLKNKEQ-UHFFFAOYSA-N triethylalumane;tris(2-methylpropyl)alumane Chemical compound CC[Al](CC)CC.CC(C)C[Al](CC(C)C)CC(C)C RFRNCCDBLKNKEQ-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- JAYPHJBLPAEMEX-UHFFFAOYSA-N trimethoxy(2-methylpentan-2-yl)silane Chemical group CCCC(C)(C)[Si](OC)(OC)OC JAYPHJBLPAEMEX-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- XZIKSWMNFLIAQP-UHFFFAOYSA-N tris(2,4,4-trimethylpentyl)alumane Chemical compound CC(C)(C)CC(C)C[Al](CC(C)CC(C)(C)C)CC(C)CC(C)(C)C XZIKSWMNFLIAQP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02080616 | 2002-12-18 | ||
| EP02080616 | 2002-12-18 | ||
| US43519502P | 2002-12-20 | 2002-12-20 | |
| US435195P | 2002-12-20 | ||
| PCT/EP2003/013807 WO2004055065A1 (en) | 2002-12-18 | 2003-11-25 | Catalyst components for the polymerization of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2420879T3 true ES2420879T3 (es) | 2013-08-27 |
Family
ID=35925132
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03789154T Expired - Lifetime ES2368425T3 (es) | 2002-12-18 | 2003-11-25 | Aductos basados en dicloruro magnésico y componentes catalíticos obtenidos a partir de ellos. |
| ES03767757T Expired - Lifetime ES2420879T3 (es) | 2002-12-18 | 2003-11-25 | Componentes catalizadores para la polimerización de olefinas |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03789154T Expired - Lifetime ES2368425T3 (es) | 2002-12-18 | 2003-11-25 | Aductos basados en dicloruro magnésico y componentes catalíticos obtenidos a partir de ellos. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7427653B2 (OSRAM) |
| EP (1) | EP1572756B1 (OSRAM) |
| JP (2) | JP2006510751A (OSRAM) |
| KR (1) | KR101102793B1 (OSRAM) |
| CN (2) | CN100554287C (OSRAM) |
| AR (1) | AR042496A1 (OSRAM) |
| AU (1) | AU2003292199A1 (OSRAM) |
| BR (1) | BR0316913B1 (OSRAM) |
| CA (1) | CA2510679C (OSRAM) |
| ES (2) | ES2368425T3 (OSRAM) |
| MX (1) | MXPA05006584A (OSRAM) |
| RU (1) | RU2322457C2 (OSRAM) |
| SA (1) | SA03240450B1 (OSRAM) |
| TW (1) | TW200417554A (OSRAM) |
| WO (1) | WO2004055065A1 (OSRAM) |
| ZA (2) | ZA200504131B (OSRAM) |
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| CN101165074B (zh) * | 2006-10-20 | 2010-12-22 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其催化剂 |
| EP2036928B1 (en) * | 2006-04-06 | 2015-12-23 | China Petroleum & Chemical Corporation | Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom |
| CN101486776B (zh) * | 2008-01-17 | 2010-12-22 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其催化剂 |
| BRPI0919385B1 (pt) * | 2008-09-26 | 2019-06-04 | Basell Poliolefine Italia S.R.L. | Componentecatalisador pré-polimerizado, sistema catalisador e processo em fase gasosa para a polimerização de olefinas |
| US8268945B2 (en) | 2009-08-21 | 2012-09-18 | China Petroleum & Chemical Corporation | Catalyst component for ethylene polymerization, preparation thereof, and a catalyst comprising the catalyst component |
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| KR101835309B1 (ko) | 2010-08-24 | 2018-03-08 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 |
| US20120053305A1 (en) * | 2010-08-24 | 2012-03-01 | Equistar Chemicals, Lp | Preparation of LLDPE having controlled xylene solubles or hexane extractables |
| US10138310B2 (en) * | 2010-08-24 | 2018-11-27 | Equistar Chemicals, Lp | Preparation of LLDPE resins and films having low gels |
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| WO2012041944A1 (en) * | 2010-09-30 | 2012-04-05 | Basell Poliolefine Italia S.R.L. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
| CN102585056A (zh) * | 2011-01-05 | 2012-07-18 | 中国石油化工股份有限公司 | 一种用于乙烯聚合或共聚合反应的催化剂 |
| EP2610273B1 (en) * | 2011-12-30 | 2018-02-07 | Borealis AG | Catalyst component |
| EP2692743A1 (en) | 2012-08-03 | 2014-02-05 | Basell Poliolefine Italia S.r.l. | Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom |
| EP2712875A1 (en) | 2012-09-28 | 2014-04-02 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| CN103788246B (zh) * | 2012-10-29 | 2015-10-21 | 中国石油化工股份有限公司 | 一种烯烃聚合催化剂载体及其制备方法和应用 |
| EA025272B1 (ru) * | 2013-01-31 | 2016-12-30 | Сауди Бейсик Индастриз Корпорейшн | Способ получения компонента катализатора полимеризации олефинов |
| SG11201506721TA (en) | 2013-02-27 | 2015-09-29 | Toho Titanium Co Ltd | Method for producing propylene block copolymer |
| CN104231140B (zh) * | 2013-06-21 | 2016-12-07 | 中国石油天然气集团公司 | 一种乙烯-α-烯烃共聚催化剂及其制备和应用 |
| US9605096B2 (en) * | 2013-07-25 | 2017-03-28 | Exxonmobil Chemical Patents Inc. | Methods for polyolefin polymerization with high activity catalyst systems |
| JP6470302B2 (ja) | 2014-03-14 | 2019-02-13 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用触媒成分 |
| FR3023183A1 (fr) * | 2014-07-04 | 2016-01-08 | IFP Energies Nouvelles | Composition catalytique et procede de dimerisation selective de l'ethylene en butene-1 |
| CA2970848C (en) | 2014-12-18 | 2023-04-11 | Borealis Ag | Ziegler-natta catalyst and preparation thereof |
| CA2975026C (en) | 2015-02-05 | 2023-10-31 | Borealis Ag | Process for producing polyethylene |
| CN107949587B (zh) * | 2015-09-11 | 2020-04-28 | 巴塞尔聚烯烃意大利有限公司 | 用于制备烯烃聚合用催化剂组分的工艺 |
| BR112019000090A2 (pt) | 2016-07-15 | 2019-04-09 | Basell Poliolefine Italia Srl | catalisador para a polimerização de olefinas |
| FI3555150T3 (fi) | 2016-12-19 | 2023-11-22 | Basell Poliolefine Italia Srl | Katalyyttikomponentteja olefiinien polymerisoimiseksi ja niistä saatuja katalyyttejä |
| EP3339333B1 (en) | 2016-12-22 | 2020-10-07 | Borealis AG | Ziegler-natta catalyst and preparation thereof |
| BR112020001201B1 (pt) | 2017-07-19 | 2023-03-21 | Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation | Sistema catalisador ziegler-natta para polimerização olefínica, componente catalisador sólido para polimerização olefínica e processo de polimerização olefínica |
| EP3720888A1 (en) | 2017-12-05 | 2020-10-14 | Univation Technologies, LLC | Modified spray-dried ziegler-natta (pro)catalyst systems |
| ES2970016T3 (es) * | 2017-12-05 | 2024-05-23 | Univation Tech Llc | Sistema catalizador de ziegler-natta activado secado mediante pulverización |
| JP7249349B2 (ja) | 2017-12-27 | 2023-03-30 | ボレアリス エージー | チーグラー・ナッタ触媒及びその調製 |
| EP3732209A1 (en) | 2017-12-28 | 2020-11-04 | Borealis AG | Catalyst and preparation thereof |
| EP3802641B1 (en) * | 2018-06-01 | 2025-09-24 | Dow Global Technologies LLC | Ziegler-natta catalyst system having a thermally treated magnesium chloride component |
| EP4038110A1 (en) | 2019-10-04 | 2022-08-10 | Borealis AG | Ziegler-natta catalysts for olefin polymerization |
| WO2021064083A1 (en) | 2019-10-04 | 2021-04-08 | Borealis Ag | Ziegler-natta catalysts for olefin polymerization |
| US12391778B2 (en) | 2019-10-04 | 2025-08-19 | Borealis Ag | Ziegler-natta catalysts for olefin polymerization |
| WO2021064081A1 (en) | 2019-10-04 | 2021-04-08 | Borealis Ag | Ziegler-natta catalysts for olefin polymerization |
| CN112812205B (zh) * | 2019-11-18 | 2023-05-09 | 中国石油化工股份有限公司 | 一种用于烯烃聚合反应的催化剂组分及其催化剂和其制法及应用 |
| US20230151124A1 (en) | 2020-04-30 | 2023-05-18 | Dow Global Technologies Llc | Ziegler-natta (pro)catalyst systems made with (multi-alkoxy)silane compound |
| JP2023546624A (ja) * | 2020-10-26 | 2023-11-06 | 中国石油化工股▲ふん▼有限公司 | オレフィン重合触媒を製造するための固体成分、その製造方法およびその利用 |
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-
2003
- 2003-11-25 ES ES03789154T patent/ES2368425T3/es not_active Expired - Lifetime
- 2003-11-25 KR KR1020057011380A patent/KR101102793B1/ko not_active Expired - Lifetime
- 2003-11-25 JP JP2004559767A patent/JP2006510751A/ja not_active Withdrawn
- 2003-11-25 MX MXPA05006584A patent/MXPA05006584A/es unknown
- 2003-11-25 CN CNB2003801061943A patent/CN100554287C/zh not_active Expired - Lifetime
- 2003-11-25 AU AU2003292199A patent/AU2003292199A1/en not_active Abandoned
- 2003-11-25 CN CNA200380106191XA patent/CN1726080A/zh active Pending
- 2003-11-25 CA CA2510679A patent/CA2510679C/en not_active Expired - Lifetime
- 2003-11-25 EP EP03767757.2A patent/EP1572756B1/en not_active Revoked
- 2003-11-25 US US10/537,077 patent/US7427653B2/en not_active Expired - Lifetime
- 2003-11-25 ES ES03767757T patent/ES2420879T3/es not_active Expired - Lifetime
- 2003-11-25 BR BRPI0316913-8A patent/BR0316913B1/pt active IP Right Grant
- 2003-11-25 RU RU2005122489/04A patent/RU2322457C2/ru active
- 2003-11-25 WO PCT/EP2003/013807 patent/WO2004055065A1/en not_active Ceased
- 2003-12-10 TW TW092134831A patent/TW200417554A/zh unknown
- 2003-12-17 AR ARP030104667A patent/AR042496A1/es unknown
- 2003-12-20 SA SA03240450A patent/SA03240450B1/ar unknown
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2005
- 2005-05-20 ZA ZA200504131A patent/ZA200504131B/en unknown
- 2005-05-20 ZA ZA200504127A patent/ZA200504127B/en unknown
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| CN1726230A (zh) | 2006-01-25 |
| MXPA05006584A (es) | 2005-08-16 |
| SA03240450B1 (ar) | 2009-01-19 |
| EP1572756A1 (en) | 2005-09-14 |
| CN100554287C (zh) | 2009-10-28 |
| AU2003292199A1 (en) | 2004-07-09 |
| KR20050084415A (ko) | 2005-08-26 |
| BR0316913A (pt) | 2005-10-18 |
| EP1572756B1 (en) | 2013-04-10 |
| RU2322457C2 (ru) | 2008-04-20 |
| CA2510679C (en) | 2013-04-23 |
| BR0316913B1 (pt) | 2014-09-09 |
| RU2005122489A (ru) | 2006-01-20 |
| ZA200504127B (en) | 2006-02-22 |
| CN1726080A (zh) | 2006-01-25 |
| US20060089251A1 (en) | 2006-04-27 |
| US7427653B2 (en) | 2008-09-23 |
| WO2004055065A1 (en) | 2004-07-01 |
| TW200417554A (en) | 2004-09-16 |
| ES2368425T3 (es) | 2011-11-17 |
| JP2006510751A (ja) | 2006-03-30 |
| KR101102793B1 (ko) | 2012-01-05 |
| AR042496A1 (es) | 2005-06-22 |
| JP2010280894A (ja) | 2010-12-16 |
| ZA200504131B (en) | 2006-02-22 |
| JP5366898B2 (ja) | 2013-12-11 |
| CA2510679A1 (en) | 2004-07-01 |
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