EP0457778A1 - Adjuvants de teinture - Google Patents

Adjuvants de teinture

Info

Publication number
EP0457778A1
EP0457778A1 EP90902238A EP90902238A EP0457778A1 EP 0457778 A1 EP0457778 A1 EP 0457778A1 EP 90902238 A EP90902238 A EP 90902238A EP 90902238 A EP90902238 A EP 90902238A EP 0457778 A1 EP0457778 A1 EP 0457778A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
surfactants
alcohols
dyeing
polyalkylene glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP90902238A
Other languages
German (de)
English (en)
Inventor
Faize Selen
Klaus Becker
Christa Hartschen
Bernd Wahle
Gilbert Schenker
Bernd-Dieter Bähr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0457778A1 publication Critical patent/EP0457778A1/fr
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/627—Sulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03—Organic sulfoxy compound containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/904—Mixed anionic and nonionic emulsifiers for dyeing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/916—Natural fiber dyeing
    • Y10S8/918—Cellulose textile

Definitions

  • the invention relates to dyeing auxiliaries and a method for single-bath, single-stage dyeing of textile fiber materials.
  • Cotton contains natural impurities, for example waxes, wax-like substances, proteins, seed husks, fruit capsules and pectins, as well as impurities that are applied as foreign substances in the course of processing, for example paraffins and / or mineral oils.
  • preparation agents Chowala / Anger: "Handbuch der Textilosstoff", pages 526-528, 537, 558 ff ., Verlag Chemie Weinheim, 1977.
  • the textile material is usually subjected to a pretreatment.
  • the pretreatment has the disadvantage that it has to be carried out in several stages.
  • processes have been developed in recent years which make the separate pretreatment process superfluous (Chwala / Anger: "Handbuch der TextiIosstoff", pages 528-529, Verlag Chemie Weinheim, 1977).
  • Single-bath, one-step dyeing is one such method.
  • the textile is pretreated and dyed in one step.
  • the baths contain the chemicals necessary for the pretreatment, such as wetting agents, detergents, dispersants, leveling agents and / or alkalis, as well as dyes.
  • the single-bath / single-stage dyeing process described in DE 36 43 752 of mixtures of carrier-free dyeable polyester fibers and cellulose fibers is carried out in the presence of disperse and reactive dyes and optionally auxiliaries at pH values between 6 and 8.5 at temperatures between 90 and 105 ° C.
  • the object of the invention was therefore to develop dyeing auxiliaries which, when used in single-bath, single-stage dyeing processes, produce uniform and vivid colorations on the textile. Furthermore, the fastness to use of the dyed fiber materials, such as light fastness, fastness to rubbing and wet fastness, should not be adversely affected by the use of such aids. Surprisingly, it has now been found that the high requirements are imposed on the color properties of textile fiber materials and in particular cellulose-containing textile fiber materials, are filled with mixtures containing 1.
  • the invention accordingly relates to dyeing auxiliaries containing anionic and nonionic surfactants, characterized in that these agents
  • surfactants from groups a) C 8-24 ⁇ alkyl and / or C 8-24 alkenyl alcohol sulfates and / or C 14-18 alkanesulfonates and / or C 10-14 alkylbenzenesulfonates in the form of their Alkali, ammonium and / or amine salts and b) castor oil with 20-50 moles of ethylene oxide and / or alkoxylated C 8-24 alkyl and / or C 8-24 _ alkenyl alcohols and / or alkoxylated C 8-12 alkyl phenols
  • sulfated hydroxyalkyl-alkylpolyalkylene glycol ethers of the general formula I in which R is an alkyl radical with 1-6 C atoms, R 1 is an alkyl radical with 6 - 18 C atoms, M is an alkali metal or ammonium cation, n is 2 or 3 and x is a number between 2 and 10 and
  • the textile auxiliaries according to the invention preferably contain
  • alkyl and / or alkenyl alcohol sulfates are prepared in the form of their alkali metal, ammonium and / or amine salts per se known manner by sulfating the corresponding alkyl and / or alkenyl alcohols with chlorosulfonic acid or sulfur trioxide.
  • the resulting sulfuric acid half-esters of the alcohols are then neutralized with, for example, alkali metal hydroxide solution, such as sodium hydroxide solution, ammonia or alkanolamines, such as monoethanolamine or triethanolamine (Winnacker / ippochler in "Chemische Technologie", Volume 7, pages 120 - 123, Carl Hanser Verlag Kunststoff-Vienna 1986) .
  • alkyl and / or alkenyl alcohols can be straight-chain or branched-chain, of natural or synthetic origin and have 8-24 carbon atoms, preferably 12-18 carbon atoms.
  • alkyl and / or alkenyl alcohols are octyl, decyl, Laufyl, myristyl, cetyl, stearyl, oleyl, behenyl alcohol and mixtures of these alcohols.
  • Alkali, ammonium and / or amine salts of alkan sulfonates with 14-18 carbon atoms can be produced on an industrial scale by reacting straight-chain paraffins with, for example, SO 2 and oxygen in the presence of radical-forming substances such as ozone, organic peroxides or UV light (Winnacker / Küchler in "Chemische Technologie", 4th edition, volume 7, pages 114-116, Carl Hanser Verlag Kunststoff-Vienna 1986).
  • radical-forming substances such as ozone, organic peroxides or UV light
  • C 10-14 alkylbenzenesulfonates in the form of their alkali, ammonium and / or amine salts are known by reacting C 10-14 -alkylbenzenes with sulfonating agents such as SO 3 / air mixtures, SO 3 / nitrogen mixtures, sulfuric acid or oleum large-scale processes can be produced (Winnacker / Küchler in "Chemische Techno.ogie", 4th edition, volume 7, pages 111 - 114, Carl Hanser Verlag Kunststoff-Vienna 1986).
  • Castor oil with 20-50 moles of ethylene oxide, alkoxylated C 8-24 alkyl and / or C 8-24 alkenyl alcohols and alkoxylated C 8-12 alkyl phenols are obtained by alkoxylation of castor oil or straight and / or branched chain alkyl and / or Alkenyl alcohols of natural and / or synthetic origin or alkylphenols with ethylene oxide and / or propylene oxide prepared by known industrial processes (see, for example, in "Chemical Technology", Volume 7, pages 131-132, Carl Hanser Verlag, Kunststoff - Vienna (1986)).
  • the average degree of oxalkylation of the oxalkylates obtained is preferably between 30 and 50 in the case of castor oil, preferably between 3 and 10, particularly preferably between 4 and 8 in the case of the alkyl and / or alkenyl alcohols, and in the case of the alkylphenols preferably between 1 and 20.
  • the alcohols and alcohol mixtures already mentioned are suitable as alkyl and / or alkenyl alcohols with 8-24 C atoms, preferably with 12-18 C atoms.
  • Sulphated hydroxyalkyl-alkyl polyalkylene glycol ethers can be prepared by the process described in EP 299 370 by sulfating hydroxyalkyl alkyl polyalkylene glycol ethers of the general formula II
  • ethers of the general formula II are according to EP 299 370 by reacting epoxides of the general formula III
  • alkoxylated linear or branched chain alkyl alcohols of the general formula IV at temperatures between 100 and 180 ° C, preferably between 150 and 160 ° C, in the presence of catalysts, for example sodium methylate.
  • catalysts for example sodium methylate.
  • the fourth component of the mixtures according to the invention can be straight-chain or branched-chain, of natural or synthetic origin.
  • Alkyl alcohols having 6-10 carbon atoms for example 2-ethylhexanol, n-octanol and / or n-decanol, are preferably used.
  • Another object of the invention is a method for single-bath, one-step dyeing of textile fiber materials in the presence of anionic and / or nonionic surfactants, which thereby is characterized in that textile fiber materials at temperatures between 20 and 95 ° C with aqueous dyeing liquors per liter of liquor
  • surfactants from groups a) C 8-24 alkyl and / or C 8-24 alkenyl alcohol sulfates and / or C 14-18 alkane sulfonates and / or C 10-14 alkyl benzene sulfonates in the form of their alkali, ammonium and / or amine salts and b) castor oil with 20-50 moles of ethylene oxide and / or alkoxylated C 8-24 alkyl and / or C 8-24 alkenyl alcohols and / or alkoxylated C 8-12 - Alkylphenols
  • R is an alkyl radical with 1-6 C atoms
  • R 1 is an alkyl radical with 6 - 18 C atoms
  • M is an alkali metal or ammonium cation
  • n is 2 or 3 and x is a number between 2 and 10 and
  • the aqueous dye liquors contain 0.5 to 5.0% by weight of dyes, based on the weight of the textile material.
  • reactive, substantive, vat, disperse, diazo, sulfur, acid and / or metal complex dyes and / or pigments are used as dyes.
  • the aqueous dyeing liquors contain aliphatic C 8-24 carboxylic acids, such as hydrogenated tallow fatty acid and / or coconut fatty acid, C 8-24 alkyl amines, such as tallow amine, defoamers, for example based on mineral oil or silicone, in a total amount of 0.01 to 1.0 g per liter of dye liquor.
  • Textile fiber materials for example cotton, viscose, wool, cotton / polyester blends or cotton / polyamide blends, which are available, for example, as knitted fabrics, woven fabrics, knitted fabrics or yarns, are dyed in the pull-out process, in which the textile at temperatures between 20 and 45 oC is brought into contact with the aqueous dye liquors.
  • the liquor ratio is between 1: 5 and 1:30, preferably between 1:10 and 1:20.
  • the dyeing liquors are then electrolytes, for example Glauber's salt, at the same or higher temperatures and / or table salt in amounts of 30 to 80 g per liter of liquor and sodium carbonate or NaOH in amounts of 2 to 20 g per liter of liquor, preferably in several portions.
  • aftertreatment in a manner known per se at temperatures between 25 and 98 ° C. by adding 0.5 to 1.5 g per liter of aftertreatment agent, such as Locanit R B, manufacturer Henkel KGaA, detergent, to the aqueous liquors and / or cationic post-fixing agents are added. After rinsing with water, drying is carried out at temperatures between 50 and 150 oC.
  • aftertreatment agent such as Locanit R B, manufacturer Henkel KGaA, detergent
  • the mixtures according to the invention which are used in aqueous dyeing liquors, have good compatibility with electrolytes and cause excellent depths of color and smoothness on cellulose-containing textile fiber materials, combined with good fastness to use, such as light fastness or wet fastness.
  • raw cotton knitwear (average fat content: 0.45% by weight) was treated at 45 ° C. with an aqueous dyeing liquor containing 1% by weight of CI Reactive Blue 71 (Procionekis HA, manufacturer : ICI), based on the weight of the raw cotton knitted fabric, and 1 g of the mixture according to the invention per liter of liquor.
  • the liquor ratio was 1:17, based on the weight of the goods.
  • the temperature was then raised and 25 g / l sodium chloride at 50 ° C, 25 g / l sodium chloride at 60 ° C and 25 g / l sodium chloride at 70 ° C. 10 g / l soda was added twice at 85 ° C.
  • FoamasterR 340 mineral oil defoamer, Henkel KGaA
  • Cotton knitwear (average fat content: 0.45% by weight), partially soiled with Paraffinum durum (softening point 62 ° C.; partial paraffin application: 1.2 g distributed over 10 spots with one area) was knitted on the jet dyeing apparatus as in Example 1 10 cm 2 each) treated at 40 ° C. with an aqueous dye liquor containing 2% by weight CI Reactive Blue 114 (Levafixbrillantblau E-BRA, manufacturer: Bayer AG), based on the weight of the goods, and 1 g / 1 mixture according to the invention contained.
  • the liquor ratio was 1:15. 50 g / l Glauber's salt in two portions and 15 g / l calcined soda in two portions were then added to the aqueous dye liquor.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Adjuvants de teinture renfermant un tensio-actif, des alkylpolyalkylèneglycoléthers d'hydroxyalkyle et un alcool d'alkyle. Procédé pour la teinture en un seul bain et en une seule étape de matières fibreuses textiles.
EP90902238A 1989-02-10 1990-02-01 Adjuvants de teinture Pending EP0457778A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3903926A DE3903926A1 (de) 1989-02-10 1989-02-10 Faerbereihilfsmittel
DE3903926 1989-02-10

Publications (1)

Publication Number Publication Date
EP0457778A1 true EP0457778A1 (fr) 1991-11-27

Family

ID=6373765

Family Applications (2)

Application Number Title Priority Date Filing Date
EP90902238A Pending EP0457778A1 (fr) 1989-02-10 1990-02-01 Adjuvants de teinture
EP90102000A Withdrawn EP0382093A1 (fr) 1989-02-10 1990-02-01 Adjuvants de teinture

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP90102000A Withdrawn EP0382093A1 (fr) 1989-02-10 1990-02-01 Adjuvants de teinture

Country Status (10)

Country Link
US (1) US5152802A (fr)
EP (2) EP0457778A1 (fr)
JP (1) JPH04503229A (fr)
KR (1) KR910700378A (fr)
CN (1) CN1044835A (fr)
CA (1) CA2009414A1 (fr)
DE (1) DE3903926A1 (fr)
TR (1) TR24432A (fr)
WO (1) WO1990009479A1 (fr)
ZA (1) ZA90994B (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5512211A (en) * 1994-12-30 1996-04-30 Cytec Technology Corp. Concentrated aqueous dialkylsulfosuccinate wetting agent formulation having low volatile organic compound content
WO1996028603A1 (fr) * 1995-03-15 1996-09-19 Ciba Specialty Chemicals Holding Inc. Amelioration de la solidite a la lumiere de teintures sur fibres polyamides
EP0879277B1 (fr) * 1996-01-19 2001-10-17 Unilever Plc Systemes non cationiques destines a des feuilles pour seche-linge
EP0881324A3 (fr) * 1997-05-26 1999-12-01 Bayer Ag Procédé pour teindre et enlever simultanément les agents d'avivage des fibres synthétiques
DE19826632C1 (de) * 1998-06-17 2000-02-03 Henkel Kgaa Verfahren und Stoffgemisch zum Behandeln von Wäsche einer im wesentlichen einheitlichen nichtweißen Farbe
WO2002092905A1 (fr) * 2001-05-16 2002-11-21 James Jung Composition acceleratrice de teinture et procede d'utilisation de celle-ci
US6702861B2 (en) * 2002-04-18 2004-03-09 Valley Forge Process for antiquing fabric
DE10309221A1 (de) * 2003-02-28 2004-09-09 Basf Ag Egalisierhilfsmittel für das Färben von Fasern

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH529257A (de) * 1970-09-05 1972-10-15 Sandoz Ag Hilfsmittel zum Färben oder Bedrucken
US4123378A (en) * 1975-09-16 1978-10-31 Ciba-Geigy Ag Stain removing agents and process for cleaning and optionally dyeing textile material
GB2022609B (en) * 1978-06-07 1982-08-11 Kemp F W Cleaning compositions
DE3115644A1 (de) * 1981-04-18 1982-11-04 Henkel KGaA, 4000 Düsseldorf "pulverfoermiger entschaeumer fuer waessrige systeme, verfahren zu seiner herstellung und seine verwendung"
US4438009A (en) * 1981-08-14 1984-03-20 S. C. Johnson & Son, Inc. Low solvent laundry pre-spotting composition
DE3660964D1 (en) * 1985-03-07 1988-11-24 Ciba Geigy Ag Auxiliary mixture and its use as a dyeing auxiliary or textile auxiliary
DE3643752A1 (de) * 1986-12-20 1988-06-23 Hoechst Ag Verfahren zum einbandig/einstufigen faerben von mischungen aus carrierfrei faerbbaren polyesterfasern und cellulosefasern
DE3713962A1 (de) * 1987-04-25 1988-11-10 Henkel Kgaa Waeschevorbehandlungsmittel fuer oel- und fettanschmutzungen
DE3723354A1 (de) * 1987-07-15 1989-01-26 Henkel Kgaa Sulfatierte hydroxy-mischether, verfahren zu ihrer herstellung und ihre verwendung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9009479A1 *

Also Published As

Publication number Publication date
DE3903926A1 (de) 1990-08-16
WO1990009479A1 (fr) 1990-08-23
US5152802A (en) 1992-10-06
JPH04503229A (ja) 1992-06-11
TR24432A (tr) 1991-11-01
KR910700378A (ko) 1991-03-15
CN1044835A (zh) 1990-08-22
EP0382093A1 (fr) 1990-08-16
CA2009414A1 (fr) 1990-08-10
ZA90994B (en) 1990-10-31

Similar Documents

Publication Publication Date Title
DE667744C (de) Verfahren zur Herstellung von in Wasser loeslichen oder leicht verteilbaren Kondensationsprodukten
DE3208309A1 (de) "zusammensetzungen aus polymeren auf acrylsaeurebasis, loesungsmitteln, tensiden und gegebenenfalls silikonoelen, deren herstellung und verwendung als entschaeumungs- und entlueftungsmittel"
EP0436470A1 (fr) Procédé pour la stabilisation photochimique de matériaux teints fibreux de polyamides
CH628369A5 (de) Fluessiges grobwasch- und reinigungsmittel.
DE2153366C3 (de) Polyglykolätherverbindungen, Verfahren zu deren Herstellung und deren Verwendung
DE19629453A1 (de) Verfahren zur reduktiven Nachreinigung von polyesterhaltigen Textilien
EP0457778A1 (fr) Adjuvants de teinture
DE3000382A1 (de) Verfahren zum faerben von nicht- vorgereinigtem textilem cellulosematerial
CH689175GA3 (de) Erhoehung der Nassgleitfaehigkeit von Textilmaterial und Nassgleitmittel dafuer.
EP0274350B1 (fr) Adjuvant textile aqueux, stable au stockage et à l'eau dure
EP0453447B1 (fr) Utilisation des esters polyoxyalkyliques d'acides monocarboxyliques sulfones en tant que produits d'entretien textile peu moussants
EP0100300A2 (fr) Procédé pour le post-traitement de matières fibreuses teintes contenant de la cellulose
EP0470106A1 (fr) Agent mouillant pour agents alcalins de traitement de textiles
CA2238259A1 (fr) Decapage du fini et teinture simultanes de fibres synthetiques
EP0965680A1 (fr) Dispersions aqueuses, leurs préparations et leurs utilisations
DE702229C (de) Verfahren zum Reinigen von Textilgut
DE3442888C2 (de) Sulfatierte, gegebenenfalls sulfonierte, oxalkylierte Alkylphenol-Formaldehyd-Kondensationsprodukte, Verfahren zu deren Herstellung und deren Verwendung als Färbereihilfsmittel
DE732744C (de) Verfahren zur Herstellung von Sulfonierungserzeugnissen aus Phosphatiden
DE4204885A1 (de) Thiodiglykol-derivate, verfahren zu ihrer herstellung und deren verwendung zum weichmachen von textilien
DE2221667A1 (de) Netzmittel und Wiederbenetzungsmittel
DE3737071A1 (de) Verwendung von aminethern als netzmittel fuer textilien
DE3230101A1 (de) Alkali-dry-verfahren fuer natuerliche cellulosefasern und deren mischungen mit synthesefasern
AT151302B (de) Verfahren zur Herstellung von als Netz-, Reinigungs-, Emulgier-, Appretur- u. dgl. -mittel geeigniten Produkten.
DE664818C (de) Netz-, Reinigungs-, Dispergier- und Faerbereihilfsmittel
DE617644C (de) Verfahren zur Verminderung der Aufnahmefaehigkeit der Fasern tierischen Ursprungs fuer Farbstoffe

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 19910802

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE FR GB IT LI NL

XX Miscellaneous (additional remarks)

Free format text: VERFAHREN ABGESCHLOSSEN INFOLGE VERBINDUNG MIT 90102000.8/0382093 (EUROPAEISCHE ANMELDENUMMER/VEROEFFENTLICHUNGSNUMMER) VOM 07.02.92.