ES2113343T3 - Procedimiento para la preparacion de polimeros de cicloolefinas. - Google Patents

Procedimiento para la preparacion de polimeros de cicloolefinas.

Info

Publication number
ES2113343T3
ES2113343T3 ES90112732T ES90112732T ES2113343T3 ES 2113343 T3 ES2113343 T3 ES 2113343T3 ES 90112732 T ES90112732 T ES 90112732T ES 90112732 T ES90112732 T ES 90112732T ES 2113343 T3 ES2113343 T3 ES 2113343T3
Authority
ES
Spain
Prior art keywords
procedure
preparation
polymerized
polymerization
cycloolefin polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90112732T
Other languages
English (en)
Inventor
Michael-Joachim Dr Brekner
Jurgen Dr Rohrmann
Walter Dr Spaleck
Martin Dr Antberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ticona GmbH
Original Assignee
Ticona GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ticona GmbH filed Critical Ticona GmbH
Application granted granted Critical
Publication of ES2113343T3 publication Critical patent/ES2113343T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F32/08—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having two condensed rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

EL INVENTO SE REFIERE A UN POLIMERIZADO DE OLEFINA POLICICLICO, QUE PRESENTA LAS FORMULA DE (I) A (IV). TIENE UN INDICE DE VISCOSIDAD MAYOR NDE 20 CM 3/G Y UNA TEMPERATURA PORQUE SE PRODUCE EL POLIMERIZADO SIN APERTTURA DEL ANILLO, CON UNA GRAN VELOCIDAD DE POLIMERIZACION, CON UNA BUENA TEMPERATURA DE POLIMERIZACION Y MEDIANTE UN CATALIZADOR QUE CONSISTE EN UN ALUMINOXANO Y EN UN COMPLEJO METALICO, QUIRAL Y ESTEREORIGIDO PERTENECIENTE AL GRUPO IVV A VIB DEL SISTEMA PERIODICO DE ELEMENTOS.-
ES90112732T 1989-07-08 1990-07-04 Procedimiento para la preparacion de polimeros de cicloolefinas. Expired - Lifetime ES2113343T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3922546A DE3922546A1 (de) 1989-07-08 1989-07-08 Verfahren zur herstellung von cycloolefinpolymeren

Publications (1)

Publication Number Publication Date
ES2113343T3 true ES2113343T3 (es) 1998-05-01

Family

ID=6384606

Family Applications (3)

Application Number Title Priority Date Filing Date
ES95115275T Expired - Lifetime ES2157280T3 (es) 1989-07-08 1990-07-04 Proceso para la preparacion de polimeros de cicloolefinas.
ES90112732T Expired - Lifetime ES2113343T3 (es) 1989-07-08 1990-07-04 Procedimiento para la preparacion de polimeros de cicloolefinas.
ES97108175T Expired - Lifetime ES2192238T3 (es) 1989-07-08 1990-07-04 Proceso para la preparacion de polimeros cicloolefinicos.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES95115275T Expired - Lifetime ES2157280T3 (es) 1989-07-08 1990-07-04 Proceso para la preparacion de polimeros de cicloolefinas.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES97108175T Expired - Lifetime ES2192238T3 (es) 1989-07-08 1990-07-04 Proceso para la preparacion de polimeros cicloolefinicos.

Country Status (8)

Country Link
US (1) US5087677A (es)
EP (4) EP0407870B1 (es)
JP (4) JP3154999B2 (es)
AU (1) AU622337B2 (es)
CA (1) CA2020640C (es)
DE (4) DE3922546A1 (es)
ES (3) ES2157280T3 (es)
ZA (1) ZA905308B (es)

Families Citing this family (229)

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JP3154999B2 (ja) 2001-04-09
EP0690078B1 (de) 2001-03-21
EP0773242A3 (de) 1998-03-11
EP0773242A2 (de) 1997-05-14
EP0690078A1 (de) 1996-01-03
JPH11315124A (ja) 1999-11-16
JP3334106B2 (ja) 2002-10-15
CA2020640A1 (en) 1991-01-09
EP0791611B1 (de) 2003-02-12
AU5872290A (en) 1991-01-10
EP0407870B1 (de) 1997-12-10
EP0791611A2 (de) 1997-08-27
ZA905308B (en) 1991-04-24
JPH0345612A (ja) 1991-02-27
EP0791611A3 (de) 1998-04-29
DE3922546A1 (de) 1991-01-17
JP2002348324A (ja) 2002-12-04
ES2192238T3 (es) 2003-10-01
DE59010777D1 (de) 1998-01-22
DE59010920D1 (de) 2001-04-26
US5087677A (en) 1992-02-11
CA2020640C (en) 2005-02-08
JP2001270915A (ja) 2001-10-02
ES2157280T3 (es) 2001-08-16
DE59010932D1 (de) 2003-03-20
EP0407870A3 (en) 1991-06-26
JP3332368B2 (ja) 2002-10-07
EP0407870A2 (de) 1991-01-16
AU622337B2 (en) 1992-04-02

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