ES2156210T3 - Polimeros biologicamente degradables, un procedimiento para su obtencion asi como su empleo para la obtencion de cuerpos moldeados biodegradables. - Google Patents

Polimeros biologicamente degradables, un procedimiento para su obtencion asi como su empleo para la obtencion de cuerpos moldeados biodegradables.

Info

Publication number
ES2156210T3
ES2156210T3 ES95925768T ES95925768T ES2156210T3 ES 2156210 T3 ES2156210 T3 ES 2156210T3 ES 95925768 T ES95925768 T ES 95925768T ES 95925768 T ES95925768 T ES 95925768T ES 2156210 T3 ES2156210 T3 ES 2156210T3
Authority
ES
Spain
Prior art keywords
mol
ester
range
obtaining
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95925768T
Other languages
English (en)
Inventor
Volker Warzelhan
Bernd Bruchmann
Dieter Boeckh
Ursula Seeliger
Motonori Yamamoto
Peter Bauer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2156210T3 publication Critical patent/ES2156210T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C08G18/4676—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/80—Separation, elimination or disposal of harmful substances during the treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4286—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones prepared from a combination of hydroxycarboxylic acids and/or lactones with polycarboxylic acids or ester forming derivatives thereof and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/32—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing two or more of boron, silicon, phosphorus, selenium, tellurium or a metal
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2230/00—Compositions for preparing biodegradable polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Materials Engineering (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Materials For Medical Uses (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

ESTERES DE POLIETER P1 BIODEGRADABLES, QUE SE SINTETIZAN POR REACCION DE UNA MEZCLA COMPUESTA ESENCIALMENTE POR (A1) UNA MEZCLA COMPUESTA ESENCIALMENTE DEL 20 AL 95 % MOLAR DE ACIDO ADIPICO O SUS DERIVADOS QUE FORMAN ESTERES, O MEZCLAS DE ELLOS, 5 A 80 % MOLAR DE ACIDO TEREFTALICO O SUS DERIVADOS QUE FORMAN ESTERES O SUS MEZCLAS, Y 0 A 5 % MOLAR DE UN COMPUESTO QUE CONTIENE GRUPOS SULFONATO, SIENDO LA SUMA DE LOS DIFERENTES PORCENTAJES 100 % MOLAR, Y (A2) UNA MEZCLA DE COMPUESTOS DIHIDROXI, COMPUESTA ESENCIALMENTE DE (A21) DE 15 A 99,8 % MOLAR DE UN COMPUESTO DIHIDROXI ELEGIDO DEL GRUPO FORMADO POR ALCANODIOLES DE C{SUB,2}-C{SUB,6} Y CICLOALCANODIOLES DE C{SUB,5}-C{SUB,10}, (A22) DE 85 A 0,2 % MOLAR DE UN COMPUESTO DIHIDROXI QUE CONTIENE FUNCIONES ETER DE FORMULA I HO[(CH{SUB,2}){SUB,N}-O]{SUB,M}-H EN LA CUAL N ES 2, 3, O 4 Y M ES UN NUMERO ENTERO DE 2 A 250, O SUS MEZCLAS, SIENDO LA RELACION MOLAR DE (A1) CON RESPECTO A (A2) DE 0,4:1 HASTA 1,5:1, CON LA CONDICION, DE QUE LOS ESTERES DE POLIETER P1 TENGAN UN PESO MOLECULAR (M{SUB,N}) DE 5000 A 80000 G/MOL, UN INDICE DE VISCOSIDAD DE 30 A 450 G/MOL (MEDIDO EN O-DICLOROBENCENO Y FENOL (RELACION EN PESO DE 50/50) CON UNA CONCENTRACION DE 0,5 % EN PESO DE POLIESTER P1 Y A UNA TEMPERATURA DE 25 CON OTRA CONDICION, QUE ES QUE SE UTILICE DE 0,01 A 5 % MOLAR, CON RELACION A LA MASA MOLAR DEL COMPONENTE (A1) UTILIZADO, DE UN COMPUESTO D QUE TIENE AL MENOS TRES GRUPOS CAPACES DE FORMAR ESTERES, PARA LA SINTESIS DE LOS ESTERES DE POLIETER P1, Y OTROS POLIMEROS Y MASAS DE MOLDEO TERMOPLASTICAS, QUE SON AMBOS BIODEGRADABLES; PROCEDIMIENTO PARA SU SINTESIS, SU UTILIZACION PARA LA FABRICACION DE CUERPOS DE MOLDEO Y DE ADHESIVOS BIODEGRADABLES, CUERPOS DE MOLDEO, ESPUMAS Y MEZCLAS CON ALMIDON TODOS BIODEGRADABLES, QUE SE OBTIENEN DE LOS POLIMEROS Y MASAS DE MOLDEO DE LA INVENCION.
ES95925768T 1994-11-15 1995-06-27 Polimeros biologicamente degradables, un procedimiento para su obtencion asi como su empleo para la obtencion de cuerpos moldeados biodegradables. Expired - Lifetime ES2156210T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4440837A DE4440837A1 (de) 1994-11-15 1994-11-15 Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper

Publications (1)

Publication Number Publication Date
ES2156210T3 true ES2156210T3 (es) 2001-06-16

Family

ID=6533414

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95925768T Expired - Lifetime ES2156210T3 (es) 1994-11-15 1995-06-27 Polimeros biologicamente degradables, un procedimiento para su obtencion asi como su empleo para la obtencion de cuerpos moldeados biodegradables.

Country Status (21)

Country Link
US (3) US6258924B1 (es)
EP (1) EP0792310B1 (es)
JP (1) JP3459258B2 (es)
KR (1) KR100342143B1 (es)
CN (1) CN1075527C (es)
AT (1) ATE200501T1 (es)
AU (1) AU691317B2 (es)
CA (1) CA2205072C (es)
CZ (1) CZ293001B6 (es)
DE (2) DE4440837A1 (es)
DK (1) DK0792310T3 (es)
ES (1) ES2156210T3 (es)
FI (1) FI117440B (es)
HU (1) HU220300B (es)
MX (1) MX9703537A (es)
NO (1) NO315121B1 (es)
NZ (1) NZ289823A (es)
PL (1) PL320223A1 (es)
PT (1) PT792310E (es)
TW (1) TW343206B (es)
WO (1) WO1996015174A1 (es)

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