EP1421582A1 - Optischer datenträger enthaltend in der informationsschicht einen phthalocyaninfarbstoff als lichtabsorbierende verbindung - Google Patents
Optischer datenträger enthaltend in der informationsschicht einen phthalocyaninfarbstoff als lichtabsorbierende verbindungInfo
- Publication number
- EP1421582A1 EP1421582A1 EP02758471A EP02758471A EP1421582A1 EP 1421582 A1 EP1421582 A1 EP 1421582A1 EP 02758471 A EP02758471 A EP 02758471A EP 02758471 A EP02758471 A EP 02758471A EP 1421582 A1 EP1421582 A1 EP 1421582A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- light
- weight
- stands
- phthalocyanine
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 39
- 150000001875 compounds Chemical class 0.000 title claims abstract description 21
- 239000001007 phthalocyanine dye Substances 0.000 title description 3
- 239000010410 layer Substances 0.000 claims abstract description 66
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000460 chlorine Substances 0.000 claims abstract description 22
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 239000011241 protective layer Substances 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 8
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims abstract description 8
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 8
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 8
- 239000011737 fluorine Substances 0.000 claims abstract description 8
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 8
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 8
- 150000002367 halogens Chemical group 0.000 claims abstract description 8
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 8
- 229910052718 tin Inorganic materials 0.000 claims abstract description 8
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 12
- 238000003860 storage Methods 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- 150000004696 coordination complex Chemical class 0.000 claims description 2
- -1 for example Substances 0.000 claims description 2
- 230000015654 memory Effects 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 14
- 239000000126 substance Substances 0.000 description 11
- 238000002310 reflectometry Methods 0.000 description 10
- 239000012790 adhesive layer Substances 0.000 description 9
- 238000004544 sputter deposition Methods 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000013500 data storage Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 238000007738 vacuum evaporation Methods 0.000 description 5
- 239000008187 granular material Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- 238000004528 spin coating Methods 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- 238000007740 vapor deposition Methods 0.000 description 4
- RZVCEPSDYHAHLX-UHFFFAOYSA-N 3-iminoisoindol-1-amine Chemical compound C1=CC=C2C(N)=NC(=N)C2=C1 RZVCEPSDYHAHLX-UHFFFAOYSA-N 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229910001507 metal halide Inorganic materials 0.000 description 3
- 150000005309 metal halides Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XQZYPMVTSDWCCE-UHFFFAOYSA-N phthalonitrile Chemical compound N#CC1=CC=CC=C1C#N XQZYPMVTSDWCCE-UHFFFAOYSA-N 0.000 description 3
- 229920006391 phthalonitrile polymer Polymers 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000001208 nuclear magnetic resonance pulse sequence Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004923 Acrylic lacquer Substances 0.000 description 1
- 229910017488 Cu K Inorganic materials 0.000 description 1
- 229910017541 Cu-K Inorganic materials 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 240000007651 Rubus glaucus Species 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- BBRNKSXHHJRNHK-UHFFFAOYSA-L p0997 Chemical compound N1=C(C2=CC=CC=C2C2=NC=3C4=CC=CC=C4C(=N4)N=3)N2[Sn](Cl)(Cl)N2C4=C(C=CC=C3)C3=C2N=C2C3=CC=CC=C3C1=N2 BBRNKSXHHJRNHK-UHFFFAOYSA-L 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 235000021013 raspberries Nutrition 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B44/00—Azo dyes containing onium groups
- C09B44/10—Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/045—Special non-pigmentary uses, e.g. catalyst, photosensitisers of phthalocyanine dyes or pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
- C09B47/085—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex substituting the central metal atom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0097—Dye preparations of special physical nature; Tablets, films, extrusion, microcapsules, sheets, pads, bags with dyes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/004—Recording, reproducing or erasing methods; Read, write or erase circuits therefor
- G11B7/0045—Recording
- G11B7/00455—Recording involving reflectivity, absorption or colour changes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/007—Arrangement of the information on the record carrier, e.g. form of tracks, actual track shape, e.g. wobbled, or cross-section, e.g. v-shaped; Sequential information structures, e.g. sectoring or header formats within a track
- G11B7/00718—Groove and land recording, i.e. user data recorded both in the grooves and on the lands
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/248—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes porphines; azaporphines, e.g. phthalocyanines
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/249—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing organometallic compounds
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/26—Apparatus or processes specially adapted for the manufacture of record carriers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/007—Arrangement of the information on the record carrier, e.g. form of tracks, actual track shape, e.g. wobbled, or cross-section, e.g. v-shaped; Sequential information structures, e.g. sectoring or header formats within a track
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/254—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/21—Circular sheet or circular blank
Definitions
- the invention relates to a write-once optical data carrier which contains at least one phthalocyanine dye in the information layer as a light-absorbing compound, and to a process for its preparation and the application of the above-mentioned dyes to a polymer substrate, in particular polycarbonate Spin coating, vapor deposition or sputtering.
- the write-once optical data carriers using special light-absorbing substances or their mixtures are particularly suitable for use with high-density writable optical data storage devices that work with blue laser diodes, in particular GaN or SHG laser diodes (360 - 460 nm) and / or for use with DVD-R or CD-R discs that work with red (635 - 660 nm) or infrared (780 - 830 nm) laser diodes.
- the next generation of optical data storage media - the DVD - was recently launched.
- the storage density can be increased by using shorter-wave laser radiation (635 to 660 nm) and a higher numerical aperture NA.
- the write-once format is the DVD-R.
- the recordable information layer made of light-absorbing organic substances must be as amorphous as possible
- the amorphous layer of light-absorbing substances should preferably have a high heat resistance, since otherwise further layers of organic or inorganic material, which are applied to the light-absorbing information layer by sputtering or vapor deposition, are diffused by diffusion Form interfaces and thus adversely affect reflectivity.
- a light-absorbing substance with too low heat resistance at the interface to a polymeric carrier can diffuse in the latter and in turn adversely affect the reflectivity.
- An excessively high vapor pressure of a light-absorbing substance can sublimate the above-mentioned sputtering or vapor deposition of further layers in a high vacuum and thus reduce the desired layer thickness. This in turn leads to a negative influence on the reflectivity.
- the object of the invention is accordingly to provide suitable connections which meet the high requirements (such as light stability, favorable signal-to-noise ratio, damage-free application to the substrate material, etc.) for use in the information layer in a write-once optical data carrier, in particular for high-density recordable optical media data storage
- Phthalocyanines show an intense absorption in the for the
- Laser important wave range 360 - 460 nm the so-called B or Soret band.
- the present invention therefore relates to an optical data carrier, comprising a preferably transparent substrate, possibly already coated with one or more reflection layers, on the surface of which an information layer which can be written on with light, optionally one or more reflection layers and optionally a protective layer or a further substrate or Cover layer are applied, which with blue light, preferably laser light, particularly preferably light with a wavelength of 360-460 nm, in particular 380-420 nm, very particularly preferably 390-410 nm, or with infrared light, preferably laser light, particularly preferably light with a wavelength from 760 - 830 nm, can be described and read, the information layer containing a light-absorbing compound and optionally a binder, characterized in that at least one phthalocyanine of the formula (I) is used as the light-absorbing compound
- Me stands for a doubly axially substituted metal atom from the group Si, Ge and Sn,
- Pc stands for an unsubstituted phthalocyanine
- Xi and X 2 independently of one another represent halogen, in particular fluorine, chlorine or bromine.
- phthalocyamines of the formula (I) are used, in which X 1 and X 2 each represent chlorine.
- the phthalocyanines used according to the invention are, for example, from Carl W. Dirk et. al. J. Am. Chem. Soc. 1983, 105, 1539 - 1550 are known as precursors for the production of electrically conductive polymers and can be produced as described there.
- the light absorbing compounds are thermally changeable.
- the thermal change preferably takes place at a temperature of ⁇ 600 ° C.
- Such a change can be, for example, a decomposition or chemical change in the chromophoric center of the light-absorbing compound.
- optical data carrier can preferably be written and read with laser light with a wavelength of 360-460 nm.
- the invention further relates to the use of the phthalocyanines of the formula (I) as light-absorbing compounds in the information layer of optical storage media.
- a phthalocyanine of the formula (Ib) with the following reflectivity maxima at 2 ⁇ (theta), measured in degrees, is likewise particularly preferably used in the X-ray diffractogram: 10.6, 11.4, 11.8, 12.3, 13.9, 14.6, 15.3, 15.5, 17.4, 18.4, 19.7, 20.5 , 22.3, 22.7, 23.0,
- the invention further relates to a particulate solid preparation of a compound of formula (I), characterized in that the particles have a medium
- Particle size from 0.5 microns to 10 mm.
- particulate solid preparations those are preferred which have an average particle size of 0.5 to 20 ⁇ m, in particular 1 to 10 ⁇ m - hereinafter referred to as finely divided powder.
- finely divided powder Such fine-grained
- Powders can be produced, for example, by grinding.
- particulate solid preparations with an average particle size of 50 to 300 ⁇ m - hereinafter referred to as fine crystalline form.
- Further preferred particulate solid preparations are those with an average particle size of 50 ⁇ m to 10 mm, preferably 100 ⁇ m to 800 ⁇ m, which form a particulate shaped body as agglomerates or conglomerates of primary particles.
- Such moldings can have the shape of drops, raspberries, scales or sticks, for example - hereinafter referred to as granules.
- the particle size of the finely crystalline form can be set, for example, by means of the synthesis parameters.
- rapid heating for example in the range from 30 to 60 min, of the mixture of the components
- a coarse particle shape is preferably formed by, for example, slow heating, for example in the range from 65 to 250 min, of the mixture of the components to the reaction temperature, for example 160 to 220 ° C.
- the particulate solid preparations according to the invention preferably contain 80-100% by weight, preferably 95-100% phthalocyanine, 0.1-1.0% by weight, preferably 0.1-0.5% by weight, residual moisture, 0-10% by weight. %, inorganic salts, 0 '- 10 wt.% o, preferably 0 - 5 wt.%>, further additives such as, for example
- Dispersing agents, surfactants and / or wetting agents the percentages being based in each case on the preparation and, the sum of the proportions given being 100%.
- the solid preparations according to the invention are preferably low-dust, free-flowing and are notable for good storage stability.
- the granules can be produced in various ways, for example by spray drying granulation, fluidized bed spray granulation, fluidized bed build-up granulation or powder-fluidized bed agglomeration.
- Granulation by spray drying is preferred, with both rotary disks and single-substance or two-substance nozzles being suitable as the spray element.
- the inlet and outlet temperatures for spray drying depend on the desired residual moisture, safety measures and economic considerations.
- the inlet temperature is preferably 120-200 ° C, in particular 140-180 ° C, and the outlet temperature preferably 40-80 ° C.
- the procedure is generally such that the dye filter cake is mixed intensively, if appropriate with auxiliaries and additives, in a stirred kettle.
- the crystals of the suspension are preferably ground in a mill, e.g. a bead mill, so that a finely divided, sprayable suspension is obtained.
- the dye suspension is an aqueous suspension.
- the granulation takes place during spray drying.
- the invention further relates to a method for coating substrates with the phthalocyanines of the formula (I). It is preferably carried out by spin coating, sputtering or vacuum evaporation.
- the phthalocyanines of the formulas (Ia), (Ib), (Ic) and (Id) can in particular be applied by vacuum evaporation or sputtering, in particular vacuum evaporation.
- phthalocyanines of the formula (I) i.e. H. finely divided powders, finely crystalline forms or granules, particulate solid preparations, solid moldings and dispersions.
- the latter serve in particular to apply the phthalocyanines in fine particles to a surface from which they can then be applied to the substrate by sputtering or vacuum evaporation.
- the invention relates in particular to an optical data carrier as described above, the light-absorbing compound of the formula (I), optionally together with the additives mentioned above, forming an information layer which is optically amorphous.
- Amorphous is understood to mean that no crystallites can be observed by light microscopy and that no X-rays can be used to observe Bragg reflections but only an amorphous halo.
- the optical data storage device can carry further layers such as metal layers, dielectric layers and protective layers.
- Metals and dielectric layers serve u. a. to adjust the reflectivity and the heat balance. Depending on the laser wavelength, metals can be gold, silver, aluminum, alloys, etc. his.
- Dielectric layers are, for example, silicon dioxide and silicon nitride.
- Protective layers are, for example, photocurable lacquers, adhesive layers and protective films.
- the adhesive layers can be pressure sensitive.
- Pressure-sensitive adhesive layers mainly consist of acrylic adhesives.
- the optical data carrier has, for example, the following layer structure (cf.
- a transparent substrate (1) optionally a protective layer (2), an information layer (3), optionally a protective layer (4), optionally an adhesive layer (5), a cover layer (6).
- the structure of the optical data carrier can preferably:
- a transparent substrate (1) on the surface of which at least one information layer (3) which can be written on with light and which can be written on with light, preferably laser light, optionally a protective layer (4), optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
- a transparent substrate (1) on the surface of which a protective layer (2), at least one information layer (3) which can be written on with light, preferably laser light, optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
- a preferably transparent substrate (1) on the surface of which there is optionally a protective layer (2), at least one information layer (3) that can be written on with light, preferably laser light, and optionally one
- Protective layer (4) optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
- a preferably transparent substrate (1) on the surface of which at least one information that can be written on with light, preferably laser light tion layer (3), optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
- the optical data carrier has, for example, the following layer structure (cf. FIG. 2): a preferably transparent substrate (11), an information layer
- the optical data carrier has, for example, the following layer structure (cf. FIG. 3): a preferably transparent substrate (21), an information layer
- the structure of the optical data carrier can be:
- Photocurable lacquers are particularly preferred as separating layers.
- the invention further relates to optical data carriers according to the invention described with blue light, in particular laser light, particularly preferably laser light with a wavelength of 360-460 nm.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02758471A EP1421582A1 (de) | 2001-08-22 | 2002-08-19 | Optischer datenträger enthaltend in der informationsschicht einen phthalocyaninfarbstoff als lichtabsorbierende verbindung |
Applications Claiming Priority (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10140165 | 2001-08-22 | ||
| DE2001140165 DE10140165A1 (de) | 2001-08-22 | 2001-08-22 | Optischer Datenträger enthaltend in der Informationsschicht einen Phthalocyaninfarbstoff als lichtabsorbierende Verbindung |
| EP01123810 | 2001-10-04 | ||
| EP01123810 | 2001-10-04 | ||
| EP01130527 | 2001-12-21 | ||
| EP01130527 | 2001-12-21 | ||
| EP02005505 | 2002-03-11 | ||
| EP02005505 | 2002-03-11 | ||
| DE10212199 | 2002-03-19 | ||
| DE10212199 | 2002-03-19 | ||
| PCT/EP2002/009240 WO2003019548A1 (de) | 2001-08-22 | 2002-08-19 | Optischer datenträger enthaltend in der informationsschicht einen phthalocyaninfarbstoff als lichtabsorbierende verbindung |
| EP02758471A EP1421582A1 (de) | 2001-08-22 | 2002-08-19 | Optischer datenträger enthaltend in der informationsschicht einen phthalocyaninfarbstoff als lichtabsorbierende verbindung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1421582A1 true EP1421582A1 (de) | 2004-05-26 |
Family
ID=27512422
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP02758471A Withdrawn EP1421582A1 (de) | 2001-08-22 | 2002-08-19 | Optischer datenträger enthaltend in der informationsschicht einen phthalocyaninfarbstoff als lichtabsorbierende verbindung |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6896945B2 (enExample) |
| EP (1) | EP1421582A1 (enExample) |
| JP (1) | JP2005500923A (enExample) |
| CN (1) | CN1545702A (enExample) |
| TW (1) | TWI256635B (enExample) |
| WO (1) | WO2003019548A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002080150A2 (en) * | 2001-03-28 | 2002-10-10 | Bayer Aktiengesellschaft | Optical data medium containing, in the information layer, a dye as a lightabsorbing compound and having a protective covering layer of predetermined thickness |
| US20050142489A1 (en) * | 2002-03-19 | 2005-06-30 | Horst Berneth | Squarylium dyes as light-absorbing compound in the information layer of optical data carriers |
| WO2005000972A2 (en) * | 2003-06-27 | 2005-01-06 | Ciba Specialty Chemicals Holding Inc. | Optical recording materials having high storage density |
| DE10329711A1 (de) * | 2003-07-02 | 2005-01-27 | Bayer Chemicals Ag | Verfahren zur Herstellung von alkoxysubstituierten Phthalocyaninen |
| JP2005141809A (ja) * | 2003-11-05 | 2005-06-02 | Fuji Photo Film Co Ltd | 光記録媒体および情報記録方法 |
| JP2005196818A (ja) * | 2003-12-26 | 2005-07-21 | Toshiba Corp | 光ディスク |
| JP2007522973A (ja) * | 2004-02-24 | 2007-08-16 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 青色レーザーを使用して書き込みが可能な光学記録材料 |
| MXPA06013852A (es) * | 2004-06-03 | 2007-03-02 | Clariant Finance Bvi Ltd | Uso de colorantes de acido escuarico en capas opticas para el registro optico de datos. |
| CN101076859A (zh) * | 2004-10-18 | 2007-11-21 | 富士胶片株式会社 | 光信息记录介质及其制作方法 |
| US20080199809A1 (en) * | 2007-02-16 | 2008-08-21 | Fujifilm Corporation | Optical information recording medium and method of recording information |
| US20080199808A1 (en) * | 2007-02-16 | 2008-08-21 | Fujifilm Corporation | Optical information recording medium and method of recording information |
| CN105722921A (zh) * | 2013-10-31 | 2016-06-29 | 沙特基础工业全球技术公司 | 用于制备轴向氟化酞菁的方法和它们在光伏应用中的用途 |
| US10642087B2 (en) | 2014-05-23 | 2020-05-05 | Eyesafe, Llc | Light emission reducing compounds for electronic devices |
| CN107924005B (zh) * | 2015-06-15 | 2022-06-17 | 人眼安全公司 | 用于电子设备的发光减少化合物 |
| US11592701B2 (en) | 2018-11-28 | 2023-02-28 | Eyesafe Inc. | Backlight unit with emission modification |
| US12321060B1 (en) | 2018-11-28 | 2025-06-03 | Eyesafe Inc. | Color filter enhancements for display devices |
| US11810532B2 (en) | 2018-11-28 | 2023-11-07 | Eyesafe Inc. | Systems for monitoring and regulating harmful blue light exposure from digital devices |
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| US3094536A (en) | 1961-01-03 | 1963-06-18 | Malcolm E Kenney | Silicon phthalocyanines |
| JP2557335B2 (ja) | 1984-03-02 | 1996-11-27 | 三菱電機株式会社 | 情報の記録・再生方法 |
| DE3716734A1 (de) | 1987-05-19 | 1988-12-01 | Basf Ag | Optisches aufzeichnungsmedium, das eine silicium-phthalocyaninderivat enthaltende reflektorschicht aufweist |
| US5109016A (en) | 1988-05-23 | 1992-04-28 | Georgia State University Foundation, Inc. | Method for inhibiting infection or replication of human immunodeficiency virus with porphyrin and phthalocyanine antiviral compositions |
| KR910005252A (ko) | 1989-08-30 | 1991-03-30 | 미다 가쓰시게 | 광정보 기록매체 |
| US5248538A (en) | 1991-06-18 | 1993-09-28 | Eastman Kodak Company | Sulfonamido or amido substituted phthalocyanines for optical recording |
| EP0540468B1 (de) | 1991-10-30 | 1996-12-04 | Ciba-Geigy Ag | NIR-Farbstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung |
| EP0575816B1 (en) | 1992-06-12 | 1999-09-22 | Mitsui Chemicals, Inc. | Light-absorbing compound and optical recording medium containing same |
| JP2865955B2 (ja) | 1992-09-09 | 1999-03-08 | 日本コロムビア株式会社 | 光記録媒体 |
| JP3218770B2 (ja) | 1993-01-14 | 2001-10-15 | 富士ゼロックス株式会社 | 電子写真感光体とそのためのフタロシアニン顔料および顔料分散液 |
| JPH07157677A (ja) * | 1993-12-03 | 1995-06-20 | Toyo Ink Mfg Co Ltd | ハロゲン化フタロシアニンの製造方法 |
| JP3523700B2 (ja) | 1995-01-12 | 2004-04-26 | 日亜化学工業株式会社 | 窒化物半導体レーザ素子 |
| JP3558747B2 (ja) | 1995-08-03 | 2004-08-25 | 松下電器産業株式会社 | 記録再生装置 |
| JPH1058828A (ja) | 1996-08-16 | 1998-03-03 | Mitsui Petrochem Ind Ltd | 光記録媒体 |
| JPH10181206A (ja) | 1996-12-26 | 1998-07-07 | Ricoh Co Ltd | 光記録媒体 |
| JPH1143481A (ja) | 1997-07-25 | 1999-02-16 | Ricoh Co Ltd | アゾ化合物、アゾ金属キレート化合物及び光記録媒体 |
| JPH1158953A (ja) | 1997-08-19 | 1999-03-02 | Matsushita Electric Ind Co Ltd | フタロシアニン昇華性材料及びそれを用いた光記録媒体、並びにその光記録再生方法 |
| DE19751448A1 (de) | 1997-11-20 | 1999-05-27 | Bayer Ag | Anorganische Pigmente enthaltende Pigmentpräparationen |
| JP3338660B2 (ja) | 1998-01-21 | 2002-10-28 | ソニー株式会社 | 光ディスク |
| EP1104431B1 (en) | 1998-08-11 | 2002-11-06 | Ciba SC Holding AG | Metallocenyl phthalocyanines |
| JP2004509785A (ja) * | 2000-09-21 | 2004-04-02 | バイエル アクチェンゲゼルシャフト | 情報層中にフタロシアニン染料を光吸収性化合物として含有する光学媒体 |
| WO2002080150A2 (en) * | 2001-03-28 | 2002-10-10 | Bayer Aktiengesellschaft | Optical data medium containing, in the information layer, a dye as a lightabsorbing compound and having a protective covering layer of predetermined thickness |
-
2002
- 2002-08-16 US US10/222,609 patent/US6896945B2/en not_active Expired - Fee Related
- 2002-08-19 CN CNA028163036A patent/CN1545702A/zh active Pending
- 2002-08-19 WO PCT/EP2002/009240 patent/WO2003019548A1/de not_active Ceased
- 2002-08-19 JP JP2003522922A patent/JP2005500923A/ja active Pending
- 2002-08-19 EP EP02758471A patent/EP1421582A1/de not_active Withdrawn
- 2002-08-20 TW TW091118734A patent/TWI256635B/zh not_active IP Right Cessation
Non-Patent Citations (1)
| Title |
|---|
| See references of WO03019548A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1545702A (zh) | 2004-11-10 |
| WO2003019548A1 (de) | 2003-03-06 |
| US6896945B2 (en) | 2005-05-24 |
| JP2005500923A (ja) | 2005-01-13 |
| US20030064192A1 (en) | 2003-04-03 |
| TWI256635B (en) | 2006-06-11 |
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