EP1175254A1 - Alkylation graduelle d'amines polymeriques - Google Patents

Alkylation graduelle d'amines polymeriques

Info

Publication number
EP1175254A1
EP1175254A1 EP00938622A EP00938622A EP1175254A1 EP 1175254 A1 EP1175254 A1 EP 1175254A1 EP 00938622 A EP00938622 A EP 00938622A EP 00938622 A EP00938622 A EP 00938622A EP 1175254 A1 EP1175254 A1 EP 1175254A1
Authority
EP
European Patent Office
Prior art keywords
polymer
acid
polymers
groups
membranes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP00938622A
Other languages
German (de)
English (en)
Inventor
Jochen Kerres
W. Zhang
C. Tang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP1175254A1 publication Critical patent/EP1175254A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B13/00—Diaphragms; Spacing elements
    • C25B13/04—Diaphragms; Spacing elements characterised by the material
    • C25B13/08—Diaphragms; Spacing elements characterised by the material based on organic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
    • B01D71/68—Polysulfones; Polyethersulfones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/80—Block polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/82—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 characterised by the presence of specified groups, e.g. introduced by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/48—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C08G75/23—Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/06—Polysulfones; Polyethersulfones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/20—Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Abstract

L'invention concerne: un procédé d'alkylation graduelle d'amines polymériques primaires par déprotonisation graduelle avec une base organo-métallique et de réaction consécutive avec un halogénure d'alkyle; un procédé de modification des amines polymériques tertiaires selon l'invention avec d'autres groupes fonctionnels; des polymères contenant des groupes aminés secondaires/tertiaires ainsi que des groupes d'ammonium quaternaires; des polymères contenant des groupes aminés secondaires/tertiaires et d'autres groupes fonctionnels, notamment des regroupements d'échangeurs de cations; des membranes constituées des polymères susmentionnés, ces membranes pouvant être non réticulées, réticulées par voie ionique ou par covalence; un procédé de production de mélanges acide-base/membranes en mélange acide-base à partir des polymères basiques selon l'invention avec des polymères contenant des groupes d'acide sulfonique, d'acide phosphonique ou des groupes carboxyle; les mélanges acide-base/membranes en mélange acide/base selon l'invention, les mélanges/ membranes en mélange pouvant être encore une fois par covalence; l'utilisation des polymères échangeurs d'ions selon l'invention comme membranes dans des processus à membrane tels que des piles à combustible à membrane électrolyte polymérique, des piles directes méthanol, des batteries d'oxydoréduction et des électrodialyses; l'utilisation des polymères hydrophiles selon l'invention comme membranes dans la dialyse et l'osmose inverse, la nanofiltration, la dialyse par diffusion, la perméation de gaz, la pervaporation et la perstraction.
EP00938622A 1999-04-30 2000-05-02 Alkylation graduelle d'amines polymeriques Withdrawn EP1175254A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19919708A DE19919708A1 (de) 1999-04-30 1999-04-30 Stufenweise Alkylierung von polymeren Aminen
DE19919708 1999-04-30
PCT/EP2000/003914 WO2000066254A1 (fr) 1999-04-30 2000-05-02 Alkylation graduelle d'amines polymeriques

Publications (1)

Publication Number Publication Date
EP1175254A1 true EP1175254A1 (fr) 2002-01-30

Family

ID=7906422

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00938622A Withdrawn EP1175254A1 (fr) 1999-04-30 2000-05-02 Alkylation graduelle d'amines polymeriques

Country Status (12)

Country Link
US (1) US7132496B2 (fr)
EP (1) EP1175254A1 (fr)
JP (2) JP2002543244A (fr)
KR (1) KR100749156B1 (fr)
CN (1) CN1212177C (fr)
AU (1) AU779428B2 (fr)
BR (1) BR0010170A (fr)
CA (1) CA2371967A1 (fr)
DE (1) DE19919708A1 (fr)
IL (2) IL146208A0 (fr)
WO (1) WO2000066254A1 (fr)
ZA (1) ZA200109818B (fr)

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Also Published As

Publication number Publication date
US20020103306A1 (en) 2002-08-01
CN1364098A (zh) 2002-08-14
JP2002543244A (ja) 2002-12-17
DE19919708A1 (de) 2001-03-01
ZA200109818B (en) 2003-02-26
JP2011026592A (ja) 2011-02-10
IL146208A0 (en) 2002-07-25
AU779428B2 (en) 2005-01-27
WO2000066254A8 (fr) 2002-05-30
CA2371967A1 (fr) 2000-11-09
BR0010170A (pt) 2002-01-15
CN1212177C (zh) 2005-07-27
IL146208A (en) 2008-11-26
KR20020016779A (ko) 2002-03-06
AU1823801A (en) 2002-01-30
KR100749156B1 (ko) 2007-08-14
WO2000066254A1 (fr) 2000-11-09
US7132496B2 (en) 2006-11-07

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