FR2369234A1 - Procede de fabrication d'alc - Google Patents

Procede de fabrication d'alc

Info

Publication number
FR2369234A1
FR2369234A1 FR7633046A FR7633046A FR2369234A1 FR 2369234 A1 FR2369234 A1 FR 2369234A1 FR 7633046 A FR7633046 A FR 7633046A FR 7633046 A FR7633046 A FR 7633046A FR 2369234 A1 FR2369234 A1 FR 2369234A1
Authority
FR
France
Prior art keywords
manufacturing process
alc manufacturing
alcohols
alc
vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7633046A
Other languages
English (en)
Other versions
FR2369234B1 (fr
Inventor
Andre Sugier
Edouard Freund
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7633046A priority Critical patent/FR2369234A1/fr
Priority to DE19772748097 priority patent/DE2748097C3/de
Priority to US05/846,486 priority patent/US4122110A/en
Priority to ZA00776429A priority patent/ZA776429B/xx
Priority to GB45035/77A priority patent/GB1547687A/en
Priority to PL1977201802A priority patent/PL107649B1/pl
Priority to AU30172/77A priority patent/AU508915B2/en
Publication of FR2369234A1 publication Critical patent/FR2369234A1/fr
Priority to FR8107968A priority patent/FR2504124A2/fr
Priority to FR8110192A priority patent/FR2506298A2/fr
Application granted granted Critical
Publication of FR2369234B1 publication Critical patent/FR2369234B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847—Vanadium, niobium or tantalum or polonium
    • B01J23/8472—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Procédé de fabrication d'alcools par réaction d'hydrogène avec le monoxyde de carbone. On opère en présence d'un catalyseur contenant du cuivre, du cobalt, un metal alcalin et un metal choisi dans le groupe : chrome, fer, vanadium et manganèse. On obtient préférentiellement des alcools primaires saturés linéaires.
FR7633046A 1976-10-29 1976-10-29 Procede de fabrication d'alc Granted FR2369234A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR7633046A FR2369234A1 (fr) 1976-10-29 1976-10-29 Procede de fabrication d'alc
DE19772748097 DE2748097C3 (de) 1976-10-29 1977-10-27 Verfahren zur herstellung von primaeren, gesaettigten und geradkettigen alkoholen
ZA00776429A ZA776429B (en) 1976-10-29 1977-10-28 Process for manufacturing alcohols,particularly linear saturated primary alcohols,from synthesis gas
GB45035/77A GB1547687A (en) 1976-10-29 1977-10-28 Catalytic production of oranic alcohols from synthesis gas
US05/846,486 US4122110A (en) 1976-10-29 1977-10-28 Process for manufacturing alcohols, particularly linear saturated primary alcohols, from synthesis gas
PL1977201802A PL107649B1 (pl) 1976-10-29 1977-10-28 Sposob wytwarzania mieszaniny alkoholi pierwszorzedowych,nasyconych
AU30172/77A AU508915B2 (en) 1976-10-29 1977-10-31 Manufacturing alcohols
FR8107968A FR2504124A2 (fr) 1976-10-29 1981-04-17 Procede de fabrication d'alcools et plus particulierement d'alcools primaires, satures et lineaires a partir de gaz de synthese
FR8110192A FR2506298A2 (fr) 1976-10-29 1981-05-20 Procede de fabrication d'alcools et plus particulierement d'alcools primaires satures et lineaires a partir de gaz de synthese

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7633046A FR2369234A1 (fr) 1976-10-29 1976-10-29 Procede de fabrication d'alc

Publications (2)

Publication Number Publication Date
FR2369234A1 true FR2369234A1 (fr) 1978-05-26
FR2369234B1 FR2369234B1 (fr) 1981-11-13

Family

ID=9179471

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7633046A Granted FR2369234A1 (fr) 1976-10-29 1976-10-29 Procede de fabrication d'alc

Country Status (7)

Country Link
US (1) US4122110A (fr)
AU (1) AU508915B2 (fr)
DE (1) DE2748097C3 (fr)
FR (1) FR2369234A1 (fr)
GB (1) GB1547687A (fr)
PL (1) PL107649B1 (fr)
ZA (1) ZA776429B (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2453125A1 (fr) * 1979-04-05 1980-10-31 Inst Francais Du Petrole Production d'alcools a partir de gaz de synthese
FR2517296A1 (fr) * 1981-12-02 1983-06-03 Snam Progetti Systeme catalytique et procede pour la production de melanges de methanol et d'alcools superieurs
FR2523957A1 (fr) * 1982-03-26 1983-09-30 Inst Francais Du Petrole Procede de fabrication d'un melange de methanol et d'alcools superieurs, a partir de gaz de synthese
EP0205130A2 (fr) * 1985-06-11 1986-12-17 BASF Aktiengesellschaft Catalyseurs à base de cuivre pour la préparation de l'hydrogène
EP1961724A3 (fr) * 2005-12-16 2008-11-19 Battelle Memorial Institute Synthèse d'alcool à partir de CO ou de CO2

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DE2846148A1 (de) * 1978-10-24 1980-05-08 Hoechst Ag Verfahren zur herstellung von ethanol aus synthesegas
FR2444654A1 (fr) * 1978-12-19 1980-07-18 Inst Francais Du Petrole Procede de fabrication d'alcools et plus particulierement d'alcools primaires, satures et lineaires, a partir de gaz de synthese
FR2480300B1 (fr) * 1980-04-09 1985-06-07 Inst Francais Du Petrole Procede de valorisation d'huiles lourdes
IN155637B (fr) * 1980-04-11 1985-02-16 Imp Chemical Ind Plc Formerly
US4301253A (en) * 1980-09-25 1981-11-17 Union Carbide Corporation Process for the selective production of ethanol and methanol directly from synthesis gas
US4333852A (en) * 1980-09-25 1982-06-08 Union Carbide Corporation Catalyst for the selective production of ethanol and methanol directly from synthesis gas
US4377643A (en) * 1981-12-21 1983-03-22 The Standard Oil Company Upgrading synthesis gas
US4476247A (en) * 1981-12-21 1984-10-09 The Standard Oil Company Synthesis gas catalyst
US4478955A (en) * 1981-12-21 1984-10-23 The Standard Oil Company Upgrading synthesis gas
US4440668A (en) * 1982-07-06 1984-04-03 Mobil Oil Corporation Catalyst for the conversion of synthesis gas to higher alcohols
DE3369311D1 (en) * 1982-07-09 1987-02-26 British Petroleum Co Plc Catalyst compostion and its use in a process for the production of alcohols from synthesis gas
US4590314A (en) * 1983-12-30 1986-05-20 Union Carbide Corporation Catalytic process for the production of alcohols from carbon monoxide, hydrogen and olefins
US4551444A (en) * 1984-02-28 1985-11-05 Phillips Petroleum Company Catalyst for alcohol synthesis
US4537909A (en) * 1984-02-28 1985-08-27 Phillips Petroleum Company Alcohol synthesis
FR2564091B1 (fr) * 1984-05-10 1986-10-03 Inst Francais Du Petrole Procede de synthese d'un melange d'alcools primaires a partir de gaz de synthese en presence d'un catalyseur contenant du cuivre, du cobalt, du zinc et de l'aluminium
US4562174A (en) * 1984-05-21 1985-12-31 Alberta Gas Chemicals Ltd. Catalyst for the production of alkanols
US4752622A (en) * 1984-07-30 1988-06-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4559316A (en) * 1984-09-21 1985-12-17 The Standard Oil Company Copper-zirconium-manganese-containing catalysts
US4766155A (en) * 1984-11-26 1988-08-23 Atlantic Richfield Company Process for producing alcohols
US4677091A (en) * 1985-07-15 1987-06-30 The Standard Oil Company Process for the preparation of mixed metal oxide catalysts
US4725626A (en) * 1985-08-05 1988-02-16 The Standard Oil Company Manufacture of alcohols from synthesis gas
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
FR2595689B1 (fr) * 1986-03-17 1988-11-04 Inst Francais Du Petrole Procede de fabrication d'un melange d'alcools primaires a partir de gaz de synthese en presence d'un catalyseur contenant du cuivre, du cobalt, du zinc et au moins un metal alcalin et/ou alcalino-terreux
US5096688A (en) * 1989-06-13 1992-03-17 Amoco Corporation Catalytic process for producing higher alcohols from synthesis gas
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EP3018113A1 (fr) 2014-11-06 2016-05-11 BP p.l.c. Procédé et appareil pour la production d'éthylène à partir de monoxyde de carbone et d'hydrogène
CN105727982B (zh) * 2014-12-11 2019-03-29 中国石油化工股份有限公司 一种合成低碳醇的催化剂及其制备方法
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CN105664964B (zh) * 2016-02-19 2017-12-05 中国科学院上海高等研究院 一种用于合成气制备高碳醇的混合氧化物催化剂
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CN112892543B (zh) * 2019-12-03 2022-06-14 中国科学院大连化学物理研究所 一种合成气油-醇联产的催化剂及其制备与应用
WO2022055509A1 (fr) * 2020-09-14 2022-03-17 Uop Llc Catalyseurs pour la synthèse d'isobutanol à partir de gaz de synthèse et d'éthanol ou de propanol
CN112495384A (zh) * 2020-11-26 2021-03-16 中国科学院山西煤炭化学研究所 一种用于合成气制低碳醇的CuCo基复合催化剂及其制备方法和应用
EP4112169A1 (fr) 2021-07-03 2023-01-04 Studiengesellschaft Kohle mbH Procédé de conversion de gaz de synthèse en alcools supérieurs

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GB1405012A (en) * 1972-01-21 1975-09-03 Ici Ltd Method of making composition convertible to a catalyst precursor and catalyst and methanol synthesis using the catalyst

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2453125A1 (fr) * 1979-04-05 1980-10-31 Inst Francais Du Petrole Production d'alcools a partir de gaz de synthese
FR2517296A1 (fr) * 1981-12-02 1983-06-03 Snam Progetti Systeme catalytique et procede pour la production de melanges de methanol et d'alcools superieurs
FR2523957A1 (fr) * 1982-03-26 1983-09-30 Inst Francais Du Petrole Procede de fabrication d'un melange de methanol et d'alcools superieurs, a partir de gaz de synthese
EP0205130A2 (fr) * 1985-06-11 1986-12-17 BASF Aktiengesellschaft Catalyseurs à base de cuivre pour la préparation de l'hydrogène
EP0205130A3 (en) * 1985-06-11 1989-12-27 Basf Aktiengesellschaft Copper containing catalysts for the preparation of hydrogen
EP1961724A3 (fr) * 2005-12-16 2008-11-19 Battelle Memorial Institute Synthèse d'alcool à partir de CO ou de CO2
AU2006329825B2 (en) * 2005-12-16 2013-09-19 Battelle Memorial Institute Alcohol synthesis from CO or CO2

Also Published As

Publication number Publication date
AU3017277A (en) 1979-05-10
GB1547687A (en) 1979-06-27
ZA776429B (en) 1978-08-30
PL201802A1 (pl) 1978-07-17
DE2748097A1 (de) 1978-05-11
PL107649B1 (pl) 1980-02-29
FR2369234B1 (fr) 1981-11-13
DE2748097C3 (de) 1989-09-21
US4122110A (en) 1978-10-24
DE2748097C2 (de) 1986-04-03
AU508915B2 (en) 1980-04-03

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