EP1101623A2 - Matériau d'enregistrement pour l'impression au jet d'encre - Google Patents

Matériau d'enregistrement pour l'impression au jet d'encre Download PDF

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Publication number
EP1101623A2
EP1101623A2 EP00123910A EP00123910A EP1101623A2 EP 1101623 A2 EP1101623 A2 EP 1101623A2 EP 00123910 A EP00123910 A EP 00123910A EP 00123910 A EP00123910 A EP 00123910A EP 1101623 A2 EP1101623 A2 EP 1101623A2
Authority
EP
European Patent Office
Prior art keywords
base paper
ink
formaldehyde
paper according
recording material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00123910A
Other languages
German (de)
English (en)
Other versions
EP1101623B1 (fr
EP1101623A3 (fr
Inventor
Hartmut Dr.-Ing. Schulz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Original Assignee
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felix Schoeller Jr Foto und Spezialpapiere GmbH filed Critical Felix Schoeller Jr Foto und Spezialpapiere GmbH
Publication of EP1101623A2 publication Critical patent/EP1101623A2/fr
Publication of EP1101623A3 publication Critical patent/EP1101623A3/fr
Application granted granted Critical
Publication of EP1101623B1 publication Critical patent/EP1101623B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508Supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5218Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays

Definitions

  • the invention relates to an ink jet. Recording material with a for this purpose novel base paper.
  • the ink jet recording process becomes tiny Ink droplets with the help of different, already several times techniques described on a recording material brought and taken up by this.
  • the recording material is different Requirements such as high color density of the printed Dots, fast ink absorption and related adequate smudge resistance, a not over that extent of dye diffusion in Transverse direction of the printed dots as well as a small one Mottle and high water resistance.
  • Ink jet recording materials consist of one Backing material, one arranged thereon Ink-receiving layer and possibly other Auxiliary layers.
  • Ink-jet printer for the production of photo-like prints use inks with a high proportion of water as Solvent.
  • inks with a high proportion of water as Solvent.
  • a ripple in the transverse direction (cockle).
  • This Ripple leads to a contact of the Recording material with the print head and has one Deterioration of the printed image. Besides, can the head contact to damage the Lead receiving material. It is therefore necessary for that Manufacture of photo-like ink-jet prints Use recording material in which the Base paper has a high dimensional stability and thus is able to use a large amount of water to record without showing the ripple mentioned above.
  • a receiving material is known from JP 06-262845 A, whose paper base contains a hardwood pulp and has a sizing of starch and alkyl ketene dimer.
  • the used paper is said to have good absorbency and have printed dot uniformity.
  • the disadvantage of this receiving material is that insufficient dimensional stability (ripple) with high Water absorption.
  • JP 11-099737 Ink jet paper can be solved, which is next to a Ink receiving layer at least one other, so-called Carrier layer contains that from a water-insoluble Resin such as polyethylene or polypropylene.
  • Carrier layer contains that from a water-insoluble Resin such as polyethylene or polypropylene.
  • the long drying time of the printed is disadvantageous Recording paper.
  • the object of the invention is a recording material to provide for the ink jet printing process, the one good dimensional stability and high Has water absorption capacity and in addition to high color density, excellent smudge resistance and has good water resistance.
  • a base paper free of bulk sizing agent and containing 5 to 55% by weight of a filler and impregnated with an impregnating resin the resin uptake being adjusted such that the base paper on the back has a liquid absorption of at most 20 g / m 2 , preferably but has 3 to 6 g / m 2 .
  • the back of the base paper is the side opposite the image-bearing side.
  • the invention further relates to an ink jet recording material with the previously described Base paper as a base and at least one on the Front side ink-receiving layer. Between the base and the ink-receiving layer and on the Ink-receiving layer can be arranged further layers his.
  • the filler contained in the base paper can be a Titanium dioxide, zinc sulfide, calcium carbonate, kaolin, talc, Clay or mixtures of these fillers.
  • a Titanium dioxide, zinc sulfide, calcium carbonate, kaolin, talc, Clay or mixtures of these fillers.
  • the Filler content is 5 to 55% by weight, preferably 20 or 25 to 50% by weight.
  • Softwood cellulose long fiber cellulose
  • hardwood cellulose short fiber cellulose
  • Softwood cellulose long fiber cellulose
  • hardwood cellulose short fiber cellulose
  • the fiber length after the milling process should preferably be 0.6 to 1.2 mm.
  • a eucalyptus pulp or a mixture of eucalyptus and softwood pulp is used.
  • the pulp suspension can also contain wet strength agents such as Polyamide / polyamine-epichlorohydrin resin, Retention aids such as quaternary polyammonium salts, Defoamers, penetration accelerators such as saccharides and other aids are added.
  • wet strength agents such as Polyamide / polyamine-epichlorohydrin resin, Retention aids such as quaternary polyammonium salts, Defoamers, penetration accelerators such as saccharides and other aids are added.
  • Base papers do not have any sizing agents that are common be used for mass sizing.
  • this contains Recording material a so-called one-sided smooth Base paper.
  • the one-sided smooth base paper is preferably made on a Yankee paper machine, the long side of the paper web using a heated cylinder is smoothed. Through the long The contact time of the paper with the cylinder can be one closed surface are created, which is a smoothness of 1000 ml / sec, measured according to Bendtson, not should fall below.
  • a open on both sides i.e. unsmoothed base paper can only be used after impregnation smoothed on one or both sides in a calender can be.
  • the resin is a common as Impregnating resin used in the paper industry. It can be selected from the group of diallyl phthalates, Epoxy resins, urea-formaldehyde resins, uric acid-acrylic acid ester copolyesters, Melamine-formaldehyde resins, Melamine-phenol-formaldehyde resins, phenol-formaldehyde resins, Poly (meth) acrylates or unsaturated polyester resins.
  • the coating composition contains a mixture of Acrylic acid ester and urea-formaldehyde resin. Especially good results are with a mix ratio (Mass) acrylic acid ester / urea formaldehyde resin from To achieve 1:10 to 10: 1.
  • the impregnation with the resin can be carried out "in-line” in the paper machine in a glue box or "off-line” outside the paper machine in a size press or an impregnation system.
  • the base paper can be impregnated from the front or from the back or from both sides, the resin penetrating into the interior of the base paper.
  • the resin absorption of the paper is adjusted so that the impregnated base paper has a liquid absorption of at most 20 g / m 2 , preferably 3 to 6 g / m 2 , on the back.
  • the amount of the resin (impregnating agent) can be 2 to 25 g / m 2 , preferably 5 to 8 g / m 2 .
  • any ink receiving layer can be applied.
  • These are mostly hydrophilic Coatings that are water soluble or contain water-dispersible polymers, for example Polyvinyl alcohol, cationic polyvinyl alcohol, Polyvinylpyrrolidone, polyvinyl acetate, starch, gelatin, Casein or carboxymethyl cellulose.
  • the Ink receiving layer can additionally pigments and cationic substances for fixing the ink dyes contain.
  • the ink-receiving layer contains a polyvinyl alcohol or a mixture of polyvinyl alcohol and an acrylic acid ester homopolymer and / or copolymer.
  • the ink-receiving layer may contain a cationic dye fixative and a pigment.
  • the application weight of the ink-receiving layer is 2 to 20 g / m 2 , in particular 6 to 15 g / m 2 .
  • the ink-receiving layer can be applied using the usual methods and air brush or roller doctor metering.
  • the recording paper can contain an additional polymer layer arranged on the receiving layer.
  • the polymer contained in this layer has a Shore hardness (D)> 50 (ASTM D 2240).
  • An acrylic acid ester homopolymer and / or copolymer is particularly suitable.
  • the application weight of the layer is 1 to 10 g / m 2 , in particular 2 to 6 g / m 2 .
  • a mixture of 90% by weight hardwood sulfate pulp and 10% by weight of softwood sulfate pulp was used in one Material density of 4% up to a freeness of 42 ° SR ground. Then 5% by weight was added. Polyamide / polyamine-epichlorohydrin resin and 25% by weight of one Pigment mixture of titanium dioxide (rutile form) and kaolin in a mixing ratio of 1: 1. The weights of the Additives relate to the pulp.
  • a raw paper with a basis weight of 100 g / m 2 and a thickness of 120 ⁇ m was produced from this mixture.
  • the paper which had an air permeability of 8 Gurley seconds per 100 ml, was impregnated with the following impregnating agent: Acrylate / styrene copolymer (47% aqueous dispersion) (Primal® E-2556) 33% by weight Urea-formaldehyde (50% aqueous solution) (Urecoll® TS) 33% by weight Defoamer (OEKOFOAM® -E 190) 1% by weight water 33% by weight
  • the impregnation was carried out in the paper machine with the help of a glue box.
  • the application weights are listed in Table 1 and refer to the dried mass. Table 1 also shows the liquid absorption measured from the back of the impregnated base paper according to DIN 53132. example Application weight, g / m 2 Liquid intake, g / m 2 B1 8th 4th B2 12th 3rd B3 18th 4th
  • the base papers produced according to the examples were coated with an ink receiving layer with the following composition: Polyvinyl alcohol, 20% aqueous solution (Mowiol® 20-98) 760 g Styrene copolymer, 20% dispersion (Basoplast® 265 D) 170 g Butanol 70 g
  • the papers were coated with a doctor knife.
  • the application weight of the ink-receiving layer was 10 g / m 2 for all papers.
  • the papers provided with the ink-receiving layer were coated with a lacquer layer with the following composition, based on the weight of the dried layer, in an amount of 3 g / m 2 : n-butyl acrylate / styrene copolymer (50% aqueous dispersion-Acronal® S 305 D) 95% by weight Crosslinking agent 5% by weight
  • the base paper produced according to Example 1 was without Impregnation with the coating composition according to the invention coated with the ink receiving layer from Example 1.
  • a raw paper with a basis weight of 100 g / m 2 was produced from a cellulose suspension with hardwood cellulose fibers, 25% by weight calcium carbonate, 0.8% by weight cationic starch and 0.5% by weight alkylketene dimer (quantitative data based on the mass of the Pulp).
  • the base paper was then surface-sized with starch and provided with an ink-receiving layer which contains 80% by weight of silica and 20% by weight of polyvinyl alcohol.
  • the recording papers according to the invention were with an inkjet printer HP Deskjet ® 550C from the company Hewlett Packard printed. On the printed papers were the Cockle behavior, the color density, the Smudge resistance, the water resistance and the Water absorption capacity checked.
  • the color density was measured using a Gretag densitometer Colors cyan, magenta, yellow and black in reflected light measured.
  • the paper to be tested was placed on a laid flat base and the flatness of the paper visually with the notes 1 to 5 (very good to very bad) judged.
  • the printed papers were at 25 ° C for one minute put warm water and dried. The color density was measured before and after watering. It is stated remaining color density in percent.
  • test results are summarized in Table 2.
  • example Color density Water resistance cockle Drying cyan magenta yellow black cyan magenta yellow black 1 2.4 2.0 1.9 2.1 98.6 81.5 98.1 98.0 1 ⁇ 10 sec 2 2.3 2.0 1.9 2.2 98.5 83.3 98.5 98.1 1 ⁇ 10 sec 3rd 2.4 2.0 1.9 2.1 99.5 82.0 98.5 98.5 1 ⁇ 10 sec V1 0.8 0.7 0.6 0.8 - - - - 1 ⁇ 10 sec V2 2.4 1.9 1.8 2.2 96.0 80.1 97.6 97.7 5 ⁇ 10 sec

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paper (AREA)
  • Ink Jet (AREA)
  • Duplication Or Marking (AREA)
  • Materials For Medical Uses (AREA)
EP00123910A 1999-11-15 2000-11-03 Matériau d'enregistrement pour l'impression au jet d'encre Expired - Lifetime EP1101623B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19955081A DE19955081C1 (de) 1999-11-15 1999-11-15 Basispapier für ein Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren
DE19955081 1999-11-15

Publications (3)

Publication Number Publication Date
EP1101623A2 true EP1101623A2 (fr) 2001-05-23
EP1101623A3 EP1101623A3 (fr) 2002-04-03
EP1101623B1 EP1101623B1 (fr) 2005-08-10

Family

ID=7929209

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00123910A Expired - Lifetime EP1101623B1 (fr) 1999-11-15 2000-11-03 Matériau d'enregistrement pour l'impression au jet d'encre

Country Status (12)

Country Link
US (1) US6599592B1 (fr)
EP (1) EP1101623B1 (fr)
JP (1) JP2001199157A (fr)
CN (1) CN1182977C (fr)
AT (1) ATE301549T1 (fr)
BR (1) BR0005397B1 (fr)
CA (1) CA2325237C (fr)
DE (2) DE19955081C1 (fr)
DK (1) DK1101623T3 (fr)
ES (1) ES2246209T3 (fr)
PL (1) PL196450B1 (fr)
PT (1) PT1101623E (fr)

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Publication number Priority date Publication date Assignee Title
WO2004003293A1 (fr) * 2002-06-27 2004-01-08 Upm-Kymmene Oyj Substrat imprime et procede d'impression
EP2865527A1 (fr) * 2013-10-22 2015-04-29 Agfa Graphics Nv Fabrication de surfaces décoratives par impression à jet d'encre
EP2865528A1 (fr) * 2013-10-22 2015-04-29 Agfa Graphics Nv Fabrication de surfaces décoratives par impression à jet d'encre
EP3848422B1 (fr) 2017-08-22 2022-11-30 Agfa Nv Fabrication de panneaux décoratifs

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JP2003054116A (ja) * 2001-08-16 2003-02-26 Konica Corp インクジェット記録媒体及びインクジェット記録装置
US20060078485A1 (en) * 2002-12-30 2006-04-13 Thiele Erik S Process of making a water dispersible titanium dioxide pigment useful in paper laminates
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DE102010051382A1 (de) 2010-11-16 2012-05-16 Dekor-Kunststoffe Gmbh Verfahren zur Herstellung einer Basisschicht, insbesondere für die Bedruckung mittels digitaler Drucktechnik
AU2012249899B2 (en) 2011-04-28 2016-07-28 E. I. Du Pont De Nemours And Company Treated inorganic pigments having improved bulk flow and their use in paper slurries
ES2598240T3 (es) 2011-06-28 2017-01-26 The Chemours Company Tt, Llc Pigmentos inorgánicos tratados que tienen menor fotoactividad y propiedades antimicrobianas y su uso en suspensiones de papel
WO2013062779A1 (fr) 2011-10-28 2013-05-02 E. I. Du Pont De Nemours And Company Particules de cœur inorganiques traitées ayant une aptitude à la dispersion améliorée
EP2771411B1 (fr) 2011-10-28 2016-11-23 The Chemours Company TT, LLC Pigments inorganiques traités possédant un degré de dispersion amélioré et leur utilisation dans les produits à base de papier
ES2615260T3 (es) 2011-10-28 2017-06-06 The Chemours Company Tt, Llc Pigmentos inorgánicos que tienen una capacidad de dispersión mejorada y su uso en composiciones de revestimiento
EP2804980B1 (fr) 2012-01-16 2016-03-16 E. I. du Pont de Nemours and Company Dispersions preparees a partir de particules inorganiques traitées pour la fabrication de papier decor presentant des performances optiques ameliorees
US9975318B2 (en) 2012-01-16 2018-05-22 The Chemours Company Fc, Llc Paper laminates made from decor paper having improved optical performance comprising treated inorganic particles
WO2013141706A1 (fr) 2012-03-20 2013-09-26 Coldenhove Know How B.V. Papier décoratif
EP2695745B1 (fr) 2012-08-06 2015-08-26 Unilin BVBA Procédé de fabrication de panneaux présentant une surface décorative
US9546450B2 (en) 2012-11-13 2017-01-17 The Chemours Company Tt, Llc Laminates prepared from decor paper comprising self-dispersing pigments
AU2013345217B2 (en) 2012-11-13 2017-01-12 E. I. Du Pont De Nemours And Company Process for preparing self-dispersing pigments
JP6231119B2 (ja) 2012-11-13 2017-11-15 ザ ケマーズ カンパニー ティーティー リミテッド ライアビリティ カンパニー 自己分散顔料
CN104936780B (zh) 2012-11-13 2017-07-18 纳幕尔杜邦公司 由包含自分散性颜料的装饰纸制备的层合体
US20150259855A1 (en) 2012-11-13 2015-09-17 E. I. Du Pont De Nemours And Company Decor paper comprising self-dispersing pigments
EP2920253A1 (fr) 2012-11-13 2015-09-23 E. I. du Pont de Nemours and Company Pigments auto-dispersants contenant de la silice
CN104937167B (zh) 2012-11-13 2017-08-08 纳幕尔杜邦公司 包含自分散性颜料的装饰纸
US10094069B2 (en) 2013-01-09 2018-10-09 The Chemours Company Fc, Llc Process for making a décor paper having improved optical performance
CN104919114B (zh) 2013-01-09 2017-11-17 纳幕尔杜邦公司 包含经处理的无机颗粒的、具有改善的光学性能的装饰纸
EP2894047B1 (fr) 2014-01-10 2019-08-14 Unilin, BVBA Procédé de fabrication des panneaux avec une surface décorative
ES2762235T3 (es) 2014-02-06 2020-05-22 Unilin Bvba Procedimiento de fabricación de paneles de piso que tienen una superficie decorativa
BE1025875B1 (nl) 2018-01-04 2019-08-06 Unilin Bvba Werkwijzen voor het vervaardigen van panelen

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WO2004003293A1 (fr) * 2002-06-27 2004-01-08 Upm-Kymmene Oyj Substrat imprime et procede d'impression
US7435473B2 (en) 2002-06-27 2008-10-14 Upm-Kymmene Oyj Printed substrate and printing method
EP2865527A1 (fr) * 2013-10-22 2015-04-29 Agfa Graphics Nv Fabrication de surfaces décoratives par impression à jet d'encre
EP2865528A1 (fr) * 2013-10-22 2015-04-29 Agfa Graphics Nv Fabrication de surfaces décoratives par impression à jet d'encre
WO2015058974A1 (fr) * 2013-10-22 2015-04-30 Agfa Graphics Nv Fabrication de surfaces décorative par jet d'encre
WO2015058865A1 (fr) * 2013-10-22 2015-04-30 Agfa Graphics Nv Fabrication de surfaces décoratives par jet d'encre
WO2015059002A1 (fr) * 2013-10-22 2015-04-30 Agfa Graphics Nv Fabrication de surfaces décoratives par jet d'encre
EP2979887A1 (fr) * 2013-10-22 2016-02-03 Agfa Graphics Nv Fabrication de surfaces decoratives par impression a jet d'encre
CN105658436A (zh) * 2013-10-22 2016-06-08 爱克发印艺公司 通过喷墨生产装饰性表面
US9724932B2 (en) 2013-10-22 2017-08-08 Agfa Graphics Nv Manufacturing of decorative surfaces by inkjet
EP2865528B1 (fr) 2013-10-22 2018-01-31 Agfa Nv Fabrication de surfaces décoratives par impression à jet d'encre
EP3293013A1 (fr) * 2013-10-22 2018-03-14 Agfa Nv Fabrication de surfaces décoratives par impression à jet d'encre
US10022956B2 (en) 2013-10-22 2018-07-17 Agfa Nv Manufacturing of decorative surfaces by inkjet
CN109572260A (zh) * 2013-10-22 2019-04-05 爱克发有限公司 通过喷墨生产装饰性表面
US11400701B2 (en) 2013-10-22 2022-08-02 Agfa Nv Manufacturing of decorative surfaces by inkjet
EP3848422B1 (fr) 2017-08-22 2022-11-30 Agfa Nv Fabrication de panneaux décoratifs

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DK1101623T3 (da) 2005-12-12
DE19955081C1 (de) 2001-08-09
CA2325237A1 (fr) 2001-05-15
BR0005397A (pt) 2001-09-18
ATE301549T1 (de) 2005-08-15
CN1182977C (zh) 2005-01-05
CN1295932A (zh) 2001-05-23
EP1101623B1 (fr) 2005-08-10
PT1101623E (pt) 2005-11-30
ES2246209T3 (es) 2006-02-16
US6599592B1 (en) 2003-07-29
CA2325237C (fr) 2005-06-14
PL196450B1 (pl) 2008-01-31
BR0005397B1 (pt) 2010-06-15
PL343882A1 (en) 2001-05-21
EP1101623A3 (fr) 2002-04-03
DE50010911D1 (de) 2005-09-15
JP2001199157A (ja) 2001-07-24

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