MX167391B - CATALYTIC PROCEDURE FOR THE PRODUCTION OF ALCOHOLS FROM CARBON MONOXIDE, HYDROGEN AND OLEFINS - Google Patents

CATALYTIC PROCEDURE FOR THE PRODUCTION OF ALCOHOLS FROM CARBON MONOXIDE, HYDROGEN AND OLEFINS

Info

Publication number
MX167391B
MX167391B MX203912A MX20391284A MX167391B MX 167391 B MX167391 B MX 167391B MX 203912 A MX203912 A MX 203912A MX 20391284 A MX20391284 A MX 20391284A MX 167391 B MX167391 B MX 167391B
Authority
MX
Mexico
Prior art keywords
alcohols
hydrogen
carbon monoxide
olefins
production
Prior art date
Application number
MX203912A
Other languages
Spanish (es)
Inventor
Nancy Ellen Kinkade
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of MX167391B publication Critical patent/MX167391B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a procedimiento catalítico para la producción de alcoholes a partir de monóxido de carbono, hidrógeno y olefinas, en donde los alcoholes son alcoholes de Cn+1 siendo n un entero positivo no menor de 2; caracterizado porque consiste en hacer reaccionar en la fase de vapor una alimentación de gas de por lo menos una olefina de Cn con monóxido de carbono e hidrógeno, en presencia de un catalizador sólido que consiste esencialmente de sulfuro de molibdeno y un compuesto alcalino que se selecciona del grupo que consiste de compuestos de metal alcalino y de metal alcalinotérreo y mezclas de los mismos, siendo la velocidad espacial en horas, del gas de reacción desde aproximadamente 1,000 hasta aproximadamente 24,000 horas -1.The present invention relates to a catalytic process for the production of alcohols from carbon monoxide, hydrogen and olefins, where the alcohols are Cn + 1 alcohols with n being a positive integer of not less than 2; characterized in that it consists in reacting in the vapor phase a gas feed of at least one Cn olefin with carbon monoxide and hydrogen, in the presence of a solid catalyst consisting essentially of molybdenum sulfide and an alkaline compound that is selected from the group consisting of alkali metal and alkaline earth metal compounds and mixtures thereof, the space velocity in hours of the reaction gas being from approximately 1,000 to approximately 24,000 hours -1.

MX203912A 1983-12-30 1984-12-28 CATALYTIC PROCEDURE FOR THE PRODUCTION OF ALCOHOLS FROM CARBON MONOXIDE, HYDROGEN AND OLEFINS MX167391B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US56724483A 1983-12-30 1983-12-30
US06/671,886 US4590314A (en) 1983-12-30 1984-11-19 Catalytic process for the production of alcohols from carbon monoxide, hydrogen and olefins

Publications (1)

Publication Number Publication Date
MX167391B true MX167391B (en) 1993-03-19

Family

ID=27074411

Family Applications (1)

Application Number Title Priority Date Filing Date
MX203912A MX167391B (en) 1983-12-30 1984-12-28 CATALYTIC PROCEDURE FOR THE PRODUCTION OF ALCOHOLS FROM CARBON MONOXIDE, HYDROGEN AND OLEFINS

Country Status (11)

Country Link
US (1) US4590314A (en)
EP (1) EP0149256B1 (en)
KR (1) KR890001914B1 (en)
AU (1) AU575899B2 (en)
BR (1) BR8407252A (en)
CA (1) CA1321604C (en)
DE (1) DE3467569D1 (en)
MX (1) MX167391B (en)
NZ (1) NZ210766A (en)
WO (1) WO1985003074A1 (en)
YU (1) YU585A (en)

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US4675344A (en) * 1984-07-30 1987-06-23 The Dow Chemical Company Method for adjusting methanol to higher alcohol ratios
US4752622A (en) * 1984-07-30 1988-06-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4882360A (en) * 1984-07-30 1989-11-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4831060A (en) * 1984-07-30 1989-05-16 The Dow Chemical Company Mixed alcohols production from syngas
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
US5068469A (en) * 1990-02-07 1991-11-26 Exxon Chemical Patents Inc. Process for preparation of condensed alcohols by alkoxide catalysts
US5082977A (en) * 1990-02-15 1992-01-21 University Of Akron Aldehydes by olefin hydroformylation
US6982355B2 (en) * 2003-08-25 2006-01-03 Syntroleum Corporation Integrated Fischer-Tropsch process for production of linear and branched alcohols and olefins
US20090156697A1 (en) * 2007-12-14 2009-06-18 Range Fuels, Inc. Catalyst compositions and methods for alcohol production from synthesis gas
US7955588B2 (en) * 2009-05-26 2011-06-07 Conocophillips Company Metal sulfide catalysts and methods of making same
US8604254B2 (en) 2009-11-11 2013-12-10 Dow Global Technologies Llc Reductive hydroformylation of an alkylene to an alkanol
US8999876B2 (en) 2010-12-06 2015-04-07 Georgia Tech Research Corporation Carbon-supported catalysts for production of higher alcohols from syngas
BR112013011294B1 (en) 2010-12-06 2021-12-21 Georgia Tech Research Corporation CATALYST COMPOSITION AND PROCESS FOR PREPARING A HIGHER ALCOHOL
WO2012087687A1 (en) 2010-12-21 2012-06-28 Dow Global Technologies Llc Three step syngas to propylene including an intermediate conversion of byproduct ethane to propanol followed by propanol dehydration process
US8815963B1 (en) 2013-11-04 2014-08-26 Auxilium Green, LLC Catalyst composition formulated for synthesis of alcohols and method of preparing the same
US10316254B2 (en) * 2014-10-31 2019-06-11 The Board Of Regents Of The University Of Texas System Hydrothermal synthesis of alkali promoted MOS2-based catalyst
US9963357B2 (en) * 2015-02-23 2018-05-08 Khalifa University of Science and Technology MoS2 foam

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US2671119A (en) * 1949-04-01 1954-03-02 Standard Oil Dev Co Hydrogenation of oxo alcohol bottoms
FR1048905A (en) * 1951-03-31 1953-12-24 Standard Oil Dev Co Process for preparing oxygenated organic compounds
US2709714A (en) * 1951-04-19 1955-05-31 Exxon Research Engineering Co Production of oxo alcohols
US2813911A (en) 1953-08-21 1957-11-19 Exxon Research Engineering Co Sulfactive aldehyde hydrogenation catalyst
US2976254A (en) * 1953-08-21 1961-03-21 Exxon Research Engineering Co Aldehyde hydrogenation catalyst preparation
US3118954A (en) * 1960-01-25 1964-01-21 Exxon Research Engineering Co Graduated hydrogenation of aldox aldehydes to alcohols
US3239569A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
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US4199522A (en) * 1977-07-11 1980-04-22 The Dow Chemical Company Process for producing olefins from carbon monoxide and hydrogen
US4115433A (en) * 1977-10-11 1978-09-19 Union Carbide Corporation Catalyst and process for producing polyhydric alcohols and derivatives
FR2444654A1 (en) * 1978-12-19 1980-07-18 Inst Francais Du Petrole PROCESS FOR THE MANUFACTURE OF ALCOHOLS AND MORE PARTICULARLY PRIMARY, SATURATED AND LINEAR ALCOHOLS FROM SYNTHESIS GAS
US4243554A (en) 1979-06-11 1981-01-06 Union Carbide Corporation Molybdenum disulfide catalyst and the preparation thereof
US4243553A (en) 1979-06-11 1981-01-06 Union Carbide Corporation Production of improved molybdenum disulfide catalysts
US4235798A (en) * 1979-06-28 1980-11-25 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
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US4377643A (en) * 1981-12-21 1983-03-22 The Standard Oil Company Upgrading synthesis gas
US4380589A (en) * 1981-12-24 1983-04-19 The Dow Chemical Company Novel Fischer-Tropsch catalysts
BR8406451A (en) * 1983-03-18 1985-03-12 Dow Chemical Co CATALYTIC PROCESS FOR THE PRODUCTION OF MIXED ALCOHOLS FROM HYDROGEN AND CARBON MONOXIDE

Also Published As

Publication number Publication date
BR8407252A (en) 1985-12-24
US4590314A (en) 1986-05-20
AU3783185A (en) 1985-07-30
KR890001914B1 (en) 1989-05-31
WO1985003074A1 (en) 1985-07-18
KR850700132A (en) 1985-10-25
NZ210766A (en) 1988-07-28
EP0149256A3 (en) 1985-08-07
YU585A (en) 1987-04-30
DE3467569D1 (en) 1987-12-23
EP0149256A2 (en) 1985-07-24
CA1321604C (en) 1993-08-24
EP0149256B1 (en) 1987-11-19
AU575899B2 (en) 1988-08-11

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