AR005010A1 - Metodo para convertir metanol a olefinas - Google Patents
Metodo para convertir metanol a olefinasInfo
- Publication number
- AR005010A1 AR005010A1 ARP960105570A ARP960105570A AR005010A1 AR 005010 A1 AR005010 A1 AR 005010A1 AR P960105570 A ARP960105570 A AR P960105570A AR P960105570 A ARP960105570 A AR P960105570A AR 005010 A1 AR005010 A1 AR 005010A1
- Authority
- AR
- Argentina
- Prior art keywords
- olefins
- molecular sieve
- transition metal
- converting methanol
- transition
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title 3
- 239000002808 molecular sieve Substances 0.000 abstract 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 229910021645 metal ion Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
- 229910001428 transition metal ion Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the eroionite or offretite type, e.g. zeolite T
- C07C2529/52—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the eroionite or offretite type, e.g. zeolite T containing iron group metals, noble metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Un catalizador de tamiz molecular de poros pequenos que contiene un metal de transicion en el cual el tamiz molecular ha sido modificado luego de lasintesis por incorporacion de un ion de metal de transicion, usando un compuesto de metald e transicion donde el ion de metal, de transicion esseleccionado del grupo formado por los Grupos VIB, VIIB o VIII o mezcla de los mismos. Tambien se describe un metodo para convertir material inicial enolefinas utilizando dicho catalizador detamiz molecular.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/571,506 US5962762A (en) | 1995-12-13 | 1995-12-13 | Use of transition metal containing small pore molecular sieve catalysts in oxygenate conversion |
Publications (1)
Publication Number | Publication Date |
---|---|
AR005010A1 true AR005010A1 (es) | 1999-04-07 |
Family
ID=24283980
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP960105570A AR005010A1 (es) | 1995-12-13 | 1996-12-09 | Metodo para convertir metanol a olefinas |
Country Status (15)
Country | Link |
---|---|
US (1) | US5962762A (es) |
EP (2) | EP1004562A1 (es) |
JP (1) | JP2000501735A (es) |
CN (1) | CN1068574C (es) |
AR (1) | AR005010A1 (es) |
AU (1) | AU717902B2 (es) |
BR (1) | BR9612017A (es) |
CA (1) | CA2239017A1 (es) |
DE (1) | DE69610645T2 (es) |
ES (1) | ES2153135T3 (es) |
MX (1) | MX202438B (es) |
MY (1) | MY117355A (es) |
NO (1) | NO982662B1 (es) |
TR (1) | TR199801084T2 (es) |
WO (1) | WO1997021652A1 (es) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6436869B1 (en) | 1996-05-29 | 2002-08-20 | Exxonmobil Chemical Patents Inc. | Iron, cobalt and/or nickel containing ALPO bound SAPO molecular sieve catalyst for producing olefins |
US6455747B1 (en) | 1998-05-21 | 2002-09-24 | Exxonmobil Chemical Patents Inc. | Method for converting oxygenates to olefins |
RO114524B1 (ro) | 1997-10-02 | 1999-05-28 | Sc Zecasin Sa | Procedeu de fabricare a oleofinelor cu greutate moleculara mica prin conversia catalitica in strat fluidizat a metanolului |
US6005155A (en) * | 1997-12-03 | 1999-12-21 | Exxon Chemicals Patents Inc. | Modification of molecular sieve catalyst for reduced methane production during conversion of oxygenates to olefins |
US6137022A (en) * | 1997-12-03 | 2000-10-24 | Exxon Chemical Patents Inc | Process for increasing the selectivity of a reaction to convert oxygenates to olefins |
US6444868B1 (en) | 1999-02-17 | 2002-09-03 | Exxon Mobil Chemical Patents Inc. | Process to control conversion of C4+ and heavier stream to lighter products in oxygenate conversion reactions |
US6437208B1 (en) | 1999-09-29 | 2002-08-20 | Exxonmobil Chemical Patents Inc. | Making an olefin product from an oxygenate |
WO2001025150A1 (en) | 1999-10-01 | 2001-04-12 | Pop, Grigore | Process for the synthesis of silicoaluminophosphate molecular sieves |
AU1460501A (en) * | 1999-11-18 | 2001-05-30 | Exxon Chemical Patents Inc. | Molecular sieves |
CN1108867C (zh) * | 1999-12-29 | 2003-05-21 | 中国科学院大连化学物理研究所 | MeAPSO-17分子筛及其合成方法 |
CN1108868C (zh) * | 1999-12-29 | 2003-05-21 | 中国科学院大连化学物理研究所 | MeAPSO-18分子筛及其合成方法 |
WO2001060746A1 (en) | 2000-02-16 | 2001-08-23 | Exxonmobil Chemical Patents Inc. | Treatment of molecular sieves with silicon containing compounds |
US6531639B1 (en) | 2000-02-18 | 2003-03-11 | Exxonmobil Chemical Patents, Inc. | Catalytic production of olefins at high methanol partial pressures |
US6743747B1 (en) | 2000-02-24 | 2004-06-01 | Exxonmobil Chemical Patents Inc. | Catalyst pretreatment in an oxgenate to olefins reaction system |
US6448197B1 (en) | 2000-07-13 | 2002-09-10 | Exxonmobil Chemical Patents Inc. | Method for making a metal containing small pore molecular sieve catalyst |
US7102050B1 (en) | 2000-05-04 | 2006-09-05 | Exxonmobil Chemical Patents Inc. | Multiple riser reactor |
US6613950B1 (en) * | 2000-06-06 | 2003-09-02 | Exxonmobil Chemical Patents Inc. | Stripping hydrocarbon in an oxygenate conversion process |
US7393990B2 (en) * | 2001-06-26 | 2008-07-01 | Exxonmobil Chemical Patents Inc. | Production of light olefins from oxygenate using framework gallium-containing medium pore molecular sieve |
US6759360B2 (en) * | 2002-03-29 | 2004-07-06 | Exxonmobil Chemical Patent Inc. | Interior surface modifications of molecular sieves with organometallic reagents and the use thereof for the conversion of oxygenates to olefins |
US7097203B2 (en) * | 2002-09-13 | 2006-08-29 | Automotive Systems Laboratory, Inc. | Inflator |
US7122160B2 (en) * | 2002-09-24 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Reactor with multiple risers and consolidated transport |
US20040064007A1 (en) * | 2002-09-30 | 2004-04-01 | Beech James H. | Method and system for regenerating catalyst from a plurality of hydrocarbon conversion apparatuses |
US7083762B2 (en) * | 2002-10-18 | 2006-08-01 | Exxonmobil Chemical Patents Inc. | Multiple riser reactor with centralized catalyst return |
US7015174B2 (en) | 2003-06-20 | 2006-03-21 | Exxonmobil Chemical Patents Inc. | Maintaining molecular sieve catalytic activity under water vapor conditions |
US7241716B2 (en) | 2003-11-10 | 2007-07-10 | Exxonmobil Chemical Patents Inc. | Protecting catalytic sites of metalloaluminophosphate molecular sieves |
US7084319B2 (en) * | 2003-12-05 | 2006-08-01 | Exxonmobil Chemical Patents Inc. | Catalyst fluidization in oxygenate to olefin reaction systems |
US7199278B2 (en) * | 2004-07-30 | 2007-04-03 | Exxonmobil Chemical Patents Inc. | Conversion of oxygenates to olefins |
CN100377784C (zh) * | 2004-09-28 | 2008-04-02 | 中国石油化工股份有限公司 | 一种金属改性的sapo-34分子筛及其应用 |
JP5330635B2 (ja) * | 2006-01-20 | 2013-10-30 | 豊田通商株式会社 | プロピレンの製造方法、触媒の再生方法、固体酸触媒 |
US7935857B2 (en) * | 2006-03-31 | 2011-05-03 | Exxonmobil Chemical Patents Inc. | Product recovery in gas-solids reactors |
US7744746B2 (en) | 2006-03-31 | 2010-06-29 | Exxonmobil Research And Engineering Company | FCC catalyst stripper configuration |
CN101121532A (zh) * | 2006-08-08 | 2008-02-13 | 中国科学院大连化学物理研究所 | 一种小孔磷硅铝分子筛的金属改性方法 |
CN101121145B (zh) * | 2006-08-08 | 2010-10-20 | 中国科学院大连化学物理研究所 | 一种含氧化合物转化制烯烃微球催化剂及其制备方法 |
CN103030158B (zh) * | 2011-09-29 | 2015-01-07 | 中国石油化工股份有限公司 | 稀土金属改性sapo-44分子筛的合成方法 |
CN104096591B (zh) * | 2013-04-07 | 2016-08-10 | 刘希尧 | Mto催化剂及其制备方法 |
WO2015094696A1 (en) | 2013-12-20 | 2015-06-25 | Exxonmobil Chemical Patents Inc. | Process for converting oxygenates to aromatic hydrocarbons |
US9783463B2 (en) | 2014-09-30 | 2017-10-10 | Exxonmobil Chemical Patents Inc. | Conversion of acetylene and methanol to aromatics |
US10850267B2 (en) * | 2015-01-30 | 2020-12-01 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | Preparation method for metal-modified SAPO molecular sieve |
CN107428628B (zh) | 2015-03-31 | 2021-03-02 | 埃克森美孚化学专利公司 | 氧化烃转化的分区方法 |
US10189763B2 (en) | 2016-07-01 | 2019-01-29 | Res Usa, Llc | Reduction of greenhouse gas emission |
WO2018004992A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Conversion of methane to dimethyl ether |
US9938217B2 (en) | 2016-07-01 | 2018-04-10 | Res Usa, Llc | Fluidized bed membrane reactor |
WO2018096171A1 (en) | 2016-11-28 | 2018-05-31 | Basf Se | Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins |
CN111250150B (zh) * | 2018-11-30 | 2023-06-20 | 中国科学院大连化学物理研究所 | 改性zsm-5分子筛催化剂制备方法及其应用、煤基乙醇制乙烯方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4021332A (en) * | 1975-06-12 | 1977-05-03 | Mobil Oil Corporation | Hydrocarbon conversion over activated erionite |
US4077910A (en) * | 1976-06-12 | 1978-03-07 | Mobil Oil Corporation | Hydrocarbon conversion over activated erionite |
US4292458A (en) * | 1978-04-18 | 1981-09-29 | Standard Oil Company (Indiana) | Production of hydrocarbons from alcohols |
US4311865A (en) * | 1979-04-04 | 1982-01-19 | Mobil Oil Corporation | Manufacture of hydrocarbons from oxygenates |
US4665268A (en) * | 1982-09-30 | 1987-05-12 | Mobil Oil Corporation | Catalytic conversion of methanol to light olefins |
AU567109B2 (en) * | 1982-09-30 | 1987-11-12 | Mobil Oil Corp. | Catalytic conversion of methanol to light olefins |
US4677243A (en) * | 1982-10-04 | 1987-06-30 | Union Carbide Corporation | Production of light olefins from aliphatic hetero compounds |
US4677242A (en) * | 1982-10-04 | 1987-06-30 | Union Carbide Corporation | Production of light olefins |
US4499327A (en) * | 1982-10-04 | 1985-02-12 | Union Carbide Corporation | Production of light olefins |
US4818739A (en) * | 1984-12-18 | 1989-04-04 | Uop | Hydrocracking catalysts and processes employing non-zeolitic molecular sieves |
US4752651A (en) * | 1986-06-16 | 1988-06-21 | Union Carbide Corporation | Production of light olefins |
US4698452A (en) * | 1986-10-02 | 1987-10-06 | Institut Nationale De La Recherche Scientifique | Ethylene light olefins from ethanol |
US4849575A (en) * | 1987-11-25 | 1989-07-18 | Uop | Production of olefins |
US5147627A (en) * | 1988-04-08 | 1992-09-15 | Mobil Oil Corporation | Synthesis of crystalline silicoaluminophosphate composition |
-
1995
- 1995-12-13 US US08/571,506 patent/US5962762A/en not_active Expired - Fee Related
-
1996
- 1996-12-09 AR ARP960105570A patent/AR005010A1/es unknown
- 1996-12-11 MY MYPI96005205A patent/MY117355A/en unknown
- 1996-12-13 BR BR9612017A patent/BR9612017A/pt not_active IP Right Cessation
- 1996-12-13 CA CA002239017A patent/CA2239017A1/en not_active Abandoned
- 1996-12-13 EP EP00102345A patent/EP1004562A1/en not_active Withdrawn
- 1996-12-13 WO PCT/US1996/019673 patent/WO1997021652A1/en active IP Right Grant
- 1996-12-13 TR TR1998/01084T patent/TR199801084T2/xx unknown
- 1996-12-13 ES ES96943680T patent/ES2153135T3/es not_active Expired - Lifetime
- 1996-12-13 JP JP9522170A patent/JP2000501735A/ja not_active Ceased
- 1996-12-13 CN CN96199641A patent/CN1068574C/zh not_active Expired - Fee Related
- 1996-12-13 EP EP96943680A patent/EP0876313B1/en not_active Expired - Lifetime
- 1996-12-13 AU AU12856/97A patent/AU717902B2/en not_active Ceased
- 1996-12-13 MX MX9804732A patent/MX202438B/es not_active IP Right Cessation
- 1996-12-13 DE DE69610645T patent/DE69610645T2/de not_active Expired - Fee Related
-
1998
- 1998-06-10 NO NO19982662A patent/NO982662B1/no unknown
Also Published As
Publication number | Publication date |
---|---|
DE69610645D1 (de) | 2000-11-16 |
MX202438B (es) | 2001-06-15 |
NO982662L (no) | 1998-06-10 |
AU717902B2 (en) | 2000-04-06 |
EP0876313B1 (en) | 2000-10-11 |
MX9804732A (es) | 1998-11-30 |
JP2000501735A (ja) | 2000-02-15 |
US5962762A (en) | 1999-10-05 |
AU1285697A (en) | 1997-07-03 |
CN1068574C (zh) | 2001-07-18 |
CN1207722A (zh) | 1999-02-10 |
NO982662B1 (no) | 2001-06-05 |
DE69610645T2 (de) | 2001-06-07 |
NO982662D0 (no) | 1998-06-10 |
EP0876313A1 (en) | 1998-11-11 |
WO1997021652A1 (en) | 1997-06-19 |
ES2153135T3 (es) | 2001-02-16 |
CA2239017A1 (en) | 1997-06-19 |
MY117355A (en) | 2004-06-30 |
EP1004562A1 (en) | 2000-05-31 |
TR199801084T2 (xx) | 1998-09-21 |
BR9612017A (pt) | 1999-02-17 |
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