ES2158559T3 - Catalizador de epoxidacion y procedimiento que lo emplea. - Google Patents
Catalizador de epoxidacion y procedimiento que lo emplea.Info
- Publication number
- ES2158559T3 ES2158559T3 ES97921844T ES97921844T ES2158559T3 ES 2158559 T3 ES2158559 T3 ES 2158559T3 ES 97921844 T ES97921844 T ES 97921844T ES 97921844 T ES97921844 T ES 97921844T ES 2158559 T3 ES2158559 T3 ES 2158559T3
- Authority
- ES
- Spain
- Prior art keywords
- epoxidation
- catalyst
- procedure
- particles
- alilic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000006735 epoxidation reaction Methods 0.000 title abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/643,158 US5801259A (en) | 1996-04-30 | 1996-04-30 | Ethylene oxide catalyst and process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2158559T3 true ES2158559T3 (es) | 2001-09-01 |
Family
ID=24579602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97921844T Expired - Lifetime ES2158559T3 (es) | 1996-04-30 | 1997-04-25 | Catalizador de epoxidacion y procedimiento que lo emplea. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5801259A (enExample) |
| EP (1) | EP0900128B1 (enExample) |
| JP (1) | JP4052673B2 (enExample) |
| CN (1) | CN1093002C (enExample) |
| AU (1) | AU711973B2 (enExample) |
| CA (1) | CA2252780C (enExample) |
| DE (1) | DE69705309T2 (enExample) |
| ES (1) | ES2158559T3 (enExample) |
| IN (2) | IN2004DE02379A (enExample) |
| MX (1) | MX217137B (enExample) |
| TW (1) | TW344675B (enExample) |
| WO (1) | WO1997040933A1 (enExample) |
Families Citing this family (99)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5939569A (en) * | 1998-03-10 | 1999-08-17 | Jones; C. Andrew | Epoxidation process |
| EP1086743B1 (en) | 1999-09-21 | 2006-08-16 | Nippon Shokubai Co., Ltd. | Catalyst for production of epoxides and methods for production thereof and epoxides |
| JP4050041B2 (ja) * | 2001-11-06 | 2008-02-20 | 株式会社日本触媒 | 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法 |
| US7193094B2 (en) | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| EP1354626B1 (en) * | 2002-04-04 | 2005-07-13 | Nippon Shokubai Co., Ltd. | Alumina-silica supported silver catalyst and use thereof in the production of epoxide |
| US6750173B2 (en) * | 2002-04-08 | 2004-06-15 | Scientific Design Company, Inc. | Ethylene oxide catalyst |
| RU2005102097A (ru) | 2002-06-28 | 2005-08-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина |
| KR100980123B1 (ko) * | 2002-06-28 | 2010-09-03 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 촉매 선택성을 향상시키는 방법 및 올레핀 에폭시화 방법 |
| DE10300526A1 (de) * | 2003-01-09 | 2004-07-22 | Hte Ag The High Throughput Experimentation Company | Silberhaltige Katalysatoren zur Umsetzung von Substraten mit C-C-Doppelbindungen |
| US7319156B2 (en) | 2003-03-25 | 2008-01-15 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
| TWI346574B (en) | 2003-03-31 | 2011-08-11 | Shell Int Research | A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition |
| ATE376879T1 (de) * | 2003-04-01 | 2007-11-15 | Shell Int Research | Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren |
| US7348444B2 (en) * | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US6858560B2 (en) | 2003-04-23 | 2005-02-22 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
| AU2004238820B2 (en) | 2003-05-07 | 2008-01-31 | Shell Internationale Research Maatschappij B.V. | Silver-containing catalysts, the manufacture of such silver containing catalysts, and the use thereof |
| US20040225138A1 (en) * | 2003-05-07 | 2004-11-11 | Mcallister Paul Michael | Reactor system and process for the manufacture of ethylene oxide |
| US20040224841A1 (en) * | 2003-05-07 | 2004-11-11 | Marek Matusz | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
| US8148555B2 (en) * | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| CN1838991A (zh) * | 2003-08-22 | 2006-09-27 | 联合碳化化学及塑料技术公司 | 改进的氧化铝载体和用于制造烯化氧的银基催化剂 |
| EP2277622B1 (en) * | 2003-10-16 | 2013-01-09 | Dow Technology Investments LLC | Method for the preparation of catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production |
| CN1301791C (zh) * | 2003-12-31 | 2007-02-28 | 中国石油化工股份有限公司北京燕山分公司研究院 | 用于环氧乙烷生产用银催化剂的载体、其制备方法及其应用 |
| TW200602123A (en) * | 2004-04-01 | 2006-01-16 | Shell Int Research | Process for preparing a catalyst, the catalyst, and a use of the catalyst |
| TW200613056A (en) * | 2004-04-01 | 2006-05-01 | Shell Int Research | A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation |
| TW200600190A (en) * | 2004-04-01 | 2006-01-01 | Shell Int Research | Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation |
| CN101023068B (zh) * | 2004-08-12 | 2013-02-13 | 万罗赛斯公司 | 使用微通道工艺技术将乙烯转化成环氧乙烷的方法 |
| JP2008514405A (ja) * | 2004-09-24 | 2008-05-08 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 成形粒子を選択するプロセス、システムを取り付けるプロセス、このようなシステム内で気体原料を反応させるプロセス、コンピュータプログラム製品、およびコンピュータシステム |
| KR20070112870A (ko) * | 2005-03-22 | 2007-11-27 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 반응기 시스템 및 에틸렌옥사이드의 제조방법 |
| US7759284B2 (en) * | 2005-05-09 | 2010-07-20 | Scientific Design Company, Inc. | Calcination in an inert gas in the presence of a small concentration of an oxidizing component |
| BRPI0611817A2 (pt) * | 2005-06-07 | 2011-12-20 | Saint Gobain Ceramics | veìculo catalisador e um processo para preparação do veìculo catalisador |
| KR101369619B1 (ko) * | 2005-06-07 | 2014-03-05 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법 |
| US20070203349A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US7459589B2 (en) * | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| US20070197808A1 (en) * | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070213545A1 (en) * | 2005-12-22 | 2007-09-13 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070203352A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070151451A1 (en) * | 2005-12-22 | 2007-07-05 | Rekers Dominicus M | Process for the cooling, concentration or purification of ethylene oxide |
| US20070203348A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| CN101384359A (zh) * | 2005-12-22 | 2009-03-11 | 国际壳牌研究有限公司 | 制备再生的环氧化催化剂的方法 |
| US20070197801A1 (en) * | 2005-12-22 | 2007-08-23 | Bolk Jeroen W | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process |
| US7704908B2 (en) * | 2005-12-22 | 2010-04-27 | Shell Oil Company | Method for reusing rhenium from a donor spent epoxidation catalyst |
| US20070203350A1 (en) * | 2005-12-22 | 2007-08-30 | Bolk Jeroen W | Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process |
| US20070154377A1 (en) * | 2005-12-22 | 2007-07-05 | Rekers Dominicus M | Process for the removal of combustible volatile contaminant materials from a process stream |
| CN100577289C (zh) * | 2006-01-28 | 2010-01-06 | 中国石油化工股份有限公司 | 环氧乙烷生产用银催化剂的载体、其制备方法及其应用 |
| JP2009525848A (ja) * | 2006-02-03 | 2009-07-16 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒の処理方法、触媒、および触媒の使用 |
| BRPI0621318B1 (pt) * | 2006-02-10 | 2017-10-10 | Saint-Gobain Ceramics & Plastics, Inc | Process for the manufacture of porosa ceramic material |
| WO2007123932A2 (en) * | 2006-04-18 | 2007-11-01 | Dow Global Technologies Inc. | Alkylene oxide catalyst and use thereof |
| US10159961B2 (en) | 2006-04-18 | 2018-12-25 | Dow Global Technologies Llc | Alkylene oxide catalyst and use thereof |
| US8097557B2 (en) | 2006-08-08 | 2012-01-17 | Sd Lizenverwertungsgesellschaft Mbh & Co. Kg | Two-stage calcination for catalyst production |
| US7977274B2 (en) | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
| US7932408B2 (en) * | 2006-09-29 | 2011-04-26 | Scientific Design Company, Inc. | Catalyst with bimodal pore size distribution and the use thereof |
| EP2125202A2 (en) | 2006-11-20 | 2009-12-02 | Shell Internationale Research Maatschappij B.V. | A process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst |
| US20080154051A1 (en) * | 2006-12-20 | 2008-06-26 | Jeroen Willem Bolk | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| US20080154052A1 (en) * | 2006-12-20 | 2008-06-26 | Jeroen Willem Bolk | Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| TWI464154B (zh) * | 2007-05-09 | 2014-12-11 | Shell Int Research | 製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法 |
| AR066468A1 (es) | 2007-05-09 | 2009-08-19 | Shell Int Research | Un catalizador de epoxidacion, un proceso para preparar el mismo, y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2 - diol eter, un 1,2- carbonato, o una alcanolamina |
| EP2152681B1 (en) | 2007-05-09 | 2017-03-29 | Shell Internationale Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| US8569527B2 (en) | 2007-05-18 | 2013-10-29 | Shell Oil Company | Reactor system, an absorbent and a process for reacting a feed |
| US9144765B2 (en) | 2007-05-18 | 2015-09-29 | Shell Oil Company | Reactor system, an absorbent and a process for reacting a feed |
| WO2008144396A2 (en) | 2007-05-18 | 2008-11-27 | Shell Oil Company | A reactor system, and a process for preparing an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate and an alkanolamine |
| US7803957B2 (en) * | 2007-09-11 | 2010-09-28 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
| US7553980B2 (en) * | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
| WO2009088040A1 (ja) * | 2008-01-11 | 2009-07-16 | Nippon Shokubai Co., Ltd. | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
| CN102015095B (zh) * | 2008-04-30 | 2013-05-08 | 陶氏技术投资有限公司 | 多孔体前体,成形多孔体,它们的制备方法和基于它们的终端产品 |
| EP2274093A1 (en) * | 2008-04-30 | 2011-01-19 | Dow Technology Investments LLC | Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same |
| US20110059843A1 (en) * | 2008-04-30 | 2011-03-10 | Howard Kevin E | Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same |
| US7763096B2 (en) | 2008-05-06 | 2010-07-27 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Recovery of rhenium |
| KR101629037B1 (ko) | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| KR101629038B1 (ko) * | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| CN102066352B (zh) | 2008-05-15 | 2014-03-19 | 国际壳牌研究有限公司 | 制备亚烷基碳酸酯和亚烷基二醇的方法 |
| BRPI0912718B1 (pt) | 2008-05-15 | 2017-12-26 | Shell Internationale Research Maataschappij B.V | Method for producing an alkylene carbonate and / or an alkylene glycol |
| CA2759560C (en) * | 2009-04-21 | 2017-05-30 | Dow Technology Investments Llc | Rhenium-promoted epoxidation catalysts and methods of making and using them |
| CN102414189B (zh) * | 2009-04-21 | 2014-09-17 | 陶氏技术投资有限公司 | 环氧化反应及其操作条件 |
| WO2010123844A1 (en) * | 2009-04-21 | 2010-10-28 | Dow Technology Investments Llc | Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
| JP2012524785A (ja) * | 2009-04-21 | 2012-10-18 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 高効率触媒を用いたアルキレンオキシド簡易製造方法 |
| JP2012522061A (ja) * | 2009-12-28 | 2012-09-20 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | アルキレンオキサイドの製造における銀触媒上への塩化銀の生成の制御方法 |
| US8937031B2 (en) | 2010-03-01 | 2015-01-20 | Shell Oil Company | Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide |
| US8586769B2 (en) * | 2010-06-04 | 2013-11-19 | Scientific Design Company, Inc. | Carrier for ethylene oxide catalysts |
| US9018126B2 (en) | 2010-07-13 | 2015-04-28 | Shell Oil Company | Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide |
| RU2581365C2 (ru) | 2010-09-29 | 2016-04-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения этиленоксида с улучшенным регулированием |
| US8742146B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| US8742147B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| CN103547365B (zh) | 2011-04-11 | 2016-03-16 | 陶氏技术投资有限责任公司 | 调节高效环氧乙烷催化剂的方法 |
| CN103502229B (zh) | 2011-04-29 | 2016-02-03 | 国际壳牌研究有限公司 | 用于改善环氧乙烷催化剂选择性的方法 |
| CN103357436B (zh) * | 2012-03-28 | 2016-02-24 | 中国石油化工股份有限公司 | 氧化铝载体碱处理改性、其负载的银催化剂的制备及应用 |
| CN103357442B (zh) * | 2012-03-28 | 2016-03-30 | 中国石油化工股份有限公司 | 烯烃环氧化用银催化剂的载体、其制备方法及其应用 |
| CN103357440B (zh) * | 2012-03-28 | 2015-03-11 | 中国石油化工股份有限公司 | 氧化铝载体的改性、及其负载的银催化剂的制备及其应用 |
| CN103566980B (zh) * | 2012-07-23 | 2015-08-19 | 中国石油化工股份有限公司 | 氧化铝载体及其负载的银催化剂的制备方法及应用 |
| CN103816940B (zh) * | 2012-11-19 | 2019-03-26 | 中国石油化工股份有限公司 | 一种氧化铝载体及其制备方法 |
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| CN104549546B (zh) * | 2013-10-29 | 2017-08-22 | 中国石油化工股份有限公司 | 氧化铝载体、制备方法及银催化剂 |
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| CN106311231A (zh) * | 2015-06-30 | 2017-01-11 | 中国石油化工股份有限公司 | 用于烯烃环氧化的银催化剂的制备方法、银催化剂及应用 |
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-
1997
- 1997-04-25 EP EP97921844A patent/EP0900128B1/en not_active Expired - Lifetime
- 1997-04-25 WO PCT/EP1997/002236 patent/WO1997040933A1/en not_active Ceased
- 1997-04-25 JP JP53860197A patent/JP4052673B2/ja not_active Expired - Fee Related
- 1997-04-25 DE DE69705309T patent/DE69705309T2/de not_active Expired - Lifetime
- 1997-04-25 TW TW86105449A patent/TW344675B/zh not_active IP Right Cessation
- 1997-04-25 MX MX9808843A patent/MX217137B/es not_active IP Right Cessation
- 1997-04-25 AU AU27760/97A patent/AU711973B2/en not_active Ceased
- 1997-04-25 ES ES97921844T patent/ES2158559T3/es not_active Expired - Lifetime
- 1997-04-25 CN CN97194296A patent/CN1093002C/zh not_active Expired - Fee Related
- 1997-04-25 CA CA002252780A patent/CA2252780C/en not_active Expired - Fee Related
- 1997-04-28 IN IN2379DE2004 patent/IN2004DE02379A/en unknown
- 1997-04-28 IN IN1084DE1997 patent/IN222717B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU711973B2 (en) | 1999-10-28 |
| US5801259A (en) | 1998-09-01 |
| WO1997040933A1 (en) | 1997-11-06 |
| EP0900128A1 (en) | 1999-03-10 |
| MX9808843A (en) | 1999-05-31 |
| MX217137B (en) | 2003-10-24 |
| CN1093002C (zh) | 2002-10-23 |
| DE69705309D1 (de) | 2001-07-26 |
| CN1216940A (zh) | 1999-05-19 |
| AU2776097A (en) | 1997-11-19 |
| DE69705309T2 (de) | 2001-11-15 |
| JP4052673B2 (ja) | 2008-02-27 |
| IN2004DE02379A (enExample) | 2009-06-19 |
| CA2252780C (en) | 2006-10-17 |
| EP0900128B1 (en) | 2001-06-20 |
| IN1997DE01084A (enExample) | 2008-01-18 |
| TW344675B (en) | 1998-11-11 |
| CA2252780A1 (en) | 1997-11-06 |
| JP2000508969A (ja) | 2000-07-18 |
| IN222717B (enExample) | 2008-09-12 |
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