EP0885998B1 - Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren - Google Patents

Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren Download PDF

Info

Publication number
EP0885998B1
EP0885998B1 EP98810523A EP98810523A EP0885998B1 EP 0885998 B1 EP0885998 B1 EP 0885998B1 EP 98810523 A EP98810523 A EP 98810523A EP 98810523 A EP98810523 A EP 98810523A EP 0885998 B1 EP0885998 B1 EP 0885998B1
Authority
EP
European Patent Office
Prior art keywords
weight
ink
und
gew
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP98810523A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0885998A2 (de
EP0885998A3 (de
Inventor
Roger Lacroix
Mickael Mheidle
Peter Scheibli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Advanced Materials Switzerland GmbH
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=4211312&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0885998(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of EP0885998A2 publication Critical patent/EP0885998A2/de
Publication of EP0885998A3 publication Critical patent/EP0885998A3/de
Application granted granted Critical
Publication of EP0885998B1 publication Critical patent/EP0885998B1/de
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6426—Heterocyclic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D06P1/382—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group directly attached to heterocyclic group
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D06P1/384—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes reactive group not directly attached to heterocyclic group
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups

Definitions

  • the present invention relates to methods for printing textile fiber materials with reactive dyes according to the inkjet printing process (jet and inkjet processes) as well as corresponding printing inks.
  • Inkjet printing processes have been in the textile industry for several years applied. These processes make it possible to produce a product that is otherwise customary Eliminate the printing stencil, so that considerable cost and time savings are achieved can be. Especially in the production of sample templates can be within reacted to changing needs much less time.
  • Corresponding inkjet printing processes should in particular be optimal have application properties. To be mentioned in this Relationship properties such as viscosity, stability, surface tension and Conductivity of the inks used. There are also increased quality requirements of the prints obtained, e.g. regarding color strength, fiber-dye binding stability as well as wet fastness properties. Of the known methods these requirements are not met in all properties, so there is still a need for there are new processes for textile inkjet printing.
  • US-A-5542972 discloses aqueous ink compositions for ink jet printing, which contain dyes with reactive cyanamido groups.
  • the invention relates to a method for printing textile fiber materials according to the inkjet printing method, which is characterized in that these fiber materials are printed with an aqueous ink which contains at least one reactive dye of the formulas and wherein Z and Z 'are independently vinyl or a radical of the formula -CH 2 -CH 2 -OSO 3 H, B 1 and B 2 represent a C 2 -C 12 alkylene radical which can be interrupted by 1, 2 or 3 members -O- and is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxy and CuPhC is a copper phthalocyanine residue, and b) 1,2-propylene glycol or N-methyl-2-pyrrolidone contains.
  • B 1 and B 2 are preferably a C 2 -C 12 alkylene radical which can be interrupted by 1 or 2 members -O- and is unsubstituted or substituted by hydroxy.
  • B and B 2 are particularly preferably a C 2 -C 6 alkylene radical.
  • B, 1,3-propylene and B 2 1,2-ethylene are very particularly preferred.
  • Z is preferably vinyl.
  • Z ' the meaning as radical of the formula -CH 2 -CH 2 -OSO 3 H is preferred.
  • B 1 is preferably 1,3-propylene, B 2 1,2-ethylene, Z vinyl and Z 'is a radical of the formula -CH 2 -CH 2 -OSO 3 H.
  • Preferred reactive dyes for the process according to the invention are those of Formulas (1a) to (1g), in particular formulas (1a) to (1f) and preferably those of of the formulas (1a), (1b), (1d) and (1f).
  • the reactive dyes of the formulas (1a) to (1i) are known or can be used in analogy to known compounds, e.g. through usual diazotization, Coupling and condensation reactions.
  • the reactive dyes of the formulas (1 a) to (1 i) used in the inks should preferably low in salt, i.e. a total salt content of less than 0.5 wt .-%, based on the weight of the dyes.
  • Reactive dyes that due to their manufacture and / or the subsequent addition of coupé agents have higher salt contents, e.g. by membrane separation processes, such as Ultrafiltration, reverse osmosis or dialysis.
  • the inks preferably contain exclusively those of the above formulas as dyes (1a) to (1i).
  • the inks preferably contain a total reactive dye content of the above Formulas (1a) to (1i) from 5 to 35% by weight, in particular 10 to 35% by weight and preferably 10 to 20% by weight based on the total weight of the ink.
  • the content of N-methyl-2-pyrrolidone or 1,2-propylene glycol in the ink is usually 5 up to 30% by weight, in particular 5 to 20% by weight and preferably 10 to 20% by weight, based on the total weight of the ink.
  • the inks preferably contain 1,2-propylene glycol, usually in an amount of 5 to 30% by weight, in particular 5 to 20% by weight and preferably 10 to 20% by weight on the total weight of the ink.
  • the inks may also contain buffer substances, e.g. Borax, borate or citrate.
  • buffer substances e.g. Borax, borate or citrate.
  • borax sodium borate, sodium tetraborate and sodium citrate.
  • she are used in particular in amounts of 0.1 to 3% by weight, preferably 0.1 to 1% by weight, based on the total weight of the ink used to achieve a pH of e.g. 4 to 9, especially 4 to 8.
  • the inks can e.g. Alginate or in particular water-soluble, contain non-ionic cellulose ether.
  • non-ionic cellulose ether come e.g. Methyl, ethyl, hydroxyethyl, methylhydroxyethyl, hydroxypropyl or Hydroxypropylmethyl cellulose into consideration.
  • Methylcellulose or in particular are preferred Hydroxyethyl cellulose.
  • the cellulose ethers as well as the algnates are in the ink usually in an amount of 0.01 to 2% by weight, in particular 0.01 to 1 wt .-% and preferably 0.01 to 0.5 wt .-%, based on the total weight of the Ink, used.
  • Both the water-soluble, non-ionic cellulose ethers and the Alginates are used as so-called thickeners and allow the setting of one certain viscosity of the ink.
  • Preferred inks for the process according to the invention are those which have a viscosity from 1 to 40 mPa ⁇ s, in particular 1 to 20 mPa ⁇ s and preferably 1 to 10 mPa ⁇ s exhibit.
  • the inks can also contain conventional additives such as e.g. foam suppressants or in particular substances that inhibit fungal and / or bacterial growth. This are usually in amounts of 0.01 to 1 wt .-%, based on the total weight the ink used.
  • foam suppressants or in particular substances that inhibit fungal and / or bacterial growth. This are usually in amounts of 0.01 to 1 wt .-%, based on the total weight the ink used.
  • the inks can be prepared in the usual way by mixing the individual components in the desired amount of water can be produced.
  • the present invention also relates to a method for printing on textiles Fiber materials according to the inkjet printing process, which is characterized is that you print these fiber materials with an aqueous ink, which at least contains a reactive dye of the formulas (1a), (1b), (1d) and (1f) given above.
  • aqueous inks can also be used which have at least one Reactive dye of the above formulas (1 a) to (1 i), in particular of the formulas (1a) to (1f), optionally at least one of the additives mentioned above for the inks contain and contain no thioglycol, preferably no further additives. in this connection the above preferences apply.
  • the methods according to the invention for printing textile fiber materials can with inkjet printers known per se and suitable for textile printing be carried out.
  • fiber materials containing hydroxyl groups come as textile fiber materials into consideration.
  • the fiber materials mentioned are preferably in the form of flat textile fabrics, knitted fabrics or webs.
  • the aqueous alkaline liquor contains at least one of the usual bases, which in conventional Reactive printing processes are used to fix the reactive dyes.
  • the base is e.g. in an amount of 10 to 100 g / l liquor, preferably 10 to 50 g / l Fleet, deployed.
  • Sodium bicarbonate is preferred, sodium carbonate or a mixture of water glass and sodium carbonate is used.
  • the pH the alkaline liquor is usually 7.5 to 13.5, preferably 8.5 to 12.5.
  • the aqueous alkaline liquor can contain other additives, e.g. hydrotropic, contain.
  • Urea is preferably used as the hydrotroping agent, e.g. in a Amount of 25 to 200 g / l liquor, preferably 50 to 150 g / l liquor is used.
  • the fiber material is preferably dried after the above pretreatment.
  • the fiber material is advantageously dried, preferably at temperatures up to 150 ° C, especially 80 to 120 ° C, and then a heat treatment process subjected to complete printing or dye fix.
  • the heat treatment can e.g. through a warm dwell process, a thermal insulation process or preferably be carried out by a steaming process.
  • the printed fiber material is e.g. one treatment in one Damper with possibly superheated steam, conveniently at one temperature from 95 to 180 ° C, advantageously in saturated steam.
  • the printed fiber material is usually washed with water in the usual way washed out to remove unfixed dye.
  • the prints obtainable by the process according to the invention have good prints General realities on; e.g. they have high fiber-dye binding stability both in the acidic and in the alkaline range, good lightfastness, good Wet fastness properties such as fastness to washing, water, sea water, over-dyeing and perspiration, one good chlorine fastness, rubbing fastness, ironing fastness and pleating fastness as well as sharp contours and high color strength.
  • the printing inks used are characterized by good stability and good viscosity properties.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
EP98810523A 1997-06-17 1998-06-09 Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren Revoked EP0885998B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH147397 1997-06-17
CH1473/97 1997-06-17
CH147397 1997-06-17

Publications (3)

Publication Number Publication Date
EP0885998A2 EP0885998A2 (de) 1998-12-23
EP0885998A3 EP0885998A3 (de) 2000-02-23
EP0885998B1 true EP0885998B1 (de) 2004-11-03

Family

ID=4211312

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98810523A Revoked EP0885998B1 (de) 1997-06-17 1998-06-09 Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren

Country Status (13)

Country Link
US (1) US6015454A (es)
EP (1) EP0885998B1 (es)
JP (1) JPH1112962A (es)
KR (1) KR100538664B1 (es)
CN (1) CN1202549A (es)
BR (1) BR9802380A (es)
DE (1) DE59812197D1 (es)
ES (1) ES2230665T3 (es)
ID (1) ID20434A (es)
PT (1) PT885998E (es)
SG (1) SG73519A1 (es)
TR (1) TR199801116A2 (es)
TW (1) TW514659B (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9813475D0 (en) * 1998-06-23 1998-08-19 Zeneca Ltd Compounds,compositions and use
WO2000046309A1 (en) 1999-02-05 2000-08-10 Ciba Specialty Chemicals Holding Inc. Black-dyeing inks and their use
US6371610B1 (en) * 2000-01-28 2002-04-16 Seiren Co., Ltd. Ink-jet printing method and ink-jet printed cloth
DE10004954A1 (de) * 2000-02-04 2001-08-16 Dystar Textilfarben Gmbh & Co Wässrige Drucktinten für den Einsatz nach dem Tintenstrahldruck-Verfahren, ihre Herstellung und ihre Verwendung auf textilen Fasermaterialien
GB0019464D0 (en) * 2000-08-09 2000-09-27 Clariant Int Ltd Organic compounds
AU2001296480A1 (en) * 2000-10-02 2002-04-15 Kimberly-Clark Worldwide, Inc. Recording medium with nanoparticles and methods of making the same
US6561642B2 (en) 2001-09-28 2003-05-13 Hewlett-Packard Development Company Ink jet printer system for printing an image on a web overlaying a removable substrate and method of assembling the printer system
US20030199611A1 (en) * 2002-03-08 2003-10-23 Chandrasekaran Casey K. Inkjet ink for textiles
US20050252412A1 (en) * 2002-06-13 2005-11-17 Markus Gisler Disazo dyes having adapted affinity
US7666410B2 (en) * 2002-12-20 2010-02-23 Kimberly-Clark Worldwide, Inc. Delivery system for functional compounds
US6780896B2 (en) * 2002-12-20 2004-08-24 Kimberly-Clark Worldwide, Inc. Stabilized photoinitiators and applications thereof
US8409618B2 (en) 2002-12-20 2013-04-02 Kimberly-Clark Worldwide, Inc. Odor-reducing quinone compounds
EP2099869B1 (en) 2006-10-31 2013-05-01 Sensient Colors Inc. Modified pigments and methods for making and using the same
CA3017708C (en) 2007-08-23 2021-09-21 Vincent Shing Self-dispersed pigments and methods for making and using the same
US20090163887A1 (en) * 2007-12-20 2009-06-25 Arehart Kelly D Odor control cellulose granules with quinone compounds
EP2246398B1 (en) * 2008-02-22 2013-10-16 Nippon Kayaku Kabushiki Kaisha Ink composition and textile printing method using the same
CN101519551B (zh) * 2008-02-25 2011-07-20 明德国际仓储贸易(上海)有限公司 墨水组成物
JP2010007192A (ja) * 2008-06-25 2010-01-14 Konica Minolta Ij Technologies Inc インクジェット捺染方法
CN102365336B (zh) * 2009-03-27 2014-05-28 日本化药株式会社 油墨组合物及染色聚酰胺类纤维的制造方法
AU2010234392A1 (en) * 2009-04-07 2011-10-27 Sensient Colors Inc. Self-dispersing particles and methods for making and using the same
TWI425055B (zh) 2009-08-21 2014-02-01 Everlight Chem Ind Corp 反應性印花染料及其液態組成物之應用
US8987544B2 (en) 2010-12-17 2015-03-24 Kimberly-Clark Worldwide, Inc. Article with heat-activatable expandable structures
US8740869B2 (en) 2011-03-11 2014-06-03 Kimberly-Clark Worldwide, Inc. Personal care articles with tactile visual cues
CN102337045B (zh) * 2011-07-13 2014-03-26 丽源(湖北)科技有限公司 蓝色活性染料混合物及其制备和应用
CN102504583B (zh) * 2011-09-29 2014-10-08 刘卫斌 一种大红偶氮染料及其制备和使用
CN106752077B (zh) * 2016-11-28 2018-07-24 浙江瑞华化工有限公司 一种蓝色活性染料组合物及其制备方法和用途

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61101574A (ja) * 1984-10-23 1986-05-20 Ricoh Co Ltd 水性インク
JPS60185886A (ja) * 1985-01-29 1985-09-21 キヤノン株式会社 捺染用液媒体
GB9102037D0 (en) * 1991-01-30 1991-03-13 Ici Plc Printing process & formulation
US5250121A (en) * 1991-09-26 1993-10-05 Canon Kabushiki Kaisha Ink-jet textile printing ink and ink-jet textile printing process
DE69302039T2 (de) * 1992-03-06 1996-09-12 Zeneca Ltd Tintenzusammensetzungen
GB9325454D0 (en) * 1993-01-12 1994-02-16 Zeneca Ltd Azo compound
DE4335958A1 (de) * 1993-10-21 1995-04-27 Bayer Ag Neue Kupferphthalocyanin-Farbstoffe und deren Verwendung
DE4417718A1 (de) * 1994-05-20 1995-11-23 Hoechst Ag Reaktivfarbstoffe für den Tintenstrahldruck
US5843217A (en) * 1996-10-11 1998-12-01 Minolta Co., Ltd. Ink for ink jet recording

Also Published As

Publication number Publication date
JPH1112962A (ja) 1999-01-19
KR100538664B1 (ko) 2006-03-14
CN1202549A (zh) 1998-12-23
ES2230665T3 (es) 2005-05-01
TR199801116A3 (tr) 1999-10-21
US6015454A (en) 2000-01-18
EP0885998A2 (de) 1998-12-23
TW514659B (en) 2002-12-21
BR9802380A (pt) 1999-07-20
SG73519A1 (en) 2000-06-20
DE59812197D1 (de) 2004-12-09
EP0885998A3 (de) 2000-02-23
ID20434A (id) 1998-12-17
KR19990007011A (ko) 1999-01-25
TR199801116A2 (xx) 1999-10-21
PT885998E (pt) 2005-03-31

Similar Documents

Publication Publication Date Title
EP0885998B1 (de) Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren
EP0885999B1 (de) Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren
EP1325945B1 (de) Verfahren zum Färben oder Bedrucken sowie neue Reaktivfarbstoffe
EP0886000B1 (de) Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren
EP1086999B1 (de) Magentafärbende Tinten enthaltend Kupferkomplexazofarbstoffe auf der Bais von 1-Naphthol-di-oder trisulfonsäuren
DE102008054404A1 (de) Faserreaktive Azofarbstoffe und Farbstoffmischungen, Verfahren zu ihrer Herstellung und ihre Verwendung
MXPA98004842A (es) Proceso para imprimir materiales de vibra textil de acuerdo con el proceso de impresion de chorro de tinta
EP0832939B1 (de) Blaufärbende Mischungen von faserreaktiven Farbstoffen und ihre Verwendung zum Färben von hydroxy- und/oder carbonamidgruppenhaltigem Fasermaterial
DE19511689A1 (de) Mischung von blaufärbenden faserreaktiven Farbstoffen und ihre Verwendung zum Färben von hydroxy- und/oder carbonamidgruppenhaltigem Fasermaterial
JP2003306627A (ja) 紡織品インクジェットプリント用インク組成物
EP1737915A1 (de) Mischungen von faserreaktiven azofarbstoffen, ihre herstellung und verwendung
DE60101051T2 (de) Verwendung einer farbstoffzusammensetzung im tintenstrahldruckverfahren
EP0885997A2 (de) Verfahren zum Bedrucken von Fasermaterialien
EP1086993B1 (de) Kupferkomplexazofarbstoffe, deren Herstellung und deren Verwendung
DE19918160A1 (de) Reaktivfarbstoffmischungen für salzarmes Färben
DE102009000417A1 (de) Faserreaktive Azofarbstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung
DE10064496A1 (de) Schwarze Farbstoffmischungen von faserreaktiven Azofarbstoffen und ihre Verwendung zum Färben von hydroxy- und/oder carbonamidgruppenhaltigem Fasermaterial
EP1102883A1 (de) Verfahren zum bedrucken von textilen fasermaterialien nach dem tintenstrahldruck-verfahren
DE19930866A1 (de) Verfahren zum Bedrucken von textilen Fasermaterialien nach dem Tintenstrahldruck-Verfahren
DE102004058151A1 (de) Mischungen von faserreaktiven Azofarbstoffen, Verfahren zu deren Herstellung und ihre Verwendung
DE102005029383A1 (de) Farbstoffmischung von wasserlöslichen faserreaktiven Farbstoffen, Verfahren zu ihrer Herstellung und ihre Verwendung
DE2712088C2 (de) Verfahren zum Färben oder Bedrucken von Fasermaterialien mit reaktionsfähigen Wasserstoffatomen mit auf der Faser erzeugten Azofarbstoffen
DE19922825A1 (de) Neue fluortriazinhaltige brillantgelbe Farbstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung zum Färben von hydroxy- und amidgruppenhaltigen Materialien
DE10037075A1 (de) Farbstoffmischung von wasserlöslichen faserreaktiven Farbstoffen Verfahren zu ihrer Herstellung und ihre Verwendung
DE2712087A1 (de) Verfahren zum faerben oder bedrucken von fasermaterialien mit reaktionsfaehigen wasserstoffatomen mit auf der faser erzeugten azofarbstoffen

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): BE CH DE ES FR GB IT LI PT

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

17P Request for examination filed

Effective date: 19990528

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

AKX Designation fees paid

Free format text: BE CH DE ES FR GB IT LI PT

17Q First examination report despatched

Effective date: 20031217

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE CH DE ES FR GB IT LI PT

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 59812197

Country of ref document: DE

Date of ref document: 20041209

Kind code of ref document: P

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20050114

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20050127

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2230665

Country of ref document: ES

Kind code of ref document: T3

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: DYSTAR TEXTILFARBEN GMBH & CO DEUTSCHLAND KG

Effective date: 20050802

ET Fr: translation filed
PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

REG Reference to a national code

Ref country code: CH

Ref legal event code: PUE

Owner name: HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH

Free format text: CIBA SPECIALTY CHEMICALS HOLDING INC.#KLYBECKSTRASSE 141#4057 BASEL (CH) -TRANSFER TO- HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH#KLYBECKSTRASSE 200#4057 BASEL (CH)

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20070529

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20070615

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20070622

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20070628

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20070621

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20070614

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20070711

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20070615

Year of fee payment: 10

RDAF Communication despatched that patent is revoked

Free format text: ORIGINAL CODE: EPIDOSNREV1

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

27W Patent revoked

Effective date: 20080628

GBPR Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state

Effective date: 20080628

REG Reference to a national code

Ref country code: PT

Ref legal event code: MP4A

Effective date: 20081114

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080609