MX167391B - Procedimiento catalitico para la produccion de alcoholes a partir de monoxido de carbono, hidrogeno y olefinas - Google Patents

Procedimiento catalitico para la produccion de alcoholes a partir de monoxido de carbono, hidrogeno y olefinas

Info

Publication number
MX167391B
MX167391B MX203912A MX20391284A MX167391B MX 167391 B MX167391 B MX 167391B MX 203912 A MX203912 A MX 203912A MX 20391284 A MX20391284 A MX 20391284A MX 167391 B MX167391 B MX 167391B
Authority
MX
Mexico
Prior art keywords
alcohols
hydrogen
carbon monoxide
olefins
production
Prior art date
Application number
MX203912A
Other languages
English (en)
Inventor
Nancy Ellen Kinkade
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of MX167391B publication Critical patent/MX167391B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a procedimiento catalítico para la producción de alcoholes a partir de monóxido de carbono, hidrógeno y olefinas, en donde los alcoholes son alcoholes de Cn+1 siendo n un entero positivo no menor de 2; caracterizado porque consiste en hacer reaccionar en la fase de vapor una alimentación de gas de por lo menos una olefina de Cn con monóxido de carbono e hidrógeno, en presencia de un catalizador sólido que consiste esencialmente de sulfuro de molibdeno y un compuesto alcalino que se selecciona del grupo que consiste de compuestos de metal alcalino y de metal alcalinotérreo y mezclas de los mismos, siendo la velocidad espacial en horas, del gas de reacción desde aproximadamente 1,000 hasta aproximadamente 24,000 horas -1.
MX203912A 1983-12-30 1984-12-28 Procedimiento catalitico para la produccion de alcoholes a partir de monoxido de carbono, hidrogeno y olefinas MX167391B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US56724483A 1983-12-30 1983-12-30
US06/671,886 US4590314A (en) 1983-12-30 1984-11-19 Catalytic process for the production of alcohols from carbon monoxide, hydrogen and olefins

Publications (1)

Publication Number Publication Date
MX167391B true MX167391B (es) 1993-03-19

Family

ID=27074411

Family Applications (1)

Application Number Title Priority Date Filing Date
MX203912A MX167391B (es) 1983-12-30 1984-12-28 Procedimiento catalitico para la produccion de alcoholes a partir de monoxido de carbono, hidrogeno y olefinas

Country Status (11)

Country Link
US (1) US4590314A (es)
EP (1) EP0149256B1 (es)
KR (1) KR890001914B1 (es)
AU (1) AU575899B2 (es)
BR (1) BR8407252A (es)
CA (1) CA1321604C (es)
DE (1) DE3467569D1 (es)
MX (1) MX167391B (es)
NZ (1) NZ210766A (es)
WO (1) WO1985003074A1 (es)
YU (1) YU585A (es)

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US4675344A (en) * 1984-07-30 1987-06-23 The Dow Chemical Company Method for adjusting methanol to higher alcohol ratios
US4752622A (en) * 1984-07-30 1988-06-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4882360A (en) * 1984-07-30 1989-11-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4831060A (en) * 1984-07-30 1989-05-16 The Dow Chemical Company Mixed alcohols production from syngas
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
US5068469A (en) * 1990-02-07 1991-11-26 Exxon Chemical Patents Inc. Process for preparation of condensed alcohols by alkoxide catalysts
US5082977A (en) * 1990-02-15 1992-01-21 University Of Akron Aldehydes by olefin hydroformylation
US6982355B2 (en) * 2003-08-25 2006-01-03 Syntroleum Corporation Integrated Fischer-Tropsch process for production of linear and branched alcohols and olefins
US20090156697A1 (en) * 2007-12-14 2009-06-18 Range Fuels, Inc. Catalyst compositions and methods for alcohol production from synthesis gas
US7955588B2 (en) * 2009-05-26 2011-06-07 Conocophillips Company Metal sulfide catalysts and methods of making same
US8604254B2 (en) 2009-11-11 2013-12-10 Dow Global Technologies Llc Reductive hydroformylation of an alkylene to an alkanol
US8999876B2 (en) 2010-12-06 2015-04-07 Georgia Tech Research Corporation Carbon-supported catalysts for production of higher alcohols from syngas
BR112013011294B1 (pt) 2010-12-06 2021-12-21 Georgia Tech Research Corporation Composição de catalisador e processo para preparar um álcool superior
WO2012087687A1 (en) 2010-12-21 2012-06-28 Dow Global Technologies Llc Three step syngas to propylene including an intermediate conversion of byproduct ethane to propanol followed by propanol dehydration process
US8815963B1 (en) 2013-11-04 2014-08-26 Auxilium Green, LLC Catalyst composition formulated for synthesis of alcohols and method of preparing the same
US10316254B2 (en) * 2014-10-31 2019-06-11 The Board Of Regents Of The University Of Texas System Hydrothermal synthesis of alkali promoted MOS2-based catalyst
US9963357B2 (en) * 2015-02-23 2018-05-08 Khalifa University of Science and Technology MoS2 foam

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Also Published As

Publication number Publication date
BR8407252A (pt) 1985-12-24
US4590314A (en) 1986-05-20
AU3783185A (en) 1985-07-30
KR890001914B1 (ko) 1989-05-31
WO1985003074A1 (en) 1985-07-18
KR850700132A (ko) 1985-10-25
NZ210766A (en) 1988-07-28
EP0149256A3 (en) 1985-08-07
YU585A (en) 1987-04-30
DE3467569D1 (en) 1987-12-23
EP0149256A2 (en) 1985-07-24
CA1321604C (en) 1993-08-24
EP0149256B1 (en) 1987-11-19
AU575899B2 (en) 1988-08-11

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