EP1786576A1 - Verfahren und vorrichtung zum giessen von metallschmelze - Google Patents
Verfahren und vorrichtung zum giessen von metallschmelzeInfo
- Publication number
- EP1786576A1 EP1786576A1 EP05778033A EP05778033A EP1786576A1 EP 1786576 A1 EP1786576 A1 EP 1786576A1 EP 05778033 A EP05778033 A EP 05778033A EP 05778033 A EP05778033 A EP 05778033A EP 1786576 A1 EP1786576 A1 EP 1786576A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mold
- casting
- molten metal
- melt
- casting mold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005266 casting Methods 0.000 title claims abstract description 126
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 42
- 239000002184 metal Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000000155 melt Substances 0.000 claims abstract description 78
- 230000005484 gravity Effects 0.000 claims abstract description 16
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000465 moulding Methods 0.000 claims description 6
- 230000008878 coupling Effects 0.000 claims description 4
- 238000010168 coupling process Methods 0.000 claims description 4
- 238000005859 coupling reaction Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000004411 aluminium Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 9
- 238000007711 solidification Methods 0.000 description 9
- 230000008023 solidification Effects 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000000630 rising effect Effects 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000001175 rotational moulding Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000289 melt material Substances 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D18/00—Pressure casting; Vacuum casting
- B22D18/04—Low pressure casting, i.e. making use of pressures up to a few bars to fill the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
- B22D17/20—Accessories: Details
- B22D17/26—Mechanisms or devices for locking or opening dies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D18/00—Pressure casting; Vacuum casting
- B22D18/08—Controlling, supervising, e.g. for safety reasons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D21/00—Casting non-ferrous metals or metallic compounds so far as their metallurgical properties are of importance for the casting procedure; Selection of compositions therefor
- B22D21/02—Casting exceedingly oxidisable non-ferrous metals, e.g. in inert atmosphere
- B22D21/04—Casting aluminium or magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
- B22D27/02—Use of electric or magnetic effects
Definitions
- the invention relates to a method and a device for casting molten metal, in particular light metal melts, such as aluminum-based melts.
- a casting mold which has a mold cavity which images the casting to be produced.
- the molten metal is then poured from a melt container into the mold cavity.
- the melt container can be, for example, a casting furnace or another container filled with melt, in which the melt is kept at a temperature level required for casting. After the melt in the casting mold has solidified to the casting to be produced, casting mold and casting are separated from each other.
- the properties of a casting are strongly influenced by the course of the solidification of the melt in the casting mold and the make-up required to compensate for the volume shrinkage.
- a particularly uniform distribution of properties shows when the mold filling with melt is carried out in a continuous process while avoiding large melt flows in the mold and evenly distributed the solidification and used on the side opposite the feeder side of the mold.
- methods are known in which the melt is conveyed against the effective direction of gravity in the mold.
- the melt container is located under the mold. The melt is then forced by pressurizing the atmosphere above the melt in the melt container atmosphere via a riser into the mold cavity of the mold.
- a negative pressure can be applied to the mold cavity of the casting mold for conveying the melt or the molten metal can be conveyed into the casting mold by means of electromagnetic forces.
- This filling of the casting mold with melt against the direction of gravity has the advantage that a smooth and controlled casting run is achieved with minimized turbulence of the melt.
- the risk of casting defects in the manufactured casting can be significantly reduced.
- a disadvantage of such methods, however, is that the molds must each remain for a long time in the casting plant, which is required for the complete solidification of each casting produced in them.
- a device for carrying out the rising casting is known, for example, from DE 100 33 904 A1.
- a slide closure is arranged between the mold and the melt container, which is formed of two superposed and mutually displaceable plates, the each having a passage opening.
- the passage openings are brought into coincidence so that melt can flow through the riser from the melt container into the casting mold.
- one of the slide plates is moved relative to the other, so that the passage openings are closed. Subsequently, the mold can be removed and another casting cycle can be started.
- the slide closure can be removed for use.
- a cooling device can be provided at the filling opening, which causes a targeted cooling of the melt present in the filling area.
- the rotation of the casting mold with the melt container achieves complete filling of the casting mold with molten metal.
- the melt passes during rotation in that in the course of the mold rotation, the molten metal filled in the casting mold is uniformly exposed to gravity, safely in all areas of the mold cavity of the mold, which images the casting to be cast.
- this casting technique also known as "rotational molding” optimizes the microstructure as a result of directional solidification, which is brought about by the orientation of the casting mold associated with the rotation. In this way, geometrically complex castings of high quality can be produced.
- the mold filling is not optimal if, in the case of cylindrical internal geometries, particularly homogeneous solidification morphologies are required.
- DE 196 49 014 Al furthermore discloses a method and a device for producing castings from aluminum alloys.
- it is provided to increase the productivity that the aluminum melt is pressed at a relatively low pressure via a riser from bottom to top in a mold made of a gasifiable foam.
- the casting mold is rotated together with the casting container about an approximately horizontal axis of rotation in the region of the inlet of the casting.
- Object of the present invention was to produce castings with high productivity, which also meet further increased quality requirements safely.
- shut-off device which is at least temporarily fixedly connected to the casting mold
- a device for casting molten metal which has a casting mold having a filling opening, with a device for coupling the casting mold to a melt container, which in this operating position is arranged below the casting mold and contains the molten metal, with a device for conveying the molten metal from the melt container into the casting mold through the filling opening in the direction of gravity, with a device for uncoupling the casting mold from the melt container, comprising means for rotating the casting mold in the state uncoupled from the melt container about a horizontal axis associated with the casting mold, with a control device which emits a signal for rotating the casting mold about its axis of rotation when the casting mold is filled with melt, and with a at least during the rotation about its horizontal axis connected to the mold shut-off device for closing the filling opening of the mold.
- the invention combines rising casting with rotational molding.
- the invention provides a closure connected to the mold, which remains firmly attached to the mold during rotation and keeps it closed. In this way, it is no longer necessary to wait until the beginning of the rotational movement that a sufficient amount of solidified melt material has formed in the filling opening of the casting mold, but the rotational movement can begin immediately after the filling of the casting mold has ended.
- significantly shorter cycle times are achieved than they are possible in the usual rising casting.
- the mold By the casting mold immediately after the filling with melt through at least during the turning process is firmly closed with the mold shut-off device is closed, the mold can be decoupled from the melt container immediately after closing with still liquid molten metal.
- the shut-off device can be separated from the mold according to an advantageous embodiment of the invention. In this position, in which the effect of gravity prevents leakage of melt from the mold, unlike in the filling position and during the turning process itself, there is no longer any risk of melt leakage.
- the separate from the mold shut-off can then be used again for closing subsequently to be filled molds.
- the melt container is ready for pouring the molten metal directly into the casting mold for the next casting and, if necessary, for refilling with molten metal , This also means that the productivity, the economy and the availability of a device according to the invention over the prior art is increased.
- the inventive arrangement of at least for the period of rotation connected to the mold shut-off device to perform the rotation of the mold without a docked to the mold melt container.
- casting of cast parts can not only take place within short cycle times, but also proceeds in a mode of operation which can be implemented simply in terms of apparatus.
- the inventive method and the device according to the invention are operationally safe to carry out.
- the shut-off device can be sufficiently firmly connected to the casting mold in order to securely hold the casting mold tightly closed during rotation despite the resulting loads and to reliably prevent leakage of the still molten metal melt from the mold. This was all the more surprising with the use of such shut-off devices which are released from the casting mold after being turned to be used again.
- high-quality castings are thus obtained by a complete mold filling with optimized solidification of the molten metal, wherein at the same time the productivity is significantly increased compared to the prior art.
- the melt container may be, for example, a casting furnace known per se for low-pressure casting.
- a device according to the invention may comprise a device for pressurizing the melt surface in the melt container.
- the device for pressurizing may in particular be one with the interior of the melt container via a valve Connected compressed gas supply act, can be passed through the gas under pressure in the interior, which acts on the surface of the melt contained in the interior of the melt container.
- the gas can be air. If the risk of oxidation in the melt container is to be reduced, however, it is also possible to use a gas which is inert with respect to the molten metal, for example nitrogen or a noble gas.
- a particularly robust embodiment of a device according to the invention results when the shut-off device is designed as a slide closure.
- a slide closure is usually characterized in that a first element of the closure can be displaced such that in a first position of the element a shut-off opening is opened and in a second position of the element, the opening is closed.
- a slide closure can be easily manufactured and takes only a small amount of space.
- the slide closure according to the model of the prior art in particular at least two plates each having a passage opening, wherein for closing the mold at least one of the plates from an open position in which the passages are in overlap, is moved to a closed position, in which the passage openings are completely offset from each other.
- Such a design of the slide closure is on the one hand robust and easy in the production technology application.
- this embodiment ensures particularly safe Way that during a rotation of the mold no molten metal escapes from the mold.
- the casting mold may be a permanent casting mold.
- molded parts such as molded sand parts.
- Such a mold also referred to as a core package, is destroyed after the casting process and the solidification of the molten metal to the casting, so that then the finished casting is obtained.
- the casting mold has both permanent casting moldings and molding cores if, for example, complex internal shapes of the casting are to be produced.
- Figures 1 to 5 each show schematically a device for casting of light metal melt in four different operating positions in a partially broken side view.
- the device V for casting an aluminum-based melt A comprises a casting mold 1, in whose wall 1a a filling opening 2 is formed.
- the filling opening 2 opens into a formed in the mold 1 feeder section 3, which feeds the mold cavity 4, through which the casting to be produced is imaged.
- cooling iron 5 are used.
- the cooling irons 5 effect a targeted solidification profile in order to form a specific microstructure in the regions of the cast part assigned to the cooling iron 5.
- shut-off device 6 designed as a slide closure is detachably fastened.
- the shut-off device 6 has a first of the wall Ia directly associated slide plate 7, in which a through hole 8 is formed at a central location, and a second slide plate 9, which lies on the first slide plate 7 and in which also a through hole 10 is formed. Diameter and shape of the passage openings 8, 10 are adapted to the diameter and the shape of the filling opening 2.
- the slide plates can be moved 7.9 against each other to bring their passage opening 8.10 in a passage position with each other and with the filling opening 2 and in a closed position in which the lying outside the passage opening 8 closed portion of the slide plate 7, the filling opening 2 closes and in which a closed, lying outside the passage opening 10 portion of the second slide plate 9 is disposed below the filling opening 2 and the filling opening 2 directly closing portion of the first slide plate 7 is supported.
- the mold 1 is rotatably mounted in a rotary bearing, not shown, about a horizontally oriented axis of rotation X. About the axis of rotation X, the mold 1 can be rotated by means also not shown become. In addition, the mold 1 can be lifted by means of a likewise not shown adjusting device in the vertical direction Y.
- the device 1 comprises a melting tank 12 ⁇ in which is stored to be cast molten aluminum A.
- the melt container 12 has a lid 13, with which the melt container 12 can be sealed tightly against the environment U. Through the lid 13, a vertically aligned riser 14 is guided, the inlet opening 15 is arranged just above the bottom 16 of the melt container 12. In the operating position, however, the outlet opening 17 of the riser 14 is positioned just above the lid 13.
- the melt container 12 is mounted on rollers 18 which are guided on rails 19.
- the orientation and rotation of the mold 1 and the working positions of the shut-off devices 6 are controlled by a control device 20.
- the interior space enclosed by the melt container 12 with the cover 13 attached can be subjected to a compressed gas, for example air or nitrogen.
- a supply line 21 is guided through the cover 13 into the interior 12a of the melt container 12.
- the supply line 21 is connected to a compressed gas supply 22, which provides a required for the expulsion of each required amount of melt gas volume with sufficient pressure.
- the shut-off device 6 is opened by the passage openings 8.10 of its slide plates 7.9 are brought to cover each other and with the filling opening 2.
- the mold sits with the outer slide plate 9 on the lid 13 of the positioned below the mold 1 and sealed by the lid melt container 12, wherein the outlet opening 17 of the riser pipe 14 is aligned with the filling opening 2 of the mold 1. In this way, the mold cavity 4 of the mold 1 is connected to the interior 12a of the melt container 12 (FIG. D).
- melt A rises through the riser 14 into the mold 1 and fills in a quiet flow the mold cavity 4 of the mold 1.
- the atmosphere contained in the mold cavity 4 escapes not over illustrated vents.
- the melt A contained in the mold cavity 4 of the mold 1 is introduced uniformly and largely avoiding turbulence in all voids formed in the mold cavity 4, so that even complex moldings, such as engine blocks for internal combustion engines or the like, are generated safely and with optimum work result can (Fig. 2).
- the control device 20 gives a signal to close the shut-off device 6.
- the slide plates 7, 9 of the shut-off devices 6 are displaced against each other while the pressure in the melt container 12 is maintained until their passage openings 8, 10 are closed by the closed section each other slide plate is closed 9.7.
- the mold 1 is lifted in the vertical direction Y and so separated from the melt container 12.
- the melt container 12 can now be moved on the rails 19 to a further, not shown here, filling station, where already another empty mold waiting for the filling (Fig. 3).
- control device 20 Immediately after the separation of the casting mold 1 from the melt container 12, the control device 20 gives a signal for rotating the casting mold 1 (FIG. 4).
- the turning device then rotates the casting mold 1 by 180 ° about the axis of rotation X, until its still closed by the shut-off device 6 filling opening 2 faces upwards. If this overhead position, which is directed counter to the direction of gravity, has been reached, the shut-off device 6 can be detached from the casting mold 1 and fed to use at a casting mold (not shown here) to be filled with molten metal A (FIG. 5).
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Dental Prosthetics (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL05778033T PL1786576T3 (pl) | 2004-09-06 | 2005-09-02 | Sposób i urządzenie do odlewania ciekłego metalu |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004043444A DE102004043444B3 (de) | 2004-09-06 | 2004-09-06 | Verfahren und Vorrichtung zum Gießen von Metallschmelze |
PCT/EP2005/009469 WO2006027174A1 (de) | 2004-09-06 | 2005-09-02 | Verfahren und vorrichtung zum giessen von metallschmelze |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1786576A1 true EP1786576A1 (de) | 2007-05-23 |
EP1786576B1 EP1786576B1 (de) | 2009-07-15 |
Family
ID=35219472
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05778033A Active EP1786576B1 (de) | 2004-09-06 | 2005-09-02 | Verfahren und vorrichtung zum giessen von metallschmelze |
Country Status (14)
Country | Link |
---|---|
US (1) | US7854251B2 (de) |
EP (1) | EP1786576B1 (de) |
JP (1) | JP4891245B2 (de) |
KR (1) | KR20070103355A (de) |
CN (1) | CN101039766A (de) |
AU (1) | AU2005281886B2 (de) |
BR (1) | BRPI0514945B1 (de) |
CA (1) | CA2578821A1 (de) |
DE (2) | DE102004043444B3 (de) |
ES (1) | ES2330027T3 (de) |
MX (1) | MX2007002351A (de) |
PL (1) | PL1786576T3 (de) |
WO (1) | WO2006027174A1 (de) |
ZA (1) | ZA200701400B (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008221312A (ja) * | 2007-03-15 | 2008-09-25 | Honda Motor Co Ltd | 遠心鋳造装置 |
JP5221195B2 (ja) * | 2008-04-17 | 2013-06-26 | 株式会社田島軽金属 | 鋳造装置,鋳造システム及び方法 |
EP2352608B1 (de) * | 2008-11-24 | 2013-09-11 | Nemak Dillingen GmbH | VERFAHREN ZUM GIEßEN EINES GUSSTEILS AUS EINER METALLSCHMELZE |
CN102632222A (zh) * | 2012-05-09 | 2012-08-15 | 周学义 | 一种铸造装置及铸造方法 |
DE102015208964A1 (de) | 2015-05-15 | 2016-11-17 | Harald Justus Weis | Verfahren zum Gießen von Metall, Adaptereinheit und Vorrichtung zum Gießen von Metall umfassend eine derartige Adaptereinheit |
WO2018192619A1 (de) * | 2017-04-20 | 2018-10-25 | Ksm Castings Group Gmbh | TRENNSCHIEBERSYSTEM, GIEßANLAGE UND GIEßVERFAHREN |
DE102019126108A1 (de) * | 2019-09-27 | 2021-04-01 | Grohe Ag | Vorrichtung zum Niederdruckgießen von Werkstücken mit einer schwenkbaren Kupplung |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2637813B2 (ja) * | 1989-01-18 | 1997-08-06 | 本田技研工業株式会社 | 金型鋳造法 |
DE4304622C2 (de) * | 1993-02-16 | 1996-09-19 | Bruehl Aluminiumtechnik | Verfahren zum Füllen einer Gießform |
DE19649014A1 (de) * | 1996-11-27 | 1998-05-28 | Ks Aluminium Technologie Ag | Verfahren und Vorrichtung zum Herstellen von Gußstücken |
FR2775917B1 (fr) * | 1998-03-10 | 2000-06-02 | Montupet Sa | Procede de moulage en grande serie de pieces d'alliage d'aluminium et equipements associes |
JP3680979B2 (ja) * | 1998-11-11 | 2005-08-10 | 新東工業株式会社 | 鋳造用砂鋳型による鋳造方法 |
DE10019309C2 (de) * | 2000-04-19 | 2002-04-18 | Vaw Mandl & Berger Gmbh Linz | Verfahren und Vorrichtung zum Rotationsgießen |
DE10033904A1 (de) * | 2000-07-12 | 2002-01-31 | Stopinc Ag Huenenberg | Schieberverschluss zum Vergiessen von Metallschmelze, sowie eine dazugehörige feuerfeste Platteneinheit |
DE10033903C1 (de) * | 2000-07-12 | 2001-11-29 | Vaw Ver Aluminium Werke Ag | Verfahren und Vorrichtung zum steigenden Giessen mit einer Giessform mit untenliegender Eingussöffnung mit einem Schieberverschluss |
AU2002952343A0 (en) * | 2002-10-30 | 2002-11-14 | Castalloy Manufacturing Pty Ltd | Apparatus and method for low pressure sand casting |
-
2004
- 2004-09-06 DE DE102004043444A patent/DE102004043444B3/de not_active Expired - Fee Related
-
2005
- 2005-09-02 ES ES05778033T patent/ES2330027T3/es active Active
- 2005-09-02 MX MX2007002351A patent/MX2007002351A/es active IP Right Grant
- 2005-09-02 CA CA002578821A patent/CA2578821A1/en not_active Abandoned
- 2005-09-02 DE DE502005007712T patent/DE502005007712D1/de active Active
- 2005-09-02 PL PL05778033T patent/PL1786576T3/pl unknown
- 2005-09-02 KR KR1020077007832A patent/KR20070103355A/ko not_active Application Discontinuation
- 2005-09-02 WO PCT/EP2005/009469 patent/WO2006027174A1/de active Application Filing
- 2005-09-02 EP EP05778033A patent/EP1786576B1/de active Active
- 2005-09-02 US US11/574,695 patent/US7854251B2/en not_active Expired - Fee Related
- 2005-09-02 CN CNA2005800298433A patent/CN101039766A/zh active Pending
- 2005-09-02 JP JP2007529335A patent/JP4891245B2/ja active Active
- 2005-09-02 AU AU2005281886A patent/AU2005281886B2/en not_active Ceased
- 2005-09-02 BR BRPI0514945-2A patent/BRPI0514945B1/pt not_active IP Right Cessation
-
2007
- 2007-02-16 ZA ZA2007/01400A patent/ZA200701400B/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2006027174A1 * |
Also Published As
Publication number | Publication date |
---|---|
BRPI0514945B1 (pt) | 2014-02-18 |
US20080190581A1 (en) | 2008-08-14 |
CA2578821A1 (en) | 2006-03-16 |
DE502005007712D1 (de) | 2009-08-27 |
ZA200701400B (en) | 2008-06-28 |
MX2007002351A (es) | 2007-08-23 |
JP4891245B2 (ja) | 2012-03-07 |
EP1786576B1 (de) | 2009-07-15 |
AU2005281886B2 (en) | 2009-10-29 |
PL1786576T3 (pl) | 2009-12-31 |
ES2330027T3 (es) | 2009-12-03 |
US7854251B2 (en) | 2010-12-21 |
KR20070103355A (ko) | 2007-10-23 |
WO2006027174A1 (de) | 2006-03-16 |
JP2008512246A (ja) | 2008-04-24 |
DE102004043444B3 (de) | 2006-06-14 |
CN101039766A (zh) | 2007-09-19 |
AU2005281886A1 (en) | 2006-03-16 |
BRPI0514945A2 (pt) | 2012-10-30 |
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