ES2182623A1 - Oligomeros de bloque conteniendo grupos de 1-hidrocarbiloxi-2,2,6,6-tetrametil-4-piperidilo como estabilizadores para materiales organicos. - Google Patents

Oligomeros de bloque conteniendo grupos de 1-hidrocarbiloxi-2,2,6,6-tetrametil-4-piperidilo como estabilizadores para materiales organicos.

Info

Publication number
ES2182623A1
ES2182623A1 ES009950063A ES9950063A ES2182623A1 ES 2182623 A1 ES2182623 A1 ES 2182623A1 ES 009950063 A ES009950063 A ES 009950063A ES 9950063 A ES9950063 A ES 9950063A ES 2182623 A1 ES2182623 A1 ES 2182623A1
Authority
ES
Spain
Prior art keywords
stabilizers
formula
organic materials
hydrocarbyloxy
tetramethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009950063A
Other languages
English (en)
Other versions
ES2182623B1 (es
Inventor
James Peter Galbo
Nicola Lelli
Valerio Borzatta
Jean-Pierre Wolf
Michael Ackerman
Piero Piccinelli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Ciba SC Holding AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2182623A1 publication Critical patent/ES2182623A1/es
Application granted granted Critical
Publication of ES2182623B1 publication Critical patent/ES2182623B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
    • C08G73/0644—Poly(1,3,5)triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Hydrogenated Pyridines (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Paper (AREA)

Abstract

Los productos de la invención responden a la fórmula (I), en donde n es un número de 2 a 14 y los radicales R1, R2, A, B y B tienen el significado expresado en la memoria y las reivindicaciones. La invención se refiere a una mezcla con estrecha distribución de peso molecular conteniendo por lo menos tres oligómeros de bloque simples diferentes, y a un método para su preparación. Los compuestos de la invención se usan como estabilizadores de la luz, estabilizadores del calor y estabilizadores de oxidación para materiales orgánicos, en particular polímeros sintéticos.
ES009950063A 1997-05-27 1998-05-14 Oligomeros de bloque conteniendo grupos de 1-hidrocarbiloxi-2,2,6,6-tetrametil-4-piperidilo como estabilizadores para materiales organicos. Expired - Fee Related ES2182623B1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP97810326 1997-05-27
EP97810326 1997-05-27

Publications (2)

Publication Number Publication Date
ES2182623A1 true ES2182623A1 (es) 2003-03-01
ES2182623B1 ES2182623B1 (es) 2004-06-16

Family

ID=8230241

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009950063A Expired - Fee Related ES2182623B1 (es) 1997-05-27 1998-05-14 Oligomeros de bloque conteniendo grupos de 1-hidrocarbiloxi-2,2,6,6-tetrametil-4-piperidilo como estabilizadores para materiales organicos.

Country Status (14)

Country Link
US (1) US6265473B1 (es)
JP (2) JP4461306B2 (es)
KR (1) KR100525180B1 (es)
CN (1) CN1106396C (es)
AU (1) AU7072298A (es)
BE (1) BE1011940A3 (es)
CA (1) CA2287557C (es)
DE (2) DE19882401T1 (es)
ES (1) ES2182623B1 (es)
FR (1) FR2763946B1 (es)
GB (1) GB2340119B (es)
IT (1) ITMI981134A1 (es)
TW (1) TW491872B (es)
WO (1) WO1998054174A1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI980366A1 (it) 1998-02-25 1999-08-25 Ciba Spec Chem Spa Preparazione di eteri amminici stericamente impediti
DE60006268T2 (de) * 1999-09-15 2004-08-05 Ciba Specialty Chemicals Holding Inc. Polimerischen stabilisatoren mit hoher affinität zur pulpen
CO5231248A1 (es) * 2000-07-26 2002-12-27 Ciba Sc Holding Ag Articulos transparentes de polimero de baja consistencia
US20090069470A1 (en) * 2004-11-02 2009-03-12 Markus Frey Process for the synthesis of n-alkoxyamines
US20060281788A1 (en) 2005-06-10 2006-12-14 Baumann Christian A Synergistic modulation of flt3 kinase using a flt3 inhibitor and a farnesyl transferase inhibitor
US8697716B2 (en) 2006-04-20 2014-04-15 Janssen Pharmaceutica Nv Method of inhibiting C-KIT kinase
UA93085C2 (en) 2006-04-20 2011-01-10 Янссен Фармацевтика Н.В. Inhibitors of c-fms kinase
EP2021335B1 (en) 2006-04-20 2011-05-25 Janssen Pharmaceutica N.V. Heterocyclic compounds as inhibitors of c-fms kinase
JO3240B1 (ar) 2007-10-17 2018-03-08 Janssen Pharmaceutica Nv c-fms مثبطات كيناز
WO2010142576A1 (en) * 2009-06-08 2010-12-16 Basf Se Novel sterically hindered amine light stabilizers
TWI454604B (zh) * 2011-12-27 2014-10-01 Ind Tech Res Inst 分散性染料組成物、聚酯纖維材料的染色方法以及染色後的聚酯纖維材料
JP6359537B2 (ja) 2012-08-07 2018-07-18 ヤンセン ファーマシューティカ エヌ．ベー． 複素環エステル誘導体の調製プロセス
JOP20180012A1 (ar) 2012-08-07 2019-01-30 Janssen Pharmaceutica Nv عملية السلفنة باستخدام نونافلوروبوتانيسولفونيل فلوريد
WO2015173190A1 (en) * 2014-05-15 2015-11-19 Basf Se Highly effective stabilizer
CN105348525B (zh) * 2015-10-19 2017-10-27 北京天罡助剂有限责任公司 一种低碱性聚合型受阻胺光稳定剂及其制备方法
CN106699639A (zh) * 2016-12-22 2017-05-24 甘肃省化工研究院 一种光稳定剂hs‑112的合成方法
MX2021010798A (es) * 2019-03-08 2021-10-01 Basf Se Mezclas estabilizadoras de aminas estericamente impedidas.
CN110845729A (zh) * 2019-11-29 2020-02-28 沈阳化工研究院有限公司 一种高分子量低碱性光稳定剂及其制备和应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0309402A1 (en) * 1987-09-21 1989-03-29 Ciba-Geigy Ag N-substituted hindered amine stabilizers
EP0389428A2 (en) * 1989-03-21 1990-09-26 Ciba-Geigy Ag N,N-Bis(l-hydroxycarbyloxy-2,2,6,6-tetramethyl-piperidin-4-yl) amino triazines and stabilized compositions
US5004770A (en) * 1988-10-19 1991-04-02 Ciba-Geigy Corporation Polymeric substrates stabilized with N-substituted hindered amines
EP0435828A1 (en) * 1989-12-28 1991-07-03 Ciba-Geigy Ag Piperidine-triazine compounds for use as stabilizers for organic materials
EP0462069A2 (en) * 1990-06-13 1991-12-18 Ciba-Geigy Ag Novel piperidine-triazine co-oligomers for use as stabilizers for organic materials
US5096950A (en) * 1988-10-19 1992-03-17 Ciba-Geigy Corporation Polyolefin compositions stabilized with NOR-substituted hindered amines
US5124378A (en) * 1987-09-21 1992-06-23 Ciba-Geigy Corporation Stabilization of ambient cured coatings

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IT1052501B (it) * 1975-12-04 1981-07-20 Chimosa Chimica Organica Spa Composti politriazinici utilizzabili per la stabilizzazione di polimeri sintetici e procedimento per la loro preparazione
US4234707A (en) * 1977-11-10 1980-11-18 Ciba-Geigy Corporation Polymeric light stabilizers for plastics
DE2933078A1 (de) * 1979-08-16 1981-03-26 Hoechst Ag, 65929 Frankfurt Neue triazinderivate, ihre herstellung und ihre verwendung als stabilisatoren fuer synthetische polymere
IT1151035B (it) * 1980-07-31 1986-12-17 Chimosa Chimica Organica Spa Piperidil-derivati di copolimeri triazinici,processi per la loro preparazione e composizioni stabilizzate che li comprendono
DE3045839A1 (de) * 1980-12-05 1982-07-08 Hoechst Ag, 6000 Frankfurt Poly-bis-triazinylamine, verfahren zu ihrer herstellung, ihre verwendung zum stabilisieren von synthetischen polymeren und die so stabilisierten polymeren
US4331586A (en) * 1981-07-20 1982-05-25 American Cyanamid Company Novel light stabilizers for polymers
US4492791A (en) * 1982-05-04 1985-01-08 Ciba-Geigy Corporation Process for the preparation of polyaminotriazines
US5204473A (en) * 1987-09-21 1993-04-20 Ciba-Geigy Corporation O-substituted N-hydroxy hindered amine stabilizers
CS270846B1 (en) * 1988-08-29 1990-08-14 Vass Frantisek New polyaminotriazines and method of their preparation
CS273098B1 (en) * 1989-01-02 1991-03-12 Manasek Zdenek Substituted polyaminotriazines and method of their preparation
DE4239437A1 (de) * 1992-11-24 1994-05-26 Basf Ag Maleinsäureimid-alpha-Olefin-Copolymerisate und ihre Verwendung als Lichtschutzmittel und Stabilisatoren für organisches Material
TW358820B (en) * 1995-04-11 1999-05-21 Ciba Sc Holding Ag Synergistic stabilizer mixture
US6046304A (en) * 1995-12-04 2000-04-04 Ciba Specialty Chemicals Corporation Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
EP0782994B1 (en) * 1995-12-04 2003-02-05 Ciba SC Holding AG Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials
JPH115790A (ja) * 1996-07-09 1999-01-12 Sumitomo Chem Co Ltd ポリアミノトリアジン混合物、その製造法及びその用途
TW509683B (en) * 1997-05-27 2002-11-11 Ciba Sc Holding Ag Triazine derivatives containing 2,2,6,6-tetramethyl-4-piperidyl groups
KR100540155B1 (ko) * 1997-05-27 2005-12-29 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 유기 물질용 안정화제로서 유용한1-히드로카르빌옥시-2,2,6,6-테트라메틸-4-피페리딜기를함유하는 블록 올리고머
TW589341B (en) * 1997-05-27 2004-06-01 Ciba Sc Holding Ag Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0309402A1 (en) * 1987-09-21 1989-03-29 Ciba-Geigy Ag N-substituted hindered amine stabilizers
US5124378A (en) * 1987-09-21 1992-06-23 Ciba-Geigy Corporation Stabilization of ambient cured coatings
US5004770A (en) * 1988-10-19 1991-04-02 Ciba-Geigy Corporation Polymeric substrates stabilized with N-substituted hindered amines
US5096950A (en) * 1988-10-19 1992-03-17 Ciba-Geigy Corporation Polyolefin compositions stabilized with NOR-substituted hindered amines
EP0389428A2 (en) * 1989-03-21 1990-09-26 Ciba-Geigy Ag N,N-Bis(l-hydroxycarbyloxy-2,2,6,6-tetramethyl-piperidin-4-yl) amino triazines and stabilized compositions
EP0435828A1 (en) * 1989-12-28 1991-07-03 Ciba-Geigy Ag Piperidine-triazine compounds for use as stabilizers for organic materials
EP0462069A2 (en) * 1990-06-13 1991-12-18 Ciba-Geigy Ag Novel piperidine-triazine co-oligomers for use as stabilizers for organic materials

Also Published As

Publication number Publication date
KR100525180B1 (ko) 2005-11-02
JP2002501519A (ja) 2002-01-15
TW491872B (en) 2002-06-21
KR20010012866A (ko) 2001-02-26
JP4461306B2 (ja) 2010-05-12
CA2287557A1 (en) 1998-12-03
BE1011940A3 (fr) 2000-03-07
AU7072298A (en) 1998-12-30
WO1998054174A1 (en) 1998-12-03
CA2287557C (en) 2008-02-19
DE19882401B3 (de) 2013-03-21
JP2010132656A (ja) 2010-06-17
ITMI981134A1 (it) 1999-11-21
CN1257493A (zh) 2000-06-21
FR2763946B1 (fr) 2001-05-11
US6265473B1 (en) 2001-07-24
GB9926848D0 (en) 2000-01-12
ES2182623B1 (es) 2004-06-16
CN1106396C (zh) 2003-04-23
DE19882401T1 (de) 2000-05-25
FR2763946A1 (fr) 1998-12-04
GB2340119A (en) 2000-02-16
DE19882401B8 (de) 2013-06-27
GB2340119B (en) 2001-07-04

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