EP1048480B1 - Matériau pour l'impression par jet d'encre contenant des couches de pigmentées - Google Patents

Matériau pour l'impression par jet d'encre contenant des couches de pigmentées Download PDF

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Publication number
EP1048480B1
EP1048480B1 EP99108448A EP99108448A EP1048480B1 EP 1048480 B1 EP1048480 B1 EP 1048480B1 EP 99108448 A EP99108448 A EP 99108448A EP 99108448 A EP99108448 A EP 99108448A EP 1048480 B1 EP1048480 B1 EP 1048480B1
Authority
EP
European Patent Office
Prior art keywords
recording material
ink
jet recording
material according
pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99108448A
Other languages
German (de)
English (en)
Other versions
EP1048480A1 (fr
Inventor
Richard Dr. Barcock
Alastair Dodds
Kirsten Dr. Werner
Dieter Dr. Becker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Original Assignee
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE59911552T priority Critical patent/DE59911552D1/de
Application filed by Felix Schoeller Jr Foto und Spezialpapiere GmbH filed Critical Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority to EP99108448A priority patent/EP1048480B1/fr
Priority to PT99108448T priority patent/PT1048480E/pt
Priority to DK99108448T priority patent/DK1048480T3/da
Priority to AT99108448T priority patent/ATE288362T1/de
Priority to ES99108448T priority patent/ES2236987T3/es
Priority to AU28911/00A priority patent/AU765905B2/en
Priority to CNB001179497A priority patent/CN1145558C/zh
Priority to JP2000130432A priority patent/JP2001010222A/ja
Priority to US09/561,396 priority patent/US6502935B1/en
Publication of EP1048480A1 publication Critical patent/EP1048480A1/fr
Application granted granted Critical
Publication of EP1048480B1 publication Critical patent/EP1048480B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings

Definitions

  • the invention relates to a recording material for the Ink jet recording method.
  • EP 0 650 850 is a recording material known, which consists of a polyolefin-coated Base paper and a receiving layer.
  • the Material allows the production of high-quality images Resolution, color and high gloss in the Overall impression with conventional photographic images are comparable.
  • a disadvantage of this Plastic coated paper is the bad pick the ink liquid, due to the sealing Effect of the plastic, causing the bad Drying behavior of the recording material leads.
  • the Recording material is characterized by Ink leakage and poor overall image properties out.
  • JP 10-119424 a recording paper with high gloss suggested that a hydrophobic carrier and two porous, silica-containing layers contains, with the silica of the upper layer has smaller particles than the silica of lower layer.
  • a disadvantage of this Recording material is the long drying time.
  • EP 0 450 540 B1 discloses an inkjet recording material having a lower pigment layer and an upper pigment layer disposed thereon. Both layers contain alumina as the main pigment, with the lower layer alumina having a smaller specific surface area ( ⁇ 90 m 2 / g) than the upper layer alumina (90-170 m 2 / g). With this recording material, images with high color density and high color fastness (little color change after storage) can be produced.
  • EP 0 806 299 A2 discloses a recording material for ink-jet printing processes comprising a barium sulfate-containing undercoat and a boehmite-containing topcoat. This recording material has high water resistance, short drying time and good bleed behavior.
  • the object of the invention is to provide a shiny Recording material for ink-jet recording method to provide with which images of high color density can be generated and which has a high ink absorbency, a short Drying time and a resulting good Has wipe resistance.
  • the object is achieved by a recording material for ink jet recording method with a carrier and pigmented layers coated thereon, wherein the recording material is a barium sulfate and at least one further pigment-containing lower layer and an alumina pigment containing topcoat or one from at least two pigments of a particle size less than about 500 nm mixture containing upper layer contains.
  • At least one further pigment is contained in the lower layer in the lower layer.
  • Particularly suitable as a further pigment is an aluminum oxide and a silica or barium oxide.
  • the alumina is a so-called active alumina which is obtained, for example, by calcination from aluminum hydroxide and has a specific surface area of about 160 to 240 m 2 / g and an average particle size of about 0.7 to 5 ⁇ m , in particular about 1 to 3 ⁇ m has.
  • precipitated silicas having a specific surface area of about 30 to 800 m 2 / g proved to be particularly suitable.
  • Precipitated silicas having a particle size of 0.7 to 5 microns, in particular 3 to 5 microns are preferably used.
  • the particle size of the barium sulfate is about 0.2 to 2.0 .mu.m , in particular about 0.7 to 1.2 .mu.m .
  • the ratio of barium sulfate / aluminum oxide is about 4: 1 to 1: 1.
  • the use of an aluminum oxide or a Silica in the lower layer causes an increase in the Absorbency of this baryt Anlagenn layer, so that the order weight of the upper class can be reduced can, without the absorption capacity of the whole Affecting recording paper.
  • the Reduction of the coating weight of the upper class can the in the drying of the layer resulting and the Image quality degrading "cracking" effect be eliminated.
  • the above-mentioned leads Modification of the barite layer to eliminate the Dusting problems and to improve the adhesion to the substrate.
  • the binder used in said undercoat may be selected from the group of hydrophilic colloidal and / or water-soluble binders are selected as Polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl acetate, Gelatin, starch, starch derivatives, casein, Cellulose esters, alginates, polyethylene glycol, Polyacrylic acid or mixtures of these binders.
  • gelatin particularly suitable as a binder in the Undercoat is gelatin.
  • This can be any type of gelatin be used.
  • the amount ratio of pigment to binder in the Underlayer is 1: 1 to 10: 1, in particular 1: 1 to 8: 1.
  • the coating weight of the underlayer is 5 to 30 g / m 2 , in particular 10 to 25 g / m 2 .
  • the pigment mixture contained in the top layer consists from at least two finely divided pigments whose Particle size may not exceed about 500 nm.
  • Particularly preferred is a mixture of alumina with a particle size of about 50 to 150 nm and Silica with a particle size of about 200 to 300nm.
  • Silica with a particle size of about 200 to 300nm.
  • a particular embodiment of the invention is a mixture of a cationically modified Alumina and a cationically modified Silica used.
  • the quantity ratio Alumina to silica is about 4: 1 to 1: 1.
  • the Upper layer barium sulfate and / or barium oxide.
  • the amount of these pigments in the upper layer can be up to 50% by weight be, based on the dried layer.
  • the binder used in said topsheet may be selected from the group of hydrophilic colloidal and / or water-soluble binders are selected as Polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl acetate, Gelatin, starch, starch derivatives, casein, Cellulose esters, alginates, polyethylene glycol, Polyacrylic acid or mixtures of these binders.
  • Particularly suitable as a binder in the upper class is polyvinyl alcohol, being a fully saponified Polyvinyl alcohol with high viscosity of 35 to 80 cP, in particular 50 to 75 cP (measured on 4% aqueous Solutions at 20 ° C) is preferred.
  • partially saponified polyvinyl alcohols or cationic modified polyvinyl alcohols can be used.
  • the amount ratio pigment / binder in the upper layer is 20: 1 to 1: 1, in particular 14: 1 to 6: 1.
  • the topsheet may also contain other adjuvants such as dye-fixing compounds, crosslinking agents, color pigments and optical brighteners.
  • the dye-fixing agents include, for example, quaternary polyammonium salts, cationic polyamines, cationic polyacrylamides, cationic polyethyleneimines.
  • the amount of the excipients may be up to 5 wt.%, Based on the dried layer.
  • the coating weight of the top layer is 10 to 25 g / m 2 , in particular 15 to 20 g / m 2 .
  • the carrier material used may preferably be a neutral or acid sized uncoated or coated paper. Particularly suitable is a one-sided on the back with resin coated paper with a basis weight of 50 to 300 g / m 2 .
  • a synthetic resin for example, polyolefins or polyesters can be used.
  • the polyolefin used to coat the base paper is preferably low density polyethylene (LDPE) and / or high density polyethylene (HDPE).
  • the application rate of the synthetic resin coating which may additionally contain pigments and other substances, is at least 5 g / m 2 , in particular up to 20 g / m 2 .
  • Layers on the substrate can be any, well-known application and dosing process be used as roller application, engraving or Nipp process and airbrush or roll doctor dosage.
  • the coated Paper After applying the layers and drying them can in a further process step, the coated Paper subjected to a smoothing process in a calender to increase the shine again.
  • the front side of an alkyl ketene dimer neutral sized and starch surface sized base paper having a basis weight of 135 g / m 2 was coated with a baryte-containing coating composition using a Meyer bar (Meyer Bar) and then dried.
  • the coating weight of the obtained undercoat 1A was 15 g / m 2 .
  • a second coating composition was applied to the first layer (lower layer) with the aid of a slot-die applicator and dried.
  • the coating weight of the obtained upper layer 1B was 20 g / m 2 .
  • a base paper according to Example 1 was provided with the following lower layers and upper layers: example Under layer / coating weight Cap / coating weight 2 2A 15 g / m 2 1B 15 g / m 2 3 3A 14 g / m 2 1B 20 g / m 2 4 3A 15 g / m 2 5B 20 g / m 2 5 2A 15 g / m 2 3B 20 g / m 2 6 2A 15 g / m 2 4B 20 g / m 2 7 4A 20 g / m 2 1B 15 g / m 2 8th 4A 14 g / m 2 2 B 15 g / m 2 9 5A 15 g / m 2 1B 20 g / m 2
  • a recording paper was prepared in the same manner as in Example 3, except that a base paper coated on the reverse side with a clear low density polyethylene (LDPE) was used as the substrate.
  • compositions of the backsheets and topsheets are shown in Tables 1 and 2.
  • Particle size 3-5 ⁇ m (Gasil® HP 35,) - - - - 17.3 Gelatin, 140 ⁇ 20 bloom 9.7 9.7 13.2 13.2 13.2 alum 0.2 0.2 0.2 0.2 0.2 TAF / formaldehyde 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Topsheet / composition Quantity, weight% 1B 2 B 3B 4B 5B Alumina, avg. Particle size: 130-140 nm, specific. Surface: 50-60 m 2 / g (Cabot® 003) 62.14 44.37 71.73 80.15 82.83 Silica, avg.
  • Particle size 300 nm, 26,60 44.37 7.97 8.59 10.35 Polyvinyl alcohol, degree of saponification: 98%, viscosity: 62-72 cP (4% aqueous solution, at 20 ° C.), (Airvol® 350) 11:10 11.10 20.00 11.10 6.70 boric acid 0.16 0.16 0.30 0.16 0.12
  • a neutral sized and surface sized base paper having a basis weight of 160 g / m 2 was first provided with a standard baryta layer in an application amount of 20 g / m 2 and in the second step with a top layer according to 1B in an application amount of 30 g / m 2 coated.
  • a neutral sized base paper having a basis weight of 160 g / m 2 was coated first with the underlayer 3A in an application amount of 15 g / m 2 and in the second step with the following top layer in an application amount of 20 g / m 2 :
  • Upper layer / Comparative Example 2 Silica, avg. Particle size: 300 nm, specific. Surface area: 23.6 m 2 / g, 88.74% by weight
  • a base paper having a basis weight of 150 g / m 2 was coated with the following subbing layer in an application amount of 15 g / m 2 .
  • the application of the top layer was carried out according to FIG. 1B in an amount of 20 g / m 2 .
  • Undercoat / Comparative Example 3 Barium sulfate, avg. Particle size: 0.7-1.2 ⁇ m, 69.1% by weight Calcium carbonate, avg. Particle size: 10 ⁇ m 17.30% by weight Gelatin, 140 ⁇ 20 bloom 13.30% by weight alum 0.20% by weight TAF / formaldehyde 0.10% by weight
  • the recording papers were read using the Ink jet printer Epson 740 at 720 DPI (dots per inch).
  • the gloss was on unprinted material with the lab Reflectometer RL3 from Dr. Ing. Long in accordance with DIN 67530 measured at a measuring angle of 60 °.
  • the color density was determined using an X-Rite densitometer type 428 in the colors cyan, magenta, yellow and black measured.
  • the smudge resistance was achieved by rubbing off the printed image checked with a white cloth. This exam was for each color done and graded individually. The grade 1 stands for a very good smudge resistance (no color residues on the cloth) and the note 5 stands for poor smudge resistance (significant color residues on the Flap recognizable).
  • test results are summarized in Table 3.
  • exam results color density drying time Bleed note smudge resistance shine cyan magenta yellow black 1 2.78 1.83 1.57 2.76 ⁇ 10 s 2 1 32 2 2.79 1.81 1.55 2.77 ⁇ 10 s 1.5 1 33 3 2.70 1.74 1.47 2.66 ⁇ 10 s 1.5 1 31 4 2.80 1.88 1.66 2.82 ⁇ 10 s 1 1 38 5 2.79 1.87 1.65 2.80 ⁇ 10 s 1 1 36 6 2.84 1.92 1.69 2.85 ⁇ 10 s 1 1 38 7 2.79 1.82 1.56 2.75 ⁇ 10 s 1 1 32 8th 2.71 1.77 1.52 2.65 ⁇ 10 s 1 1 20 9 2.76 1.81 1.59 2.76 ⁇ 10 s 1 1 30 10 2.65 1.82 1.68 2.66 ⁇ 10 s 1 1 31 Vergl.1 2.53 1.71 1.45 2.47 ⁇ 30 s 3 2 24 COMP.2 2.05 1.33 1.27 2.05 ⁇ 10 s 1 1 5 Vergl.3 2.53 1.65 1.

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Paper (AREA)
  • Materials For Medical Uses (AREA)

Claims (15)

  1. Matériau d'impression pour procédés d'impression à jet d'encre, qui présente un support sur lequel sont appliquées des couches qui contiennent des pigments, caractérisé en ce que le matériau d'impression contient une couche inférieure qui contient du sulfate de baryum et au moins un autre pigment et une couche supérieure qui contient comme pigment de l'oxyde d'aluminium ou une couche supérieure qui contient un mélange constitué d'au moins deux pigments dont la taille des particules est inférieure à environ 500 nm.
  2. Matériau d'impression selon la revendication 1, caractérisé en ce que le ou les autres pigments de la couche inférieure présentent des particules d'une taille d'environ 0,7 à 5 µm.
  3. Matériau d'impression selon la revendication 2, caractérisé en ce que l'autre pigment est un oxyde d'aluminium, de l'acide silicique ou de l'oxyde de baryum.
  4. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que la couche inférieure contient comme liant de la gélatine.
  5. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que la quantité de sulfate de baryum dans la couche inférieure est d'environ 450 à 80 % en poids par rapport à la quantité totale du pigment dans la couche.
  6. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que les proportions pondérales entre le pigment et le liant de la couche inférieure sont de 10:1 à 1:1 et en particulier de 8:1 à 1:1.
  7. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que la couche supérieure contient un mélange d'oxyde d'aluminium et d'acide silicique.
  8. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que la couche supérieure contient du sulfate de baryum et/ou de l'oxyde de baryum.
  9. Matériau d'impression selon la revendication 7, caractérisé en ce que l'oxyde d'aluminium présente des particules d'une taille de 50 à 150 nm.
  10. Matériau d'impression selon la revendication 7, caractérisé en ce que l'acide silicique présente des particules d'une taille de 200 à 300 nm.
  11. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que la quantité d'oxyde d'aluminium dans la couche supérieure est de 50 à 80 % en poids par rapport au mélange de pigments.
  12. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que la couche supérieure contient de l'alcool polyvinylique comme liant.
  13. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que les proportions pondérales entre le pigment et le liant dans la couche supérieure sont de 20:1 à 1:1 et en particulier de 14:1 à 6:1.
  14. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que le matériau de support est un papier revêtu ou non revêtu.
  15. Matériau d'impression selon l'une des revendications précédentes, caractérisé en ce que le matériau de support est un papier dont le verso est revêtu de polyéthylène.
EP99108448A 1999-04-30 1999-04-30 Matériau pour l'impression par jet d'encre contenant des couches de pigmentées Expired - Lifetime EP1048480B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
EP99108448A EP1048480B1 (fr) 1999-04-30 1999-04-30 Matériau pour l'impression par jet d'encre contenant des couches de pigmentées
PT99108448T PT1048480E (pt) 1999-04-30 1999-04-30 Material para gravacao por jacto de tinta compreendendo camadas de pigmentos
DK99108448T DK1048480T3 (da) 1999-04-30 1999-04-30 Inkjet-optegnelsespapir med pigmentlag
AT99108448T ATE288362T1 (de) 1999-04-30 1999-04-30 Ink-jet-aufzeichnungspapier mit pigmentschichten
ES99108448T ES2236987T3 (es) 1999-04-30 1999-04-30 Papel de impresion de chorro de tinta con capas pigmentadas.
DE59911552T DE59911552D1 (de) 1999-04-30 1999-04-30 Ink-Jet-Aufzeichnungspapier mit Pigmentschichten
AU28911/00A AU765905B2 (en) 1999-04-30 2000-04-20 Ink-jet recording material comprising pigment layers
CNB001179497A CN1145558C (zh) 1999-04-30 2000-04-28 含颜料层的喷墨记录材料
JP2000130432A JP2001010222A (ja) 1999-04-30 2000-04-28 顔料層を含むインクジェット記録材料
US09/561,396 US6502935B1 (en) 1999-04-30 2000-04-28 Ink-jet recording material comprising pigment layers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP99108448A EP1048480B1 (fr) 1999-04-30 1999-04-30 Matériau pour l'impression par jet d'encre contenant des couches de pigmentées

Publications (2)

Publication Number Publication Date
EP1048480A1 EP1048480A1 (fr) 2000-11-02
EP1048480B1 true EP1048480B1 (fr) 2005-02-02

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EP99108448A Expired - Lifetime EP1048480B1 (fr) 1999-04-30 1999-04-30 Matériau pour l'impression par jet d'encre contenant des couches de pigmentées

Country Status (10)

Country Link
US (1) US6502935B1 (fr)
EP (1) EP1048480B1 (fr)
JP (1) JP2001010222A (fr)
CN (1) CN1145558C (fr)
AT (1) ATE288362T1 (fr)
AU (1) AU765905B2 (fr)
DE (1) DE59911552D1 (fr)
DK (1) DK1048480T3 (fr)
ES (1) ES2236987T3 (fr)
PT (1) PT1048480E (fr)

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EP1747901A1 (fr) 2005-07-26 2007-01-31 Kanzan Spezialpapiere GmbH Matériau pour l'enregistrement à jet d'encre.

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1747901A1 (fr) 2005-07-26 2007-01-31 Kanzan Spezialpapiere GmbH Matériau pour l'enregistrement à jet d'encre.

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PT1048480E (pt) 2005-05-31
AU765905B2 (en) 2003-10-02
CN1272430A (zh) 2000-11-08
CN1145558C (zh) 2004-04-14
JP2001010222A (ja) 2001-01-16
US6502935B1 (en) 2003-01-07
ATE288362T1 (de) 2005-02-15
DE59911552D1 (de) 2005-03-10
EP1048480A1 (fr) 2000-11-02
AU2891100A (en) 2000-11-02
ES2236987T3 (es) 2005-07-16
DK1048480T3 (da) 2005-06-06

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