ES2153058T3 - Procedimiento para la preparacion de compuestos epoxi. - Google Patents

Procedimiento para la preparacion de compuestos epoxi.

Info

Publication number
ES2153058T3
ES2153058T3 ES95943918T ES95943918T ES2153058T3 ES 2153058 T3 ES2153058 T3 ES 2153058T3 ES 95943918 T ES95943918 T ES 95943918T ES 95943918 T ES95943918 T ES 95943918T ES 2153058 T3 ES2153058 T3 ES 2153058T3
Authority
ES
Spain
Prior art keywords
alilo
compounds
compound
epoxi
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95943918T
Other languages
English (en)
Inventor
Andrew T Au
J Lowell Nafziger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2153058T3 publication Critical patent/ES2153058T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B43/00—Formation or introduction of functional groups containing nitrogen
    • C07B43/04—Formation or introduction of functional groups containing nitrogen of amino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/06—Formation or introduction of functional groups containing sulfur of mercapto or sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/18—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to carbon atoms of six-membered aromatic rings or from amines having nitrogen atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/10—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with ester groups or with a carbon-halogen bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/28—Chemically modified polycondensates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Resins (AREA)
  • Laminated Bodies (AREA)

Abstract

LOS COMPUESTOS QUE CONTIENEN EPOXI SE PREPARAN: (1) UTILIZANDO UN REACTIVO DE ALILO; (2) ALILANDO UNO O MAS COMPUESTOS QUE CONTENGAN AL MENOS UN ATOMO DE HIDROGENO ACTIVO POR MOLECULA UTILIZANDO EL REACTIVO DE ALILO DEL PASO (1) CON LO QUE SE FORMA UN COMPUESTO DE ETER DE ALILO, AMINA DE ALILO O TIOETER DE ALILO; Y (3) CONVIRTIENDO LOS GRUPOS ALILO DEL COMPUESTO DEL PASO (2) EN GRUPOS EPOXIDO CON LO QUE SE FORMA UN COMPUESTO DE ETER DE GLICIDILO, AMINA DE GLICIDILO O TIOETER DE GLICIDILO, QUE SE CARACTERIZA PORQUE EL REACTIVO DE ALILO ES UN CARBOXILATO DE ALILO O CARBONATO DE ALILO. LOS COMPUESTOS QUE CONTIENEN EPOXI SON UTILES PARA REVESTIMIENTOS, FUNDICIONES Y LAMINADOS.
ES95943918T 1994-12-23 1995-12-19 Procedimiento para la preparacion de compuestos epoxi. Expired - Lifetime ES2153058T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/363,129 US5578740A (en) 1994-12-23 1994-12-23 Process for preparation of epoxy compounds essentially free of organic halides

Publications (1)

Publication Number Publication Date
ES2153058T3 true ES2153058T3 (es) 2001-02-16

Family

ID=23428936

Family Applications (2)

Application Number Title Priority Date Filing Date
ES95943917T Expired - Lifetime ES2133845T3 (es) 1994-12-23 1995-12-19 Procedimiento para la preparacion de compuestos de eter alilico, tioeter alilico y amina alilica.
ES95943918T Expired - Lifetime ES2153058T3 (es) 1994-12-23 1995-12-19 Procedimiento para la preparacion de compuestos epoxi.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES95943917T Expired - Lifetime ES2133845T3 (es) 1994-12-23 1995-12-19 Procedimiento para la preparacion de compuestos de eter alilico, tioeter alilico y amina alilica.

Country Status (11)

Country Link
US (2) US5578740A (es)
EP (2) EP0799261B1 (es)
JP (2) JP3819426B2 (es)
KR (2) KR100395987B1 (es)
CN (2) CN1080732C (es)
BR (2) BR9510241A (es)
CZ (2) CZ190397A3 (es)
DE (2) DE69519807T2 (es)
ES (2) ES2133845T3 (es)
TW (1) TW372987B (es)
WO (2) WO1996020233A1 (es)

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EP0799261B1 (en) 1999-05-26
CN1080732C (zh) 2002-03-13
WO1996020232A1 (en) 1996-07-04
KR100395987B1 (ko) 2003-11-14
CN1066464C (zh) 2001-05-30
EP0799262B1 (en) 2001-01-03
DE69509920T2 (de) 1999-09-23
WO1996020233A1 (en) 1996-07-04
CN1171124A (zh) 1998-01-21
DE69519807D1 (de) 2001-02-08
EP0799261A1 (en) 1997-10-08
EP0799262A1 (en) 1997-10-08
ES2133845T3 (es) 1999-09-16
CN1171125A (zh) 1998-01-21
BR9510241A (pt) 1997-11-04
CZ193897A3 (en) 1997-11-12
DE69519807T2 (de) 2001-07-19
CZ190397A3 (en) 1997-11-12
JPH10511722A (ja) 1998-11-10
TW372987B (en) 1999-11-01
DE69509920D1 (de) 1999-07-01
JP3819426B2 (ja) 2006-09-06
US5908943A (en) 1999-06-01
BR9510242A (pt) 1997-11-04

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