BR0316913A - Componentes catalìticos para a polimerização de olefinas - Google Patents

Componentes catalìticos para a polimerização de olefinas

Info

Publication number
BR0316913A
BR0316913A BR0316913-8A BR0316913A BR0316913A BR 0316913 A BR0316913 A BR 0316913A BR 0316913 A BR0316913 A BR 0316913A BR 0316913 A BR0316913 A BR 0316913A
Authority
BR
Brazil
Prior art keywords
catalytic components
olefin polymerization
polymerization
chains
molar ratio
Prior art date
Application number
BR0316913-8A
Other languages
English (en)
Other versions
BR0316913B1 (pt
Inventor
Diego Brita
Gianni Collina
Giampiero Morini
Gianni Vitale
Original Assignee
Basell Poliolefine Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=35925132&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR0316913(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Poliolefine Spa filed Critical Basell Poliolefine Spa
Publication of BR0316913A publication Critical patent/BR0316913A/pt
Publication of BR0316913B1 publication Critical patent/BR0316913B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"COMPONENTES CATALìTICOS PARA A POLIMERIZAçãO DE OLEFINAS". O presente invento se refere a um componente catalítico para a (co)polimerização de olefinas, e em particular para a preparação de LLDPE, compreendendo Mg, Ti, um halogênio e um composto doador de elétrons (ED) pertencente a éteres, ésteres, aminas, cetonas ou nitrilas, em que a razão molar Mg/Ti é maior que 5, e a razão molar ED/Ti é maior que 3,5. Os ditos componentes catalíticos exibem uma distribuição homogênea do comonómero nas cadeias e entre as cadeias do copolímero.
BRPI0316913-8A 2002-12-18 2003-11-25 Componente catalítico sólido para a polimerização de olefinas, catalisador para a polimerização de olefinas e processo para a BR0316913B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP02080616.2 2002-12-18
EP02080616 2002-12-18
US43519502P 2002-12-20 2002-12-20
US60/435,195 2002-12-20
PCT/EP2003/013807 WO2004055065A1 (en) 2002-12-18 2003-11-25 Catalyst components for the polymerization of olefins

Publications (2)

Publication Number Publication Date
BR0316913A true BR0316913A (pt) 2005-10-18
BR0316913B1 BR0316913B1 (pt) 2014-09-09

Family

ID=35925132

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0316913-8A BR0316913B1 (pt) 2002-12-18 2003-11-25 Componente catalítico sólido para a polimerização de olefinas, catalisador para a polimerização de olefinas e processo para a

Country Status (16)

Country Link
US (1) US7427653B2 (pt)
EP (1) EP1572756B1 (pt)
JP (2) JP2006510751A (pt)
KR (1) KR101102793B1 (pt)
CN (2) CN100554287C (pt)
AR (1) AR042496A1 (pt)
AU (1) AU2003292199A1 (pt)
BR (1) BR0316913B1 (pt)
CA (1) CA2510679C (pt)
ES (2) ES2420879T3 (pt)
MX (1) MXPA05006584A (pt)
RU (1) RU2322457C2 (pt)
SA (1) SA03240450B1 (pt)
TW (1) TW200417554A (pt)
WO (1) WO2004055065A1 (pt)
ZA (2) ZA200504127B (pt)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1626996B1 (en) 2003-05-29 2017-04-26 Basell Poliolefine Italia S.r.l. Process for the preparation of a catalyst component and components therefrom obtained
EP1780225A1 (en) 2005-11-01 2007-05-02 Borealis Technology Oy Ziegler-Natta catalyst and its use to prepare multimodal polyolefin
CN101165074B (zh) * 2006-10-20 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
EP2036928B1 (en) * 2006-04-06 2015-12-23 China Petroleum & Chemical Corporation Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom
CN101486776B (zh) * 2008-01-17 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
WO2010034664A1 (en) 2008-09-26 2010-04-01 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
EP2287212B1 (en) 2009-08-21 2014-03-26 China Petroleum & Chemical Corporation A catalyst component for ethylene polymerization, preparation thereof and a catalyst comprising the catalyst component
SA3686B1 (ar) * 2009-10-16 2014-10-22 China Petroleum& Chemical Corp مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه
US20110319571A1 (en) * 2010-06-29 2011-12-29 Botros Maged G Polyolefin adhesive composition
US10138310B2 (en) * 2010-08-24 2018-11-27 Equistar Chemicals, Lp Preparation of LLDPE resins and films having low gels
US20120053305A1 (en) * 2010-08-24 2012-03-01 Equistar Chemicals, Lp Preparation of LLDPE having controlled xylene solubles or hexane extractables
KR101835309B1 (ko) * 2010-08-24 2018-03-08 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분
WO2012041813A1 (en) * 2010-09-28 2012-04-05 Basell Polyolefine Gmbh Polyethylene extruded articles
WO2012041944A1 (en) * 2010-09-30 2012-04-05 Basell Poliolefine Italia S.R.L. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
CN102585056A (zh) * 2011-01-05 2012-07-18 中国石油化工股份有限公司 一种用于乙烯聚合或共聚合反应的催化剂
EP2610273B1 (en) * 2011-12-30 2018-02-07 Borealis AG Catalyst component
EP2692743A1 (en) * 2012-08-03 2014-02-05 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
EP2712875A1 (en) 2012-09-28 2014-04-02 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
CN103788246B (zh) * 2012-10-29 2015-10-21 中国石油化工股份有限公司 一种烯烃聚合催化剂载体及其制备方法和应用
US9663596B2 (en) * 2013-01-31 2017-05-30 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins
CN105008407B (zh) * 2013-02-27 2018-03-06 东邦钛株式会社 用于生产丙烯嵌段共聚物的方法
CN104231140B (zh) * 2013-06-21 2016-12-07 中国石油天然气集团公司 一种乙烯-α-烯烃共聚催化剂及其制备和应用
WO2015012963A1 (en) * 2013-07-25 2015-01-29 Exxonmobil Chemical Patents Inc. Methods for polyolefin polymerization with high activity catalyst systems
BR112016020160B1 (pt) 2014-03-14 2021-12-14 Basell Poliolefine Italia S.R.L. Componentes catalisadores para polimerização de olefinas, seu processo de preparação, catalisador para (co)polimerização de olefinas, processo de (co)polimerização de olefinas e aduto de base de lewis
FR3023183A1 (fr) * 2014-07-04 2016-01-08 IFP Energies Nouvelles Composition catalytique et procede de dimerisation selective de l'ethylene en butene-1
WO2016097193A1 (en) 2014-12-18 2016-06-23 Borealis Ag Ziegler-natta catalyst and preparation thereof
EP3253807B1 (en) 2015-02-05 2023-04-26 Borealis AG Process for producing polyethylene
KR102046267B1 (ko) * 2015-09-11 2019-11-18 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분의 제조 방법
EP3484932A1 (en) 2016-07-15 2019-05-22 Basell Poliolefine Italia S.r.l. Catalyst for the polymerization of olefins
KR102187011B1 (ko) * 2016-12-19 2020-12-07 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀의 중합용 촉매 성분 및 이로부터 얻어지는 촉매
EP3339333B1 (en) 2016-12-22 2020-10-07 Borealis AG Ziegler-natta catalyst and preparation thereof
KR102336976B1 (ko) 2017-07-19 2021-12-07 차이나 페트로리움 앤드 케미컬 코포레이션 시클로트리베라트릴렌 및 이의 유도체를 포함하는 올레핀 중합 촉매
ES2970016T3 (es) * 2017-12-05 2024-05-23 Univation Tech Llc Sistema catalizador de ziegler-natta activado secado mediante pulverización
US11325928B2 (en) 2017-12-05 2022-05-10 Univation Technologies, Llc Modified spray-dried Ziegler-Natta (pro)catalyst systems
WO2019129797A1 (en) 2017-12-27 2019-07-04 Borealis Ag Ziegler-natta catalyst and preparation thereof
US11753486B2 (en) 2017-12-28 2023-09-12 Borealis Ag Catalyst and preparation thereof
BR112020023633A2 (pt) * 2018-06-01 2021-02-17 Dow Global Technologies Llc procatalisador heterogêneo, processos para polimerizar polímeros à base de etileno e para produzir um procatalisador, e, polímero à base de etileno.
CN114599687A (zh) 2019-10-04 2022-06-07 北欧化工公司 用于烯烃聚合的齐格勒-纳塔催化剂
CN114466872B (zh) 2019-10-04 2024-01-30 北欧化工公司 用于烯烃聚合的齐格勒纳塔催化剂
US20220380496A1 (en) 2019-10-04 2022-12-01 Borealis Ag Ziegler-natta catalysts for olefin polymerization
CN114599690B (zh) 2019-10-04 2023-09-26 北欧化工公司 用于烯烃聚合的齐格勒-纳塔催化剂
CN112812205B (zh) * 2019-11-18 2023-05-09 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂组分及其催化剂和其制法及应用
MX2022013473A (es) 2020-04-30 2022-11-30 Dow Global Technologies Llc Sistemas (pro)catalizadores ziegler-natta elaborados con compuesto (multi-alcoxi)silano.

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL162661B (nl) * 1968-11-21 1980-01-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1.
YU35844B (en) * 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
NL160286C (pt) * 1971-06-25
IT1037112B (it) * 1975-03-28 1979-11-10 Montedison Spa Catalizzatori per la polimerizzazione delle olfine
GB1603724A (en) * 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
US4302565A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
IT1096661B (it) * 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
US4379759A (en) * 1979-02-16 1983-04-12 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
FI80055C (fi) * 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
JP2637076B2 (ja) * 1986-07-21 1997-08-06 三井石油化学工業 株式会社 プロピレンブロツク共重合体の製法
FR2640273B1 (fr) * 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
FI89176C (fi) * 1989-03-20 1993-08-25 Neste Oy Foerfarande foer framstaellning av en polymerisationskatalysatorkomponent, en medelst foerfarandet framstaelld polymerisationskatalysatorkomponent och dess anvaendning
FI85151C (fi) * 1989-09-06 1992-03-10 Neste Oy Ny baerarkatalysator foer polymerisation av eten.
JP2879347B2 (ja) * 1989-10-02 1999-04-05 チッソ株式会社 オレフィン重合用触媒の製法
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1250731B (it) 1991-07-31 1995-04-21 Himont Inc Procedimento per la preparazione di polietilene lineare a bassa densita'
IT1254279B (it) * 1992-03-13 1995-09-14 Montecatini Tecnologie Srl Procedimento per la polimerizzazione in fase gas delle olefine
US5290745A (en) * 1992-08-10 1994-03-01 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content
JPH07206916A (ja) * 1993-12-17 1995-08-08 Union Carbide Chem & Plast Technol Corp ヘキサン抽出性物質の含有率が低減されたエチレンポリマーを製造する方法
JPH10158319A (ja) * 1996-11-29 1998-06-16 Tokuyama Corp ポリプロピレンの製造方法
EP0914351B1 (en) 1997-03-29 2004-02-18 Basell Poliolefine Italia S.p.A. Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom
JP3895050B2 (ja) * 1997-08-11 2007-03-22 三井化学株式会社 固体状チタン触媒成分の調製方法
JP2002538244A (ja) * 1999-03-03 2002-11-12 イーストマン ケミカル カンパニー ポリエチレンの製造方法
CN1194993C (zh) 2002-06-06 2005-03-30 中国石油化工股份有限公司 用于乙烯聚合的固体催化剂组分及其催化剂
US7275148B2 (en) * 2003-09-08 2007-09-25 Freescale Semiconductor, Inc. Data processing system using multiple addressing modes for SIMD operations and method thereof

Also Published As

Publication number Publication date
KR101102793B1 (ko) 2012-01-05
ZA200504127B (en) 2006-02-22
US7427653B2 (en) 2008-09-23
SA03240450B1 (ar) 2009-01-19
TW200417554A (en) 2004-09-16
CN100554287C (zh) 2009-10-28
EP1572756A1 (en) 2005-09-14
ZA200504131B (en) 2006-02-22
BR0316913B1 (pt) 2014-09-09
CA2510679C (en) 2013-04-23
CA2510679A1 (en) 2004-07-01
AU2003292199A1 (en) 2004-07-09
MXPA05006584A (es) 2005-08-16
ES2368425T3 (es) 2011-11-17
CN1726230A (zh) 2006-01-25
JP2006510751A (ja) 2006-03-30
RU2005122489A (ru) 2006-01-20
WO2004055065A1 (en) 2004-07-01
RU2322457C2 (ru) 2008-04-20
JP2010280894A (ja) 2010-12-16
AR042496A1 (es) 2005-06-22
ES2420879T3 (es) 2013-08-27
US20060089251A1 (en) 2006-04-27
JP5366898B2 (ja) 2013-12-11
KR20050084415A (ko) 2005-08-26
CN1726080A (zh) 2006-01-25
EP1572756B1 (en) 2013-04-10

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Legal Events

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B25D Requested change of name of applicant approved

Owner name: BASELL POLIOLEFINE ITALIA S.R.L. (IT)

Free format text: ALTERADA DE: BASELL POLIOLEFINE ITALIA S.P.A.

B25A Requested transfer of rights approved

Owner name: BASELL POLYOLEFINE GMBH (DE)

Free format text: TRANSFERIDO DE: BASELL POLIOLEFINE ITALIA S.R.L.

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 09/09/2014, OBSERVADAS AS CONDICOES LEGAIS.