EP1738918B1 - Matériau pour l'enregistrement par jet d'encre - Google Patents

Matériau pour l'enregistrement par jet d'encre Download PDF

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Publication number
EP1738918B1
EP1738918B1 EP05014012A EP05014012A EP1738918B1 EP 1738918 B1 EP1738918 B1 EP 1738918B1 EP 05014012 A EP05014012 A EP 05014012A EP 05014012 A EP05014012 A EP 05014012A EP 1738918 B1 EP1738918 B1 EP 1738918B1
Authority
EP
European Patent Office
Prior art keywords
substrate
recording material
material according
inkjet recording
boehmite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP05014012A
Other languages
German (de)
English (en)
Other versions
EP1738918A1 (fr
Inventor
Gerhard Dr. Stork
Karsten Lerius
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi HiTech Paper Flensburg GmbH
Stora Spezialpapiere GmbH
Original Assignee
Mitsubishi HiTech Paper Flensburg GmbH
Stora Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi HiTech Paper Flensburg GmbH, Stora Spezialpapiere GmbH filed Critical Mitsubishi HiTech Paper Flensburg GmbH
Priority to AT05014012T priority Critical patent/ATE393030T1/de
Priority to EP05014012A priority patent/EP1738918B1/fr
Priority to DE502005003846T priority patent/DE502005003846D1/de
Priority to US11/478,167 priority patent/US8377521B2/en
Publication of EP1738918A1 publication Critical patent/EP1738918A1/fr
Application granted granted Critical
Publication of EP1738918B1 publication Critical patent/EP1738918B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/529—Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds

Definitions

  • the present invention relates to an ink jet recording material having a substrate made of paper and having on at least one side a coating containing binder and inorganic pigment.
  • Ink jet recording materials especially those with a paper substrate, are well known in the art.
  • the known ink jet recording materials have a multi-layer coating, which is then formed, for example, of at least one or more ink-receiving layers and at least one protective layer, wherein the at least one protective layer is formed over the at least one ink-receiving layer.
  • an intermediate layer connected to the ink-receiving layer is additionally provided directly on the substrate.
  • the essential components of the known ink-receiving layers are inorganic pigments and binders, of which as pigments in particular silicon dioxide and the hydroxides and oxides of aluminum and as a binder polyvinyl alcohol are widely used.
  • An ink-jet recording paper having an ink-receiving layer and having an upper layer covering the ink-receiving layer is known from US-A-4,436,347 EP-A-0 806 299 known. While the ink-receiving layer does not contain any pigments, the upper layer comprises inorganic pigment particles, exemplified by a boehmite type aluminum hydroxide having a pore radius distribution of 10 to 35 angstroms, corresponding to 1 to 3.5 nm.
  • the substrates used are in particular baryth-coated or polyolefin-coated papers.
  • the DE-A-19 952 356 also describes a multi-layered ink jet recording paper.
  • the known paper has on at least one side of its support as a first layer an ink-receiving layer with fine inorganic particles and a binder resin.
  • the ink-receiving layer is then coated or impregnated with a coating liquid in the form of a topcoat and then dried.
  • the coating liquid contains at least one specific tetraalkoxy titanium dissolved in an organic solvent.
  • Suitable inorganic particles in the ink-receiving layer are those of synthetic amorphous silica, kaolin, talc, calcium sulfate, barium sulfate, titanium dioxide, zinc oxide, zinc sulfide, zinc carbonate, aluminum hydroxide, alumina and alumina hydrate (pseudoboehmitsol), alone or in combination of two or more.
  • alumina hydrate or colloidal silica as fine inorganic particles is described, with an alumina hydrate having a pseudoboehmite structure being particularly preferred.
  • the EP-A-0 732 219 proposes a printing medium in which an ink-receiving layer, which in turn is covered by a surface layer, is provided on a liquid-absorbent base material of paper. While the ink-receiving layer comprises a binder and a cationic substance, the surface layer is intended to contain cationic ultrafine particles of alumina or alumina hydrate having a particle diameter in the range of 1 nm to 500 nm. For the surface layer, a gloss of 45% or more at a viewing angle of 75 ° is disclosed.
  • inorganic pigments of the ink-receiving layer among a variety of other pigments, there are mentioned, inter alia, alumina and alumina hydrate. In addition, organic particles may still be present. A suitable range for the particle sizes is 0.1 to 20 m, corresponding to 100 to 20,000 nm.
  • a recording material is known, in particular for ink-jet printing, whose porous recording layer applied to a substrate contains not only nonionic or cationic water-insoluble resin particles but also aluminum oxide hydrate particles, with boehmite having a secondary particle size of 100 to 200 nm being preferred here.
  • the drying thereof is made in contact with a smooth surface.
  • the recording layer may be covered with a silicon dioxide layer to improve the scratch resistance.
  • the EP-A-0 810 101 discloses a recording material having a porous ink-receiving layer which may contain both the pure hydroxides of aluminum and pure alumina, including boehmite alumina hydroxide wherein the microcrystals of the alumina hydroxide are aligned in a particular degree of parallelism.
  • a porous ink-receiving layer which may contain both the pure hydroxides of aluminum and pure alumina, including boehmite alumina hydroxide wherein the microcrystals of the alumina hydroxide are aligned in a particular degree of parallelism.
  • the proposal is known to treat alumina hydroxide with the rare earth salts and to use it to prepare the recording layer of an ink jet recording material.
  • polyester films are proposed as suitable substrates and, if paper is considered, preferably baryte-coated or polyolefin-coated paper.
  • Uncoated papers of various types may also be used, but their composition and properties are not specified. At this point it is merely stated that they can vary greatly.
  • the EP-A-0 701 904 discloses an ink jet recording material having a substrate having a coating on at least one side, the coating containing polyvinyl alcohol (may be silanated) as a binder and boehmite as a pigment.
  • the objects of the prior art recording materials are mostly aimed at the high price sector with very high surface standards, which is explained by the fact that the recent increase in digital photography has created a growing demand for high quality printing substrates for multicolor photographic printing.
  • inkjet recording materials which find their use, for example, in everyday business, which on the one hand have to be cheaper to produce than the above-mentioned print carrier for digital photography, on the other hand, however, have a much higher quality standard than, for example, many more used simple copying papers.
  • the inkjet recording materials to be used successfully in business at very high printing speeds should be printable by means of an inkjet printer and, in addition to good storage stability, should also ensure a high resistance of the inkjet print image to environmental influences.
  • the application area "business area” requires everyone Case for costs that are appropriate to the application. This requires both the quantitative use of raw materials to limit as well as to minimize manufacturing costs.
  • the objects of the invention can be achieved if, in the case of an inkjet recording material having a substrate, the coating to be applied directly to the substrate is produced from only a single layer. Then, the substrate used has at least partly to take over the function which is perceived in known from the prior art ink jet recording materials by the arrangement of multiple layers. The selection of a suitable substrate is therefore of very particular importance in the context of the present invention.
  • the boehmite may also be present as a pigment mixture of various boehmite varieties in the recording layer, in which case the characteristic of an average crystal size in a range from 10 to 50 nm applies to all boehmite varieties.
  • the selection of eucalyptus pulp as the main used pulp with a preferred weight fraction will be from 75 to 100 wt% (atro) based on the total pulp content in the substrate, and especially the setting the degree of pulp grinding for the pulp in a range from 25 to 30 ° Schopper Riegler (SR) to an absorbent paper, the substrate having a Cobb 60 value according to the invention in a range of 19 to 25 g / m 2 for the uptake of the liquid components of the recording layer printed on inkjet ink and for fixing the ink is essential. Very particular preference is given to a substrate whose pulp consists entirely of eucalyptus pulp.
  • the density of the substrate must also be in a range from 0.6 to 1.0 g / cm 3 , due to the only slightly ground pulp, which is particularly advantageous for rapid liquid absorption when printing the recording layer with inkjet ink. Ink serves.
  • the substrate of the proposed recording material comprises, in a preferred embodiment, an inorganic pigment, with an addition amount in a range from 2 to 10% by weight (atro), based on the total solids content of the substrate, being particularly suitable here.
  • an inorganic pigment in particular those selected from the group comprising natural and calcined kaolin, silica, bentonite, calcium carbonate and aluminum oxide, and especially here, can be used as pigments Boehmite, are used.
  • pigments Boehmite are used.
  • very particular preference is given to calcium carbonate as pigment incorporated into the substrate.
  • the substrate receives a size sizing, with resin size in a proportion of 0.4 to 0.6% by weight (atro), based on the total solids content of the substrate, being considered preferred.
  • the uncoated substrate has a negligible gloss of less than 5%, measured according to Tappi 450 or ISO 2813 with a reflection angle of 75 °.
  • a negligible gloss of less than 5%, measured according to Tappi 450 or ISO 2813 with a reflection angle of 75 °.
  • low smoothness of the substrate in a range of 5 to 50 Bekk-sec is helpful.
  • the boehmite can also be present as a pigment mixture of different boehmite varieties in the two recording layers, in which case the characteristic of an average crystal size in a range from 10 to 50 nm applies to all boehmite varieties.
  • both recording layers are produced from the same coating composition and thus have the same constituents in the same amounts and are described by the same measured values.
  • coating devices for application of the at least one side applied to the substrate recording layer virtually all known coating devices can be used, for example, selected from the list, comprising curtain coater and spray coater, film press and roller applicator, Air brush coater, doctor blade and roller blade coater.
  • a film press has the advantage that it can be designed as a coating unit applying double-sided.
  • the substrate As an alternative to the preferred embodiment of two recording layers applied directly to the substrate on both sides, it is also possible for the substrate to carry a directly applied recording layer on one side and a simple starch and / or pigment preparation on the other side.
  • the backside preparation is crosslinked and contains at least one component acting as a crosslinker with diisocyanate and in particular hexamethylene diisocyanate.
  • the backside preparation preferably comprises calcium carbonate and at least one binder selected from the list comprising: starch, styrene-butadiene latex and carboxy-methyl cellulose.
  • the binder in the recording layer consists of 80 to 100% by weight of silanized polyvinyl alcohol. Accordingly, a maximum of 20 wt .-% further binder in the respective recording layer are possible.
  • These further binders are especially selected from the list comprising non-silanized polyvinyl alcohol, starch, gelatin, polyacrylates, polyvinyl acetate mixed polymers, polystyrene-butadiene latices and cellulose derivatives. It is particularly preferred if the one recording layer applied directly to the substrate or if the two recording layers applied directly to the two sides of the substrate have as binder exclusively a silanized polyvinyl alcohol. In particular, a degree of saponification of the silanized polyvinyl alcohol of 98.5 ⁇ 0.5 mol% is considered to be very particularly preferred.
  • the recording layer in the preferred embodiment leaves the substrate shine through with regard to its area-related mass and its pigment content, which can also be explained by a preferred and conscious omission of optical brighteners in the one or both recording layers.
  • the whiteness of the substrate also assumes a certain importance, which is optionally in the range of 85 to 110% by the addition of optical brightener into the substrate, determined in accordance with the specifications of ISO 2469 in conjunction with ISO 2470
  • the boehmite-type aluminum hydroxide which constitutes the incorporated pigment in the recording layer directly applied on at least one side of the substrate, has a mean crystal size in a range of 18 to 22 nm.
  • the pigment has an average pore radius of 85 to 110 angstroms, corresponding to 8.5 to 11 nm, as a preferred range.
  • the boehmite it this first variant has an average specific surface in a preferred range of 135 to 165 m 2 / g.
  • the boehmite-type aluminum hydroxide which constitutes the incorporated pigment in the recording layer directly applied to at least one side of the substrate, has an average crystal size in a range of 34 to 43 nm.
  • the boehmite points it. of this second variant has an average pore radius in a preferred range of 180 to 220 angstroms, corresponding to 18 to 22 nm and an average specific surface in a preferred range of 85 to 115 m 2 / g.
  • a pore volume in a range from 0.5 to 0.9 ml / g and especially from 0.6 to 0.8 ml / g is considered to be preferred for the boehmite used according to the invention in one or both recording layers.
  • the pigment consists of a recording layer applied directly to the substrate or recording layers of a pigment mixture consisting of a boehmite of the first variant with a mean crystal size in the range of 18 to 22 nm and from a boehmite of the second variant with a mean crystal size in a range of 34 to 43 nm.
  • the preferred mixing ratio Böhmit variente 1 : boehmite variant 2 is a range from 3: 1 to 1: 3.
  • the boehmite to be used in one or both of the recording layers is platelet-shaped as the primary particle to which the specified average crystal sizes apply.
  • Secondary particles formed from the primary particles have a particle size in a range from 70 to 350 ⁇ m with a pore volume of 0.5 to 0.9 ml / g and particularly preferably with a pore volume of 0.6 to 0.8 ml / g.
  • the one or both of the recording layer (s) applied directly to the substrate ideally have a Bekk smoothness of 60 to 150 seconds and a relatively low gloss, so that the recording material on its at least one recording layer can be referred to as a "satin finish" .
  • the measured gloss of the recording layer in a preferred range of 10 to 40%, measured according to Tappi 450 or ISO 2813 with a reflection angle of 75 °, corresponds to the gloss of higher quality business papers and gives the inkjet recording material of the invention a more elegant appearance over plain writing or copying papers.
  • a base paper with a basis weight of 67 g / m 2 is made from a pulp consisting of eucalyptus pulp, which has been milled to 28 ° Schopper Riegler (SR).
  • SR Schopper Riegler
  • calcium carbonate in an amount of 5% by weight and resin glue in an amount of 0.5% by weight, based on the total solids content of the substrate, are added to the pulp as filler.
  • a base paper web is prepared, which is dried and compacted by a calender, and which is used as a substrate for the proposed ink jet recording material over a density of 0.8 g / cm 3 , a Cobb 60 value of 21 g / m 2 and a Smoothness of 40 Bekk-sec features.
  • the base paper web is applied as a substrate on both sides with the following coating composition according to Table 1 in a separate coating unit, wherein in each case a basis weight of 9 g / m 2 is set:
  • Table 1 Formulation for the coating composition for the production of recording layers, which are to be applied directly on both sides of the substrate Parts by weight (lutro) %
  • (atro) water 218.59 Nitric acid 65% 9.87 0.99 aluminum hydroxide 82.27 82.27 Hexamethylene-bis-Dimethylcarbazid 4.11 4.11 Silanized PVAI * 82.27 8.23 Dye fixing 13.71 4.11 wetting agent 2.88 0.29 Total atro - 100 Total lutro 413.71 * polyvinyl alcohol
  • the primary particles of the aluminum hydroxide have an average particle size of 19 nm.
  • the average specific surface area is in a range from 135 to 165 m 2 / g, while the average pore radius is in a range of 8.5 to 11 nm.
  • the silanized polyvinyl alcohol has a saponification degree of 98.5 ⁇ 0.5 mol%.
  • the treatment takes place on a flattening device, resulting in a gloss of 35%, measured according to Tappi 450 or ISO 2813 with a reflection angle of 75 °, and a smoothness of 80 Bekk-sec.
  • the ink jet recording material produced in this way is also less expensive to produce than comparable recording materials because of the single-layered configuration of the recording layers applied on both sides.
  • Printing tests with an Epson Stylus Photo 950 and for comparison with an additional Hewlett-Packard 720 show a very good printability, printed full areas are wiping resistant after a time of about 2 sec.
  • the printed images are drizzled with water. After 2 seconds exposure wiping several times with one finger under constant pressure Ober the printed image.
  • the printed image should be as little as possible, ideally not to be blurred at all. Again, the proposed recording materials can convince to a particular extent.

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Paper (AREA)

Claims (17)

  1. Matériau d'enregistrement à jet d'encre avec un substrat en papier qui présente, sur au moins une face, un revêtement qui contient un liant et un pigment inorganique, caractérisé en ce que
    (a) le substrat présente une masse volumique dans une plage de 0,6 à 1,0 g/cm3 et une valeur Cobb60 dans une plage de 19 à 25 g/m2,
    (b) le revêtement n'est constitué que d'une seule couche conçue comme couche d'enregistrement, qui est appliquée directement sur le substrat,
    (c) le pigment présent dans la couche d'enregistrement est constitué d'une boehmite synthétique colloïdale ayant une taille cristalline moyenne dans une plage de 10 à 50 nm, et
    (d) le liant présent dans la couche d'enregistrement est à 80 à 100 % en poids un alcool polyvinylique silanisé.
  2. Matériau d'enregistrement à jet d'encre selon la revendication 1, caractérisé en ce que le matériau fibreux utilisé pour la fabrication du papier présente un degré de broyage selon Schopper Riegler (SR) de 25 à 30°.
  3. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 et 2, caractérisé en ce que le matériau fibreux est constitué pour 75 à 100 % en poids (à siccité) de pâte d'eucalyptus.
  4. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 et 2, caractérisé en ce que le matériau fibreux est constitué de cellulose d'eucalyptus.
  5. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 à 4, caractérisé en ce que les deux faces du substrat présentent un revêtement, les deux revêtements contenant respectivement un liant et un pigment inorganique, et en ce que
    (a) les deux revêtements ne sont constitués respectivement que d'une seule couche conformée en couche d'enregistrement qui sont appliqués directement sur le substrat,
    (b) le pigment présent respectivement dans les deux couches d'enregistrement est constitué d'une boehmite synthétique colloïdale avec une taille cristalline moyenne dans une plage de 10 à 50 nm, et
    (c) le liant présent respectivement dans les deux couches d'enregistrement est un alcool polyvinylique silanisé pour 80 à 100 % en poids.
  6. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 à 5, caractérisé en ce que la couche d'enregistrement appliquée directement au moins sur une face du substrat est présente avec une masse spécifique de 7 à 12 g/m2, la boehmite étant contenue en quantité de 6 à 8,5 g/m2 dans la couche d'enregistrement.
  7. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 à 6, caractérisé en ce que la boehmite présente une taille cristalline moyenne dans une plage de 18 à 22 nm.
  8. Matériau d'enregistrement à jet d'encre selon la revendication 7, caractérisé en ce que la boehmite présente un rayon moyen de pores de 85 à 110 Å, correspondant à des valeurs de 8,5 à 11 nm.
  9. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 7 et 8, caractérisé en ce que la boehmite présente une surface spécifique moyenne dans une plage de 135 à 165 m2/g.
  10. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 à 6, caractérisé en ce que la boehmite présente une taille cristalline moyenne dans une plage de 34 à 43 nm.
  11. Matériau d'enregistrement à jet d'encre selon la revendication 10, caractérisé en ce que la boehmite présente un rayon moyen de pores de 180 à 220 Å, correspondant à des valeurs de 18 à 22 nm.
  12. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 10 et 11, caractérisé en ce que la boehmite présente une surface spécifique moyenne dans une plage de 85 à 115 m2/g.
  13. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 à 12, caractérisé en ce que l'alcool polyvinylique silanisé de la couche d'enregistrement appliquée directement au moins sur une face du substrat est présent en quantité de 0,6 à 0,85 g/M 2.
  14. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 à 13, caractérisé en ce que la couche d'enregistrement appliquée directement au moins sur une face du substrat contient un agent antioxydant.
  15. Matériau d'enregistrement à jet d'encre selon la revendication 14, caractérisé en ce que l'agent antioxydant est le bis-diméthylcarbazide d'hexaméthylène.
  16. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 à 15, caractérisé en ce que la couche d'enregistrement appliquée directement au moins sur une face du substrat présente un lissage Bekk de 60 à 150 secondes.
  17. Matériau d'enregistrement à jet d'encre selon l'une quelconque des revendications 1 à 16, caractérisé en ce que la couche d'enregistrement appliquée directement au moins sur une face du substrat présente une brillance dans une plage de 10 à 40 %, mesurée selon la norme Tappi 450 ou ISO 2813 sous un angle de réflexion de 75 °.
EP05014012A 2005-06-29 2005-06-29 Matériau pour l'enregistrement par jet d'encre Not-in-force EP1738918B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AT05014012T ATE393030T1 (de) 2005-06-29 2005-06-29 Tintenstrahlaufzeichnungsmaterial
EP05014012A EP1738918B1 (fr) 2005-06-29 2005-06-29 Matériau pour l'enregistrement par jet d'encre
DE502005003846T DE502005003846D1 (de) 2005-06-29 2005-06-29 Tintenstrahlaufzeichnungsmaterial
US11/478,167 US8377521B2 (en) 2005-06-29 2006-06-29 Ink jet recording material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP05014012A EP1738918B1 (fr) 2005-06-29 2005-06-29 Matériau pour l'enregistrement par jet d'encre

Publications (2)

Publication Number Publication Date
EP1738918A1 EP1738918A1 (fr) 2007-01-03
EP1738918B1 true EP1738918B1 (fr) 2008-04-23

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EP05014012A Not-in-force EP1738918B1 (fr) 2005-06-29 2005-06-29 Matériau pour l'enregistrement par jet d'encre

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US (1) US8377521B2 (fr)
EP (1) EP1738918B1 (fr)
AT (1) ATE393030T1 (fr)
DE (1) DE502005003846D1 (fr)

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Publication number Priority date Publication date Assignee Title
AT511619B1 (de) * 2011-06-22 2016-02-15 Mondi Ag Verfahren zur oberflächenbehandlung von papier sowie papier

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JP3911077B2 (ja) * 1997-11-07 2007-05-09 三菱製紙株式会社 インクジェット用被記録材料
DE19828532C2 (de) * 1998-06-26 2001-12-06 Schoeller Felix Jun Foto Träger für ein Tintenstrahl-Aufzeichnungsmaterial
JP3707966B2 (ja) 1998-10-26 2005-10-19 三菱製紙株式会社 インクジェット記録シート及びその製造方法
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US20040209010A1 (en) * 2001-10-09 2004-10-21 Cuch Simon R. Aqueous coating formulation suitable for use with high speed coaters such as rod and blade coaters, and ink jet recording materials prepared therefrom
US6987244B2 (en) * 2002-07-31 2006-01-17 Illinois Tool Works Inc. Self-contained locking trigger assembly and systems which incorporate the assembly
JP2004330483A (ja) * 2003-05-01 2004-11-25 Fuji Photo Film Co Ltd インクジェット記録媒体
DE50301695D1 (de) * 2003-09-08 2005-12-22 Ilford Imaging Ch Gmbh Aufzeichnungsmaterial für den Tintenstrahldruck
JP4064909B2 (ja) * 2003-11-19 2008-03-19 富士フイルム株式会社 インクジェット記録方法及びインクジェット画像

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US8377521B2 (en) 2013-02-19
DE502005003846D1 (de) 2008-06-05
EP1738918A1 (fr) 2007-01-03
US20070002120A1 (en) 2007-01-04

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