RU94031164A - Кристаллические микропористые силикоалюмофосфаты, способ их получения и применение - Google Patents

Кристаллические микропористые силикоалюмофосфаты, способ их получения и применение

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Publication number
RU94031164A
RU94031164A RU94031164/26A RU94031164A RU94031164A RU 94031164 A RU94031164 A RU 94031164A RU 94031164/26 A RU94031164/26 A RU 94031164/26A RU 94031164 A RU94031164 A RU 94031164A RU 94031164 A RU94031164 A RU 94031164A
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RU
Russia
Prior art keywords
producing
synthesized
silicoalumophosphates
catalysts
utilization
Prior art date
Application number
RU94031164/26A
Other languages
English (en)
Other versions
RU2091305C1 (ru
Inventor
Квисле Стейнар
No]
Веннельбо Руне
Эрен Ханне
Original Assignee
Норск Хюдро А.С. (NO)
Норск Хюдро А.С.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Норск Хюдро А.С. (NO), Норск Хюдро А.С. filed Critical Норск Хюдро А.С. (NO)
Publication of RU94031164A publication Critical patent/RU94031164A/ru
Application granted granted Critical
Publication of RU2091305C1 publication Critical patent/RU2091305C1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/30—Alpo and sapo

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Изобретение относится к улучшенному способу получения силикоалюмофсфатных катализаторов превращения метанола в легкие олефины, такие как этилен и пропилен (реакция МТС). Улучшенный способ синтеза можно использовать для регулирования химического состава силикоалюмофосфатов, особенно содержания кремния. В частности, найдено, что катализаторы можно синтезировать более стабильными к дезактивации "коксованием", что очень важно для разработки процессов МТС на основе синтезированных силикоалюмофосфатов. 7 табл.

Claims (1)

  1. Изобретение относится к улучшенному способу получения силикоалюмофсфатных катализаторов превращения метанола в легкие олефины, такие как этилен и пропилен (реакция МТС). Улучшенный способ синтеза можно использовать для регулирования химического состава силикоалюмофосфатов, особенно содержания кремния. В частности, найдено, что катализаторы можно синтезировать более стабильными к дезактивации "коксованием", что очень важно для разработки процессов МТС на основе синтезированных силикоалюмофосфатов. 7 табл.
RU9294031164A 1991-12-23 1992-12-09 Кристаллические микропористые силикоалюмофосфаты, способ их получения и катализатор для синтеза олефинов из метанола RU2091305C1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NO19915080A NO174341B1 (no) 1991-12-23 1991-12-23 Fremg for fremst av krystallinske mikroporose SiAl-fosfater med kontrollert Si-innh, krystallinske mikroporose SiAl-fosfater med forbedret stabilitet mot deaktivering og en anv av disse ved fremstilling av olefiner fra metanol
NO915080 1991-12-23
PCT/NO1992/000193 WO1993013013A1 (en) 1991-12-23 1992-12-09 Procedure for synthesis of crystalline microporous silico-alumino-phosphates

Publications (2)

Publication Number Publication Date
RU94031164A true RU94031164A (ru) 1996-05-27
RU2091305C1 RU2091305C1 (ru) 1997-09-27

Family

ID=19894708

Family Applications (1)

Application Number Title Priority Date Filing Date
RU9294031164A RU2091305C1 (ru) 1991-12-23 1992-12-09 Кристаллические микропористые силикоалюмофосфаты, способ их получения и катализатор для синтеза олефинов из метанола

Country Status (11)

Country Link
US (1) US5663471A (ru)
EP (1) EP0619800B1 (ru)
JP (1) JP2562863B2 (ru)
AU (1) AU666691B2 (ru)
CA (1) CA2126575C (ru)
DE (1) DE69221638T2 (ru)
ES (1) ES2107559T3 (ru)
NO (1) NO174341B1 (ru)
NZ (1) NZ246097A (ru)
RU (1) RU2091305C1 (ru)
WO (1) WO1993013013A1 (ru)

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US5817906A (en) * 1995-08-10 1998-10-06 Uop Llc Process for producing light olefins using reaction with distillation as an intermediate step
US5714662A (en) * 1995-08-10 1998-02-03 Uop Process for producing light olefins from crude methanol
US5744680A (en) * 1995-08-10 1998-04-28 Uop Process for producing light olefins
US5990369A (en) * 1995-08-10 1999-11-23 Uop Llc Process for producing light olefins
NO311208B1 (no) * 1996-03-13 2001-10-29 Norsk Hydro As Mikroporös krystallinsk metallofosfatforbindelse, en fremgangsmåte for fremstilling av forbindelsen og anvendelse derav
NO310106B1 (no) * 1996-03-13 2001-05-21 Norsk Hydro As Mikroporöse, krystallinske metallofosfatforbindelser, en fremgangsmåte for fremstilling og anvendelse derav
US6040264A (en) * 1996-04-04 2000-03-21 Exxon Chemical Patents Inc. Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion
US6436869B1 (en) 1996-05-29 2002-08-20 Exxonmobil Chemical Patents Inc. Iron, cobalt and/or nickel containing ALPO bound SAPO molecular sieve catalyst for producing olefins
US5849258A (en) * 1996-06-06 1998-12-15 Intevep, S.A. Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same
CA2264700C (en) * 1996-09-06 2006-11-21 Exxon Chemical Patents, Inc. Alkylation process using zeolite beta
NO304108B1 (no) * 1996-10-09 1998-10-26 Polymers Holding As En mikroporos silikoaluminofosfat-sammensetning, katalytisk materiale som omfatter denne sammensetningen og fremgangsmate for fremstilling derav, og bruken av disse for a fremstille olefiner fra metanol
RO114524B1 (ro) 1997-10-02 1999-05-28 Sc Zecasin Sa Procedeu de fabricare a oleofinelor cu greutate moleculara mica prin conversia catalitica in strat fluidizat a metanolului
US6162415A (en) * 1997-10-14 2000-12-19 Exxon Chemical Patents Inc. Synthesis of SAPO-44
JP4168214B2 (ja) 1998-10-15 2008-10-22 三菱瓦斯化学株式会社 メチルアミン製造触媒及び該触媒の製造方法
US6051745A (en) * 1999-03-04 2000-04-18 Phillips Petroleum Company Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins
US6046371A (en) * 1999-05-05 2000-04-04 Phillips Petroleum Company Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins
US6316683B1 (en) * 1999-06-07 2001-11-13 Exxonmobil Chemical Patents Inc. Protecting catalytic activity of a SAPO molecular sieve
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ATE356102T1 (de) 2001-07-02 2007-03-15 Exxonmobil Chem Patents Inc Inhibierung der katalysatorverkokung bei der herstellung eines olefins
JP5485505B2 (ja) * 2001-10-11 2014-05-07 三菱樹脂株式会社 ゼオライト、及び該ゼオライトを含む水蒸気吸着材
US6696032B2 (en) 2001-11-29 2004-02-24 Exxonmobil Chemical Patents Inc. Process for manufacturing a silicoaluminophosphate molecular sieve
US6872680B2 (en) 2002-03-20 2005-03-29 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
US7271123B2 (en) 2002-03-20 2007-09-18 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion process
US6793901B2 (en) * 2002-06-12 2004-09-21 Exxonmobil Chemical Patents, Inc. Synthesis of molecular sieves having the CHA framework type
US6897179B2 (en) * 2003-06-13 2005-05-24 Exxonmobil Chemical Patents Inc. Method of protecting SAPO molecular sieve from loss of catalytic activity
US7015174B2 (en) * 2003-06-20 2006-03-21 Exxonmobil Chemical Patents Inc. Maintaining molecular sieve catalytic activity under water vapor conditions
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US20070059236A1 (en) * 2005-09-09 2007-03-15 Broach Robert W Molecular sieves with high selectivity towards light olefins in methanol to olefin conversion
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Also Published As

Publication number Publication date
US5663471A (en) 1997-09-02
AU666691B2 (en) 1996-02-22
DE69221638T2 (de) 1998-02-26
NO174341C (no) 1994-04-20
EP0619800B1 (en) 1997-08-13
NO174341B (no) 1994-01-10
NO915080A (no) 1993-06-24
DE69221638D1 (de) 1997-09-18
RU2091305C1 (ru) 1997-09-27
NO174341B1 (no) 1994-04-21
NZ246097A (en) 1996-01-26
CA2126575A1 (en) 1993-07-08
CA2126575C (en) 2004-06-22
NO915080D0 (no) 1991-12-23
AU3097292A (en) 1993-07-28
JPH07502250A (ja) 1995-03-09
WO1993013013A1 (en) 1993-07-08
EP0619800A1 (en) 1994-10-19
JP2562863B2 (ja) 1996-12-11
ES2107559T3 (es) 1997-12-01

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Effective date: 20081210