ES2107559T3 - Procedimiento para la sintesis de silico-alumino-fosfatos microporosos cristalinos. - Google Patents

Procedimiento para la sintesis de silico-alumino-fosfatos microporosos cristalinos.

Info

Publication number
ES2107559T3
ES2107559T3 ES92924936T ES92924936T ES2107559T3 ES 2107559 T3 ES2107559 T3 ES 2107559T3 ES 92924936 T ES92924936 T ES 92924936T ES 92924936 T ES92924936 T ES 92924936T ES 2107559 T3 ES2107559 T3 ES 2107559T3
Authority
ES
Spain
Prior art keywords
alumino
silico
synthesis
procedure
phosphates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92924936T
Other languages
English (en)
Inventor
Steinar Kvisle
Rune Wendelbo
Hanne Oren
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Norsk Hydro ASA
Original Assignee
Norsk Hydro ASA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Norsk Hydro ASA filed Critical Norsk Hydro ASA
Application granted granted Critical
Publication of ES2107559T3 publication Critical patent/ES2107559T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates (SAPO compounds), e.g. CoSAPO
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates (SAPO compounds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/30—Alpo and sapo

Abstract

LA APLICACION CONCIERNE A UN METODO MEJORADO DE PRODUCIR CATALIZADORES DE SILICO-ALUMINO-FOSFATO PARA LA CONVERSION DE METANOL EN OLEFINAS LIGERAS TALES COMO ETILENO Y PROPILENO (LA REACCION MTO). EL METODO MEJORADO DE SINTESIS SE PUEDE USAR PARA CONTROL DE LA COMPOSICION QUIMICA DE SILICO-ALUMINO-FOSFATOS, ESPECIALMENTE EL CONTENIDO EN SILICONA. EN PARTICULAR, SE HA DESCUBIERTO QUE SE PUEDEN SINTETIZAR CATALIZADORES QUE SON MAS ESTABLES A DESACTIVACION POR "CARBONIZACION", LO CUAL ES MUY IMPORTANTE PARA EL DISEÑO DE UN PROCESO MTO BASADO EN LOS SILICO-ALUMINO-FOSFATOS SINTETIZADOS.
ES92924936T 1991-12-23 1992-12-09 Procedimiento para la sintesis de silico-alumino-fosfatos microporosos cristalinos. Expired - Lifetime ES2107559T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NO19915080A NO174341B1 (no) 1991-12-23 1991-12-23 Fremg for fremst av krystallinske mikroporose SiAl-fosfater med kontrollert Si-innh, krystallinske mikroporose SiAl-fosfater med forbedret stabilitet mot deaktivering og en anv av disse ved fremstilling av olefiner fra metanol

Publications (1)

Publication Number Publication Date
ES2107559T3 true ES2107559T3 (es) 1997-12-01

Family

ID=19894708

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92924936T Expired - Lifetime ES2107559T3 (es) 1991-12-23 1992-12-09 Procedimiento para la sintesis de silico-alumino-fosfatos microporosos cristalinos.

Country Status (11)

Country Link
US (1) US5663471A (es)
EP (1) EP0619800B1 (es)
JP (1) JP2562863B2 (es)
AU (1) AU666691B2 (es)
CA (1) CA2126575C (es)
DE (1) DE69221638T2 (es)
ES (1) ES2107559T3 (es)
NO (1) NO174341B1 (es)
NZ (1) NZ246097A (es)
RU (1) RU2091305C1 (es)
WO (1) WO1993013013A1 (es)

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NO300012B1 (no) * 1993-08-17 1997-03-17 Polymers Holding As Mikroporost krystallinsk silikoaluminofosfat, fremgangsmate for fremstilling av dette, samt anvendelse derav
US5817906A (en) * 1995-08-10 1998-10-06 Uop Llc Process for producing light olefins using reaction with distillation as an intermediate step
US5714662A (en) * 1995-08-10 1998-02-03 Uop Process for producing light olefins from crude methanol
US5990369A (en) * 1995-08-10 1999-11-23 Uop Llc Process for producing light olefins
US5744680A (en) * 1995-08-10 1998-04-28 Uop Process for producing light olefins
NO311208B1 (no) * 1996-03-13 2001-10-29 Norsk Hydro As Mikroporös krystallinsk metallofosfatforbindelse, en fremgangsmåte for fremstilling av forbindelsen og anvendelse derav
NO310106B1 (no) * 1996-03-13 2001-05-21 Norsk Hydro As Mikroporöse, krystallinske metallofosfatforbindelser, en fremgangsmåte for fremstilling og anvendelse derav
US6040264A (en) * 1996-04-04 2000-03-21 Exxon Chemical Patents Inc. Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion
US6436869B1 (en) 1996-05-29 2002-08-20 Exxonmobil Chemical Patents Inc. Iron, cobalt and/or nickel containing ALPO bound SAPO molecular sieve catalyst for producing olefins
US5849258A (en) * 1996-06-06 1998-12-15 Intevep, S.A. Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same
US6002057A (en) * 1996-09-06 1999-12-14 Exxon Chemical Patents Inc. Alkylation process using zeolite beta
NO304108B1 (no) 1996-10-09 1998-10-26 Polymers Holding As En mikroporos silikoaluminofosfat-sammensetning, katalytisk materiale som omfatter denne sammensetningen og fremgangsmate for fremstilling derav, og bruken av disse for a fremstille olefiner fra metanol
RO114524B1 (ro) 1997-10-02 1999-05-28 Sc Zecasin Sa Procedeu de fabricare a oleofinelor cu greutate moleculara mica prin conversia catalitica in strat fluidizat a metanolului
US6162415A (en) * 1997-10-14 2000-12-19 Exxon Chemical Patents Inc. Synthesis of SAPO-44
JP4168214B2 (ja) 1998-10-15 2008-10-22 三菱瓦斯化学株式会社 メチルアミン製造触媒及び該触媒の製造方法
US6051745A (en) * 1999-03-04 2000-04-18 Phillips Petroleum Company Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins
US6046371A (en) * 1999-05-05 2000-04-04 Phillips Petroleum Company Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins
US6316683B1 (en) * 1999-06-07 2001-11-13 Exxonmobil Chemical Patents Inc. Protecting catalytic activity of a SAPO molecular sieve
US6559428B2 (en) * 2001-01-16 2003-05-06 General Electric Company Induction heating tool
US6437208B1 (en) 1999-09-29 2002-08-20 Exxonmobil Chemical Patents Inc. Making an olefin product from an oxygenate
WO2001025150A1 (en) 1999-10-01 2001-04-12 Pop, Grigore Process for the synthesis of silicoaluminophosphate molecular sieves
WO2001060746A1 (en) 2000-02-16 2001-08-23 Exxonmobil Chemical Patents Inc. Treatment of molecular sieves with silicon containing compounds
US6531639B1 (en) 2000-02-18 2003-03-11 Exxonmobil Chemical Patents, Inc. Catalytic production of olefins at high methanol partial pressures
US6743747B1 (en) 2000-02-24 2004-06-01 Exxonmobil Chemical Patents Inc. Catalyst pretreatment in an oxgenate to olefins reaction system
US6303839B1 (en) 2000-06-14 2001-10-16 Uop Llc Process for producing polymer grade olefins
US6953767B2 (en) 2001-03-01 2005-10-11 Exxonmobil Chemical Patents Inc. Silicoaluminophosphate molecular sieve
WO2003004444A1 (en) 2001-07-02 2003-01-16 Exxonmobil Chemical Patents Inc. Inhibiting catalyst coke formation in the manufacture of an olefin
JP5485505B2 (ja) * 2001-10-11 2014-05-07 三菱樹脂株式会社 ゼオライト、及び該ゼオライトを含む水蒸気吸着材
US6696032B2 (en) 2001-11-29 2004-02-24 Exxonmobil Chemical Patents Inc. Process for manufacturing a silicoaluminophosphate molecular sieve
US6872680B2 (en) 2002-03-20 2005-03-29 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7271123B2 (en) 2002-03-20 2007-09-18 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion process
US6793901B2 (en) * 2002-06-12 2004-09-21 Exxonmobil Chemical Patents, Inc. Synthesis of molecular sieves having the CHA framework type
US6897179B2 (en) * 2003-06-13 2005-05-24 Exxonmobil Chemical Patents Inc. Method of protecting SAPO molecular sieve from loss of catalytic activity
US7015174B2 (en) * 2003-06-20 2006-03-21 Exxonmobil Chemical Patents Inc. Maintaining molecular sieve catalytic activity under water vapor conditions
US7199277B2 (en) * 2004-07-01 2007-04-03 Exxonmobil Chemical Patents Inc. Pretreating a catalyst containing molecular sieve and active metal oxide
US20070059236A1 (en) * 2005-09-09 2007-03-15 Broach Robert W Molecular sieves with high selectivity towards light olefins in methanol to olefin conversion
EA010151B1 (ru) * 2006-03-22 2008-06-30 Генрих Семёнович Фалькевич Способ очистки углеводородных смесей от метанола
JP5756461B2 (ja) 2009-06-12 2015-07-29 アルベマール・ユーロプ・エスピーアールエル Ｓａｐｏ分子篩触媒と、その調製および使用
KR101161845B1 (ko) 2010-04-26 2012-07-03 송원산업 주식회사 알켄 화합물의 제조 방법
CN103771437B (zh) * 2012-10-26 2016-01-13 中国石油化工股份有限公司 一种含磷的改性β分子筛
US9211530B2 (en) 2012-12-14 2015-12-15 Uop Llc Low silicon SAPO-42 and method of making
CN107074571B (zh) 2014-08-22 2022-09-27 格雷斯公司 使用一异丙醇胺合成磷酸硅铝-34分子筛的方法

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US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4677242A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins
US4673559A (en) * 1983-12-19 1987-06-16 Mobil Oil Corporation Silicoaluminophosphate crystallization using hydrolysis
US5158665A (en) * 1988-02-12 1992-10-27 Chevron Research And Technology Company Synthesis of a crystalline silicoaluminophosphate
FR2645141B1 (fr) * 1989-03-31 1992-05-29 Elf France Procede de synthese de precurseurs de tamis moleculaires du type silicoaluminophosphate, precurseurs obtenus et leur application a l'obtention desdits tamis moleculaires
SG48303A1 (en) * 1992-05-27 1998-04-17 Exon Chemicals Patents Inc Acid extracted molecular sieve catalysts to improve ethylene yield

Also Published As

Publication number Publication date
EP0619800B1 (en) 1997-08-13
NO915080A (no) 1993-06-24
RU94031164A (ru) 1996-05-27
DE69221638D1 (de) 1997-09-18
EP0619800A1 (en) 1994-10-19
NO174341B1 (no) 1994-04-21
NZ246097A (en) 1996-01-26
CA2126575C (en) 2004-06-22
US5663471A (en) 1997-09-02
NO174341C (no) 1994-04-20
AU3097292A (en) 1993-07-28
NO174341B (no) 1994-01-10
AU666691B2 (en) 1996-02-22
RU2091305C1 (ru) 1997-09-27
JPH07502250A (ja) 1995-03-09
WO1993013013A1 (en) 1993-07-08
CA2126575A1 (en) 1993-07-08
JP2562863B2 (ja) 1996-12-11
DE69221638T2 (de) 1998-02-26
NO915080D0 (no) 1991-12-23

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