ES2143316T3 - Procedimiento para la obtencion de elastomeros termoplasticos. - Google Patents

Procedimiento para la obtencion de elastomeros termoplasticos.

Info

Publication number
ES2143316T3
ES2143316T3 ES97930482T ES97930482T ES2143316T3 ES 2143316 T3 ES2143316 T3 ES 2143316T3 ES 97930482 T ES97930482 T ES 97930482T ES 97930482 T ES97930482 T ES 97930482T ES 2143316 T3 ES2143316 T3 ES 2143316T3
Authority
ES
Spain
Prior art keywords
charge
group
denotes
acceptor
donor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97930482T
Other languages
English (en)
Inventor
Starzewski Karl-Heinz A Ostoja
Warren Mark Kelly
Andreas Stumpf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19627064A external-priority patent/DE19627064C2/de
Priority claimed from DE19714058A external-priority patent/DE19714058A1/de
Application filed by Bayer AG filed Critical Bayer AG
Application granted granted Critical
Publication of ES2143316T3 publication Critical patent/ES2143316T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5018—Cycloaliphatic phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

SE PUEDEN SINTETIZAR ELASTOMEROS TERMOPLASTICOS MEDIANTE (CO)POLIMERIZACION DE MONOMEROS DEL GRUPO DE LAS AL OLEFINAS DE C 2 -C 8 , DE LAS DIOLEFINAS DE C 4 C 15 , ASI COMO DE OTROS MONOMEROS EN FASE SOLIDA, DISUELTA, PASTOSA O GASEOSA, UTILIZANDOSE COMO CATALIZADORES COMPUESTOS DE METALOCENO DE FORMULA (I) O COMPUESTOS DE COMPLEJO PI DE FORMULA (I) O (XIII), EN LA QUE CPL Y CPLL REPRESENTAN CARBANIONES CON UNA ESTRUCTURA QUE CONTIENE CICLOPENTADIENILO, PI I Y PI II REPRESENTAN SISTEMAS CARGADOS O ELECTRICAMENTE NEUTRALES DE PI , D ES UN ATOMO DONADOR Y A ES UN ATOMO ACEPTOR, ESTANDO UNIDOS D Y A MEDIANTE UN ENLACE COORDENADO REVERSIBLE DE TAL MANERA, QUE EL GRUPO DONADOR ACEPTA UNA CARGA (PARCIAL) POSITIVA Y EL GRUPO ACEPTOR ACEPTA UNA CARGA (PARCIAL) NEGATIVA, M ES UN METAL DE TRANSICION DE LOS GRUPOS SECUNDARIOS III., IV., V. O VI. DEL SISTEMA PERIODICO DE LOS ELEMENTOS (MENDELEJEW) INCLUYENDO LOS LANTANIDOS Y ACTINIDOS, X ES UN EQUIVALENTE ANIONICO Y N SEGUN LA CARGA DE M SIGNIFICA EL NUMERO CERO, UNO, DOS, TRES O CUATRO.
ES97930482T 1996-07-05 1997-07-02 Procedimiento para la obtencion de elastomeros termoplasticos. Expired - Lifetime ES2143316T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19627064A DE19627064C2 (de) 1996-07-05 1996-07-05 Metallocen-Verbindungen, Verfahren zu deren Herstellung, sowie ihre Verwendung
DE19714058A DE19714058A1 (de) 1997-04-05 1997-04-05 pi-Komplex-Verbindungen

Publications (1)

Publication Number Publication Date
ES2143316T3 true ES2143316T3 (es) 2000-05-01

Family

ID=26027225

Family Applications (5)

Application Number Title Priority Date Filing Date
ES97930480T Expired - Lifetime ES2146106T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de (co)polimeros de cicloolefina para aplicaciones tecnicas.
ES97933647T Expired - Lifetime ES2151740T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de (co)polimeros de cicloolefina para la aplicacion en memorias opticas de datos.
ES97929315T Expired - Lifetime ES2146103T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de elastomeros.
ES97930482T Expired - Lifetime ES2143316T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de elastomeros termoplasticos.
ES97930481T Expired - Lifetime ES2144871T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de poliolefinas de alto punto de fusion.

Family Applications Before (3)

Application Number Title Priority Date Filing Date
ES97930480T Expired - Lifetime ES2146106T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de (co)polimeros de cicloolefina para aplicaciones tecnicas.
ES97933647T Expired - Lifetime ES2151740T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de (co)polimeros de cicloolefina para la aplicacion en memorias opticas de datos.
ES97929315T Expired - Lifetime ES2146103T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de elastomeros.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES97930481T Expired - Lifetime ES2144871T3 (es) 1996-07-05 1997-07-02 Procedimiento para la obtencion de poliolefinas de alto punto de fusion.

Country Status (13)

Country Link
US (5) US6174974B1 (es)
EP (5) EP0909285B1 (es)
JP (5) JP2000514119A (es)
KR (1) KR20000022453A (es)
CN (5) CN1229417A (es)
AT (5) ATE192755T1 (es)
AU (5) AU3345697A (es)
CA (5) CA2259438C (es)
DE (5) DE59701657D1 (es)
ES (5) ES2146106T3 (es)
NO (5) NO985860L (es)
RU (3) RU2205189C2 (es)
WO (5) WO1998001484A1 (es)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19757218A1 (de) * 1997-12-22 1999-06-24 Bayer Ag Verfahren zur Herstellung von Elastomeren
DE19850898A1 (de) * 1998-11-05 2000-05-11 Bayer Ag Verfahren zur Herstellung von EP(D)M
EP1054914B1 (de) * 1998-12-12 2004-03-03 Basell Polyolefine GmbH Zwitterionische, neutrale übergansmetallverbindung
JP2000248015A (ja) * 1999-02-26 2000-09-12 Idemitsu Petrochem Co Ltd オレフィン−スチレン類共重合用触媒及びオレフィン−スチレン系共重合体の製造方法
DE19915108A1 (de) * 1999-04-01 2000-10-05 Bayer Ag Geträgerte Katalysatoren mit einer Donor-Akzeptor-Wechselwirkung
AU4996900A (en) 1999-06-04 2000-12-28 Dow Chemical Company, The Boron-substituted cyclopentadienes and metal complexes thereof
DE19927766A1 (de) * 1999-06-17 2000-12-21 Basf Ag Trägerkatalysator zur Olefinpolymerisation
US6756414B2 (en) * 1999-07-30 2004-06-29 Sanyo Chemical Industries, Ltd. Polymer polyol composition, process for producing the same, and process for producing polyurethane resin
MXPA02011811A (es) * 2000-05-31 2003-05-14 Du Pont Polimerizacion de olefinas.
JP2004512341A (ja) * 2000-10-24 2004-04-22 ダウ　グローバル　テクノロジーズ　インコーポレイティド 架橋イリド基を含む金属錯体
KR100417037B1 (ko) * 2000-12-22 2004-02-05 이동호 시클로올레핀 함량이 높고 물성이 우수한 시클로올레핀공중합체를 제조하는 방법
FR2820137B1 (fr) 2001-01-26 2005-12-23 Atofina Biphospholes pontes et metallocenes prepares a partir de ce ceux-ci
JP4895430B2 (ja) * 2001-03-22 2012-03-14 ルネサスエレクトロニクス株式会社 半導体装置及び半導体装置の製造方法
DE10114345A1 (de) 2001-03-23 2002-09-26 Bayer Ag Katalysator mit einer Donor-Akzeptor-Wechselwirkung
JP4238501B2 (ja) * 2001-04-27 2009-03-18 Ｊｓｒ株式会社 熱可塑性ノルボルネン系樹脂系光学用フィルム
JP3899511B2 (ja) * 2001-04-27 2007-03-28 Ｊｓｒ株式会社 熱可塑性ノルボルネン系樹脂系光学用フィルム
US6713582B2 (en) * 2001-12-14 2004-03-30 Uniroyal Chemical Company, Inc. Process for the oligomerization of α-olefins having low unsaturation, the resulting polymers, and lubricants containing same
JP4178810B2 (ja) * 2001-12-25 2008-11-12 Ｊｓｒ株式会社 熱可塑性ノルボルネン系樹脂系光学用フィルム
DE10244214A1 (de) * 2002-09-23 2004-04-01 Bayer Ag Übergangsmetallverbindungen mit Donor-Akzeptor-Wechselwirkung und speziellem Substitutionsmuster
DE10244213A1 (de) * 2002-09-23 2004-04-01 Bayer Ag Verfahren zur Herstellung von Homo-, Copolymeren und/oder Blockcopolymeren mit Metallocenen mit einer Donor-Akzeptor-Wechselwirkung nach der lebenden Polymerisation
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
CA2499951C (en) * 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
EP1422249A1 (en) * 2002-11-20 2004-05-26 ATOFINA Research New metallocene catalyst system
SG108945A1 (en) * 2003-01-20 2005-02-28 Sumitomo Chemical Co Metal compound, and catalyst component and catalyst for addition polymerization, and process for producing addition polymer
GB0314220D0 (en) * 2003-06-19 2003-07-23 Univ Durham Bifunctional catalyst
JP2005302605A (ja) * 2004-04-14 2005-10-27 Canon Inc 半導体装置
WO2005108410A1 (en) * 2004-04-23 2005-11-17 Exxonmobil Chemical Patents Inc. Phosphorus substituted metallocene compounds for olefin polymerization
US7214746B2 (en) * 2004-04-23 2007-05-08 Exxonmobil Chemical Patents Inc. Phosphorus bridged metallocene compounds for olefin polymerization
KR20070015453A (ko) * 2004-05-11 2007-02-02 닛토덴코 가부시키가이샤 편광자 보호 필름, 편광판 및 화상 표시 장치
US20070211334A1 (en) * 2004-05-11 2007-09-13 Nitto Denko Corporation Polarizer protective film, polarizing plate and image display
EP1908784B1 (en) * 2005-06-30 2018-10-10 Mitsui Chemicals, Inc. Process for producing cycloolefinic resin composition, and cycloolefinic resin composition
US8445594B2 (en) 2006-05-02 2013-05-21 Dow Global Technologies Llc High-density polyethylene compositions, method of making the same, articles made therefrom, and method of making such articles
JP2008031319A (ja) * 2006-07-28 2008-02-14 Fujifilm Corp ノルボルネン系重合体、フィルム、偏光板および液晶表示装置
EP1894938A1 (en) 2006-08-31 2008-03-05 Evonik Degussa GmbH New cyclopentadienyl, indenyl or fluorenyl substituted phosphine compounds and their use in catalytic reactions
FR2917381B1 (fr) * 2007-06-15 2009-10-16 Ceva Sante Animale Sa Conditionnement plastique multicouche pour la conservation d'une composition pharmaceutique
CN101139428B (zh) * 2007-08-23 2010-06-09 南京红宝丽股份有限公司 利用小桐子油制备聚氨酯泡沫塑料的方法
JP5022973B2 (ja) * 2008-04-02 2012-09-12 三菱レイヨン株式会社 重合体及びその製造方法
CN106008777B (zh) * 2016-06-20 2018-12-11 安徽欧凯密封件有限公司 一种稀土催化体系制备三元乙丙橡胶的方法
JP6418227B2 (ja) * 2016-12-26 2018-11-07 宇部興産株式会社 共役ジエンの重合用触媒溶液及びそれを用いた重合方法
JP7002310B2 (ja) 2017-12-05 2022-02-04 株式会社ブリヂストン 多元共重合体の製造方法
CN110105636B (zh) * 2019-06-06 2021-07-16 江苏通用科技股份有限公司 一种自修复胎面胶的制备方法
FR3104585B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Système catalytique à base d’un métallocène et d’un diorganomagnésien
JP7175426B2 (ja) * 2020-07-31 2022-11-18 ポリプラスチックス株式会社 環状オレフィン共重合体の製造方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5580939A (en) 1983-06-06 1996-12-03 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
US5567776A (en) * 1992-05-26 1996-10-22 Mitsui Petrochemical Industries, Ltd. Cycloolefin copolymer composition and method for the preperation thereof
IT1256403B (it) * 1992-08-18 1995-12-05 Montecatini Tecnologie Srl Componenti e catalizzatori a base di vanadio per la polimerizzazione di olefine,e processi di polimerizzazione impieganti gli stessi
DE59402624D1 (de) * 1993-02-12 1997-06-12 Hoechst Ag Verfahren zur Herstellung von Cycloolefincopolymeren
TW369545B (en) 1993-02-12 1999-09-11 Hoechst Ag Process for preparing cycloolefin copolymers
GB9304521D0 (en) 1993-03-05 1993-04-21 Exxon Chemical Patents Inc Improved alumoxane,method for its preparation and polymerisation process using such alumoxane
FR2703049B1 (fr) 1993-03-22 1995-04-21 Rhone Poulenc Rorer Sa Procédé de purification des taxoïdes.
EP0636593B1 (en) 1993-07-27 1998-09-30 Ngk Insulators, Ltd. Zirconia diaphragm structure, method of producing the same, and piezoelectric/ electro-strictive film element having the zirconia diaphragm structure
EP0638593A1 (en) 1993-08-02 1995-02-15 Shell Internationale Researchmaatschappij B.V. Catalyst compositions
DE4420456A1 (de) 1994-06-13 1995-12-14 Hoechst Ag Übergangsmetallverbindung
MY112177A (en) * 1994-09-30 2001-04-30 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
EP0709393A3 (en) * 1994-10-25 2003-04-16 Tosoh Corporation Olefin polymerization catalyst and process for producing olefin polymer

Also Published As

Publication number Publication date
DE59701656D1 (de) 2000-06-15
ES2146106T3 (es) 2000-07-16
NO319759B1 (no) 2005-09-12
NO318243B1 (no) 2005-02-21
WO1998001483A1 (de) 1998-01-15
CA2259435C (en) 2006-01-24
CA2259435A1 (en) 1998-01-15
ES2144871T3 (es) 2000-06-16
CA2259553A1 (en) 1998-01-15
EP0909283B1 (de) 2000-03-15
EP0909283A1 (de) 1999-04-21
RU2203290C2 (ru) 2003-04-27
ES2151740T3 (es) 2001-01-01
US6191241B1 (en) 2001-02-20
CN1229415A (zh) 1999-09-22
EP0909284B1 (de) 2000-02-02
EP0909285B1 (de) 2000-10-04
NO990013D0 (no) 1999-01-04
CA2259438C (en) 2006-01-24
AU3692797A (en) 1998-02-02
ATE190632T1 (de) 2000-04-15
NO990014L (no) 1999-01-04
JP2000514119A (ja) 2000-10-24
AU3345697A (en) 1998-02-02
US6232413B1 (en) 2001-05-15
EP0909284A1 (de) 1999-04-21
EP0909281A1 (de) 1999-04-21
DE59701269D1 (de) 2000-04-20
DE59702429D1 (de) 2000-11-09
EP0909281B1 (de) 2000-05-10
AU3441497A (en) 1998-02-02
WO1998001484A1 (de) 1998-01-15
US6174974B1 (en) 2001-01-16
AU3441697A (en) 1998-02-02
CN1229417A (zh) 1999-09-22
JP2000514118A (ja) 2000-10-24
NO985860L (no) 1999-02-15
EP0909285A1 (de) 1999-04-21
RU2203288C2 (ru) 2003-04-27
NO990015L (no) 1999-01-04
NO990017L (no) 1999-02-15
JP2000514116A (ja) 2000-10-24
ATE192756T1 (de) 2000-05-15
KR20000022453A (ko) 2000-04-25
ES2146103T3 (es) 2000-07-16
CN1100799C (zh) 2003-02-05
US6156857A (en) 2000-12-05
NO990014D0 (no) 1999-01-04
ATE192755T1 (de) 2000-05-15
CN1229418A (zh) 1999-09-22
EP0909282B1 (de) 2000-05-10
WO1998001485A1 (de) 1998-01-15
RU2205189C2 (ru) 2003-05-27
NO318242B1 (no) 2005-02-21
NO990015D0 (no) 1999-01-04
CA2259438A1 (en) 1998-01-15
DE59701094D1 (de) 2000-03-09
CN1097059C (zh) 2002-12-25
JP2000514117A (ja) 2000-10-24
CN1228790A (zh) 1999-09-15
EP0909282A1 (de) 1999-04-21
CN1229416A (zh) 1999-09-22
ATE196771T1 (de) 2000-10-15
DE59701657D1 (de) 2000-06-15
CA2259422A1 (en) 1998-01-15
NO985860D0 (no) 1998-12-14
WO1998001487A1 (de) 1998-01-15
NO990013L (no) 1999-03-02
NO990017D0 (no) 1999-01-04
CA2259434C (en) 2006-01-24
AU3441597A (en) 1998-02-02
CN1105118C (zh) 2003-04-09
CN1097060C (zh) 2002-12-25
ATE189465T1 (de) 2000-02-15
CA2259434A1 (en) 1998-01-15
WO1998001486A1 (de) 1998-01-15
JP2000514120A (ja) 2000-10-24
US6172169B1 (en) 2001-01-09

Similar Documents

Publication Publication Date Title
ES2143316T3 (es) Procedimiento para la obtencion de elastomeros termoplasticos.
DE59706978D1 (de) Metallocen-verbindungen
NO971461L (no) Substituerte indenyl ikke-brodannede metallocener
ATE133984T1 (de) Random-cycloolefin-kopolymerzusammensetzung
NO176188C (no) Gjenstand for beskyttelse av et substrat
FR2477165B1 (fr) Compositions de polymeres a base d'un copolymere ethylene/a-olefine et d'un polymere d'ethylene
NO176964C (no) Metall-koordinasjonskomplekser, fremgangsmåte for fremstilling, samt anvendelse
ATE135731T1 (de) Elastomerzusammensetzung die elastomer und amorphes propylene/hexene copolymer enthält
MY104251A (en) Optical recording media
YU146691A (sh) Katalitička kompozicija za polimerizaciju alfa-olefina
ATE203255T1 (de) Auf organopolysiloxanmikrogelpartikeln immobilisierte organoaluminiumverbindungen
MY104252A (en) Optical recording media.
IT1132915B (it) Procedimento per la produzione di gomme di copolimeri olefinici
MX9710321A (es) Metalocenos, su preparacion y uso en la polimerizacion de alfa-olefinas.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 909284

Country of ref document: ES