ES2146449T3 - Transesterificacion catalizada por estaño organico. - Google Patents
Transesterificacion catalizada por estaño organico.Info
- Publication number
- ES2146449T3 ES2146449T3 ES97201737T ES97201737T ES2146449T3 ES 2146449 T3 ES2146449 T3 ES 2146449T3 ES 97201737 T ES97201737 T ES 97201737T ES 97201737 T ES97201737 T ES 97201737T ES 2146449 T3 ES2146449 T3 ES 2146449T3
- Authority
- ES
- Spain
- Prior art keywords
- acid
- alcohol
- group
- polyol
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyesters Or Polycarbonates (AREA)
- Saccharide Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
LOS ESTERES DE ACIDOS MONOCARBOXILICOS SON TRANSESTERIFICADOS CON 1,2- Y 1,3-POLIOLES MEDIANTE LA REACCION EN PRESENCIA DE UNA CANTIDAD CATALITICAMENTE EFECTIVA DE UN OXIDO DE DIALKILESTAÑO MEZCLADO CON UN EXCESO DE DICLORURO DE DIALKILESTAÑO, DE MODO QUE SE FORMA UN ESTER DE POLIOL DEL ACIDO MONOCARBOXILICO. TAMBIEN SE PRESENTA UNA REACCION DE TRANSESTERIFICACION DE ALCOHOLES Y POLIOLES CON ESTERES DE ACIDOS MONO- O POLICARBOXILICOS DE METILO O ETILO UTILIZANDO UN CATALIZADOR DE DIMETILESTAÑO, EN DONDE EL ESTER DE ALCOHOL O POLIOL DEL ACIDO CARBOXILICO FORMADO NO CONTIENE ESENCIALMENTE EL CATALIZADOR DE ORGANOESTAÑO. TAMBIEN SE PRESENTAN ESTERES DE ACIDOS CARBOXILICOS PRODUCIDOS SEGUN LOS METODOS DESCRITOS, ASI COMO ESTERES DE ACIDOS CARBOXILICOS QUE NO CONTIENEN CATALIZADORES DE ORGANOESTAÑO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/116,448 US5498751A (en) | 1993-09-03 | 1993-09-03 | Organotin catalyzed transesterification |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2146449T3 true ES2146449T3 (es) | 2000-08-01 |
Family
ID=22367259
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES97201737T Expired - Lifetime ES2146449T3 (es) | 1993-09-03 | 1994-08-12 | Transesterificacion catalizada por estaño organico. |
ES94850135T Expired - Lifetime ES2127908T3 (es) | 1993-09-03 | 1994-08-12 | Procedimiento para preparar esteres superiores. |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES94850135T Expired - Lifetime ES2127908T3 (es) | 1993-09-03 | 1994-08-12 | Procedimiento para preparar esteres superiores. |
Country Status (8)
Country | Link |
---|---|
US (2) | US5498751A (es) |
EP (3) | EP0646567B1 (es) |
JP (1) | JP3853386B2 (es) |
AT (3) | ATE192427T1 (es) |
DE (3) | DE69424320T2 (es) |
DK (1) | DK0646567T3 (es) |
ES (2) | ES2146449T3 (es) |
TW (1) | TW420660B (es) |
Families Citing this family (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5606103A (en) * | 1993-09-03 | 1997-02-25 | Cps Chemical Company, Inc. | Organotin catalyzed transesterification |
DE4401132A1 (de) * | 1994-01-17 | 1995-07-20 | Roehm Gmbh | Verfahren zur Umesterung von (Meth)acrylsäureestern |
DE19652017A1 (de) * | 1996-12-13 | 1998-06-18 | Basf Ag | Verfahren zur Herstellung von omega-Hydroxyestern alpha,beta-ungesättigter Carbonsäuren |
EP0946487B1 (de) | 1996-12-20 | 2002-08-07 | Ciba SC Holding AG | An feste trägermaterialien fixierte umesterungskatalysatoren |
US5896088A (en) * | 1997-04-16 | 1999-04-20 | Southeastern Univ. Research Assn. | Incipient fire detection system |
DE69807394T2 (de) * | 1997-05-30 | 2003-03-20 | Mitsubishi Chem Corp | Verfahren zur Herstellung von Hydroxyalkylmonoacrylat |
US6008404A (en) * | 1997-08-11 | 1999-12-28 | Ciba Specialty Chemicals Corporation | Acrylate monomer preparation using alkali metal alkoxides as ester interchange catalysts and bromide salt polymerization inhibitors |
US6215018B1 (en) | 1997-08-11 | 2001-04-10 | Ciba Specialty Chemicals Corporation | Acrylate monomer preparation using alkali metal alkoxides as ester interchange catalysts and bromide salt polymerization inhibitors |
WO1999024512A1 (en) | 1997-11-06 | 1999-05-20 | The Edgington Company | Coating composition |
EP1036105A1 (en) * | 1997-12-04 | 2000-09-20 | Eastman Chemical Company | Preparation of polyesters and esters from compounds containing secondary hydroxyl groups |
US7277424B1 (en) * | 1998-07-21 | 2007-10-02 | Dowling Eric M | Method and apparatus for co-socket telephony |
US6323255B1 (en) * | 1998-09-30 | 2001-11-27 | Dsm N.V. | Radiation-curable composition |
US6175037B1 (en) | 1998-10-09 | 2001-01-16 | Ucb, S.A. | Process for the preparation of (meth)acrylate esters and polyester (meth)acrylates using microwave energy as a heating source |
JP2000319252A (ja) * | 1999-05-10 | 2000-11-21 | Dainippon Ink & Chem Inc | マレイミド誘導体の製造方法 |
DE19941136A1 (de) | 1999-08-30 | 2001-03-01 | Basf Ag | Verfahren zur Herstellung von (Meth)acrylsäureestern |
JP4701497B2 (ja) * | 2000-03-07 | 2011-06-15 | Dic株式会社 | マレイミド誘導体の製造方法 |
JP2001348364A (ja) * | 2000-06-06 | 2001-12-18 | Mitsubishi Gas Chem Co Inc | 芳香族カーボネートの製造方法 |
US6710204B2 (en) * | 2001-03-26 | 2004-03-23 | Mitsubishi Rayon Co., Ltd. | Decreasing method of N-oxyl compound |
US6846900B2 (en) * | 2001-03-26 | 2005-01-25 | Showa Denko K.K. | Polyvalent carboxylic acid ester, process for producing the carboxylic acid ester, plastic lens composition using the carboxylic ester, plastic lens obtained by curing the composition and process for producing the plastic lens |
FR2824063B1 (fr) | 2001-04-26 | 2004-03-05 | Atofina | Procede de fabrication du chlorure de l'acrylate de 1,3-bis (dimethylbenzylammonium) isopropyle seul ou en melange d'autres monomeres et (co) polymers correspondant |
FR2824062B1 (fr) | 2001-04-27 | 2004-10-15 | Atofina | Procede de fabrication de solutions aqueuses de sels insatures d'ammonium quaternaire |
FR2824061B1 (fr) * | 2001-04-26 | 2004-03-05 | Atofina | Procede de fabrication du (meth) acrylate de 2-(dimethylamino)-1-(dimethylaminomethyl) ethyle |
GB0124967D0 (en) | 2001-10-17 | 2001-12-05 | Unilever Plc | Cosmetic and personal care compositions |
DE10301902A1 (de) * | 2003-01-17 | 2003-12-04 | Basf Ag | Verfahren zur Herstellung von (Meth)acrylsäureestern |
JP2006028080A (ja) * | 2004-07-15 | 2006-02-02 | Osaka Organic Chem Ind Ltd | (メタ)アクリル酸エステルの精製方法 |
WO2008076285A1 (en) * | 2006-12-14 | 2008-06-26 | Dsm Ip Assets B.V. | D1364 bt secondary coating on optical fiber |
KR101105116B1 (ko) * | 2006-12-14 | 2012-01-16 | 디에스엠 아이피 어셋츠 비.브이. | 광섬유에 대한 d1365 bj 선 경화성 1차 코팅 |
KR101155014B1 (ko) * | 2006-12-14 | 2012-06-11 | 디에스엠 아이피 어셋츠 비.브이. | 광섬유에 대한 d1378 ca 선 경화성 1차 코팅 |
ATE499331T1 (de) * | 2006-12-14 | 2011-03-15 | Dsm Ip Assets Bv | Strahlungshärtbare d1379-grundierbeschichtung für optische fasern |
EP2089334B1 (en) * | 2006-12-14 | 2011-06-01 | DSM IP Assets B.V. | D1369 d radiation curable secondary coating for optical fiber |
US8426020B2 (en) * | 2006-12-14 | 2013-04-23 | Dsm Ip Assets B.V. | D1381 supercoatings for optical fiber |
KR101105035B1 (ko) * | 2006-12-14 | 2012-01-16 | 디에스엠 아이피 어셋츠 비.브이. | 광섬유용 d1370 r 방사선 경화성 2차 코팅 |
KR101105053B1 (ko) * | 2006-12-14 | 2012-01-16 | 디에스엠 아이피 어셋츠 비.브이. | 광섬유용 d1368 cr 방사선 경화성 1차 코팅 |
EP2089333B1 (en) * | 2006-12-14 | 2011-02-16 | DSM IP Assets B.V. | D1363 bt radiation curable primary coatings on optical fiber |
WO2009047786A2 (en) * | 2007-06-18 | 2009-04-16 | Dai-Ichi Karkaria Limited | A pour point depressant polymer composition |
US9527224B2 (en) * | 2011-02-17 | 2016-12-27 | Xerox Corporation | Endless flexible members with a polymeric release agent for imaging devices |
US8344172B2 (en) | 2011-03-25 | 2013-01-01 | Stepan Company | Preparation of antiplasticizers for thermoplastic polyesters |
GB201119871D0 (en) | 2011-11-17 | 2011-12-28 | Davy Process Techn Ltd | Process |
GB201218078D0 (en) | 2012-10-09 | 2012-11-21 | Davy Process Techn Ltd | Process |
JP6424532B2 (ja) * | 2014-09-17 | 2018-11-21 | 東洋インキScホールディングス株式会社 | フルフリルメタクリレートの製造方法 |
US20160090348A1 (en) * | 2014-09-30 | 2016-03-31 | Basf Se | Preparation of c8-c24 alkyl (meth)acrylates |
WO2016071052A1 (de) * | 2014-11-05 | 2016-05-12 | Basf Se | Verfahren zur herstellung von c8-c22-alkyl(meth)acrylaten |
CN105467043B (zh) * | 2015-12-30 | 2018-08-07 | 大连谱尼测试科技有限公司 | 一种测定1,6-己二醇二丙烯酸酯含量的方法 |
CN110573489A (zh) * | 2017-04-26 | 2019-12-13 | 大阪有机化学工业株式会社 | 多官能丙烯酸酯的制造方法 |
TWI689491B (zh) * | 2018-10-24 | 2020-04-01 | 中國石油化學工業開發股份有限公司 | 鄰苯基苯氧烷基丙烯酸酯及其製備方法 |
CN109651136B (zh) * | 2018-12-10 | 2021-12-14 | 江苏华星新材料科技股份有限公司 | 一种酯交换合成三羟甲基丙烷三甲基丙烯酸酯和三羟甲基丙烷三丙烯酸酯的方法 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2396434A (en) * | 1944-07-19 | 1946-03-12 | Nasa | Acrylic esters of glycol monoethers |
US2883418A (en) * | 1953-11-14 | 1959-04-21 | Basf Ag | Acrylic acid ester production |
US3328439A (en) * | 1963-08-08 | 1967-06-27 | Mobil Oil Corp | Catalytic inter-esterification |
US3714234A (en) * | 1968-07-02 | 1973-01-30 | Rohm & Haas | Catalysts and esterification process |
US3642877A (en) * | 1968-12-27 | 1972-02-15 | Du Pont | Process for the preparation of dimethylaminoethyl methacrylate |
US3663569A (en) * | 1969-09-02 | 1972-05-16 | Atlas Chem Ind | Process for preparing cyclic carbonates from polyhydric alcohols |
US3686768A (en) * | 1971-06-30 | 1972-08-29 | Cedar Rapids Eng Co | Two-plane bore leveling device |
JPS52153913A (en) * | 1976-06-18 | 1977-12-21 | Nitto Chem Ind Co Ltd | Preparation of dimethylaminoethylmethacrylate |
US4112235A (en) * | 1976-10-28 | 1978-09-05 | Uop Inc. | Transesterification of carboxylic acids |
JPS5365816A (en) * | 1976-11-26 | 1978-06-12 | Nitto Chem Ind Co Ltd | Preparation of dimethylaminoethyl methacrylate |
JPS5441814A (en) * | 1977-09-02 | 1979-04-03 | Nitto Chem Ind Co Ltd | Preparation of acrylate or methacrylate |
US4229362A (en) * | 1979-04-16 | 1980-10-21 | The Dow Chemical Company | Esterification process |
JPS5671045A (en) * | 1979-11-15 | 1981-06-13 | Kureha Chem Ind Co Ltd | Preparation of allyl ester of aromatic dicarboxylic acid |
JPS57197245A (en) * | 1981-05-28 | 1982-12-03 | Mitsui Petrochem Ind Ltd | Tetrakis(3-(3,5-dibutyl-4-hydroxyphenyl) propionyloxymethyl)methane |
DE3126411A1 (de) * | 1981-07-04 | 1983-01-13 | Degussa Ag, 6000 Frankfurt | Verfahren zur herstellung von aromatischen glycidylestern |
JPS58170730A (ja) * | 1982-03-31 | 1983-10-07 | Mitsui Toatsu Chem Inc | アクリル酸又はメタアクリル酸エステルの製造方法 |
EP0164614B1 (en) * | 1984-05-21 | 1988-01-20 | Toagosei Chemical Industry Co., Ltd. | Process for the production of acrylic acid or methacrylic acid |
DE3423441A1 (de) * | 1984-06-26 | 1986-01-02 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung von estern der acryl- und methacrylsaeure durch umesterung |
JPH0679746B2 (ja) * | 1984-07-30 | 1994-10-12 | 昭和電線電纜株式会社 | 異形断面素線の撚合せ方法 |
CN85102522A (zh) * | 1985-04-10 | 1987-02-04 | 中国中文信息研究会汉字编码专业委员会 | 电脑型汉语拼音文字输入法 |
JPH0653711B2 (ja) * | 1986-02-24 | 1994-07-20 | 三井東圧化学株式会社 | アクリル酸またはメタクリル酸のアルキルアミノアルキルエステルの精製方法 |
DE3613875A1 (de) * | 1986-04-24 | 1987-10-29 | Basf Ag | Verfahren zur herstellung von polyester-polyolen |
JPH0747568B2 (ja) * | 1986-10-31 | 1995-05-24 | 三井東圧化学株式会社 | アクリル酸又はメタクリル酸のアルキルアミノアルキルエステルの製造方法 |
ATE94865T1 (de) * | 1987-02-13 | 1993-10-15 | Ciba Geigy Ag | Verfahren zur herstellung von tert.-alkylestern der bernsteinsaeure. |
JPH01265058A (ja) * | 1988-04-14 | 1989-10-23 | Yoshitomi Pharmaceut Ind Ltd | テトラキス〔3−(3,5−ジ第3級ブチル−4−ヒドロキシフェニル)プロピオニルオキシメチル〕メタンの製造方法 |
JPH0267264A (ja) * | 1988-09-01 | 1990-03-07 | Yoshitomi Pharmaceut Ind Ltd | ビス(2,2,6,6−テトラメチル−4−ピペリジノ)セバケートの製造方法 |
DE3836093A1 (de) * | 1988-10-22 | 1990-04-26 | Degussa | Verfahren zur herstellung von hochsiedenden acrylaten bzw. methacrylaten |
DE3904586A1 (de) * | 1989-02-16 | 1990-08-23 | Huels Chemische Werke Ag | Verfahren zur herstellung von dmt-zwischenprodukt bestimmter reinheit sowie dessen weiterverarbeitung zu reinst-dmt und/oder mittel- oder hochreiner terephthalsaeure |
JPH0341051A (ja) * | 1989-07-07 | 1991-02-21 | Idemitsu Petrochem Co Ltd | アクリル酸エステル又はメタクリル酸エステルの製造方法 |
JP2793045B2 (ja) * | 1990-08-10 | 1998-09-03 | 株式会社日本触媒 | アクリル酸またはメタクリル酸のアルキルアミノアルキルエステル及びその第4級塩の製造方法 |
AT394571B (de) * | 1991-01-10 | 1992-05-11 | Wimmer Theodor | Verfahren zur herstellung von fettsaeureestern kurzkettiger alkohole |
DE4317428C1 (de) * | 1993-05-26 | 1994-06-16 | Goldschmidt Ag Th | Verwendung von Katalysatoren auf Zinnbasis zur Umesterung von monomeren oder polymeren (Meth)acrylsäurealkylestern |
-
1993
- 1993-09-03 US US08/116,448 patent/US5498751A/en not_active Expired - Lifetime
-
1994
- 1994-07-27 TW TW083106864A patent/TW420660B/zh not_active IP Right Cessation
- 1994-08-12 DK DK94850135T patent/DK0646567T3/da active
- 1994-08-12 EP EP94850135A patent/EP0646567B1/en not_active Expired - Lifetime
- 1994-08-12 AT AT97201737T patent/ATE192427T1/de not_active IP Right Cessation
- 1994-08-12 DE DE69424320T patent/DE69424320T2/de not_active Expired - Fee Related
- 1994-08-12 DE DE69414516T patent/DE69414516T2/de not_active Expired - Lifetime
- 1994-08-12 EP EP99200490A patent/EP0930290B1/en not_active Expired - Lifetime
- 1994-08-12 EP EP97201737A patent/EP0799816B1/en not_active Expired - Lifetime
- 1994-08-12 ES ES97201737T patent/ES2146449T3/es not_active Expired - Lifetime
- 1994-08-12 DE DE69434318T patent/DE69434318T2/de not_active Expired - Fee Related
- 1994-08-12 AT AT99200490T patent/ATE292103T1/de not_active IP Right Cessation
- 1994-08-12 AT AT94850135T patent/ATE173246T1/de active
- 1994-08-12 ES ES94850135T patent/ES2127908T3/es not_active Expired - Lifetime
- 1994-09-05 JP JP23444894A patent/JP3853386B2/ja not_active Expired - Fee Related
-
1995
- 1995-06-07 US US08/473,188 patent/US5554785A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0930290B1 (en) | 2005-03-30 |
DE69434318D1 (de) | 2005-05-04 |
US5554785A (en) | 1996-09-10 |
ATE173246T1 (de) | 1998-11-15 |
DE69424320T2 (de) | 2000-09-14 |
DE69414516D1 (de) | 1998-12-17 |
EP0799816B1 (en) | 2000-05-03 |
JPH0782217A (ja) | 1995-03-28 |
EP0646567A2 (en) | 1995-04-05 |
TW420660B (en) | 2001-02-01 |
EP0930290A1 (en) | 1999-07-21 |
ATE292103T1 (de) | 2005-04-15 |
EP0646567A3 (en) | 1995-06-21 |
DE69424320D1 (de) | 2000-06-08 |
EP0646567B1 (en) | 1998-11-11 |
JP3853386B2 (ja) | 2006-12-06 |
DE69434318T2 (de) | 2006-01-26 |
ES2127908T3 (es) | 1999-05-01 |
DE69414516T2 (de) | 1999-07-15 |
DK0646567T3 (da) | 1999-07-26 |
EP0799816A1 (en) | 1997-10-08 |
ATE192427T1 (de) | 2000-05-15 |
US5498751A (en) | 1996-03-12 |
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Legal Events
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