GB317808A - Improvements in the manufacture and production of organic compounds from oxides of carbon and hydrogen - Google Patents

Improvements in the manufacture and production of organic compounds from oxides of carbon and hydrogen

Info

Publication number
GB317808A
GB317808A GB1463928A GB1463928A GB317808A GB 317808 A GB317808 A GB 317808A GB 1463928 A GB1463928 A GB 1463928A GB 1463928 A GB1463928 A GB 1463928A GB 317808 A GB317808 A GB 317808A
Authority
GB
United Kingdom
Prior art keywords
hydrogen
hydrocarbons
carbon
carbon monoxide
amount
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1463928A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB1463928A priority Critical patent/GB317808A/en
Publication of GB317808A publication Critical patent/GB317808A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)

Abstract

317,808. Johnson, J. Y., (I. G. Farbenindustrie Akt.-Ges.). May 18, 1928. Oxygenated organic compounds; hydrocarbons. -Organic compounds, particularly those containing oxygen such as methyl, ethyl and higher alcohels, acids, esters, ketones, and fats, and also hydrocarbons, are prepared by treating gaseous mixtures comprising oxides of carbon and an amount of hydrogen or a gas rich in hydrogen greater than that of the carbon monoxide puresent, at a pressure more than 20 atmospheres with a catalyst comprising a mixture of an element from the first sub group of the periodic system and a large amount of an element from the eighth group of the periodic system and preferably from the iron group, if desired with the addition of less than 5 per cent of a metal forming a difficultly reducible oxide. A catalyst free from cadmium or thallium is used if the gaseous mixture contains oxides of carbon in an amount exceeding 25 per cent of the amount of hydrogen present. In examples, (1) ferric nitrate, cupric nitrate and a small amount of potassium carbonate are deposited on pumice, stone, calcined, and reduced by hydrogen; a mixture of carbon monoxide with excess of hydrogen is passed over the product at 350‹ C. under pressure, giving an oil containing higher hydrocarbons, alcohols and esters and also an aqueous condensate containing lower alcohols and fatty acids, hydrocarbons of the benzine type being recovered by charcoal from the residual gases; (2) ferric nitrate and cupric nitrate are precipitated with potassium carbonate, and the precipitate is washed and dried and used as in example 1, similar products being obtained; carbon dioxide gives the same result if used instead of carbon monoxide: (3) a solution of the nitrates of iron, zinc and copper is precipitated with potassium carbonate and the precipitate dried; a mixture containing carbon monoxide, hydrogen, methane and a little nitrogen is passed over this catalyst at a high temperature and pressure, a liquid being obtained in two layers, the upper one consisting chiefy of hydrocarbons the lower containing 30-40 per cent of ethyl alcohol; benzines may be recovered as in the other examples. Specifications 2306/14. [Class 1 (i), Chemical processes &c.]. and 300,294 are referred to.
GB1463928A 1928-05-18 1928-05-18 Improvements in the manufacture and production of organic compounds from oxides of carbon and hydrogen Expired GB317808A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1463928A GB317808A (en) 1928-05-18 1928-05-18 Improvements in the manufacture and production of organic compounds from oxides of carbon and hydrogen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1463928A GB317808A (en) 1928-05-18 1928-05-18 Improvements in the manufacture and production of organic compounds from oxides of carbon and hydrogen

Publications (1)

Publication Number Publication Date
GB317808A true GB317808A (en) 1929-08-19

Family

ID=10044874

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1463928A Expired GB317808A (en) 1928-05-18 1928-05-18 Improvements in the manufacture and production of organic compounds from oxides of carbon and hydrogen

Country Status (1)

Country Link
GB (1) GB317808A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE766152C (en) * 1940-01-30 1953-02-23 Ruhrchemie Ag Process for the production of high molecular weight alcohols, aldehydes and ketones from water gas or other gas mixtures rich in carbon oxides
DE2748097A1 (en) * 1976-10-29 1978-05-11 Inst Francais Du Petrol METHOD FOR PRODUCING ALCOHOLS, ESPECIALLY PRIMARY, SATURATED AND STRAIN-CHAIN ALCOHOLS, FROM SYNTHESIS GAS
US4237063A (en) * 1979-05-23 1980-12-02 Mobil Oil Corporation Synthesis gas conversion
FR2523957A1 (en) * 1982-03-26 1983-09-30 Inst Francais Du Petrole PROCESS FOR PRODUCING A MIXTURE OF METHANOL AND HIGHER ALCOHOLS FROM SYNTHESIS GAS
US4766155A (en) * 1984-11-26 1988-08-23 Atlantic Richfield Company Process for producing alcohols

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE766152C (en) * 1940-01-30 1953-02-23 Ruhrchemie Ag Process for the production of high molecular weight alcohols, aldehydes and ketones from water gas or other gas mixtures rich in carbon oxides
DE2748097A1 (en) * 1976-10-29 1978-05-11 Inst Francais Du Petrol METHOD FOR PRODUCING ALCOHOLS, ESPECIALLY PRIMARY, SATURATED AND STRAIN-CHAIN ALCOHOLS, FROM SYNTHESIS GAS
DE2748097C3 (en) * 1976-10-29 1989-09-21 Inst Francais Du Petrole PROCESS FOR PREPARING PRIMARY, SAVED AND STRAIGHT CHAINED ALCOHOLS
US4237063A (en) * 1979-05-23 1980-12-02 Mobil Oil Corporation Synthesis gas conversion
FR2523957A1 (en) * 1982-03-26 1983-09-30 Inst Francais Du Petrole PROCESS FOR PRODUCING A MIXTURE OF METHANOL AND HIGHER ALCOHOLS FROM SYNTHESIS GAS
US4766155A (en) * 1984-11-26 1988-08-23 Atlantic Richfield Company Process for producing alcohols

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