EP0633927B1 - Reinigungsmittel für harte oberflächen - Google Patents

Reinigungsmittel für harte oberflächen Download PDF

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Publication number
EP0633927B1
EP0633927B1 EP93906597A EP93906597A EP0633927B1 EP 0633927 B1 EP0633927 B1 EP 0633927B1 EP 93906597 A EP93906597 A EP 93906597A EP 93906597 A EP93906597 A EP 93906597A EP 0633927 B1 EP0633927 B1 EP 0633927B1
Authority
EP
European Patent Office
Prior art keywords
weight
cleaning
foam
fatty alcohol
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP93906597A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0633927A1 (de
Inventor
Eva Kiewert
Peter Jeschke
Birgit Middelhauve
Giuseppe Carrer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0633927A1 publication Critical patent/EP0633927A1/de
Application granted granted Critical
Publication of EP0633927B1 publication Critical patent/EP0633927B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the invention relates to low-foaming cleaning agents for hard surfaces. All non-textile surfaces occurring in the household and commercial sector, with the exception of dishes, are to be understood as such.
  • the term all-purpose cleaner hereinafter referred to as AZR
  • Low-foaming AZR are those that develop a small volume of foam when used manually, which significantly reduces within a few minutes.
  • AZR have been known for a long time. These are essentially aqueous surfactant solutions of various types with or without the addition of builders and with or without the addition of water-soluble solvents or solubilizers.
  • a disadvantage of manual application in practice has been its high foaming power. Although the consumer wants to perceive a certain amount of foam in the application solution at the beginning of his cleaning work to prove its effectiveness, the foam should then collapse as quickly as possible, so that once cleaned surfaces do not have to be wiped down.
  • alkyl polyglucosides (hereinafter referred to as APG) in washing and cleaning agents is becoming increasingly popular.
  • alkyl polyglucosides are known to be highly foaming surfactants. In particular, however, they are used for products with the desired high foaming power, for example for dishwashing agents to be used manually or recommended for shampooing.
  • EP-A-70 074, 70 075, 70 076 and 70 077 (Procter & Gamble) describe such high-foaming detergents and cleaning agents based on various APG-containing surfactant combinations. Consequently, these combinations are not recommended for the AZR area.
  • EP-A-0 202 638 relates to a liquid cleaning concentrate for strongly alkaline cleaning formulations, the C8-C12 alkyl polyglucoside, C8-C18 fatty alcohol ethoxy propoxylate, an adduct of unsaturated C12-C24 fatty acid and maleic anhydride and 2-ethylhexanoic acid or isononanoic acid contains.
  • EP-A-0 474 915 discloses liquid preparations for washing textiles which, inter alia, contain a mixture of C8-C11- and C12-C18 alkyl polyglucosides.
  • the object of the invention was to provide means for the manual cleaning of hard surfaces, with the exception of dishes, which at the same time have good cleaning properties, good biodegradability and markedly low foaming power.
  • the criterion should be that foam that initially forms visibly reduces within 5 minutes.
  • a preferred embodiment of the invention includes AZR of the above type with an additional content of conventional anionic surfactants such as fatty alcohol sulfates, fatty alcohol ether sulfates, olefin sulfonates, paraffin sulfonates or mixtures thereof, the amounts of which are less than 25%, preferably less than 20% of the total amount of surfactant according to a) + b) + c), so as not to impair the foaming behavior of the cleaning agent.
  • conventional anionic surfactants such as fatty alcohol sulfates, fatty alcohol ether sulfates, olefin sulfonates, paraffin sulfonates or mixtures thereof, the amounts of which are less than 25%, preferably less than 20% of the total amount of surfactant according to a) + b) + c), so as not to impair the foaming behavior of the cleaning agent.
  • Addition products of about 3 to 20, preferably about 4 to 10, moles of ethylene oxide (EO) with 1 mole of fatty alcohol having 6 to 16, preferably 8 to 10, carbon atoms in the alkyl chain are particularly preferred.
  • the fatty alcohols used as raw materials can be produced from natural oils and fats as well as synthetically.
  • the fatty acids to be used according to the invention are carboxylic acids with 8 to 22, preferably 10 to 18, carbon atoms in the alkyl chain. Depending on the pH of the agents according to the invention, they are either in free form or partially or completely neutralized, ie in salt form. Suitable cations of these salts are alkali metal cations or nitrogen-containing cations such as ammonium or alkanolammonium ions.
  • the optional auxiliary substances are substances that are common in AZR as builders, solvents, hydrotropes, cleaning enhancers, viscosity regulators, pH regulators, preservatives, colors and fragrances, opacifiers, etc.
  • the AZR according to the invention do not contain any foam-promoting surfactants such as amimoxides or fatty acid alkanolamides.
  • Cleaning agents containing 1 to 90 wt .-% C8 - C18 alkyl polyglucosides with 1.5 to 10 glucose units in the molecule, 1 to 90 wt .-% C8 -C22 fatty alcohol ethoxylates with 2 to 12 moles of ethylene oxide and HLB values from 6 to 15, 1 to 15 wt .-% C8 - C24 fatty acids and optionally contain further synthetic anionic surfactants are known from EP-A-75 995 (Procter &Gamble); however, they are only used for and on textile cleaning Foam behavior is not discussed in detail.
  • Liquid cleaning agents with 2 to 60 wt .-% C8 -C18 alkyl monoglucosides, 0.1 to 10 wt .-% nonionic surfactants with an HLB value of less than 5 and 0.1 to 10 wt .-% nonionic surfactants with a HLB values of not less than 5 and 0.001 to 8% by weight of one or more intentional organic or inorganic salts are known from EP-A-408 965 (Kao). You foam strongly. The prior art did not suggest the new and inventive use of the special agents.
  • test method described below according to "Seifen- ⁇ le-Fette-Wwachs", 112 , 371, (1986) was used to test the cleaning ability and provides very reproducible results.
  • the cleaning agent to be tested was then placed on an artificially soiled plastic surface.
  • a mixture of carbon black, machine oil, triglyceride, saturated fatty acids and low-boiling aliphatic hydrocarbon was used as artificial soiling for the dilute use of the cleaning agent.
  • the test area of 26 x 28 cm was evenly coated with 2 g of the artificial soiling with the aid of a surface coater.
  • a plastic sponge was impregnated with 10 ml of the detergent solution to be tested and moved mechanically on the test surface, which was also coated with 10 ml of the detergent solution to be tested.
  • the cleaning effect i.e. the degree of whiteness of the plastic surface cleaned in this way, was measured using a "Microcolor" color difference measuring device (Dr. B. Lange).
  • the clean white plastic surface served as the white standard.
  • % RV percentage cleaning capacity
  • the standard AZR used at the time of the invention had the composition: 2.0% alkane sulfonate 1.5% fatty alcohol ethoxylate 0.5% soap 4.0% butyl diglycol ad 100.0% water, colors and fragrances, preservatives
  • the test product is placed in a large glass beaker. Then the amount of tap water is allowed to flow in freely from a height of 30 cm, the recommended application solution with the amount of product presented of the product.
  • the foam height in the beaker is read off immediately after the addition of water and after 3 minutes.
  • the foam height after 3 minutes is set in relation to the initial foam and the foam breakdown is calculated as follows:
  • Foam decay % Foam height start-foam height 3 minutes
  • a typical low-foaming AZR has a foam breakdown of over 50%.
  • Example 3 0.5% fatty alcohol ether sulfate was added in order to deliberately not let the foam break down to 100%. The content of additional surfactant had no effect on the cleaning performance. The foam disintegration was 90%.
  • the relative cleaning power compared to the 1% application solution of the standard was 180%.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Lubricants (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Glass Compositions (AREA)
  • Physical Vapour Deposition (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP93906597A 1992-03-30 1993-03-24 Reinigungsmittel für harte oberflächen Expired - Lifetime EP0633927B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4210365A DE4210365C2 (de) 1992-03-30 1992-03-30 Verwendung von Reinigungsmitteln für harte Oberflächen
DE4210365 1992-03-30
PCT/EP1993/000707 WO1993020179A1 (de) 1992-03-30 1993-03-24 Reinigungsmittel für harte oberflächen

Publications (2)

Publication Number Publication Date
EP0633927A1 EP0633927A1 (de) 1995-01-18
EP0633927B1 true EP0633927B1 (de) 1996-05-01

Family

ID=6455410

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93906597A Expired - Lifetime EP0633927B1 (de) 1992-03-30 1993-03-24 Reinigungsmittel für harte oberflächen

Country Status (9)

Country Link
US (1) US5591376A (pt)
EP (1) EP0633927B1 (pt)
JP (1) JPH07505183A (pt)
AT (1) ATE137531T1 (pt)
BR (1) BR9306163A (pt)
DE (2) DE4210365C2 (pt)
DK (1) DK0633927T3 (pt)
ES (1) ES2086223T3 (pt)
WO (1) WO1993020179A1 (pt)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE9300955L (sv) * 1993-03-23 1994-09-24 Berol Nobel Ab Alkylglykosid och dess användning
DE4404199A1 (de) * 1994-02-10 1995-08-17 Henkel Kgaa Reinigungsmittel für harte Oberflächen
JPH093498A (ja) * 1995-06-20 1997-01-07 Th Goldschmidt Ag 貯蔵安定性の濃縮水性界面活性剤組成物
DE19644252A1 (de) * 1996-10-24 1998-04-30 Henkel Ecolab Gmbh & Co Ohg Reinigung harter Oberflächen mit rheopexen wäßrigen Reinigungsmitteln
US6224685B1 (en) * 1997-06-03 2001-05-01 Henkel Corporation Microemulsion composition for cleaning hard surfaces
US5952287A (en) * 1997-06-03 1999-09-14 Henkel Corporation Microemulsion composition for cleaning hard surfaces
US6384010B1 (en) 2000-06-15 2002-05-07 S.C. Johnson & Son, Inc. All purpose cleaner with low organic solvent content
US6300300B1 (en) * 2001-03-09 2001-10-09 Mwj, L.L.C. Liquid cleaning, degreasing, and disinfecting concentrate and methods of use
US8673865B2 (en) * 2005-03-03 2014-03-18 Kao Corporation Agent for enhancing antiseptic power
US9410111B2 (en) 2008-02-21 2016-08-09 S.C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US8993502B2 (en) 2008-02-21 2015-03-31 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion to a vertical hard surface and providing residual benefits
US9481854B2 (en) 2008-02-21 2016-11-01 S. C. Johnson & Son, Inc. Cleaning composition that provides residual benefits
US8980813B2 (en) 2008-02-21 2015-03-17 S. C. Johnson & Son, Inc. Cleaning composition having high self-adhesion on a vertical hard surface and providing residual benefits
DE102012221021A1 (de) * 2012-11-19 2014-05-22 Henkel Ag & Co. Kgaa Wasch- und Reinigungsmittel mit Alkylpolypentosiden
CN108137962A (zh) * 2015-02-21 2018-06-08 吉欧科技聚合物有限责任公司 从聚乙烯膜清除涂层
US10196591B2 (en) 2015-07-10 2019-02-05 S. C. Johnson & Sons, Inc. Gel cleaning composition
US10000728B2 (en) 2015-07-17 2018-06-19 S. C. Johnson & Son, Inc. Cleaning composition with propellant
US10358625B2 (en) 2015-07-17 2019-07-23 S. C. Johnson & Son, Inc. Non-corrosive cleaning composition
WO2017034793A1 (en) 2015-08-27 2017-03-02 S. C. Johnson & Son, Inc. Cleaning gel with glycine betaine amide
WO2017034792A1 (en) 2015-08-27 2017-03-02 S. C. Johnson & Son, Inc. Cleaning gel with glycine betaine ester
CN109477035A (zh) 2015-10-20 2019-03-15 吉欧科技聚合物有限责任公司 纤维表面覆盖物的回收
US11339353B2 (en) 2015-12-07 2022-05-24 S.C. Johnson & Son, Inc. Acidic hard surface cleaner with glycine betaine ester
WO2017099932A1 (en) 2015-12-07 2017-06-15 S.C. Johnson & Son, Inc. Acidic hard surface cleaner with glycine betaine amide

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1370377A (en) * 1971-11-15 1974-10-16 Procter & Gamble Ltd Composition and method for cleaning hard surfaces
US4079078A (en) * 1974-06-21 1978-03-14 The Procter & Gamble Company Liquid detergent compositions
US4065409A (en) * 1975-08-01 1977-12-27 Corporate Brands, Inc. Hard surface detergent composition
CA1083911A (en) * 1976-12-13 1980-08-19 Thaddeus J. Kaniecki Liquid cleaning compositions and process therefor
EP0070075B2 (en) * 1981-07-13 1992-11-04 THE PROCTER & GAMBLE COMPANY Foaming dishwashing liquid compositions
DE3275201D1 (en) * 1981-07-13 1987-02-26 Procter & Gamble Foaming surfactant compositions
DE3275200D1 (en) * 1981-07-13 1987-02-26 Procter & Gamble Foaming surfactant compositions
EP0070074B2 (en) * 1981-07-13 1997-06-25 THE PROCTER & GAMBLE COMPANY Foaming surfactant compositions
GR76286B (pt) * 1981-09-28 1984-08-04 Procter & Gamble
US4483780A (en) * 1982-04-26 1984-11-20 The Procter & Gamble Company Detergent compositions containing polyglycoside and polyethoxylate detergent surfactants
US4488981A (en) * 1983-09-06 1984-12-18 A. E. Staley Manufacturing Company Lower alkyl glycosides to reduce viscosity in aqueous liquid detergents
EP0199765B1 (en) * 1984-11-06 1990-05-23 Henkel Kommanditgesellschaft auf Aktien Monoglycosides as viscosity modifiers in detergents
US4627931A (en) * 1985-01-29 1986-12-09 A. E. Staley Manufacturing Company Method and compositions for hard surface cleaning
US4606850A (en) * 1985-02-28 1986-08-19 A. E. Staley Manufacturing Company Hard surface cleaning composition and cleaning method using same
DE3518672A1 (de) * 1985-05-24 1986-11-27 Basf Ag, 6700 Ludwigshafen Fluessiges reinigungskonzentrat fuer stark alkalische reinigungsformulierungen
USH468H (en) * 1985-11-22 1988-05-03 A. E. Staley Manufacturing Company Alkaline hard-surface cleaners containing alkyl glycosides
DE3708330A1 (de) * 1987-03-14 1988-09-22 Henkel Kgaa Fluessige, alkalische reinigerkonzentrate
WO1988009369A1 (en) * 1987-05-18 1988-12-01 Staley Continental, Inc. Low foaming detergent composition
DE3928602A1 (de) * 1989-08-30 1991-03-07 Henkel Kgaa Alkalistabile und stark alkalisch formulierbare antischaummittel fuer die gewerbliche reinigung, insbesondere fuer die flaschen- und cip-reinigung
GB8927956D0 (en) * 1989-12-11 1990-02-14 Unilever Plc Detergent composition
DE4009533A1 (de) * 1990-03-24 1991-09-26 Henkel Kgaa Schwachschaeumendes nichtionisches tensidgemisch
DE4029035A1 (de) * 1990-09-13 1992-03-19 Huels Chemische Werke Ag Waschmittel
US5290472A (en) * 1992-02-21 1994-03-01 The Procter & Gamble Company Hard surface detergent compositions
US5223179A (en) * 1992-03-26 1993-06-29 The Procter & Gamble Company Cleaning compositions with glycerol amides
DE4216380A1 (de) * 1992-05-18 1993-11-25 Henkel Kgaa Verfahren zur Reinigung von Badezimmerarmaturen
US5342534A (en) * 1992-12-31 1994-08-30 Eastman Kodak Company Hard surface cleaner

Also Published As

Publication number Publication date
WO1993020179A1 (de) 1993-10-14
DE4210365C2 (de) 1995-06-08
BR9306163A (pt) 1998-01-13
US5591376A (en) 1997-01-07
DK0633927T3 (da) 1996-09-09
ATE137531T1 (de) 1996-05-15
EP0633927A1 (de) 1995-01-18
DE59302457D1 (de) 1996-06-05
ES2086223T3 (es) 1996-06-16
JPH07505183A (ja) 1995-06-08
DE4210365A1 (de) 1993-10-07

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