CN100554287C - 烯烃聚合用催化剂组分 - Google Patents

烯烃聚合用催化剂组分 Download PDF

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Publication number
CN100554287C
CN100554287C CNB2003801061943A CN200380106194A CN100554287C CN 100554287 C CN100554287 C CN 100554287C CN B2003801061943 A CNB2003801061943 A CN B2003801061943A CN 200380106194 A CN200380106194 A CN 200380106194A CN 100554287 C CN100554287 C CN 100554287C
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China
Prior art keywords
catalyst component
solid catalyst
compound
electron donor
catalyst
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Expired - Lifetime
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CNB2003801061943A
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English (en)
Chinese (zh)
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CN1726230A (zh
Inventor
D·布里塔
G·科利纳
G·莫里尼
G·瓦伊塔尔
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Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB2003801061943A 2002-12-18 2003-11-25 烯烃聚合用催化剂组分 Expired - Lifetime CN100554287C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP02080616 2002-12-18
EP02080616.2 2002-12-18
US60/435,195 2002-12-20

Publications (2)

Publication Number Publication Date
CN1726230A CN1726230A (zh) 2006-01-25
CN100554287C true CN100554287C (zh) 2009-10-28

Family

ID=35925132

Family Applications (2)

Application Number Title Priority Date Filing Date
CNB2003801061943A Expired - Lifetime CN100554287C (zh) 2002-12-18 2003-11-25 烯烃聚合用催化剂组分
CNA200380106191XA Pending CN1726080A (zh) 2002-12-18 2003-11-25 氯化镁基加合物及由其制备的催化剂组分

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNA200380106191XA Pending CN1726080A (zh) 2002-12-18 2003-11-25 氯化镁基加合物及由其制备的催化剂组分

Country Status (16)

Country Link
US (1) US7427653B2 (OSRAM)
EP (1) EP1572756B1 (OSRAM)
JP (2) JP2006510751A (OSRAM)
KR (1) KR101102793B1 (OSRAM)
CN (2) CN100554287C (OSRAM)
AR (1) AR042496A1 (OSRAM)
AU (1) AU2003292199A1 (OSRAM)
BR (1) BR0316913B1 (OSRAM)
CA (1) CA2510679C (OSRAM)
ES (2) ES2368425T3 (OSRAM)
MX (1) MXPA05006584A (OSRAM)
RU (1) RU2322457C2 (OSRAM)
SA (1) SA03240450B1 (OSRAM)
TW (1) TW200417554A (OSRAM)
WO (1) WO2004055065A1 (OSRAM)
ZA (2) ZA200504131B (OSRAM)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2380380C2 (ru) * 2003-05-29 2010-01-27 Базелль Полиолефин Италия С.Р.Л. Способ получения компонента катализатора и получаемые из него компоненты
EP1780225A1 (en) 2005-11-01 2007-05-02 Borealis Technology Oy Ziegler-Natta catalyst and its use to prepare multimodal polyolefin
CN101165074B (zh) * 2006-10-20 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
EP2036928B1 (en) * 2006-04-06 2015-12-23 China Petroleum & Chemical Corporation Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom
CN101486776B (zh) * 2008-01-17 2010-12-22 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其催化剂
BRPI0919385B1 (pt) * 2008-09-26 2019-06-04 Basell Poliolefine Italia S.R.L. Componentecatalisador pré-polimerizado, sistema catalisador e processo em fase gasosa para a polimerização de olefinas
US8268945B2 (en) 2009-08-21 2012-09-18 China Petroleum & Chemical Corporation Catalyst component for ethylene polymerization, preparation thereof, and a catalyst comprising the catalyst component
SA3686B1 (ar) * 2009-10-16 2014-10-22 China Petroleum& Chemical Corp مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه
US20110319571A1 (en) * 2010-06-29 2011-12-29 Botros Maged G Polyolefin adhesive composition
KR101835309B1 (ko) 2010-08-24 2018-03-08 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분
US20120053305A1 (en) * 2010-08-24 2012-03-01 Equistar Chemicals, Lp Preparation of LLDPE having controlled xylene solubles or hexane extractables
US10138310B2 (en) * 2010-08-24 2018-11-27 Equistar Chemicals, Lp Preparation of LLDPE resins and films having low gels
WO2012041813A1 (en) * 2010-09-28 2012-04-05 Basell Polyolefine Gmbh Polyethylene extruded articles
WO2012041944A1 (en) * 2010-09-30 2012-04-05 Basell Poliolefine Italia S.R.L. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
CN102585056A (zh) * 2011-01-05 2012-07-18 中国石油化工股份有限公司 一种用于乙烯聚合或共聚合反应的催化剂
EP2610273B1 (en) * 2011-12-30 2018-02-07 Borealis AG Catalyst component
EP2692743A1 (en) 2012-08-03 2014-02-05 Basell Poliolefine Italia S.r.l. Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom
EP2712875A1 (en) 2012-09-28 2014-04-02 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
CN103788246B (zh) * 2012-10-29 2015-10-21 中国石油化工股份有限公司 一种烯烃聚合催化剂载体及其制备方法和应用
EA025272B1 (ru) * 2013-01-31 2016-12-30 Сауди Бейсик Индастриз Корпорейшн Способ получения компонента катализатора полимеризации олефинов
SG11201506721TA (en) 2013-02-27 2015-09-29 Toho Titanium Co Ltd Method for producing propylene block copolymer
CN104231140B (zh) * 2013-06-21 2016-12-07 中国石油天然气集团公司 一种乙烯-α-烯烃共聚催化剂及其制备和应用
US9605096B2 (en) * 2013-07-25 2017-03-28 Exxonmobil Chemical Patents Inc. Methods for polyolefin polymerization with high activity catalyst systems
JP6470302B2 (ja) 2014-03-14 2019-02-13 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用触媒成分
FR3023183A1 (fr) * 2014-07-04 2016-01-08 IFP Energies Nouvelles Composition catalytique et procede de dimerisation selective de l'ethylene en butene-1
CA2970848C (en) 2014-12-18 2023-04-11 Borealis Ag Ziegler-natta catalyst and preparation thereof
CA2975026C (en) 2015-02-05 2023-10-31 Borealis Ag Process for producing polyethylene
CN107949587B (zh) * 2015-09-11 2020-04-28 巴塞尔聚烯烃意大利有限公司 用于制备烯烃聚合用催化剂组分的工艺
BR112019000090A2 (pt) 2016-07-15 2019-04-09 Basell Poliolefine Italia Srl catalisador para a polimerização de olefinas
FI3555150T3 (fi) 2016-12-19 2023-11-22 Basell Poliolefine Italia Srl Katalyyttikomponentteja olefiinien polymerisoimiseksi ja niistä saatuja katalyyttejä
EP3339333B1 (en) 2016-12-22 2020-10-07 Borealis AG Ziegler-natta catalyst and preparation thereof
BR112020001201B1 (pt) 2017-07-19 2023-03-21 Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation Sistema catalisador ziegler-natta para polimerização olefínica, componente catalisador sólido para polimerização olefínica e processo de polimerização olefínica
EP3720888A1 (en) 2017-12-05 2020-10-14 Univation Technologies, LLC Modified spray-dried ziegler-natta (pro)catalyst systems
ES2970016T3 (es) * 2017-12-05 2024-05-23 Univation Tech Llc Sistema catalizador de ziegler-natta activado secado mediante pulverización
JP7249349B2 (ja) 2017-12-27 2023-03-30 ボレアリス エージー チーグラー・ナッタ触媒及びその調製
EP3732209A1 (en) 2017-12-28 2020-11-04 Borealis AG Catalyst and preparation thereof
EP3802641B1 (en) * 2018-06-01 2025-09-24 Dow Global Technologies LLC Ziegler-natta catalyst system having a thermally treated magnesium chloride component
EP4038110A1 (en) 2019-10-04 2022-08-10 Borealis AG Ziegler-natta catalysts for olefin polymerization
WO2021064083A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
US12391778B2 (en) 2019-10-04 2025-08-19 Borealis Ag Ziegler-natta catalysts for olefin polymerization
WO2021064081A1 (en) 2019-10-04 2021-04-08 Borealis Ag Ziegler-natta catalysts for olefin polymerization
CN112812205B (zh) * 2019-11-18 2023-05-09 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂组分及其催化剂和其制法及应用
US20230151124A1 (en) 2020-04-30 2023-05-18 Dow Global Technologies Llc Ziegler-natta (pro)catalyst systems made with (multi-alkoxy)silane compound
JP2023546624A (ja) * 2020-10-26 2023-11-06 中国石油化工股▲ふん▼有限公司 オレフィン重合触媒を製造するための固体成分、その製造方法およびその利用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4379759A (en) * 1979-02-16 1983-04-12 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4829034A (en) * 1986-06-09 1989-05-09 Neste Oy Procedure for manufacturing catalyst components for polymerizing olefines
CN1034371A (zh) * 1986-07-21 1989-08-02 三井石油化学工株式会社 丙烯共聚物的制备方法
US5324698A (en) * 1989-09-06 1994-06-28 Neste Oy New carrier catalyst for the polymerization of ethylene
EP0661301A1 (en) * 1993-12-17 1995-07-05 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK133012C (da) 1968-11-21 1976-08-09 Montedison Spa Katalysator til polymerisation af alkener
YU35844B (en) 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
NL160286C (OSRAM) 1971-06-25
IT1037112B (it) 1975-03-28 1979-11-10 Montedison Spa Catalizzatori per la polimerizzazione delle olfine
GB1603724A (en) 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
US4302565A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
IT1096661B (it) 1978-06-13 1985-08-26 Montedison Spa Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
JPS5883006A (ja) * 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd オレフインの重合方法
FR2640273B1 (fr) * 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
FI89176C (fi) 1989-03-20 1993-08-25 Neste Oy Foerfarande foer framstaellning av en polymerisationskatalysatorkomponent, en medelst foerfarandet framstaelld polymerisationskatalysatorkomponent och dess anvaendning
JP2879347B2 (ja) 1989-10-02 1999-04-05 チッソ株式会社 オレフィン重合用触媒の製法
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1250731B (it) 1991-07-31 1995-04-21 Himont Inc Procedimento per la preparazione di polietilene lineare a bassa densita'
IT1254279B (it) 1992-03-13 1995-09-14 Montecatini Tecnologie Srl Procedimento per la polimerizzazione in fase gas delle olefine
US5290745A (en) * 1992-08-10 1994-03-01 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content
RU2144041C1 (ru) * 1992-08-31 2000-01-10 Мицуи Кемикалз Инк. Твердый титановый компонент катализатора для полимеризации олефинов, способ его получения, катализатор для полимеризации олефинов и способ полимеризации олефинов
JP3280477B2 (ja) * 1992-08-31 2002-05-13 三井化学株式会社 オレフィン重合用固体状チタン触媒成分の調製方法
JPH10158319A (ja) * 1996-11-29 1998-06-16 Tokuyama Corp ポリプロピレンの製造方法
ES2213898T3 (es) 1997-03-29 2004-09-01 Basell Poliolefine Italia S.P.A. Aductos de dicloruro de magnesio/alcohol, procedimiento para su preparacion y componentes catalizadores obtenidos a partir de estos.
JP3895050B2 (ja) * 1997-08-11 2007-03-22 三井化学株式会社 固体状チタン触媒成分の調製方法
WO2000052068A1 (en) * 1999-03-03 2000-09-08 Eastman Chemical Company Process for producing polyethylene
CN1194993C (zh) 2002-06-06 2005-03-30 中国石油化工股份有限公司 用于乙烯聚合的固体催化剂组分及其催化剂
US7275148B2 (en) * 2003-09-08 2007-09-25 Freescale Semiconductor, Inc. Data processing system using multiple addressing modes for SIMD operations and method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4379759A (en) * 1979-02-16 1983-04-12 Union Carbide Corporation Impregnated polymerization catalyst, process for preparing, and use for ethylene copolymerization
US4829034A (en) * 1986-06-09 1989-05-09 Neste Oy Procedure for manufacturing catalyst components for polymerizing olefines
CN1034371A (zh) * 1986-07-21 1989-08-02 三井石油化学工株式会社 丙烯共聚物的制备方法
US5324698A (en) * 1989-09-06 1994-06-28 Neste Oy New carrier catalyst for the polymerization of ethylene
EP0661301A1 (en) * 1993-12-17 1995-07-05 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content

Also Published As

Publication number Publication date
CN1726230A (zh) 2006-01-25
MXPA05006584A (es) 2005-08-16
SA03240450B1 (ar) 2009-01-19
EP1572756A1 (en) 2005-09-14
AU2003292199A1 (en) 2004-07-09
KR20050084415A (ko) 2005-08-26
BR0316913A (pt) 2005-10-18
EP1572756B1 (en) 2013-04-10
RU2322457C2 (ru) 2008-04-20
CA2510679C (en) 2013-04-23
BR0316913B1 (pt) 2014-09-09
RU2005122489A (ru) 2006-01-20
ZA200504127B (en) 2006-02-22
CN1726080A (zh) 2006-01-25
US20060089251A1 (en) 2006-04-27
US7427653B2 (en) 2008-09-23
WO2004055065A1 (en) 2004-07-01
TW200417554A (en) 2004-09-16
ES2368425T3 (es) 2011-11-17
JP2006510751A (ja) 2006-03-30
KR101102793B1 (ko) 2012-01-05
ES2420879T3 (es) 2013-08-27
AR042496A1 (es) 2005-06-22
JP2010280894A (ja) 2010-12-16
ZA200504131B (en) 2006-02-22
JP5366898B2 (ja) 2013-12-11
CA2510679A1 (en) 2004-07-01

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Granted publication date: 20091028