KR920000795A - 경올레핀 소중합 방법 - Google Patents

경올레핀 소중합 방법 Download PDF

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Publication number
KR920000795A
KR920000795A KR1019910010299A KR910010299A KR920000795A KR 920000795 A KR920000795 A KR 920000795A KR 1019910010299 A KR1019910010299 A KR 1019910010299A KR 910010299 A KR910010299 A KR 910010299A KR 920000795 A KR920000795 A KR 920000795A
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KR
South Korea
Prior art keywords
alumina
reaction
carried out
silica
polymerization method
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KR1019910010299A
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English (en)
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KR940000786B1 (ko
Inventor
벨루씨 지우세페
카바니 파브리찌오
아리고니 비르지니오
게찌 로베르토
Original Assignee
원본미기재
에니리체르케 쏘시에떼 퍼 아찌오니
에니켐 신테시스 쏘시에떼 퍼 아찌오니
스남프로게티 쏘시에떼 퍼 아찌오니
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Application filed by 원본미기재, 에니리체르케 쏘시에떼 퍼 아찌오니, 에니켐 신테시스 쏘시에떼 퍼 아찌오니, 스남프로게티 쏘시에떼 퍼 아찌오니 filed Critical 원본미기재
Publication of KR920000795A publication Critical patent/KR920000795A/ko
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Publication of KR940000786B1 publication Critical patent/KR940000786B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/10—Catalytic processes with metal oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)

Abstract

내용 없음.

Description

경올레핀 소중합 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 30/1 내지 500/1 의 실리카/알루미나 몰비율과 500 내지 1000㎡/g의 비표면적과, 0.3 내지 0.6ml/g의 총 공극부피와, 기공의 평균직경 크기가 10Å 이하이고, 30Å 이상의 직경크기로된 기공은 없은 것을 특징으로 하는 X-선 비결정형 알루미나-실리카겔 촉매로 올레핀을 반응시키는 것으로된 프로필렌 소중합방법.
  2. 제1항에 있어서, 반응이 100℃ 내지 250℃ 온도로 실행되는 것을 특징으로 하는 방법.
  3. 제1항에 있어서, 반응이 120℃ 내지 200℃의 온도에서 실행되는 것을 특징으로 하는 방법.
  4. 제1항에 있어서, 반응이 10 내지 70atm의 압력에서 실행되는 것을 특징으로 하는 방법.
  5. 제1항에 있어서, 접촉시간이 5 내지 90분인 것을 특징으로 하는 방법.
  6. 제1항에 있어서, 알루미나-실리카겔 촉매를 알루미나, 실리카 또한 티타늄과 마그네슘 산화물중 선택된 금속산화물과 혼합하여 사용하고 금속산화물에 대한 겔의 중량비가 50/50 내지 95/5 특히 70/30 내지 90/10인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910010299A 1990-06-22 1991-06-21 경올레핀 소중합방법 KR940000786B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT02074490A IT1248985B (it) 1990-06-22 1990-06-22 Procedimento per oligomerizzare olefine leggere
IT20744A/90 1990-06-22

Publications (2)

Publication Number Publication Date
KR920000795A true KR920000795A (ko) 1992-01-29
KR940000786B1 KR940000786B1 (ko) 1994-01-31

Family

ID=11171423

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910010299A KR940000786B1 (ko) 1990-06-22 1991-06-21 경올레핀 소중합방법

Country Status (14)

Country Link
US (1) US5149896A (ko)
EP (1) EP0463673B1 (ko)
JP (1) JP3136492B2 (ko)
KR (1) KR940000786B1 (ko)
AT (1) ATE117664T1 (ko)
BR (1) BR9102614A (ko)
CA (1) CA2044735C (ko)
DE (1) DE69106948T2 (ko)
DK (1) DK0463673T3 (ko)
ES (1) ES2067139T3 (ko)
GR (1) GR3015112T3 (ko)
IT (1) IT1248985B (ko)
MX (1) MX172234B (ko)
RU (1) RU2014315C1 (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1410844A1 (en) * 2002-10-15 2004-04-21 Centre National De La Recherche Scientifique (Cnrs) Silicon-based porous catalytic system for oligomerising light olefins
ES2247921B1 (es) * 2004-04-07 2007-06-16 Universidad Politecnica De Valencia Un material amorfo microporoso, procedimiento de preparacion y su uso en la conversion catalitica de compuestos organicos.
US7615673B2 (en) * 2006-09-08 2009-11-10 Catalytic Distillation Technologies Propylene oligomerization process
US8395008B2 (en) * 2008-01-14 2013-03-12 Catalytic Distillation Technologies Process and catalyst for cracking of ethers and alcohols
FR2926812B1 (fr) 2008-01-28 2010-04-30 Inst Francais Du Petrole Procede d'oligomerisation des olefines utilisant un catalyseur a base de silice-alumine.
FR2951164B1 (fr) 2009-10-08 2011-10-21 Inst Francais Du Petrole Procede d'oligomerisation d'une charge hydrocarbonee olefinique utilisant un catalyseur a base d'une silice-alumine macroporeuse
FR2973394A1 (fr) 2011-03-31 2012-10-05 IFP Energies Nouvelles Procede d'oligomerisation d'une charge hydrocarbonee olefinique utilisant un catalyseur comprenant un materiau de la famille des zif de type structural sod
EP2792730A1 (en) 2013-04-16 2014-10-22 Sasol Technology (Proprietary) Limited Process for producing jet fuel from a hydrocarbon synthesis product stream
FR3017622B1 (fr) 2014-02-19 2017-05-26 Ifp Energies Now Procede d'oligomerisation d'olefines utilisant un catalyseur comprenant une zeolithe et un liant silicique ayant subi une etape de traitement thermique specifique
FR3044310B1 (fr) 2015-11-30 2019-04-19 Axens Procede d'oligomerisation d'olefines legeres au moyen d'une section reactionnelle comprenant au moins deux reacteurs permutables favorisant la selectivite vers les distillats
FR3053355B1 (fr) 2016-06-30 2019-07-26 IFP Energies Nouvelles Procede d'oligomerisation utilisant un catalyseur zeolithique et un catalyseur comprenant une silice alumine

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2145576A (en) * 1937-07-29 1939-01-31 Process Man Co Inc Conversion of hydrocarbons
DE766151C (de) * 1939-01-01 1954-07-12 Ig Farbenindustrie Ag Verfahren zur Polymerisation von Kohlenwasserstoffen
BE608029A (ko) * 1957-02-05 1900-01-01
US3188360A (en) * 1961-02-02 1965-06-08 Exxon Research Engineering Co Propylene polymerization to c13-c20 olefins for detergents
US4335022A (en) * 1979-07-27 1982-06-15 Shell Oil Company Modified silica composition
FR2547830B1 (fr) * 1983-06-22 1988-04-08 Inst Francais Du Petrole Procede de production de supercarburant par polymerisation des coupes c4
IT1219692B (it) * 1988-05-06 1990-05-24 Eniricerche Spa Gel di silice e allumina cataliticamente attivo e procedimento per la sua preparazione

Also Published As

Publication number Publication date
IT9020744A1 (it) 1991-12-22
RU2014315C1 (ru) 1994-06-15
IT1248985B (it) 1995-02-11
GR3015112T3 (en) 1995-05-31
MX172234B (es) 1993-12-08
ES2067139T3 (es) 1995-03-16
EP0463673A1 (en) 1992-01-02
JPH04226104A (ja) 1992-08-14
DE69106948T2 (de) 1995-06-08
CA2044735A1 (en) 1991-12-23
ATE117664T1 (de) 1995-02-15
EP0463673B1 (en) 1995-01-25
KR940000786B1 (ko) 1994-01-31
DK0463673T3 (da) 1995-05-08
US5149896A (en) 1992-09-22
JP3136492B2 (ja) 2001-02-19
CA2044735C (en) 2001-06-05
DE69106948D1 (de) 1995-03-09
IT9020744A0 (ko) 1990-06-22
BR9102614A (pt) 1992-01-21

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