Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
  • D06P3/79—Polyolefins
  • D06P3/792—Polyolefins using basic dyes
• • D—TEXTILES; PAPER
  • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
  • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
  • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
  • D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D01F6/30—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising olefins as the major constituent
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
  • D06P3/79—Polyolefins
  • D06P3/791—Polyolefins using acid dyes
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
  • D06P3/79—Polyolefins
  • D06P3/794—Polyolefins using dispersed dyes
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
  • D06P3/79—Polyolefins
  • D06P3/798—Polyolefins using reactive dyes
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
  • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
  • D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
  • Y10S8/92—Synthetic fiber dyeing
  • Y10S8/928—Polyolefin fiber
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
  • Y10T442/40—Knit fabric [i.e., knit strand or strip material]

Definitions

• the invention relates to a process for the production of modified polypropylene yarns dyeable from an aqueous dyeing liquor, the polypropylene yarns obtained by this process and the use of the polypropylene yarns for the production of textile fabrics.
• the invention also relates to a method for dyeing the polypropylene yarns or the textile fabrics.
• the yarns are spin-dyed in that a colored masterbatch granulate, produced from a type of polypropylene suitable for fiber formation and a suitable color pigment, is used in the extrusion process.
• a colored masterbatch granulate produced from a type of polypropylene suitable for fiber formation and a suitable color pigment, is used in the extrusion process.
• the present invention has for its object to provide a process for the production of modified polypropylene yarns which can be dyed using a standard extraction process from aqueous dye liquor with great depths of color. This coloring is to be achieved with commercially available dyes using customary dye concentrations.
• the process should continue to have as few process steps as possible, which leads to cost savings, and should also be ecologically harmless.
• this object is achieved by a process which is characterized in that CR polypropylene suitable for fiber formation is mixed with a reactant which can react with the CR polypropylene and the mixture obtained is processed into yarns in an extrusion spinning plant.
• the controlled flow behavior can be achieved in various ways, for example by mechanical-thermal stress, ⁇ -radiation, oxidation or by the addition of peroxides.
• the most common method is to add organic peroxides to the powdered polymer during the preparation or processing process.
• free radicals are formed, which preferably split off hydrogen from the statistically predominantly longest chains of hydrogen, lead to chain splitting via subsequent reactions and thus bring about a narrower molar mass distribution, which increases the melt index.
• the easy-flowing CR polypropylene thus, like any other thermally oxidatively stressed polypropylene type, contains hydroxyl groups. These are present in the polypropylene types mentioned as inevitably produced end or side groups.
• the melt index MFR (melt flow rate, at 2.16 kg / 10 min) of the CR polypropylene used is in the range from about 10 to 1200.
• the melt index is preferably in the range from about 15 to 300.
• a range from is particularly preferred about 20 to 120 das
• the molecular weight of the CR polypropylene used is therefore in the range from approximately 300,000 to 80,000, preferably in the range from approximately 250,000 to 110,000 and particularly preferably in the range from approximately 220,000 to 130,000.
• the reactant it is of crucial importance to select the reactant so that it can react via its functional groups with the CR polypropylene, for example additively or through a substitution reaction.
• This functionality is then used so that when dyeing from an aqueous dye liquor, the respective dyes, in accordance with their interaction options, react with the functional groups and thereby produce deep and permanent dyeings of the polypropylene yarn.
• the necessary anchor groups are available, which are also able to bond with the respective dyes to a greater extent by means of bonds other than van der Waalssche, for example ionic or covalent binding mechanisms interact and thus enable deeper colors.
• CR polypropylene which is suitable for fiber formation is thus processed together with a specific reaction partner, as a result of which during the extrusion and during the thread formation the necessary conditions are created for a dye used in a later dyeing process to be able to soak up from an aqueous dye liquor and above is sufficiently liable.
• the process according to the invention does not require a separate, and therefore costly, processing step.
• the invention thus not only opens up a cost-effective method, but also access to a market which has hitherto been unattainable and which is determined by rapidly changing fashion-related color specifications.
• Another advantage of the invention is that the CR polypropylene can be used almost independently of its molecular weight and its molecular weight distribution.
• a difunctional carboxylic acid or a corresponding carboxylic acid derivative in particular a carboxylic acid ester, a carboxylic acid anhydride, a carboxylic acid amide, a carboximide, a carboxylic acid halide or a Use carbonitrile. Because of their chemical structure, these compounds are particularly well suited to react with the polypropylene.
• the reactant is used in an amount of up to about 12% by weight, preferably up to about 3% by weight and in particular up to about 1% by weight. The lower the amount of reactant used, the cheaper the process.
• a peroxidic additive as a reaction initiator.
• concentration by weight percent of which is approximately a power of ten lower than that of the reactant.
• Inorganic and organic peroxides such as, for example, 2,5-dimethyl-2,5-bis (t-butylperoxy-hexane), have proven to be particularly suitable reaction initiators.
• the spun filament yarns have residual elongation values in the order of magnitude of 200-700%.
• the tensile strengths achieved in the drawn filament yarns are in the range of about 50-60 cN / tex and therefore do not differ from yarns that were made from unmodified polypropylene.
• the yarns according to the invention can be processed further under normal conditions to give textile fabrics, preferably knitted fabrics.
• Another object of the present invention is a method for dyeing the polypropylene yarns and textile fabrics according to the invention.
• the polypropylene yarns according to the invention and the flat structures according to the invention can be dyed in a simple manner from an aqueous dyeing liquor by a standard extraction process. It is possible to achieve dyeings with extremely great depths of color using the usual dye concentrations, based on the weight of the goods.
• Almost any type of dye can be used which is capable of reacting with the polypropylene yarns or fabrics according to the invention via its own functional groups. As a result, not only a deep but also a permanent color is achieved.
• Acid, disperse and reactive dyes and cationic dyes have proven to be particularly suitable. When using these dyes, it is possible to comply with the dyeing conditions specified by the dye manufacturers in the color cards. Finally, it can be advantageous in individual cases to set conditions other than those recommended by the manufacturers with regard to the pH value, the dyeing temperature and the dyeing time. In this way, pH values from strongly acidic to strongly alkaline and high dyeing temperatures, even up to about 135 ° C, ie as under HT conditions, can be selected. It is also possible to increase the dyeing time up to 2 hours.
• dyeing aids such as, for example, ionic and nonionic wetting agents, dispersing agents, anti-static agents, leveling agents and retarders.
• Granule mixtures as described in Example 1, only with a mixture proportion of pyromellitic dianhydride of 1 or 3% by weight are produced under the same conditions as in Example 1 processed into filament threads.
• Example 1 Commercial CR polypropylene granules, as described in Example 1, are mixed with a masterbatch of polypropylene and maleic anhydride, available from Hoechst AG under the name Hostamont TP AR 504, so that the mixture contains a mixture of 1.75% maleic anhydride. This mixture is processed into filament yarn in the extrusion spinning system at 235 ° C.
• Granule mixtures as described in Examples 1 and 2, but provided with a further additive each in a concentration of 0.5 or 1 g / kg of granule mixture, are processed into filament yarns at the temperatures given in the examples mentioned.
• the said additive in turn represents a mixture consisting of low molecular weight polypropylene and 7.5% by weight of 2,5-dimethyl-2,5-bis- (t.-butylperoxy-hexane).
• Granule mixtures as described in Examples 5 to 8, only with the replacement of the pyromellitic dianhydride used there by caprolactam, are processed to filament yarns at temperatures of 265 ° C.
• Granule mixtures from the CR polypropylene granulate described in Example 1 and a self-produced masterbatch - consisting of the same CR polypropylene, commercial polyamide PA12 granulate and a peroxidic addition of the latter in a concentration of 1, as described in Examples 5 to 8 g / kg of masterbatch and a further 1 g of the peroxidic additive mentioned per kg of the finished granulate mixture are mixed in the appropriate ratio so that the mixture contains 0.5, 1 or 3% by weight of PA12. These mixtures become at 265 ° C Filament yarn processed.
• Knitted fabrics produced from filament yarns from Example 4, are dyed in a closed dyeing beaker according to the following program: enter the liquor at 60 ° C. and dwell for 15 minutes, then heat to 125 ° C. within 45 minutes and dye at this temperature for 120 minutes, then Cool to 50 ° C for 40 min, take colored samples and aftertreat 60 min at boiling temperature in an open bath with 1-2 g / 1 of a polyglycol ether derivative and soda.
• Typically used dye liquors with a liquor ratio of 1:50 and a pH value between pH2 and pHIO are generally 0.1-5% in cationic dye and contain 5 g / 1 of an anionic, synergetic surfactant mixture.

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• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Artificial Filaments (AREA)
• Coloring (AREA)

Applications Claiming Priority (3)

Publications (2)

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• 1997
  • 1997-10-22 DE DE19746635A patent/DE19746635B4/de not_active Expired - Fee Related
• 1998
  • 1998-10-22 AT AT98958229T patent/ATE243784T1/de not_active IP Right Cessation
  • 1998-10-22 WO PCT/EP1998/006700 patent/WO1999020817A1/fr active IP Right Grant
  • 1998-10-22 EP EP98958229A patent/EP1025293B1/fr not_active Expired - Lifetime
  • 1998-10-22 JP JP2000517132A patent/JP4188557B2/ja not_active Expired - Fee Related
  • 1998-10-22 US US09/529,929 patent/US6555038B1/en not_active Expired - Fee Related

Non-Patent Citations (1)

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