EP0656819B1 - Verfahren und vorrichtung zum giessen von bauteilen - Google Patents
Verfahren und vorrichtung zum giessen von bauteilen Download PDFInfo
- Publication number
- EP0656819B1 EP0656819B1 EP94918839A EP94918839A EP0656819B1 EP 0656819 B1 EP0656819 B1 EP 0656819B1 EP 94918839 A EP94918839 A EP 94918839A EP 94918839 A EP94918839 A EP 94918839A EP 0656819 B1 EP0656819 B1 EP 0656819B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- casting
- mould
- melt
- container
- ingate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005266 casting Methods 0.000 title claims abstract description 158
- 238000000034 method Methods 0.000 title claims abstract description 59
- 230000008569 process Effects 0.000 title claims abstract description 38
- 239000000155 melt Substances 0.000 claims abstract description 37
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims description 25
- 238000007711 solidification Methods 0.000 claims description 20
- 230000008023 solidification Effects 0.000 claims description 20
- 239000011261 inert gas Substances 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 abstract description 17
- 230000015572 biosynthetic process Effects 0.000 abstract description 9
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 238000005429 filling process Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000005465 channeling Effects 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 210000002105 tongue Anatomy 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/09—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting by using pressure
- B22D27/13—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting by using pressure making use of gas pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D23/00—Casting processes not provided for in groups B22D1/00 - B22D21/00
- B22D23/006—Casting by filling the mould through rotation of the mould together with a molten metal holding recipient, about a common axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/003—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting by using inert gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F1/00—Cylinders; Cylinder heads
- F02F1/24—Cylinder heads
Definitions
- the invention relates to a method and an apparatus for casting Components, made of metal alloys according to the tilting principle according to the respective Generic term of independent claims 1, 3 and 15.
- the liquid material state is a variety of different processes and devices known that more or less resemble a high quality Workpiece requirements with regard to freedom of design, Surface quality and in particular optimal material properties to reach.
- the main difficulties initially lie in the mold filling process, the initially compact melt volume divided and a large one Surface is exposed to the attack of the air atmosphere, which by appropriate Reactions lead to an impairment of the material quality.
- Molten metal alloys, their Alloy components have a high reactivity with the oxygen, Have nitrogen and water vapor in the air. It became like this early on sensitive alloys, for example the Durville tipping process applied.
- DE-PS 377 683 proposes a method in which an elongated Casting vessel numerous castings are made in succession.
- the melt container is erected, which limits one higher metallostatic pressure can be achieved.
- the Atmosphere free access to the melt, so that especially as it progresses easily drain oxide from the bath surface into the mold cavity can reach.
- a direct remains during the solidification of the casting
- DE-PS 505 224 describes a method in which on a similar one Swing arranged casting container two molds are mounted, which alternate be filled with melt. Here, too, the air has free access to the melt pool with a large surface, so that the impurities present here can easily get into the mold.
- DE-PS 21 64 755 describes a high-performance casting process for large series, in which the disadvantages of the aforementioned proposals largely could be eliminated.
- the solidification process in the casting mold usually occurs through volume contraction and gas excretion cavities and pores in the component structure must be combated with considerable effort.
- the shrinking processes also locally lead to the formation of gaps between the cast wall and mold wall surfaces, which significantly affects the heat transfer, what also has negative repercussions on the structure quality and also Sink marks on the casting surface that make the component unusable do.
- GB 2 080 714 A describes a method and an apparatus of the type described in the introduction.
- the device comprises a Pouring canister, which during the implementation of the process of a mold cavity through a channel with an elongated constriction is separated, with at least the after tilting in oxide skin located in a feeder head is washed into the casting will be.
- the mold filling controlled in the sense of throttling, whereby a layered mold filling is not possible.
- the flow paths of the melt from the gate the channel with the constriction and the feeder head are in relation to the casting size very long and affect the Melt quality considerably due to reactions and temperature losses, which greatly reduces the mold filling and fluidity becomes.
- the object of the present invention is, using novel methods and a new type of pouring device for high-quality component production to create necessary favorable conditions, both when filling the mold as well as during the solidification of the castings, at the same time a special one to enable rational manufacturing and thereby the disadvantages of the above Avoid procedures and devices. Turbulence and Distribution of the melt during mold filling can be avoided. After a Further tasks are the reactions of the alloy melt with the Gases of the atmosphere and the mold cavity are prevented. After a Another advanced task is preferably a sharp-contoured filling achieved and an optimally fine-grained and dense component structure during the Solidification process can be ensured.
- the gate creates the direct connection between the casting container and the mold cavity and should be such that a throttling or Swirling of the melt when overflowing can be avoided. Its big Cross section based on the cross section of the cut mold cavity or the adjacent mold wall parts of the component can after a first Approach over 40%, especially over 50% of the latter cross-sectional areas be.
- the large cross section related to the cross section of the cut mold cavity or the cross section of the adjacent mold wall parts extends according to the invention over essentially the entire length of the latter areas.
- the gate communicates here each with the deepest parts of the mold cavity or the mold wall part before turning. Only their cross-sectional areas parallel to the gate cross-section are referred to as cut surfaces on which the relative dimensioning of the gate.
- the process is peculiar to that for a casting process one corresponding to the gross volume of the melt quantity for a casting Quantity is poured into the casting tank during the casting process completely solidified, with only a small volume fraction of the melt, the the feeder volume forms, in the gate itself or, if necessary, in small quantities remains in the casting tank.
- a quantity corresponding to the melting quantity becomes fixed metal volume introduced into the casting tank, first then the sealing connection between the casting container and the casting mold and the interior was purged with protective gas, whereupon the melt quantum is melted for a cast in the casting container. Otherwise runs the procedure unchanged. Here, too, the oxidation processes liquid phase effectively avoided.
- an increase in pressure of the protective gas is carried out during made of the solidification process, whereby the feed volume and thus the Use of metal can be reduced because of the overpressure on the melt level the otherwise usual metallostatic pressure of high-reaching feeders replaced.
- the risk of contamination and the inclusions in the casting excluded in that Comparison to the adjacent component surface or the cut part of the mold cavity, a large gate cross section is provided, or that a compared to the size of the casting or the mold cavity in the direction of Long gating axis of rotation is provided. This results in a calm overflow, preferably completely under the bath level from the casting container into the casting mold, so that a faultless casting is created.
- the gate with a large cross-section is with the pouring channel or barrel identical and at the same time represents the volume of feeder. It forms the immediate one Connection between the interior of the casting container and the mold cavity.
- the mold cavity for an elongated component is aligned in the direction of the axis of rotation. This enables a wide melt front to be represented.
- Another design is that the cores lie towards the casting container are arranged. As a result, the cut mold wall parts themselves reduced to end wall parts of the component to improve the quality.
- the solidification should be carried out in a known manner, if necessary by heating and / or Cooling can be controlled so that it is the most distant from the casting tank Position of the component progresses towards the gate.
- a further overflow channel becomes parallel intended for gate, so that initially a gas or air volume compensation can take place to avoid foaming.
- an increased, in particular variable, protective gas pressure during the solidification very special advantages.
- a strong increase in gas pressure mainly due to the melt level at the end of the mold filling acts below which the feed volume of the casting is, can Appropriate increase of the feed pressure is achieved and thus a substantial Sealing feed of the cast structure can be forced.
- a vigorously pressing the cast part surfaces against the mold walls and through Prevention of the harmful gap formation an increased heat transfer causes.
- Improvements can also be made in the use of inert gas.
- the application A protective gas pump not only allows the application of several bar pressure, it also allows for a subsequent pressure reduction Recovery of the protective gas. This way the losses stay up unavoidable leakage is limited.
- the proposed methods offer ideal conditions for use in a casting cell sealed off from the outside world reliable prevention of foundry emissions.
- a casting mold 31 (mold) is with a mold cavity 1 through a mold cover plate 2, side parts 3, Cores 4 and a mold base plate 5 are formed.
- a casting container 30 with a housing 6 and one Refractory lining 7, which is a melt quantum 8 metered for a casting contains.
- the melt quantum 8 is with the help of a not shown Dosing furnace in particular through the filling opening 9 with the closure 10 open filled under protective gas; then the shutter 10 is closed.
- a protective gas connection 11 is shown on the closure 10.
- the horizontal is in the direction of the longitudinal extent of Casting mold 31 and casting container 30 extending axis of rotation 12 of the casting device shown.
- As an opening within the mold base plate 5 is a Bleed 13 formed with a large cross section.
- An arrow above the mold cover plate 2 symbolizes the direction of movement the same for demolding the finished component.
- the mold 31 with the mold cavity 1 can also be seen in FIG. 2, those from the mold cover plate 2, side parts 3, cores 4 and the mold base plate 5 exists.
- the base plate 5 In the base plate 5 are the gate 13 and a parallel further overflow channel 14 can be seen.
- the housing 6 On the casting container 30 is the housing 6, the refractory lining 7 and the contained therein for a casting metered melt quantum 8 recognizable.
- FIG. 3 shows a rotatable casting device 19 with a rotary drive 27 and a casting container 30 and a casting mold 31 connecting them Bracing means 32 shown within a casting cell 21.
- the axis of rotation 12 the pouring device is also shown.
- the casting container 30 is over a line 26 with a pump and storage system shown only symbolically 18, 28 connected.
- a metering furnace is located within the casting cell 21 15, which has an elastic gas-tight coupling 23 with the filling opening 9 of the casting container 30 is connected.
- the metering oven 15 is a Lock 22 connected to an area outside the casting cell 21.
- To the Lock 22 can alternatively be a charging device 16 for lumpy Feed material or a charging device 17 for liquid feed material connect.
- the casting cell comprises a further lock 22. Above the mold 31, a manipulator 20 for cores can be seen.
- FIG. 4 shows a casting device consisting of a casting container 30 and a mold 31 shown.
- the casting container 30 differs from that shown in FIG. 1 in that that it has no fill opening. However, it points within the refractory layer 7 means for heating 24.
- a solid metal quatum 25 is in the Casting container 30 used. Corresponds in cross section perpendicular to the axis of rotation 12 this pouring device shown in Figure 2.
- the casting mold 31 essentially corresponds to that shown in FIG. 1. It comprises a mold cover plate 2, mold side parts 3 and one Mold base plate 5. However, means 29 for cooling are in the side parts shown. Cores 4 are used in the mold. The axis of rotation of the device is designated 12.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Processing Of Solid Wastes (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Dental Prosthetics (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
- Continuous Casting (AREA)
- Mold Materials And Core Materials (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE9421585U DE9421585U1 (de) | 1993-06-02 | 1994-06-03 | Vorrichtung zum Gießen von Bauteilen |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4318252A DE4318252A1 (de) | 1993-06-02 | 1993-06-02 | Verfahren und Vorrichtung zum Giessen von Bauteilen |
DE4318252 | 1993-06-02 | ||
PCT/EP1994/001813 WO1994029050A2 (de) | 1993-06-02 | 1994-06-03 | Verfahren und vorrichtung zum giessen von bauteilen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0656819A1 EP0656819A1 (de) | 1995-06-14 |
EP0656819B1 true EP0656819B1 (de) | 1999-03-10 |
Family
ID=6489414
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94918839A Expired - Lifetime EP0656819B1 (de) | 1993-06-02 | 1994-06-03 | Verfahren und vorrichtung zum giessen von bauteilen |
Country Status (9)
Country | Link |
---|---|
US (1) | US5626180A (hu) |
EP (1) | EP0656819B1 (hu) |
JP (1) | JP2952523B2 (hu) |
AT (1) | ATE177354T1 (hu) |
CZ (1) | CZ290291B6 (hu) |
DE (2) | DE4318252A1 (hu) |
ES (1) | ES2131199T3 (hu) |
HU (1) | HU217381B (hu) |
WO (1) | WO1994029050A2 (hu) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10019309A1 (de) * | 2000-04-19 | 2001-10-31 | Vaw Mandl & Berger Gmbh Linz | Verfahren und Vorrichtung zum Rotationsgießen |
DE102016220240A1 (de) | 2015-10-15 | 2017-04-20 | Volkswagen Aktiengesellschaft | Rotationsgießverfahren |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19647713C2 (de) * | 1996-11-11 | 2000-01-05 | Strikfeldt & Koch | Vorrichtung zur Erfassung eines Pegels von flüssigem Metall |
US6263951B1 (en) | 1999-04-28 | 2001-07-24 | Howmet Research Corporation | Horizontal rotating directional solidification |
TWI386262B (zh) * | 2004-09-01 | 2013-02-21 | Commw Scient Ind Res Org | 合金鑄造裝置 |
US10933467B2 (en) * | 2014-03-28 | 2021-03-02 | Inductotherm Corp. | Clean cell environment roll-over electric induction casting furnace system |
CN110125344B (zh) * | 2019-06-12 | 2024-08-23 | 陕西三毅有岩材料科技有限公司 | 一种铸造难熔金属的方法及难熔金属锭 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE377683C (de) * | 1923-06-23 | Schmidt Karl | Verfahren zum Giessen von Metallen | |
DE505224C (de) * | 1929-11-18 | 1930-08-15 | Frank Stuhl | Vorrichtung zum Giessen von Roheisen unter Druck |
US2233405A (en) * | 1938-12-27 | 1941-03-04 | Permold Co | Method of and apparatus for casting cylinder heads |
FR879762A (fr) * | 1942-02-27 | 1943-03-04 | Procédé pour la coulée de pièces métalliques dans des moules en sable | |
FR996838A (fr) * | 1949-08-25 | 1951-12-27 | Procédé et dispositif pour la coulée dans le vide de pièces d'acier magnétique,en particulier de carcasses pour moteurs électriques; de tôles pour transformateurs, etc. | |
FR1083506A (fr) * | 1953-04-29 | 1955-01-10 | Fonderie Tech De Vitry Sur Sei | Perfectionnements aux moules de coulée de pièces en alliages spéciaux |
FR1304944A (fr) * | 1961-11-03 | 1962-09-28 | Engstfeld Wilh | Machine pour la coulée de pièces métalliques dans des moules durables |
FR1424958A (fr) * | 1964-07-24 | 1966-01-14 | Machine à couler, avec porte-moules inclinable | |
US3333625A (en) * | 1964-11-19 | 1967-08-01 | Howard A Fromson | Method of casting fusible materials |
US3635791A (en) * | 1969-08-04 | 1972-01-18 | Gen Motors Corp | Pressure pouring in a vacuum environment |
DE2164755C3 (de) * | 1971-12-27 | 1975-10-16 | Friedhelm Prof. Dr.-Ing. 6332 Ehringshausen Kahn | Verfahren und Vorrichtung zum Gießen und zur Erstarrungslenkung von Gußstücken in Gießformen |
US3863704A (en) * | 1973-01-02 | 1975-02-04 | Freidhelm Kahn | Method of casting by pouring metal from a melt supply through a feeder into a mold |
DE2358719A1 (de) * | 1973-11-26 | 1975-06-05 | Dso Metalurgia Rudodobiv | Verfahren und vorrichtung zum giessen von metallen und metall-legierungen |
JPS5396920A (en) * | 1977-02-04 | 1978-08-24 | Honda Kinzoku Gijutsu Kk | Casting machine |
DE2936418A1 (de) * | 1979-09-08 | 1981-03-26 | Siegerländer Kupferwerke GmbH, 5900 Siegen | Verfahren und einrichtung zum giessen von metallen unter verwendung einer form |
GB2080714B (en) * | 1980-07-31 | 1984-07-25 | Richards Brinley James | Tilting mould in casting |
DE3521086A1 (de) * | 1985-06-12 | 1986-12-18 | MKB Enebra Metallguß-Gesellschaft mbH, 8078 Eichstätt | Verfahren und vorrichtung zum giessen von gegenstaenden aus metallen |
GB8604386D0 (en) * | 1986-02-21 | 1986-03-26 | Cosworth Res & Dev Ltd | Casting |
JPH02274372A (ja) * | 1989-04-12 | 1990-11-08 | Asahi Tec Corp | 鋳造装置 |
JPH03118956A (ja) * | 1989-09-29 | 1991-05-21 | Asahi Tec Corp | 可傾鋳造装置および可傾鋳造法 |
US5163500A (en) * | 1991-12-13 | 1992-11-17 | Ford Motor Company | Rollover method for metal casting |
-
1993
- 1993-06-02 DE DE4318252A patent/DE4318252A1/de not_active Withdrawn
-
1994
- 1994-06-03 JP JP7501289A patent/JP2952523B2/ja not_active Expired - Lifetime
- 1994-06-03 WO PCT/EP1994/001813 patent/WO1994029050A2/de active IP Right Grant
- 1994-06-03 ES ES94918839T patent/ES2131199T3/es not_active Expired - Lifetime
- 1994-06-03 US US08/379,544 patent/US5626180A/en not_active Expired - Lifetime
- 1994-06-03 HU HU9500291A patent/HU217381B/hu unknown
- 1994-06-03 AT AT94918839T patent/ATE177354T1/de active
- 1994-06-03 CZ CZ1995246A patent/CZ290291B6/cs not_active IP Right Cessation
- 1994-06-03 EP EP94918839A patent/EP0656819B1/de not_active Expired - Lifetime
- 1994-06-03 DE DE59407918T patent/DE59407918D1/de not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10019309A1 (de) * | 2000-04-19 | 2001-10-31 | Vaw Mandl & Berger Gmbh Linz | Verfahren und Vorrichtung zum Rotationsgießen |
DE10019309C2 (de) * | 2000-04-19 | 2002-04-18 | Vaw Mandl & Berger Gmbh Linz | Verfahren und Vorrichtung zum Rotationsgießen |
US6715535B2 (en) | 2000-04-19 | 2004-04-06 | Vaw Mandl & Berger Gmbh | Method of and device for rotary casting |
DE102016220240A1 (de) | 2015-10-15 | 2017-04-20 | Volkswagen Aktiengesellschaft | Rotationsgießverfahren |
Also Published As
Publication number | Publication date |
---|---|
JP2952523B2 (ja) | 1999-09-27 |
WO1994029050A3 (de) | 1995-03-23 |
DE59407918D1 (de) | 1999-04-15 |
DE4318252A1 (de) | 1994-12-08 |
ATE177354T1 (de) | 1999-03-15 |
CZ290291B6 (cs) | 2002-07-17 |
US5626180A (en) | 1997-05-06 |
WO1994029050A2 (de) | 1994-12-22 |
CZ24695A3 (en) | 1996-01-17 |
EP0656819A1 (de) | 1995-06-14 |
HU217381B (hu) | 2000-01-28 |
ES2131199T3 (es) | 1999-07-16 |
JPH07509664A (ja) | 1995-10-26 |
HUT68972A (en) | 1995-08-28 |
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