EP1514599A1 - Catalyseur et procede de clarification de gaz d'echappement - Google Patents
Catalyseur et procede de clarification de gaz d'echappement Download PDFInfo
- Publication number
- EP1514599A1 EP1514599A1 EP03730799A EP03730799A EP1514599A1 EP 1514599 A1 EP1514599 A1 EP 1514599A1 EP 03730799 A EP03730799 A EP 03730799A EP 03730799 A EP03730799 A EP 03730799A EP 1514599 A1 EP1514599 A1 EP 1514599A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- catalyst
- exhaust gas
- zeolite
- methanol
- proton type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/21—Organic compounds not provided for in groups B01D2251/206 or B01D2251/208
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20746—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
- B01D2255/502—Beta zeolites
Definitions
- the present invention relates to an catalyst for purifying exhaust gas effective for removing nitrogen oxides (NO x ) contained in various types of combustion exhaust gas from boilers, diesel engine motors or diesel engine motor vehicles and from industrial facilities and a method for purifying the exhaust gas using the catalyst.
- NO x nitrogen oxides
- Nitrogen oxides (NO x ) such as nitrogen monoxide and nitrogen dioxide are contained in various types of exhaust gas from factories, electric power facilities, other industrial facilities and motor vehicles. This NO x not only affects especially on the respiratory system of human body but also causes acid rain seen as a problem in global environment conservation. Therefore, a technical development effective for removing nitrogen oxides in various types of exhaust gas is desired.
- a reduction catalyst which comprises alumina or silica-alumina including 0.1-4 weight % Cu, Fe, Cr, Zn, Ni or V of 0.1-4 has been reported (Refer to JP KOKAI Hei 04-284848).
- each method for purifying the exhaust gas using NO x removal catalyst has a problem that, in the exhaust gas containing sulfur oxides and excess oxygen, the NO x removal performance deteriorates remarkably and the practicable durability is insufficient. Furthermore, it has also a problem that NO x removal performance is low if the majority of the exhaust gas is at relatively low temperature of 300-400°C.
- An object of this invention is, in consideration of such circumstances, to provide a catalyst for purifying exhaust gas, having an excellent NO x removal performance and durability even against the exhaust gas containing sulfur oxides, and having a high denitration performance and an excellent practicality even when the exhaust gas is at relatively low temperature of 300-400°C, and to provide a method of purifying exhaust gas using the catalyst.
- the catalyst for purifying exhaust gas according to the present invention is able to reduce and remove nitrogen oxides in the exhaust gas in which excessive oxygen exsists, under the existence of methanol and/or dimethyl ether, is characterized in that it consists of a proton type ⁇ zeolite.
- the method for purifying the exhaust gas according to the present invention in order to reduce and remove nitrogen oxides in the exhaust gas, comprises a step of making the exhaust gas in which excessive oxygen exists contact with the proton type ⁇ zeolite catalyst under the existence of methanol and /or dimethyl ether which is a reducing agent.
- a SiO 2 /Al 2 O 3 molar ratio of the proton type ⁇ zeolite is within 20-70.
- the present invention can provide a catalyst for purifying exhaust gas having an excellent NO x removal performance and durability, and by using the catalyst, it is possible to effectively remove NO x in the exhaust gas in which excessive oxygen exists.
- the exhaust gas purifying catalyst according to the present invention shows a high NO x removal efficiency even against the exhaust gas containing a large amount of sulfur oxides, and it is quite excellent in practice because the denitration performance does not deteriorate even when the exhaust gas is at relatively low temperature of 300-400°C.
- the present invention at the denitration of nitrogen oxides (NO x ) in the exhaust gas in which excessive oxygen exists, uses a proton type ⁇ zeolite as a catalyst.
- a proton type ⁇ zeolite As the zeolite, besides type ⁇ , there are many types such as type Y, L, ZSM-5 (FMI), mordenite and the like, and among them, it is cleared that the proton type ⁇ zeolite which is a hydrogenated ⁇ zeolite is especially quite effective for purifying the exhaust gas containing sulfur oxides. That is, by using proton type ⁇ zeolite, the nitrogen oxides in the exhaust gas containing sulfur oxides can be reduced and removed under the existence of methanol and /or dimethyl ether.
- the proton type ⁇ zeolite is made, for example, by treating ⁇ zeolite with aqueous ammonium nitrate solution and the like so as to be ammonium type, and thereafter burning it to make ammonia emitted.
- the proton type ⁇ zeolite can be molded and can be formed as various shape catalysts in accordance with usage.
- a silica (SiO 2 )-alumina (Al 2 O 3 ) ratio of the proton type ⁇ zeolite is, in terms of the denitration performance which removes NO x , within 20-70 in molar ratio. Above 40 of the molar ratio, the denitration performance tends to deteriorate, and, considering stability against heat and vapor, it is more desirable that a SiO 2 -Al 2 O 3 molar ratio is within 20-40.
- the proton type ⁇ zeolite catalyst can be molded in various shapes such as spherical, honeycomb, pellet state and the like by conventional molding methods. These shapes and sizes may be selected arbitrarily according to use conditions of catalyst. Furthermore, a catalyst can be made by means of wash-coating or otherwise proton type ⁇ zeolite on the surface of a support plate having fireproof construction with some through-holes in the flow direction of the exhaust gas.
- the exhaust gas may be contacted with the above-mentioned proton type ⁇ zeolite catalyst of the present invention under the existence of methanol and/or dimethyl ether.
- the amount of methanol and/or dimethyl ether coexisting in the exhaust gas as reducing agent may be selected arbitrarily according to the NO x removal efficiency or running cost which are operationally required, but typically, it is desirable that the molar ratio (in carbon (C)) of the exhaust gas to nitrogen oxides is 0.5-5 degree.
- exhaust gases containing nitrogen oxides to which the present invention is applied there are gases exhausted from various combustion facilities such as boiler or the like, internal combustion engines of diesel engine motor vehicles or stationary diesel engines or the like, and industrial facilities such as nitric acid production facility.
- These exhaust gases generally contain reducing component such as CO, HC (Hydrocarbon) and H 2 , and oxidizing component such as NO x and O 2 , but contain oxygen amount in excess of stoichiometric amount necessary for complete oxygen reduction reaction of the oxidising component.
- NO x in the exhaust gas in which excessive oxygen exists is reduced and decomposited into N 2 and H 2 O, by making the exhaust gas contact with the catalyst of the present invention under the existence of methanol and/or dimethyl ether.
- a gas space velocity (SV) in the method for purifying the exhaust gas using the catalyst according to the present invention is, not to be considered limited to, 1,000-100,000 mh -1 . Furthermore, even when the exhaust gas is at relatively low temperature of 300-400°C, an excellent denitration performance can be obtained substantially equivalent to the case at high temperature. Besides, the catalyst of the present invention has an excellent denitration performance even against the exhaust gas containing sulfur oxides and is also excellent in its durability.
- the exhaust gas when the exhaust gas is treated by the method according to the present invention, depending on reaction condition, unburned methanol or dimethyl ether and poor combustion product are exhausted in the gas.
- the methanol or dimethyl ether and poor combustion product can be removed by making the exhaust gas contact with an oxidation catalyst which is for example supported by precious metals such as Pt or Pd.
- a proton type ⁇ zeolite was obtained by burning NH 4 type ⁇ zeolite (SiO 2 /Al 2 O 3 molar ratio: 27) on the market at 450°C for 5 hours. This zeolite was pressure-formed, grained to the particle size of 350-500 ⁇ m, and defined as Catalyst 1 of the present invention. Furthermore, another proton type ⁇ zeolite was obtained by above-mentioned method except for using NH 4 type ⁇ zeolite (SiO 2 /Al 2 O 3 molar ratio: 37) on the market. This zeolite was defined herein as Catalyst 2 of the present invention.
- Catalyst C1 is a proton type ⁇ zeolite which is obtained by burning a commercially available NH 4 type ⁇ zeolite (SiO 2 /Al 2 O 3 molar ratio: 75) at 450°C for 5 hours.
- Catalyst C2 is a proton type ⁇ zeolite which is obtained by burning a commercially available NH 4 type ⁇ mordenite (SiO 2 /Al 2 O 3 molar ratio: 20) at 450°C for 5 hours.
- Catalyst C3 is a proton type ZSM-5 which is obtained by burning NH 4 type ZSM-5(SiO 2 /Al 2 O 3 molar ratio: 27) on the market at 450°C for 5 hours.
- Catalyst C4 is made of ⁇ zeolite carrying CO which is obtained by mixing 100g of ion-exchanged water with 1.3g of cobalt acetate tetrahydrate, dispersing 10g of proton type ⁇ zeolite (SiO 2 /Al 2 O 3 molar ratio: 27) obtained by the above-mentioned method of Catalyst 1 into the solution, agitating at 60°C for 12 hours, and then, after filtering, wet-cleaning and drying at 110°C, burning at 500°C for 3 hours in the atmosphere.
- the amount of Co in the Catalyst 4 was 2.7 weight % in metal to the whole catalyst.
- Catalyst 1, 2 and comparative examples of Catalyst C1-C4 obtained by the above-mentioned methods were filled into each reaction tube of steel measuring 15mm in inner diameter so as to form catalyst body, and these were fixed on the atmospheric fixed bed flow reactor.
- a mixed gas consisting of NO: 1,000ppm, O 2 : 10%, methanol: 1,000ppm, H 2 O: 10%, SO 2 : 100ppm, and remnant: N 2 was supplied under the condition that the special velocity is 30,0000h -1 , and the NO x removal performance of each catalyst was evaluated.
- gas temperature was changed to at 300, 350 and 400°C, respectively.
- the denitration performance of each catalyst was evaluated in the same way by changing gas composition of the model exhaust gas. That is, the denitration performance was evaluated by changing methanol: 1,500ppm which was added in the above-mentioned exhaust gas model as reducing agent to dimethyl ether :750ppm, and by using Catalyst 1, C2 and C3. Furthermore, the denitration performance was evaluated by changing the reducing agent to propylene: 500ppm and 1,000ppm and using Catalyst 1.
- NO x removal efficiency [NO x concentration at reaction tube entry- NO x concentration at reaction tube exit/(NO x concentration at reaction tube entry)] x 100.
- Catalysts 1 and 2 according to the present invention compared to comparison example Catalysts C1-C4, have remarkably excellent NO x removal performance in the exhaust gas containing excessive oxygen in which a large amount of sulfur oxides exists, even at relatively low temperature of 300-400°C
- Catalyst 1 and 2 according to the invention by using methanol and / or dimethyl ether as reducing agent, an excellent denitration performance is appeared.
- Catalyst C1 which is a proton type ⁇ zeolite but SiO 2 /Al 2 O 3 molar ratio is 75 has an extremely small NO x removal efficiency.
- Sample Catalyst Reducing agent NOx removal efficiency (%) 300°C 350°C 400°C 1
- the catalyst which is made of the proton type ⁇ zeolite catalyst according to the present invention keeps a high activity and has an excellent durability.
- the catalysts of comparative examples proton type mordenite? catalyst C2 and proton type ZSM-5 catalyst C3 having low denitration performance show favorable durability, but Catalyst C4 having comparatively excellent denitration performance, which is made of ⁇ zeolite which supports CO is inferior in durability.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Crystallography & Structural Chemistry (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002175187 | 2002-06-17 | ||
JP2002175187 | 2002-06-17 | ||
JP2002341623A JP3994862B2 (ja) | 2002-06-17 | 2002-11-26 | 排ガス浄化触媒及び浄化方法 |
JP2002341623 | 2002-11-26 | ||
PCT/JP2003/007017 WO2003106026A1 (fr) | 2002-06-17 | 2003-06-03 | Catalyseur et procede de clarification de gaz d'echappement |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1514599A1 true EP1514599A1 (fr) | 2005-03-16 |
EP1514599A4 EP1514599A4 (fr) | 2006-04-19 |
Family
ID=29738412
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03730799A Withdrawn EP1514599A4 (fr) | 2002-06-17 | 2003-06-03 | Catalyseur et procede de clarification de gaz d'echappement |
Country Status (6)
Country | Link |
---|---|
US (1) | US7405175B2 (fr) |
EP (1) | EP1514599A4 (fr) |
JP (1) | JP3994862B2 (fr) |
CN (1) | CN1305568C (fr) |
AU (1) | AU2003244103A1 (fr) |
WO (1) | WO2003106026A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006052168A1 (fr) * | 2004-10-11 | 2006-05-18 | Volvo Lastvagnar Ab | Systeme et procede de reduction des oxydes d'azote des gaz d'echappement generes par un moteur a combustion interne a melange pauvre |
EP3165274A3 (fr) * | 2015-11-09 | 2017-07-19 | M.A.L. Umwelttechnik - GmbH | Procédé de réduction sélective d'oxydes d'azote dans des gaz chauds |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201608643D0 (en) * | 2016-05-17 | 2016-06-29 | Thermo Fisher Scient Bremen | Elemental analysis system and method |
CN106423297A (zh) * | 2016-11-02 | 2017-02-22 | 金福兴 | 一种汽车尾气处理净化剂及其制备方法 |
CN110711465A (zh) * | 2018-07-11 | 2020-01-21 | 陕西捷强科贸有限公司 | 一种高温脱硝剂及采用其进行烟气脱硝处理的方法 |
CN112156630B (zh) * | 2020-10-10 | 2022-02-08 | 清华大学 | 一种500-900度脱硝增效方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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US5279997A (en) * | 1991-10-07 | 1994-01-18 | Ford Motor Company | Selective reduction of NOx |
US5374410A (en) * | 1992-07-08 | 1994-12-20 | Grasselli; Robert K. | NOx abatement process |
EP0945166A1 (fr) * | 1993-11-04 | 1999-09-29 | ENITECNOLOGIE S.p.a. | Catalyseur pour la réduction de NOx dans des gaz de combustion |
DE19854502A1 (de) * | 1998-11-25 | 2000-05-31 | Siemens Ag | Katalysatorkörper und Verfahren zum Abbau von Stickoxiden |
US6150291A (en) * | 1995-04-27 | 2000-11-21 | Engelhard Corporation | Method of abating NOx and preparation of catalytic material therefor |
EP1166856A2 (fr) * | 2000-06-28 | 2002-01-02 | ICT Co., Ltd. | Catalyseur pour la purification de gaz d'échappement |
Family Cites Families (20)
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US3308069A (en) * | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
EP0330424A3 (fr) | 1988-02-23 | 1992-03-11 | Digital Equipment Corporation | Système d'expert pour l'identification des limites de performance des opérations de traitement d'un système de traitement numérique de données |
JPH07106300B2 (ja) | 1989-12-08 | 1995-11-15 | 財団法人産業創造研究所 | 燃焼排ガス中の窒素酸化物除去法 |
KR100201748B1 (ko) * | 1990-05-28 | 1999-06-15 | 사또 다께오 | 배기가스로부터 질소산화물을 제거하는 방법 |
JPH07112527B2 (ja) | 1991-02-01 | 1995-12-06 | 工業技術院長 | 気体中の窒素酸化物の除去方法 |
JPH04267946A (ja) | 1991-02-25 | 1992-09-24 | Toyota Motor Corp | 排気ガス浄化用触媒 |
JPH04354536A (ja) | 1991-05-29 | 1992-12-08 | Asahi Glass Co Ltd | 窒素酸化物分解触媒と窒素酸化物の分解方法 |
JPH05103949A (ja) | 1991-10-21 | 1993-04-27 | Nippon Shokubai Co Ltd | 窒素酸化物除去用触媒及びそれを用いてなる窒素酸化物除去方法 |
JP2506598B2 (ja) * | 1992-03-12 | 1996-06-12 | 工業技術院長 | 窒素酸化物の除去方法 |
US5407880A (en) * | 1992-11-09 | 1995-04-18 | Nissan Motor Co., Ltd. | Catalysts for adsorption of hydrocarbons |
US6171556B1 (en) * | 1992-11-12 | 2001-01-09 | Engelhard Corporation | Method and apparatus for treating an engine exhaust gas stream |
US5776423A (en) * | 1994-05-10 | 1998-07-07 | Engelhard Corporation | Trimetallic zeolite catalyst and method of NOx abatement using the same |
CN1043313C (zh) * | 1994-06-29 | 1999-05-12 | 中国石油化工总公司抚顺石油化工研究院 | 一种由苯胺合成二苯胺的催化剂及其制备方法 |
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KR100284936B1 (ko) * | 1998-12-31 | 2001-04-02 | 김충섭 | 촉매 활성 귀금속 담지 제올라이트계 탈질 촉매의 제조 방법 |
JP2002219338A (ja) * | 2000-11-27 | 2002-08-06 | National Institute Of Advanced Industrial & Technology | 窒素酸化物の還元処理方法 |
-
2002
- 2002-11-26 JP JP2002341623A patent/JP3994862B2/ja not_active Expired - Fee Related
-
2003
- 2003-06-03 EP EP03730799A patent/EP1514599A4/fr not_active Withdrawn
- 2003-06-03 AU AU2003244103A patent/AU2003244103A1/en not_active Abandoned
- 2003-06-03 CN CNB038139863A patent/CN1305568C/zh not_active Expired - Fee Related
- 2003-06-03 WO PCT/JP2003/007017 patent/WO2003106026A1/fr active Application Filing
- 2003-06-03 US US10/518,005 patent/US7405175B2/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5279997A (en) * | 1991-10-07 | 1994-01-18 | Ford Motor Company | Selective reduction of NOx |
US5374410A (en) * | 1992-07-08 | 1994-12-20 | Grasselli; Robert K. | NOx abatement process |
EP0945166A1 (fr) * | 1993-11-04 | 1999-09-29 | ENITECNOLOGIE S.p.a. | Catalyseur pour la réduction de NOx dans des gaz de combustion |
US6150291A (en) * | 1995-04-27 | 2000-11-21 | Engelhard Corporation | Method of abating NOx and preparation of catalytic material therefor |
DE19854502A1 (de) * | 1998-11-25 | 2000-05-31 | Siemens Ag | Katalysatorkörper und Verfahren zum Abbau von Stickoxiden |
EP1166856A2 (fr) * | 2000-06-28 | 2002-01-02 | ICT Co., Ltd. | Catalyseur pour la purification de gaz d'échappement |
Non-Patent Citations (1)
Title |
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See also references of WO03106026A1 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006052168A1 (fr) * | 2004-10-11 | 2006-05-18 | Volvo Lastvagnar Ab | Systeme et procede de reduction des oxydes d'azote des gaz d'echappement generes par un moteur a combustion interne a melange pauvre |
EP3165274A3 (fr) * | 2015-11-09 | 2017-07-19 | M.A.L. Umwelttechnik - GmbH | Procédé de réduction sélective d'oxydes d'azote dans des gaz chauds |
Also Published As
Publication number | Publication date |
---|---|
CN1305568C (zh) | 2007-03-21 |
EP1514599A4 (fr) | 2006-04-19 |
JP3994862B2 (ja) | 2007-10-24 |
WO2003106026A1 (fr) | 2003-12-24 |
US20050207957A1 (en) | 2005-09-22 |
AU2003244103A1 (en) | 2003-12-31 |
CN1662305A (zh) | 2005-08-31 |
JP2004074139A (ja) | 2004-03-11 |
US7405175B2 (en) | 2008-07-29 |
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