EP0967087B1 - Support pour un matériau pour l'enregistrement par jet d'encre - Google Patents

Support pour un matériau pour l'enregistrement par jet d'encre Download PDF

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Publication number
EP0967087B1
EP0967087B1 EP99111205A EP99111205A EP0967087B1 EP 0967087 B1 EP0967087 B1 EP 0967087B1 EP 99111205 A EP99111205 A EP 99111205A EP 99111205 A EP99111205 A EP 99111205A EP 0967087 B1 EP0967087 B1 EP 0967087B1
Authority
EP
European Patent Office
Prior art keywords
recording material
ink
layer
weight
material according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99111205A
Other languages
German (de)
English (en)
Other versions
EP0967087A2 (fr
EP0967087A3 (fr
Inventor
Rainer Dr. Gumbiowski
Wolfgang Storbeck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Original Assignee
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felix Schoeller Jr Foto und Spezialpapiere GmbH filed Critical Felix Schoeller Jr Foto und Spezialpapiere GmbH
Publication of EP0967087A2 publication Critical patent/EP0967087A2/fr
Publication of EP0967087A3 publication Critical patent/EP0967087A3/fr
Application granted granted Critical
Publication of EP0967087B1 publication Critical patent/EP0967087B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/38—Intermediate layers; Layers between substrate and imaging layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254—Polymeric or resinous material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31993—Of paper

Definitions

  • the invention relates to a recording material for Ink jet printing process (ink jet printing process).
  • the ink jet recording process is one of the electronic printing process and is already multiple have been described. It will be in a wide Field of application for the production of color graphics, Color images and also text prints used. To the at recording materials used in this technology high demands are made. This includes for example high color density, high resolution, short Ink drying times, light stability as well Dimensional stability. Another important requirement for commercial applications, the surface gloss This is particularly true in the manufacture of Art graphics important. But also in the generation of Images that require a photo-like impression gloss is an important requirement.
  • EP0 650 850 A is a recording material known that from a polyolefin coated Base paper and a receiving layer.
  • the Recording material enables the production of High resolution images, color density and high Gloss that overall with conventional photographic images are comparable.
  • the polyethylene coated carrier is the bad one Absorption of the ink liquid due to the Sealing the paper with a plastic, which for poor drying behavior of the recording material leads.
  • EP 0 709 221 A describes a recording material suggested that a paper substrate with a certain Sheffield smoothness and a sheen of more than 20, measured at 60 ° measuring angle, and one Ink receiving layer with water soluble components contains, wherein the entire recording material Has a gloss of more than 50, measured at 60 ° Measuring angle.
  • EP 0 742 486 A describes a support with a base paper and a layer, the layer containing a pigment mixture of BaSO 4 and hollow microspheres.
  • JP 3 114 873 A describes a support for an inkjet recording material with a base paper and a layer which contains BaSO 4 .
  • glossy ones Claimed recording materials in which the Receiving layer in a cast coating process (cast coating) against a heated mirror smooth Cylinder surface is pressed, which the Recording material has a high-gloss surface receives.
  • the object of the invention is to provide an ink jet recording material provide on the particularly glossy and photo-like images with common ones Inkjet inks can be created.
  • a recording material for the ink jet printing process containing a carrier with a base paper and one arranged on it Ink receiving layer, with the base paper on a barium sulfate on at least one side and layer containing thermoplastic hollow microspheres having.
  • Hollow polymeric microspheres are particularly suitable made of a thermoplastic plastic Polystyrene / acrylic base and styrene or acrylic resin base.
  • the microspheres have a diameter of at least 0.4 ⁇ m.
  • Microspheres with a diameter of 0.2 to 5 ⁇ m.
  • the microsphere content in the barium sulfate-containing layer can be 1 to 70% by weight, based on the layer. Particularly good results were obtained at 20 up to 50% by weight of microspheres reached.
  • the binder used in the above layer can be from the group of hydrophilic colloidal and / or water-soluble binders can be selected as Polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylamide, Gelatin, starch, starch derivatives, polyvinyl acetate, Polyethylene glycol, cellulose esters, proteins, alginates, Polyacrylic acid or mixtures of these binders.
  • the coating weight of the layer is 10 to 50 g / m 2 , in particular 15 to 25 g / m 2 .
  • the base paper has a base paper core, for the production of which cellulose or cellulose mixtures with a short fiber content of 80 to 98% by weight, in particular 85 to 95% by weight, are preferably used (unground cellulose).
  • Hardwood-pulp mixtures are particularly suitable with a fiber length of 0.50 to 0.60 mm (unground Pulp) or 0.40 to 0.50 mm (with a grinding degree between 25 and 35 ° SR).
  • the pulp mixture in particular has a freeness of 28 to 32 ° SR (measured according to Schopper-Riegler).
  • the base paper can contain other substances such as sizing agents and Contain fillers.
  • sizing agents can basically all for paper production usual connections are used.
  • the base paper contains kaolin and calcium carbonate in a ratio of 2: 1 to 1: 2 and has a Cobb value of 20 to 100.
  • the base paper can also be surface-sized with starch, gelatin or polyvinyl alcohol.
  • the basis weight of the base paper is 60 to 220 g / m 2 , but in particular 80 to 160 g / m 2 .
  • the recording material according to the invention can at least one side has additional functional layers, for example adhesive, antistatic or "non-curl” layers contain.
  • the carrier of the recording material according to the invention is then subjected to a satinizing process in a known manner.
  • Any ink-receiving layer for ink-jet printing processes can be applied to the front of the carrier.
  • the ink receiving layer is usually a hydrophilic layer which is suitable for the reception of the mostly aqueous inks.
  • An ink-receiving layer generally contains a hydrophilic or water-soluble binder, cationic dye-fixing compounds, pigments and optionally other auxiliaries.
  • the application weight of the ink receiving layer is 5 to 20 g / m 2 .
  • the present invention is based on the following Examples are explained in more detail.
  • the front of the base papers according to Examples 1 to 3 was then coated with an aqueous coating composition containing barite, dried and the coated paper was then satinized.
  • the layers obtained have the following composition: Examples 1.1 1.2 1.3 1.4 2.1 2.2 2.3 3.1 3.2 barium sulfate 59.2 37,00 25,00 10.00 55,00 25,00 74,00 40,00 25,00 microspheres 14.80 37,00 50,00 65,00 20.00 50,00 1.00 20.00 50,00 gelatin 25.56 25.73 24.73 - 24.73 - 24.73 39.63 - PVA - - - 24.93 - 24.93 - - 24.93 alum 0.20 0.20 0.20 - 0.20 - 0.20 0.30 - citric acid 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 Application weight, g / m 2 10 15 15 15 15 20 25 25 25 15 15
  • the front of the base papers produced according to Examples 4 and 5 was coated with an aqueous coating composition containing barite, dried and the coated paper was then satinized.
  • the layers obtained have the following composition: Examples 4.1 4.2 5.1 5.2 barium sulfate 50,00 25,00 65,00 15.00 microspheres 20.00 50,00 10.00 60,00 gelatin 29.70 - 24.73 - polyvinyl alcohol - 24.93 24.93 alum 0.23 - 0.20 - citric acid 0.07 0.07 0.07 0.07 Application weight, g / m 2 15 25 15 35
  • the manufactured according to the comparative examples V1 to V3 Base papers were coated on the front with a barite coating coated, dried and that coated paper then satined.
  • the barite layer consists of 74% by weight barium sulfate and 26% by weight Gelatin.
  • a blend of 70% by weight hardwood sulfate pulp and 30% by weight softwood sulfate pulp was at a consistency of 4.5% to a Milling degree of 37 ° SR ground.
  • the pulp suspension then became the following
  • the coated papers were coated with an ink-receiving layer.
  • Any receiving layer can be used for ink jet printing processes.
  • the ink-receiving layer used for the test purposes in the present case has the following composition: % By weight polyvinyl alcohol 31.6 polyvinylpyrrolidone 31.6 Vinyl acetate / butyl acrylate Cop. 31.6 Polydiallyldimethylammonium chloride 5.2
  • the application weight of the ink-receiving layer was 10 g / m 2 .
  • the papers according to the invention provided with the ink-receiving layer were printed with the aid of a so-called "thermal jet” process and then analyzed. The test results are summarized in Table 6.
  • the gloss values were measured in the laboratory Reflectometer RL3 from Dr. Long according to DIN 67530 a measuring angle of 60 °.
  • the drying behavior of the recording material was determined as follows:
  • Black ink Pure Black
  • a bar is printed and after a waiting period of Load 2 minutes of paper (20 sheets).
  • the color transfer on the paper lying on it is used as a measure of drying taken.
  • the drying time is for the areas ⁇ 2 (very good), 2-7 (medium) and> 7 minutes (bad) assessed.
  • the ink punch behavior is determined by the intensity the discoloration judged by the leakage of the Ink color on the back of the paper is due. Here grades 1 to 12 (very good to very bad) forgive.
  • test results shine Drying time min dimensional stability Ink penetration 1.1 57 6.5 2 2 1.2 62 7.0 2 2 1.3 67 7.5 2 3 1.4 65 5.3 2 3 2.1 53 7.5 1 1 2.2 66 6.0 1 2 2.3 43 7.8 1 1 3.1 50 6.9 1 1 3.2 65 6.3 1 2 V1 45 8.0 6 4 V2 42 8.7 7 5 V3 44 9.0 7 5
  • the base papers according to the invention compared to the Comparative papers above all have a significantly higher gloss as well as better dimensional stability.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paper (AREA)
  • Ink Jet (AREA)
  • Pens And Brushes (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Claims (7)

  1. Matériau d'enregistrement pour le procédé d'impression par jet d'encre, contenant un support avec un papier de base et une couche d'absorption d'encre disposée dessus, caractérisé en ce que le papier de base présente sur au moins une face, une couche contenant du sulfate de baryum et des microbilles creuses thermoplastiques.
  2. Matériau d'enregistrement suivant la revendication 1, caractérisé en ce que la teneur en microbilles s'élève à au moins 1% en poids, sur base du poids de la couche sèche.
  3. Matériau d'enregistrement suivant la revendication 1, caractérisé en ce que la quantité en microbilles se situe dans l'intervalle allant de 20 à 50% en poids, sur base du poids de la couche sèche.
  4. Matériau d'enregistrement suivant les revendications 1 à 3, caractérisé en ce que la couche contient un liant colloïdal hydrophile et/ou soluble dans l'eau.
  5. Matériau d'enregistrement suivant les revendications 1 à 4, caractérisé en ce que le papier de base contient un mélange de cellulose avec une fraction de fibres courtes allant de 80 à 98% en poids, en particulier de 85 à 95% en poids.
  6. Matériau d'enregistrement suivant les revendications 1 à 5, caractérisé en ce que le papier de base contient du kaolin et du carbonate de calcium en un rapport massique variant de 2:1 à 1:2.
  7. Matériau d'enregistrement suivant les revendications 1 à 6, caractérisé en ce que le papier de base présente un taux d'encollage avec une valeur Cobb variant de 20 à 100.
EP99111205A 1998-06-26 1999-06-09 Support pour un matériau pour l'enregistrement par jet d'encre Expired - Lifetime EP0967087B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19828532 1998-06-26
DE19828532A DE19828532C2 (de) 1998-06-26 1998-06-26 Träger für ein Tintenstrahl-Aufzeichnungsmaterial

Publications (3)

Publication Number Publication Date
EP0967087A2 EP0967087A2 (fr) 1999-12-29
EP0967087A3 EP0967087A3 (fr) 2001-05-30
EP0967087B1 true EP0967087B1 (fr) 2003-08-20

Family

ID=7872121

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99111205A Expired - Lifetime EP0967087B1 (fr) 1998-06-26 1999-06-09 Support pour un matériau pour l'enregistrement par jet d'encre

Country Status (8)

Country Link
US (1) US6524696B1 (fr)
EP (1) EP0967087B1 (fr)
JP (1) JP4271781B2 (fr)
AT (1) ATE247562T1 (fr)
DE (2) DE19828532C2 (fr)
DK (1) DK0967087T3 (fr)
ES (1) ES2205639T3 (fr)
PT (1) PT967087E (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040096598A1 (en) * 2000-10-16 2004-05-20 Mitsubishi Paper Mill Limited Ink-jet recording medium and method for production thereof
DE10222454B4 (de) * 2002-05-22 2004-04-15 Felix Schoeller Jr. Foto- Und Spezialpapiere Gmbh & Co. Kg Ink-Jet-Aufzeichnungsblatt mit verbesserter Ozonresistenz
DE10309705B4 (de) * 2003-03-06 2005-03-24 Felix Schoeller Jr. Foto- Und Spezialpapiere Gmbh & Co. Kg Ink-Jet Aufzeichnungsblatt mit verbesserter Ozon-und Lichtstabilität
EP1560103A1 (fr) * 2004-01-29 2005-08-03 CGP Industries Papier couché, imprimable en jet d'encre sur une face et anti-glisse sur l'autre
US7651216B2 (en) 2004-06-24 2010-01-26 Hewlett-Packard Development Company, L.P. Fusible inkjet recording materials containing hollow beads, system using the recording materials, and methods of using the recording materials
EP1738918B1 (fr) * 2005-06-29 2008-04-23 Mitsubishi HiTec Paper Flensburg GmbH Matériau pour l'enregistrement par jet d'encre

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3669899A (en) * 1969-04-29 1972-06-13 Us Plywood Champ Papers Inc Microcapsular opacifier system
JP3005006B2 (ja) * 1989-09-29 2000-01-31 三菱製紙株式会社 インクジェット記録媒体
US5576088A (en) * 1994-05-19 1996-11-19 Mitsubishi Paper Mills Limited Ink jet recording sheet and process for its production
CA2160619A1 (fr) * 1994-10-28 1996-04-29 Sen Yang Papier glace pour imprimante a jet d'encre
DE19517040C2 (de) * 1995-05-10 1997-07-03 Schoeller Felix Jun Foto Trägermaterial zur Herstellung von Farb-Prüfdrucken im Analog-Prüfsystem
JP3721782B2 (ja) * 1998-05-19 2005-11-30 コニカミノルタホールディングス株式会社 インクジェット記録用紙

Also Published As

Publication number Publication date
DE19828532A1 (de) 1999-12-30
EP0967087A2 (fr) 1999-12-29
DK0967087T3 (da) 2003-12-01
US6524696B1 (en) 2003-02-25
ES2205639T3 (es) 2004-05-01
JP4271781B2 (ja) 2009-06-03
DE59906640D1 (de) 2003-09-25
PT967087E (pt) 2003-11-28
ATE247562T1 (de) 2003-09-15
JP2000033771A (ja) 2000-02-02
EP0967087A3 (fr) 2001-05-30
DE19828532C2 (de) 2001-12-06

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