ES2103248T1 - Sistema de aglutinante a base de poliuretano para mezclas de materiales de moldeo para la fabricacion de moldes y machos de fundicion. - Google Patents
Sistema de aglutinante a base de poliuretano para mezclas de materiales de moldeo para la fabricacion de moldes y machos de fundicion.Info
- Publication number
- ES2103248T1 ES2103248T1 ES96116921T ES96116921T ES2103248T1 ES 2103248 T1 ES2103248 T1 ES 2103248T1 ES 96116921 T ES96116921 T ES 96116921T ES 96116921 T ES96116921 T ES 96116921T ES 2103248 T1 ES2103248 T1 ES 2103248T1
- Authority
- ES
- Spain
- Prior art keywords
- fatty acid
- polyurethane
- acid methyl
- methyl esters
- components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
- B22C1/22—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/54—Polycondensates of aldehydes
- C08G18/542—Polycondensates of aldehydes with phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
- B22C1/22—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins
- B22C1/2233—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B22C1/2273—Polyurethanes; Polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0847—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers
- C08G18/0852—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of solvents for the polymers the solvents being organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mold Materials And Core Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
SE DESCRIBE LA UTILIZACION DE ESTERES METILO DE ACIDO GRASO, ES DECIR DE ESTERES MONOMETILO DE ACIDOS GRASOS CON UNA CADENA DE CARBONOS A PARTIR DE 12 ATOMOS DE C, POR EJEMPLO A BASE DE ESTER METILO DE ACEITE DE COLZA, COMO DISOLVENTE SOLO O COMPONENTE-DISOLVENTE PARA COMPONENTES INDIVIDUALES O AMBOS COMPONENTES DE AGLOMERANTE-MATERIAL DE MOLDEO DE FUNDICION SOBRE LA BASE DE POLIURETANO, CUYOS COMPONENTES ABARCAN RESINA FENOL QUE CONTIENE GRUPOS OH LIBRES Y UN POLIISOCIANATO COMO PARTNER DE REACCION. LOS ESTERES METILO DE ACIDO GRASO PUEDEN SER UTILIZADOS COMO DISOLVENTES SOLOS, PUEDEN AL MENOS SER UTILIZADOS PARA EL POLIISOCIANATO TAMBIEN CONJUNTAMENTE CON HIDROCARBUROS AROMATICOS DE ALTO PUNTO DE EBULLICION (DONDE LA PORCION DE ESTER METILO DE ACIDO GRASO DEBE PREDOMINAR EN EL DISOLVENTE CON RESPECTO A LA PORCION DEL HIDROCARBURO), Y PUEDEN SER UTILIZADOS AL MENOS PARA LA RESINA FENOL BAJO ADICION DE DISOLVENTES DE ALTA POLARIDAD. A TRAVES DE LA UTILIZACION DE ESTERES METILO DE ACIDO GRASO RESULTAN VENTAJAS CONSIDERABLES. ESPECIALMENTE PUEDE RENUNCIARSE A LA ADICION PRESENTE DE FORMA NECESARIA CONTINUA HASTA AHORA DE HIDROCARBUROS AROMATICOS DE ALTO PUNTO DE EBULLICION DE FORMA COMPLETA O AMPLIAMENTE.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19542752 | 1995-11-01 | ||
DE19542752A DE19542752A1 (de) | 1995-11-01 | 1995-11-01 | Bindemittelsystem auf Polyurethan-Basis für Formstoff-Mischungen zur Herstellung von Gießformen und Kernen |
DE1996112017 DE19612017A1 (de) | 1996-03-15 | 1996-03-15 | Bindemittelsystem auf Polyurethan-Basis für Formstoff-Mischungen zur Herstellung von Gießformen und Kernen |
DE19612017 | 1996-03-15 |
Publications (3)
Publication Number | Publication Date |
---|---|
ES2103248T1 true ES2103248T1 (es) | 1997-09-16 |
ES2103248T3 ES2103248T3 (es) | 1999-01-01 |
ES2103248T5 ES2103248T5 (es) | 2004-07-16 |
Family
ID=26020421
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES96116921T Expired - Lifetime ES2103248T5 (es) | 1995-11-01 | 1996-10-22 | Aglutinante a base de poliuretanos para la fabricacion de composiciones de moldes y machos de fundicion. |
Country Status (25)
Country | Link |
---|---|
US (1) | US6136888A (es) |
EP (1) | EP0771599B2 (es) |
JP (2) | JP3647998B2 (es) |
KR (1) | KR100366819B1 (es) |
CN (1) | CN1159373A (es) |
AR (1) | AR004231A1 (es) |
AT (1) | ATE171405T1 (es) |
AU (1) | AU704232B2 (es) |
BG (1) | BG100947A (es) |
BR (1) | BR9604485A (es) |
CA (1) | CA2189106C (es) |
CZ (1) | CZ291051B6 (es) |
DE (1) | DE59600596D1 (es) |
DK (1) | DK0771599T4 (es) |
ES (1) | ES2103248T5 (es) |
HR (1) | HRP960510A2 (es) |
HU (1) | HU216901B (es) |
IL (1) | IL119503A0 (es) |
MX (1) | MX9605232A (es) |
NO (1) | NO315614B1 (es) |
NZ (1) | NZ299622A (es) |
PL (1) | PL181888B1 (es) |
SI (1) | SI0771599T2 (es) |
TR (1) | TR199600848A2 (es) |
YU (1) | YU57796A (es) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SI0771599T2 (en) * | 1995-11-01 | 2004-04-30 | Huettenes-Albertus | Binder based on polyurethanes for producing foundry mould and core compositions |
US6720366B1 (en) * | 1995-11-01 | 2004-04-13 | Huttenes-Albertus Chemische Werke Gmbh | Binder system on the basis of polyurethane for molding material mixtures for use in the production of casting molds and cores |
DE19617938A1 (de) * | 1996-04-27 | 1997-11-06 | Chemex Gmbh | Speisereinsätze und deren Herstellung |
US6772820B2 (en) * | 1998-11-04 | 2004-08-10 | Ashland Inc. | Polyurethane based binder system for the manufacture of foundry cores and molds |
JP2002348463A (ja) * | 2001-05-24 | 2002-12-04 | Asahi Glass Polyurethane Material Co Ltd | ウレタン系硬化性組成物 |
US7019047B2 (en) * | 2003-07-25 | 2006-03-28 | Ashland Licensing And Intellectual Property Llc | Acrylate-free binders containing an epoxy resin and an alkyl silicate |
US7122583B2 (en) * | 2003-07-25 | 2006-10-17 | Ashland Licensing And Intellectual Property Llc | Cold-box binders containing an epoxy resin, acrylate, and certain akyl esters |
US7081487B2 (en) * | 2003-07-25 | 2006-07-25 | Ashland Licensing And Intellectual Property Llc | Cold-box binders containing an epoxy resin and ester of a fatty acid |
US7129283B2 (en) * | 2003-07-25 | 2006-10-31 | Ashland Licensing And Intellectual Property Llc | Binders containing an epoxy resin, an ester of a fatty acid, and a fluorinated acid |
MY144777A (en) * | 2005-08-04 | 2011-11-15 | Malaysian Palm Oil Board Mpob | A process for the production of polyurethane products |
DE102006037288B4 (de) * | 2006-08-09 | 2019-06-13 | Ask Chemicals Gmbh | Formstoffmischung enthaltend Cardol und/oder Cardanol in Gießereibindemitteln auf Polyurethanbasis, Verfahren zur Herstellung eines Formkörpers sowie Verwendung desselben |
ES2739455T3 (es) * | 2007-01-22 | 2020-01-31 | Arkema France | Proceso para fabricar núcleos conformados de fundición y para colar metales |
DE102008007181A1 (de) * | 2008-02-01 | 2009-08-06 | Ashland-Südchemie-Kernfest GmbH | Verwendung von verzweigten Alkandiolcarbonsäurediestern in Gießereibindemitteln auf Polyurethanbasis |
CN101538451B (zh) * | 2009-04-29 | 2012-07-25 | 山东莱芜润达化工有限公司 | 一种耐火材料用无水树脂结合剂及其制备方法 |
US8426494B2 (en) * | 2009-10-06 | 2013-04-23 | Amcol International Corp. | Lignite urethane based resins for enhanced foundry sand performance |
US8623959B2 (en) * | 2009-10-06 | 2014-01-07 | Joseph M. Fuqua | Non-veining urethane resins for foundry sand casting |
US8436073B2 (en) | 2009-10-06 | 2013-05-07 | Amcol International | Lignite-based foundry resins |
US8309620B2 (en) * | 2009-10-06 | 2012-11-13 | Amcol International Corp. | Lignite-based urethane resins with enhanced suspension properties and foundry sand binder performance |
US8853299B2 (en) * | 2009-10-06 | 2014-10-07 | Amcol International Corp. | Lignite-based urethane resins with enhanced suspension properties and foundry sand binder performance |
DE102010032734A1 (de) | 2010-07-30 | 2012-02-02 | Ashland-Südchemie-Kernfest GmbH | Bindemittelsystem auf Polyurethanbasis zur Herstellung von Kernen und Gießformen unter Verwendung cyclischer Formale, Formstoffmischung und Verfahren |
DE102010046981A1 (de) | 2010-09-30 | 2012-04-05 | Ashland-Südchemie-Kernfest GmbH | Bindemittel enthaltend substituierte Benzole und Napthaline zur Herstellung von Kernen und Formen für den Metallguss, Formstoffmischung und Verfahren |
EP2640778A2 (de) * | 2010-11-19 | 2013-09-25 | Hüttenes-Albertus Chemische-Werke GmbH | Sulfonsäure enthaltendes bindemittel für formstoff-mischungen zur herstellung von formen und kernen |
FR2972946B1 (fr) * | 2011-03-22 | 2013-03-29 | Rhodia Poliamida E Especialidades Ltda | Systemes liants de fonderie |
DE102011078112B4 (de) | 2011-06-27 | 2018-05-17 | Hüttenes-Albertus Chemische Werke GmbH | Verwendung von organischen Farbstoffsystemen in Gießerei-Formstoffen, Gießerei-Formstoffe und deren Verwendung, Gießerei-Sandkerne sowie Gießerei-Sandkerne und Verfahren zu ihrer Herstellung |
DE102013004663B4 (de) | 2013-03-18 | 2024-05-02 | Ask Chemicals Gmbh | Bindemittelsystem, Formstoffmischung enthaltend dasselbe, Verfahren zur Herstellung der Formstoffmischung, Verfahren zur Herstellung eines Gießformteils oder Gießkerns, Gießformteil oder Gießkern sowie Verwendung des so erhältlichen Gießformteils oder Gießkerns für den Metallguss |
DE102013004662A1 (de) | 2013-03-18 | 2014-09-18 | Ask Chemicals Gmbh | Verwendung von Monoestern epoxidierter Fettsäuren in PU-Bindemitteln zur Herstellung von Kernen und Formen für den Metallguss |
DE102013004661A1 (de) | 2013-03-18 | 2014-09-18 | Ask Chemicals Gmbh | Verwendung von Carbonsäuren und Fettaminen in PU-Bindemitteln zur Herstellung von Kernen und Formen für den Metallguss |
RU2528284C1 (ru) * | 2013-06-19 | 2014-09-10 | Закрытое акционерное общество "Научно-производственное объединение "Промэкология" | Связующее для литейных форм и стержней |
CN103878297A (zh) * | 2014-03-25 | 2014-06-25 | 宁夏共享集团有限责任公司 | 一种铸造用粘结剂的生产方法 |
DE102014110189A1 (de) | 2014-07-18 | 2016-01-21 | Ask Chemicals Gmbh | CO-Katalysatoren für Polyurethan-Coldbox-Bindemittel |
DE102015201614A1 (de) | 2014-09-10 | 2016-03-10 | Hüttenes-Albertus Chemische Werke GmbH | Zweikomponenten-Bindemittelsystem für den Polyurethan-Cold-Box-Prozess |
DE102014117284A1 (de) | 2014-11-25 | 2016-05-25 | Ask Chemicals Gmbh | Polyurethan-Bindemittelsystem zur Herstellung von Kernen und Gießformen, Formstoffmischung enthaltend das Bindemittel und ein Verfahren unter Verwendung des Bindemittels |
CN107530766B (zh) | 2015-04-14 | 2019-09-10 | 胡坦斯·阿尔伯图斯法国公司 | 酚醛树脂组合物和相应的双组分粘合剂体系,应用及方法 |
BR112018008817B1 (pt) | 2015-10-30 | 2022-06-21 | ASK Chemicals LLC | Sistema aglutinante para mistura de material de moldagem, bem como mistura de material de moldagem e método para produção de molde ou núcleo para fundição de metal fundido |
DE102016203896A1 (de) | 2016-03-09 | 2017-09-14 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Zweikomponenten-Bindemittelsystem für den Polyurethan-Cold-Box-Prozess |
CN105907077A (zh) * | 2016-04-05 | 2016-08-31 | 济南圣泉集团股份有限公司 | 无芳烃冷芯盒树脂粘结剂 |
DE102016205960A1 (de) | 2016-04-08 | 2017-10-12 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Verwendung von geschlossen-porigen Mikro-Kugeln aus expandiertem Perlit als Füllstoff für die Herstellung von Formkörpern für die Gießereiindustrie |
DE102016125624A1 (de) | 2016-12-23 | 2018-06-28 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Phenolharz zur Verwendung in der Phenolharzkomponente eines Zweikomponenten- Bindemittelsystems |
JP6887286B2 (ja) * | 2017-03-30 | 2021-06-16 | 旭有機材株式会社 | 鋳型用ウレタン硬化型有機粘結剤並びにこれを用いて得られる鋳物砂組成物及び鋳型 |
JP6887287B2 (ja) * | 2017-03-30 | 2021-06-16 | 旭有機材株式会社 | 鋳型用ウレタン硬化型有機粘結剤並びにこれを用いて得られる鋳物砂組成物及び鋳型 |
KR102180125B1 (ko) | 2019-03-11 | 2020-11-17 | 이상현 | 포장용 종이백 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3485797A (en) * | 1966-03-14 | 1969-12-23 | Ashland Oil Inc | Phenolic resins containing benzylic ether linkages and unsubstituted para positions |
US3904559A (en) * | 1971-10-26 | 1975-09-09 | Hooker Chemicals Plastics Corp | Foundry aggregate binders |
US3963656A (en) * | 1972-10-03 | 1976-06-15 | Bayer Aktiengesellschaft | Thermoplastic polyurethanes and a two-stage process for their preparation |
US3905934A (en) | 1974-05-23 | 1975-09-16 | Ashland Oil Inc | Phenolic resin-polyisocyanate binder systems containing dialkyl phthalate solvents |
DE2448134A1 (de) * | 1974-10-09 | 1976-04-22 | Bayer Ag | Textilimpraegnierung mit polyisocyanaten |
AT341125B (de) | 1975-08-21 | 1978-01-25 | Ashland Suedchemie Kernfest | Sandmischung fur das herstellen von formen und kernen und verfahren zum ausharten dieser sandmischung |
DE2759262C2 (de) | 1977-12-31 | 1983-04-28 | Hüttenes-Albertus Chemische Werke GmbH, 4000 Düsseldorf | Bindemittelsystem auf Polyurethan- Basis für Formstoff-Mischungen zur Herstellung von Gießformen und Kernen |
US4268425A (en) * | 1979-05-14 | 1981-05-19 | Ashland Oil, Inc. | Phenolic resin-polyisocyanate binder systems containing a drying oil and use thereof |
US4618630A (en) * | 1984-08-27 | 1986-10-21 | The Dow Chemical Co. | Organic polymer composition containing an antistatic agent comprising a nonvolatile ionizable metal salt and a salt or ester of a carboxylic acid |
DE3541478A1 (de) * | 1985-11-23 | 1987-05-27 | Beiersdorf Ag | Herzklappenprothese und verfahren zu deren herstellung |
DE3633365A1 (de) * | 1986-10-01 | 1988-04-14 | Bayer Ag | Gegebenenfalls zellfoermige polyurethane, die mit einem anderen werkstoff verbunden oder konfektioniert worden sind, und verfahren zu ihrer herstellung |
KR960011003B1 (ko) * | 1991-06-19 | 1996-08-16 | 미쯔이 도오아쯔 가가쿠 가부시기가이샤 | 우레탄화 반응 방법 |
JP3242755B2 (ja) * | 1993-06-18 | 2001-12-25 | 三井化学株式会社 | インテグラルスキン付ポリウレタンフォームの製造法 |
US5516859A (en) * | 1993-11-23 | 1996-05-14 | Ashland Inc. | Polyurethane-forming no-bake foundry binder systems |
SI0771599T2 (en) * | 1995-11-01 | 2004-04-30 | Huettenes-Albertus | Binder based on polyurethanes for producing foundry mould and core compositions |
-
1996
- 1996-10-22 SI SI9630033T patent/SI0771599T2/xx not_active IP Right Cessation
- 1996-10-22 NZ NZ299622A patent/NZ299622A/xx unknown
- 1996-10-22 DK DK96116921T patent/DK0771599T4/da active
- 1996-10-22 DE DE59600596T patent/DE59600596D1/de not_active Expired - Lifetime
- 1996-10-22 ES ES96116921T patent/ES2103248T5/es not_active Expired - Lifetime
- 1996-10-22 AT AT96116921T patent/ATE171405T1/de active
- 1996-10-22 EP EP96116921A patent/EP0771599B2/de not_active Expired - Lifetime
- 1996-10-24 TR TR96/00848A patent/TR199600848A2/xx unknown
- 1996-10-28 AR ARP960104940A patent/AR004231A1/es unknown
- 1996-10-28 IL IL11950396A patent/IL119503A0/xx unknown
- 1996-10-29 PL PL96316773A patent/PL181888B1/pl unknown
- 1996-10-29 CA CA002189106A patent/CA2189106C/en not_active Expired - Lifetime
- 1996-10-29 KR KR1019960049449A patent/KR100366819B1/ko active IP Right Grant
- 1996-10-29 BG BG100947A patent/BG100947A/xx unknown
- 1996-10-30 NO NO19964589A patent/NO315614B1/no not_active IP Right Cessation
- 1996-10-30 MX MX9605232A patent/MX9605232A/es unknown
- 1996-10-30 CZ CZ19963179A patent/CZ291051B6/cs not_active IP Right Cessation
- 1996-10-30 CN CN96122764A patent/CN1159373A/zh active Pending
- 1996-10-30 HR HR19612017.9A patent/HRP960510A2/hr not_active Application Discontinuation
- 1996-10-31 JP JP30424096A patent/JP3647998B2/ja not_active Expired - Lifetime
- 1996-10-31 AU AU70523/96A patent/AU704232B2/en not_active Ceased
- 1996-10-31 HU HU9603016A patent/HU216901B/hu not_active IP Right Cessation
- 1996-10-31 BR BR9604485A patent/BR9604485A/pt not_active IP Right Cessation
- 1996-10-31 US US08/742,945 patent/US6136888A/en not_active Expired - Lifetime
- 1996-10-31 YU YU57796A patent/YU57796A/sh unknown
-
2004
- 2004-11-26 JP JP2004341495A patent/JP4061299B2/ja not_active Expired - Lifetime
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