ES2189860T3 - Oligomeros de bloque conteniendo grupos de 2,2,6,6-tetrametil-4-piperidilo como estabilizadores para materiales organicos. - Google Patents
Oligomeros de bloque conteniendo grupos de 2,2,6,6-tetrametil-4-piperidilo como estabilizadores para materiales organicos.Info
- Publication number
- ES2189860T3 ES2189860T3 ES96810823T ES96810823T ES2189860T3 ES 2189860 T3 ES2189860 T3 ES 2189860T3 ES 96810823 T ES96810823 T ES 96810823T ES 96810823 T ES96810823 T ES 96810823T ES 2189860 T3 ES2189860 T3 ES 2189860T3
- Authority
- ES
- Spain
- Prior art keywords
- sub
- organic materials
- radicals
- piperidilo
- tetrametil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011368 organic material Substances 0.000 title abstract 2
- 239000003381 stabilizer Substances 0.000 title 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000000306 recurrent effect Effects 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
- 229920001059 synthetic polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Dental Preparations (AREA)
Abstract
COMPUESTOS DE FORMULA (I) EN LA QUE LA POLIDISPERSIVIDAD M{SUB,W}/M{SUB,N} ES 1; N ES 3,4,5,6,7,8,9,10,11,12,13,14 O 15; LOS RADICALES R{SUB,1} SON, P.EJ., HIDROGENO, O ALQUILO C{SUB,1}-C{SUB,8}; R{SUB,2} ES, P.EJ., ALQUILENO C{SUB,2}-C{SUB,12}; LOS RADICALES A SON, INDEPENDIENTEMENTE ENTRE SI, -OR{SUB,3}, -N(R{SUB,4})(R{SUB,5}), O UN GRUPO DE FORMULA R{SUB,3}, R{SUB,4} Y R{SUB,5}, QUE SON IDENTICOS O DIFERENTES, SON P.EJ. HIDROGENO O ALQUILO C{SUB,1}-C{SUB,18}, O -N(R{SUB,4})(R{SUB,5}) ES ADICIONALMENTE UN GRUPO DE FORMULA DONDE Y ES -O-, -CH{SUB,2}, -CH{SUB,2}CH{SUB,2}, O >N-CH{SUB,3}; X ES -O- O >N-R{SUB,6}; R{SUB,6} ES P.EJ. HIDROGENO O ALQUILO C{SUB,1}-C{SUB,18}; R ES, PREFERIBLEMENTE, UN GRUPO DE FORMULA Y LOS RADICALES B TIENEN, INDEPENDIENTEMENTE ENTRE SI, LAS DEFINICIONES DADAS PARA A; CON LA CONDICION DE QUE, EN LAS UNIDADES INDIVIDUALES RECURRENTES DE FORMULA (I), CADA UNO DE LOS RADICALES B, R, R{SUB,1} Y R{SUB,2} TIENE EL MISMO O DISTINTO SIGNIFICADO. LOS COMPUESTOS DESCRITOS SON UTILES COMO FOTOESTABILIZANTES, TERMOESTABILIZANTES Y ESTABILIZANTES CONTRA LA OXIDACION, PARA MATERIALES ORGANICOS, ESPECIALMENTE POLIMEROS SINTETICOS.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95810756 | 1995-12-04 | ||
EP96810053 | 1996-01-29 | ||
EP96810458 | 1996-07-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2189860T3 true ES2189860T3 (es) | 2003-07-16 |
Family
ID=27236983
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96810823T Expired - Lifetime ES2189860T3 (es) | 1995-12-04 | 1996-11-26 | Oligomeros de bloque conteniendo grupos de 2,2,6,6-tetrametil-4-piperidilo como estabilizadores para materiales organicos. |
Country Status (17)
Country | Link |
---|---|
US (2) | US6046304A (es) |
JP (1) | JP3635317B2 (es) |
KR (1) | KR100449430B1 (es) |
CN (1) | CN1120165C (es) |
AT (1) | ATE232206T1 (es) |
AU (1) | AU718067B2 (es) |
BR (1) | BR9605826A (es) |
CA (1) | CA2191832C (es) |
CZ (1) | CZ294258B6 (es) |
DE (1) | DE69626095T2 (es) |
ES (1) | ES2189860T3 (es) |
MX (1) | MX9606006A (es) |
MY (1) | MY128982A (es) |
NO (1) | NO310421B1 (es) |
PT (1) | PT782994E (es) |
RU (1) | RU2175660C2 (es) |
SK (1) | SK283984B6 (es) |
Families Citing this family (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU7072698A (en) | 1997-05-27 | 1998-12-30 | Ciba Specialty Chemicals Holding Inc. | Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials |
TW428008B (en) * | 1997-05-27 | 2001-04-01 | Ciba Sc Holding Ag | Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethy1-4-piperidyl groups as stabilizers for organic materials |
TW491872B (en) * | 1997-05-27 | 2002-06-21 | Ciba Sc Holding Ag | Block oligomers containing l-hydrocarbyloxy-2,2,6,6-tetramethyl-4- piperidyl groups as stabilizers for lower polyolefin |
SG74700A1 (en) * | 1998-02-25 | 2000-08-22 | Ciba Sc Holding Ag | Preparation of sterically hindered amine ethers |
WO2001092393A2 (en) * | 2000-05-31 | 2001-12-06 | Ciba Specialty Chemicals Holding Inc. | Stabilizer mixtures |
US6747077B2 (en) | 2000-10-17 | 2004-06-08 | Ciba Specialty Chemicals Corporation | Stabilized metallocene polypropylene |
US20030225191A1 (en) | 2002-04-12 | 2003-12-04 | Francois Gugumus | Stabilizer mixtures |
DE60319695T2 (de) * | 2002-05-30 | 2009-03-26 | Ciba Holding Inc. | Stabilisierte gegenstände |
US20030236325A1 (en) * | 2002-05-30 | 2003-12-25 | Michela Bonora | Agricultural articles |
US7595011B2 (en) | 2004-07-12 | 2009-09-29 | Ciba Specialty Chemicals Corporation | Stabilized electrochromic media |
SI1807395T1 (sl) | 2004-11-02 | 2016-04-29 | Basf Se | Proces za sintezo N-alkoksiaminov |
CN101405306B (zh) * | 2006-03-16 | 2011-07-27 | 克莱里安特财务(Bvi)有限公司 | 改性蜡、其制备方法及其用途 |
US20070231502A1 (en) | 2006-03-24 | 2007-10-04 | Jones Kyle R | Method for incorporating additives into polymers |
WO2009120094A2 (en) * | 2008-03-27 | 2009-10-01 | Auckland Uniservices Limited | Substituted pyrimidines and triazines and their use in cancer therapy |
ITMI20080747A1 (it) | 2008-04-24 | 2009-10-25 | 3V Sigma Spa | Miscele di ammine stericamente impedite per la stabilizzazione di polimeri |
ES2434120T3 (es) * | 2008-12-18 | 2013-12-13 | Dow Global Technologies Llc | Estabilizantes para polímeros retardantes de llama que contienen bromo enlazado alifáticamente |
US9068073B2 (en) | 2008-12-22 | 2015-06-30 | Basf Se | Method of improving scratch resistance and related products and uses |
EP2393876B1 (en) * | 2009-02-04 | 2013-08-14 | Basf Se | N-substituted macrocyclic triazine-hals stabilizers |
WO2011005631A2 (en) | 2009-07-07 | 2011-01-13 | Basf Se | Potassium cesium tungsten bronze particles |
KR20120104164A (ko) | 2009-08-18 | 2012-09-20 | 바스프 에스이 | Uv-안정화된 광전 모듈 |
IT1399477B1 (it) | 2010-03-15 | 2013-04-19 | 3V Sigma Spa | Miscele di ammine stericamente impedite per la stabilizzazione di polimeri |
BR112013008734B1 (pt) | 2010-10-20 | 2018-08-28 | Basf Se | composto, composição, artigo modelado, método para estabilizar um polímero termoplástico natural ou sintético contra degradação induzido por luz, calor ou oxidação |
ITMI20110802A1 (it) | 2011-05-10 | 2012-11-11 | 3V Sigma Spa | Miscele di ammine stericamente impedite per la stabilizzazione di polimeri |
JP6246223B2 (ja) | 2012-10-23 | 2017-12-13 | ビーエーエスエフ エスイー | ポリマー安定剤基を含有するエチレン性不飽和オリゴマー |
EP2816097A1 (en) | 2013-06-18 | 2014-12-24 | Shell Internationale Research Maatschappij B.V. | Lubricating oil composition |
JP6136723B2 (ja) * | 2013-08-01 | 2017-05-31 | 東洋インキScホールディングス株式会社 | 顔料組成物及びカラーフィルタ |
US10428204B2 (en) | 2013-09-27 | 2019-10-01 | Basf Se | Polyolefin compositions for building materials |
EP3071544B1 (en) | 2013-11-22 | 2022-07-06 | Polnox Corporation | Macromolecular antioxidants based on dual type moiety per molecule: structures methods of making and using the same |
TWI685524B (zh) | 2013-12-17 | 2020-02-21 | 美商畢克美國股份有限公司 | 預先脫層之層狀材料 |
BR112016026329B1 (pt) | 2014-05-15 | 2021-09-14 | Basf Se | Composição, artigo, e, método para estabilizar um material orgânico |
MX2016000701A (es) | 2015-01-22 | 2016-11-24 | Evonik Degussa Gmbh | Proceso para preparar un compuesto de triacetonamina n-metil sustituida. |
SA116370295B1 (ar) | 2015-02-20 | 2016-12-06 | باسف اس اى | رقائق، وأشرطة وفتائل أحادية من البولي أوليفين مثبتة للضوء |
WO2016156328A1 (en) | 2015-03-31 | 2016-10-06 | Shell Internationale Research Maatschappij B.V. | Use of a lubricating composition comprising a hindered amine light stabilizer for improved piston cleanliness in an internal combustion engine |
CN104725361B (zh) * | 2015-04-09 | 2017-05-31 | 江苏富比亚化学品有限公司 | 一种受阻胺类光稳定剂3346的制备方法 |
CN104818486B (zh) * | 2015-05-08 | 2017-06-27 | 山东应天节能环保科技有限公司 | 一种黄铜专用缓蚀剂及其制备方法 |
CN107735451B (zh) * | 2015-07-09 | 2022-12-27 | 日本瑞翁株式会社 | 树脂组合物、树脂成型体及光学构件 |
US20190010308A1 (en) | 2015-07-20 | 2019-01-10 | Basf Se | Flame Retardant Polyolefin Articles |
JP6843831B2 (ja) * | 2015-07-27 | 2021-03-17 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 添加剤混合物 |
CN106117184A (zh) * | 2016-06-30 | 2016-11-16 | 南通市振兴精细化工有限公司 | 一种混合型光稳定剂的制备方法 |
ES2757778T3 (es) | 2016-08-26 | 2020-04-30 | Total Res & Technology Feluy | Capuchones o cierres fabricados con una composición de resina que comprende polietileno |
KR102570881B1 (ko) | 2017-03-28 | 2023-08-29 | 바스프 에스이 | 광 안정화제 혼합물 |
IT201700073726A1 (it) | 2017-06-30 | 2018-12-30 | 3V Sigma Spa | Ammine impedite polimeriche |
US10941285B2 (en) | 2017-07-06 | 2021-03-09 | Basf Se | Stabilized polyolefin compositions comprising benzofuranones and acid scavengers |
IT201700078234A1 (it) | 2017-07-11 | 2019-01-11 | 3V Sigma Spa | Ammine impedite |
CN108623566A (zh) * | 2018-04-28 | 2018-10-09 | 宿迁联盛科技有限公司 | 一种受阻胺光稳定剂944的合成工艺 |
CA3107042A1 (en) | 2018-08-22 | 2020-02-27 | Basf Se | Stabilized rotomolded polyolefin |
CN109942549A (zh) * | 2018-10-29 | 2019-06-28 | 北京天罡助剂有限责任公司 | 一种低碱性聚合型受阻胺光稳定剂及其制备方法 |
CN109251313A (zh) * | 2018-10-29 | 2019-01-22 | 北京天罡助剂有限责任公司 | 一种受阻胺光稳定剂及其制备方法 |
JP2022513710A (ja) | 2018-12-04 | 2022-02-09 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリエチレン又はポリプロピレン物品 |
SG11202106588VA (en) | 2018-12-21 | 2021-07-29 | Basf Se | A polypropylene composition |
US20230220239A1 (en) | 2019-03-18 | 2023-07-13 | Basf Se | Uv curable compositions for dirt pick-up resistance |
US20220282064A1 (en) | 2019-07-30 | 2022-09-08 | Basf Se | Stabilizer composition |
IL295065A (en) | 2020-02-10 | 2022-09-01 | Basf Se | Light stabilizer mixture |
EP4323445A1 (en) | 2021-04-13 | 2024-02-21 | TotalEnergies OneTech Belgium | Process to produce an additived composition of polyethylene comprising post-consumer resin and caps or closures made from this composition |
Family Cites Families (27)
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IT1052501B (it) * | 1975-12-04 | 1981-07-20 | Chimosa Chimica Organica Spa | Composti politriazinici utilizzabili per la stabilizzazione di polimeri sintetici e procedimento per la loro preparazione |
IT1060458B (it) * | 1975-12-18 | 1982-08-20 | Chimosa Chimica Organica Spa | Composti piperidil triazinici adatti per la stabilizzazione di polimeri sintetici e procedimento per la loro preparazione |
US4234707A (en) * | 1977-11-10 | 1980-11-18 | Ciba-Geigy Corporation | Polymeric light stabilizers for plastics |
DE2933078A1 (de) * | 1979-08-16 | 1981-03-26 | Hoechst Ag, 65929 Frankfurt | Neue triazinderivate, ihre herstellung und ihre verwendung als stabilisatoren fuer synthetische polymere |
US4316837A (en) * | 1980-09-10 | 1982-02-23 | Carstab Corporation | Polyalkylated 4-aminopiperidine derivatives as stabilizers for synthetic polymers |
US4331586A (en) * | 1981-07-20 | 1982-05-25 | American Cyanamid Company | Novel light stabilizers for polymers |
IT1195277B (it) * | 1981-10-02 | 1988-10-12 | Chimosa Chimica Organica Spa | Piperidil derivati di composti triazinici macrociclici,aventi attivita' stabilizzante per i polimeri e processi per la loro preparazione |
US4492791A (en) * | 1982-05-04 | 1985-01-08 | Ciba-Geigy Corporation | Process for the preparation of polyaminotriazines |
IT1193659B (it) * | 1983-02-04 | 1988-07-21 | Chimosa Chimica Organica Spa | Composti piperidinil-triazinici utili come stabilizzanti per polimeri sintetici |
JPS6250342A (ja) * | 1985-08-30 | 1987-03-05 | Adeka Argus Chem Co Ltd | 安定化された高分子材料組成物 |
US4789706A (en) * | 1986-04-21 | 1988-12-06 | Nl Chemicals, Inc. | Narrow molecular weight polyester oligomers and method of preparation |
US4746692A (en) | 1986-05-05 | 1988-05-24 | Shell Oil Company | Polyolefin compositions for use with water systems |
CS270846B1 (en) * | 1988-08-29 | 1990-08-14 | Vass Frantisek | New polyaminotriazines and method of their preparation |
US5004770A (en) * | 1988-10-19 | 1991-04-02 | Ciba-Geigy Corporation | Polymeric substrates stabilized with N-substituted hindered amines |
US4889882A (en) * | 1988-12-15 | 1989-12-26 | Ici Americas Inc. | Tetramethyl piperidyl terminated triazine oligomeric esters and amides |
CS273098B1 (en) * | 1989-01-02 | 1991-03-12 | Manasek Zdenek | Substituted polyaminotriazines and method of their preparation |
IT1230091B (it) * | 1989-04-27 | 1991-10-05 | Ciba Geigy Spa | Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici. |
IT1237129B (it) * | 1989-11-10 | 1993-05-18 | Valerio Borzatta | Composti piperidin-triazinici atti all'impiego come stabilizzanti per materiali organici. |
EP0446171A3 (en) * | 1990-03-08 | 1992-05-20 | Ciba-Geigy Ag | Stabilised chlorinated polymer compositions |
US5324834A (en) * | 1990-06-13 | 1994-06-28 | Ciba-Geigy Corporation | Piperidine-triazine co-oligomers for use as stabilizers for organic materials |
US5208385A (en) * | 1992-02-19 | 1993-05-04 | Arco Chemical Technology, L.P. | Preparation of tetrahydrofuran polymers having a narrow molecular weight distribution using an amorphous silica-alumina catalyst |
TW251307B (es) * | 1992-10-05 | 1995-07-11 | Ciba Geigy | |
IT1270975B (it) * | 1993-06-03 | 1997-05-26 | Ciba Geigy Spa | Composti piperidin-triazinici atti all'impiego come stabilizzanti allaluce, al calore e alla ossidazione per materiali organici |
TW302377B (es) * | 1993-12-24 | 1997-04-11 | Sumitomo Chemical Co | |
DE4403085A1 (de) * | 1994-02-02 | 1995-08-03 | Basf Ag | Verfahren zur Herstellung von N,N'-verbrückten Bis-tetramethylpiperidinyl-Verbindungen |
US5603885A (en) * | 1995-07-06 | 1997-02-18 | E. I. Du Pont De Nemours And Company | Process for the preparation of nonwoven fibrous sheets |
JPH0940773A (ja) | 1995-07-31 | 1997-02-10 | Sumitomo Chem Co Ltd | ポリアミノトリアジン組成物 |
-
1996
- 1996-11-25 US US08/756,225 patent/US6046304A/en not_active Expired - Lifetime
- 1996-11-26 ES ES96810823T patent/ES2189860T3/es not_active Expired - Lifetime
- 1996-11-26 DE DE69626095T patent/DE69626095T2/de not_active Expired - Lifetime
- 1996-11-26 AT AT96810823T patent/ATE232206T1/de active
- 1996-11-26 PT PT96810823T patent/PT782994E/pt unknown
- 1996-11-27 AU AU74142/96A patent/AU718067B2/en not_active Expired
- 1996-11-28 MY MYPI96004986A patent/MY128982A/en unknown
- 1996-11-28 RU RU96122845/04A patent/RU2175660C2/ru active
- 1996-12-02 CA CA002191832A patent/CA2191832C/en not_active Expired - Lifetime
- 1996-12-02 CZ CZ19963523A patent/CZ294258B6/cs not_active IP Right Cessation
- 1996-12-02 MX MX9606006A patent/MX9606006A/es unknown
- 1996-12-02 SK SK1543-96A patent/SK283984B6/sk not_active IP Right Cessation
- 1996-12-03 BR BR9605826A patent/BR9605826A/pt not_active IP Right Cessation
- 1996-12-03 CN CN96121514A patent/CN1120165C/zh not_active Expired - Lifetime
- 1996-12-03 NO NO19965150A patent/NO310421B1/no not_active IP Right Cessation
- 1996-12-04 JP JP33898096A patent/JP3635317B2/ja not_active Expired - Lifetime
- 1996-12-04 KR KR1019960062958A patent/KR100449430B1/ko not_active IP Right Cessation
-
1999
- 1999-11-04 US US09/433,468 patent/US6297299B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CZ352396A3 (en) | 1997-06-11 |
MY128982A (en) | 2007-03-30 |
SK154396A3 (en) | 1997-10-08 |
DE69626095D1 (de) | 2003-03-13 |
MX9606006A (es) | 1997-08-30 |
NO310421B1 (no) | 2001-07-02 |
CZ294258B6 (cs) | 2004-11-10 |
BR9605826A (pt) | 1998-09-01 |
AU718067B2 (en) | 2000-04-06 |
SK283984B6 (sk) | 2004-06-08 |
RU2175660C2 (ru) | 2001-11-10 |
JPH09216946A (ja) | 1997-08-19 |
CA2191832C (en) | 2006-01-24 |
US6046304A (en) | 2000-04-04 |
NO965150L (no) | 1997-06-05 |
US6297299B1 (en) | 2001-10-02 |
CA2191832A1 (en) | 1997-06-05 |
DE69626095T2 (de) | 2003-07-31 |
PT782994E (pt) | 2003-06-30 |
CN1165138A (zh) | 1997-11-19 |
ATE232206T1 (de) | 2003-02-15 |
AU7414296A (en) | 1997-06-12 |
KR100449430B1 (ko) | 2004-11-26 |
NO965150D0 (no) | 1996-12-03 |
CN1120165C (zh) | 2003-09-03 |
JP3635317B2 (ja) | 2005-04-06 |
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