EP0406479B2 - Kältemaschinenschmiermittel - Google Patents
Kältemaschinenschmiermittel Download PDFInfo
- Publication number
- EP0406479B2 EP0406479B2 EP89119265A EP89119265A EP0406479B2 EP 0406479 B2 EP0406479 B2 EP 0406479B2 EP 89119265 A EP89119265 A EP 89119265A EP 89119265 A EP89119265 A EP 89119265A EP 0406479 B2 EP0406479 B2 EP 0406479B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- saturated fatty
- monovalent saturated
- lubricant
- branched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/32—Esters
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- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
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- C10M105/32—Esters
- C10M105/38—Esters of polyhydroxy compounds
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/42—Flashing oils or marking oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/44—Super vacuum or supercritical use
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/50—Medical uses
Definitions
- This invention relates to lubricants for compressors, and more particularly to lubricants suitable for use in the compression of refrigerants containing no chlorine such as, HFC-134a (1,1,1,2-tetrafluoroethane) and to the use of a lubricant for compressors using a hydrofluorocarbon refrigerant containing no chlorine.
- Japanese Patent laid open No. 61-281199 describes a mixture of polyglycol represented by a general formula of R 1 [O-(R 2 O) m -R 3 ] n , an alkylbenzene
- Japanese Patent laid open No. 57-63395 describes an oil obtained by mixing a polyether such as high molecular weight polyoxypropylene monobutyl ether with an epoxycycloalkyl compound
- Japanese Patent laid open No. 59-117590 describes a high viscosity mixed oil of a polyether compound and a paraffinic or naphthanic mineral oil.
- the conventional synthetic lubricants as mentioned above cannot be a refrigeration lubricant using HFC-134a as a refrigerant from a viewpoint of compatibility and the like.
- polyoxyalkylene glycol (hereinafter abbreviated as PAG) having hydroxyl groups (-OH) at both terminals is reported as a refrigeration lubricant using HFC-134a.
- PAG polyoxyalkylene glycol
- -OH hydroxyl groups
- HFC-134a is a replacing refrigerant of R-12 and is mainly expected for use in a car air conditioner or a refrigerator, for example.
- the refrigerator it is required to have a good compatibility between lubricant and refrigerant, and further the lubricant itself is necessary to have an electric insulating property because the motor is substantially existent in the refrigeration system.
- the conventional compounds examined as a lubricant for HFC-134a refrigerant inclusive of PAG disclosed in US Patent No. 4,755,316 are remarkably poor in the electric insulating property as compared with the conventional refrigeration mineral oil and high in the hygroscopicity.
- an object of the invention to provide a refrigeration lubricant having an excellent compatibility with a new refrigerant containing no chlorine such as HFC-134a within a wide temperature range, a high electric insulating property and a low hygroscopicity.
- esters At the present, a part of commercially available esters is used in systems using refrigerants R-12 and R-22 for instance, but is incompatible with HFC-134a as a new refrigerant or is very narrow in the compatible range therewith.
- the inventors have aimed at the fact that the ester has a high electric insulating property, a low hygroscopicity, a good lubricity and a high stability as compared with PAG and made various studies with respect to the molecule design of the ester showing a wide range of compatibility with HFC-134a, and found that only esters having a considerably restricted structure can be used in the HFC-134a refrigeration system, and as a result, the invention has been accomplished.
- the present invention is directed to the use of a lubricant for compressors using a hydrofluorocarbon refrigerant containing no chlorine, comprising as a main component an ester(s) obtained by reacting (a) neopentyl glycol with (b) a mixture of at least one of straight chain monovalent saturated fatty acids having a carbon number of 5-10 and at least one of branched-chain monovalent saturated fatty acids selected from isoheptanoic acid, 2-ethylhexanoic acid, and 3,5,6-trimethylhexanoic acid, wherein the amount of the branched-chain monovalent saturated fatty acid is not less than 50 mol% per total monovalent saturated fatty acid used.
- the invention refers to the use of a lubricant for compressors using a hydrofluorocarbon refrigerant containing no chlorine, comprising as a main component an ester(s) obtained by reacting (a) neopentyl glycol with (b) a mixture of at least one of straight chain monovalent saturated fatty acids having a carbon number of 5-10 and at least one of branched-chain monovalent saturated fatty acids selected from isoheptanoic acid, 2-ethylhexanoic acid, and 3,5,6-trimethylhexanoic acid, wherein the amount of the branched-chain monovalent saturated fatty acid is not less than 50 mol% per total monovalent saturated fatty acid used, and (c) at least one polybasic acid having a carbon number of 4-10, wherein the amount of the polybasic acid is not more than 80 mol% per total monovalent saturated fatty acid used.
- the hydrofluorocarbon refrigerant is 1,1,1,2-tetrafluoroethane (HFC-134a).
- the present invention refers to a lubricant for compressors using 1,1,1,2-tetrafluoroethane refrigerant, comprising as a main component an ester(s) obtained by reacting (a) neopentyl glycol with (b) a mixture of at least one of straight chain monovalent saturated fatty acids having a carbon number of 5-10 and at least one of branched-chain monovalent saturated fatty acids selected from isoheptanoic acid, 2-ethylhexanoic acid, and 3,5,6-trimethylhexanoic acid, wherein the amount of the branched-chain monovalent saturated fatty acid is not less than 50 mol% per total monovalent saturated fatty acid used, and (c) at least one polybasic acid having a carbon number of 4-10, wherein the amount of the polybasic acid is not more than 80 mol% per total monovalent saturated fatty acid used.
- the monovalent fatty acid mention may be made of, pentanoic acid, hexanoic acid, heptanoic acid, isoheptanoic acid, octanoic acid, 2-ethyl hexanoic acid, nonanoic acid, 3,5,5-trimethyl hexanoic acid and decanoic acid.
- a mixture of at least one of straight-chain monovalent fatty acids having a carbon number of 5-10 and at least one of branched-chain monovalent fatty acids selected from isoheptanoic acid, 2-ethylhexanoic acid, and 3,5,6-trimethylhexanoic acid is properly mixed and esterified with neopentyl glycol in order to obtain an ester satisfying desirable physical properties required for various refrigerators.
- the amount of the branched-chain fatty acid used is not less than 50 mol% per the total monovalent fatty acid used.
- At least one polybasic acid having a carbon number of 4-10 may be esterified with neopentyl glycol in an amount of not more than 80 mol% per total fatty acid.
- the polybasic acids considering the more compatibility with the refrigerant HFC-134a and the like and the physical properties of the resulting ester, a polybasic acid having a carbon number of 4-10 is used.
- the polybasic acid includes succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, phthalic acid, maleic acid, trimellitic acid and so on.
- the polybasic acid having a carbon number of not more than 3 is a special product and is difficult to be cheaply available and is poor in the stability of the ester after the synthesis. While, when the carbon number exceeds 36, the compatibility of the resulting ester with HFC-134a and the like is largely lowered.
- the reason why the amount of the polybasic acid added is limited to not more than 80 mol% per the total fatty acid is due to the fact that when it exceeds 80 mol%, the gelation may be caused and it is difficult to obtain desirable physical properties.
- the ester compounds according to the first invention can be obtained by the esterification reaction through dehydration reaction between the specified polyvalent alcohol and the specified fatty acid as mentioned above, or the general esterification reaction through an acid anhydride, an acid chloride or the like as a derivative of the fatty acid.
- the ester according to the invention can be obtained by the above method, the remaining acid value and hydroxyl value are not particularly critical.
- the acid value exceeds 3 mg KOH/g, there may be caused an unfavorable phenomenon that the metal soap is formed and precipitated by the reaction with a metal used inside the refrigerator, so that the acid value is preferable to be not more than 3 mg KOH/g.
- the hydroxyl value exceeds 50 mg KOH/g, there may be caused an unfavorable phenomenon that the resulting ester becomes cloudy, so that the hydroxyl value is preferable to be not more than 50 mg KOH/g.
- the esters according to the invention exhibit a good compatibility with the refrigerant HFC-134a and the like over a wide range of from low temperature to high temperature as a lubricant for use in a refrigerator using HFC-134a as a refrigerant, whereby the lubricity and thermal stability of the refrigeration lubricant can be considerably improved. Furthermore, they are high in the electric insulating property and small in the hygroscopicity as compared with PAG conventionally examined as a refrigeration lubricant for HFC-134a.
- the refrigeration lubricants comprising the ester according to the invention as a main component can solve the problems on the compatibility with HFC-134a and the hygroscopicity, which have never been solved in the conventional technique, and can further enhance the electric insulating property, which comes into problem when HFC-134a is used in a compressor for a refrigerator.
- additives usually used in the lubricant such as antioxidant, anti-wear agent, epoxy compound and the like may properly be added to the refrigeration lubricant according to the invention.
- Seizuring load (Falex load-carrying capacity) was measured according to ASTM D-3233-73 under a controlled atmosphere of HFC-134a blown.
- test lubricant Into a beaker of 100 ml was charged 60 g of the test lubricant, which was left to stand at a temperature of 25 ° C and a humidity of 70% for 3 hours and then the water concentration was measured.
- the electric insulating property represented by the dielectric constant is 100,000 times or more and the two-phase separation at a high temperature is not caused. Furthermore, the seizuring load is excellent and the hygroscopicity is low.
- the thermal stability is equal in case of the HFC-134a system, but is considerably excellent in case of the R-12 system. This is very advantageous in practical use because the mixing of HFC-134a and R-12 is not avoided at a stage of replacing the refrigerant from R-12 to HFC-134a.
- esters according to the invention are compared with the commercially available esters (C-1 - C-2), the two-phase separation temperature is extremely different and the conventional esters are insoluble in HFC-134a. In this point, the molecule designed esters according to the invention have a great merit.
- the esters according to the invention are fairly excellent in the performances as a lubricant as compared with Comparative Examples.
- the HFC-134a has been mentioned as a possible replacement for R-12 and is used for car air conditioner, refrigerator and the like. Particularly, in case of the car air conditioner, the compressor is driven in summer season, so that the compatibility between oil and refrigerant at high temperature becomes important. When the two-phase separation between oil and refrigerant is caused in the compressor during the driving, the refrigerant having a larger specific gravity remains in the lower portion of the compressor, resulting in the occurrence of compressor seizuring.
- the motor is included in the compressor, so that leakage of electricity comes into problem.
- the esters according to the invention have a dielectric constant higher by 100,000 times or more than that of the conventional PAG and are excellent in the electric insulating property, so that they can be said to be a refrigeration lubricant for the refrigerator.
- HFC-134a causing substantially no breakage of ozone layer is closed up instead of R-12 widely used as a refrigerant in order to cope with the breakage of ozone layer through chlorofluorocarbon and hydrochlorofluorocarbon being a greatest problem in world-wide scale, but is poor in the compatibility with the conventional refrigeration lubricant, which is a bar for the development of replacement system.
- the refrigeration lubricants according to the invention have a sufficient compatibility with HFC-134a as a refrigerant and a high electric insulating property and also are excellent in the total performances, so that they have an effect that the conventional systems can be used as they are even when HFC-134a is used instead of the conventional R-12 and R-22 as a refrigerant.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Claims (9)
- Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden, umfassend als Hauptbestandteil einen Ester oder Ester erhalten durch Reagieren von (a) Neopentylglykol mit (b) einer Mischung von mindestens einer geradkettigen, einwertigen, gesättigten Fettsäure mit einer Kohlenstoffanzahl von 5 bis 10 und mindestens einer verzweigtkettigen, einwertigen, gesättigten Fettsäure, ausgewählt aus Isoheptansäure, 2-Ethylhexansäure und 3,5,5-Trimethylhexansäure, wobei der Anteil der verzweigtkettigen, einwertigen, gesättigten Fettsäure nicht weniger als 50 Mol-% der Gesamtmenge an verwendeter einwertiger, gesättigter Fettsäure beträgt.
- Verwendung eines Schmierstoffs gemäß Anspruch 1, worin der genannte Ester einen Gesamtsäurewert von nicht mehr als 3 mg KOH/g und einen Hydroxylwert von nicht mehr als 50 mg KOH/g hat.
- Verwendung eines Schmierstoffs gemäß Anspruch 1 oder 2, worin das Fluorkohlenwasserstoff-Kältemittel 1,1,1,2-Tetrafluorethan ist.
- Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden, umfassend als Hauptbestandteil einen Ester oder Ester erhalten durch Reagieren von (a) Neopentylglykol mit (b) einer Mischung von mindestens einer geradkettigen, einwertigen, gesättigten Fettsäure mit einer Kohlenstoffanzahl von 5 bis 10 und mindestens einer verzweigtkettigen, einwertigen, gesättigten Fettsäure, ausgewählt aus Isoheptansäure, 2-Ethylhexansäure und 3,5,5-Trimethylhexansäure, wobei der Anteil der verzweigtkettigen, einwertigen, gesättigten Fettsäure nicht weniger als 50 Mol-% der Gesamtmenge an verwendeter einwertiger, gesättigter Fettsäure beträgt, und (c) mindestens einer mehrbasigen Säure mit einer Kohlenstoffanzahl von 4 bis 10, wobei der Anteil der mehrbasigen Säure nicht mehr als 80 Mol-% der Gesamtmenge an verwendeter einwertiger, gesättigter Fettsäure beträgt.
- Verwendung eines Schmierstoffs gemäß Anspruch 4, wobei die mehrbasige Säure aus der Gruppe bestehend aus Bernsteinsäure, Glutarsäure, Adipinsäure, Pimelinsäure, Korksäure, Azelainsäure und Sebacinsäure ausgewählt ist.
- Verwendung eines Schmierstoffs gemäß einem der Ansprüche 4 oder 5, wobei der genannte Ester einen Gesamtsäurewert von nicht mehr als 3 mg KOH/g und einen Hydroxylwert von nicht mehr als 50 mg KOH/g hat.
- Verwendung eines Schmierstoffs gemäß einem der Ansprüche 4 bis 6, wobei das genannte Fluorkohlenwasserstoff-Kältemittel 1,1,1,2-Tetrafluorethan ist.
- Verfahren zum Herstellen eines Schmierstoffs für Kompressoren, die 1,1,1,2-Tetrafluorethan-Kältemittel verwenden, durch Herstellen eines Schmierstoffs umfassend als Hauptbestandteil einen Ester oder Ester erhalten durch Reagieren von (a) Neopentylglykol mit (b) einer Mischung von mindestens einer geradkettigen, einwertigen, gesättigten Fettsäure mit einer Kohlenstoffanzahl von 5 bis 10 und mindestens einer verzweigtkettigen, einwertigen, gesättigten Fettsäure, ausgewählt aus Isoheptansäure, 2-Ethylhexansäure und 3,5,5-Trimethylhexansäure, wobei der Anteil der verzweigtkettigen, einwertigen, gesättigten Fettsäure nicht weniger als 50 Mol-% der Gesamtmenge an verwendeter einwertiger, gesättigter Fettsäure beträgt, und (c) mindestens einer mehrbasigen Säure mit einer Kohlenstoffanzahl von 4 bis 10, wobei der Anteil der mehrbasigen Säure nicht mehr als 80 Mol-% der Gesamtmenge an verwendeter einwertiger, gesättigter Fettsäure beträgt.
- Schmierstoff für Kompressoren, die 1,1,1,2-Tetrafluorethan-Kältemittel verwenden, umfassend als Hauptbestandteil einen Ester oder Ester erhalten durch Reagieren von (a) Neopentylglykol mit (b) einer Mischung von mindestens einer geradkettigen, einwertigen, gesättigten Fettsäure mit einer Kohlenstoffanzahl von 5 bis 10 und mindestens einer verzweigtkettigen, einwertigen, gesättigten Fettsäure, ausgewählt aus Isoheptansäure, 2-Ethylhexansäure und 3,5,5-Trimethylhexansäure, wobei der Anteil der verzweigtkettigen, einwertigen, gesättigten Fettsäure nicht weniger als 50 Mol-% der Gesamtmenge an verwendeter einwertiger, gesättigter Fettsäure beträgt, und (c) mindestens einer mehrbasigen Säure mit einer Kohlenstoffanzahl von 4 bis 10, wobei der Anteil der mehrbasigen Säure nicht mehr als 80 Mol-% der Gesamtmenge an verwendeter einwertiger, gesättigter Fettsäure beträgt.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP91121100A EP0480479B2 (de) | 1989-07-05 | 1989-10-17 | Vervendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden |
EP91121101A EP0479338B1 (de) | 1989-07-05 | 1989-10-17 | Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden. |
EP92121965A EP0536814B1 (de) | 1989-07-05 | 1989-10-17 | Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden. |
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17200189 | 1989-07-05 | ||
JP172001/89 | 1989-07-05 | ||
JP172000/89 | 1989-07-05 | ||
JP17200189 | 1989-07-05 | ||
JP17200289 | 1989-07-05 | ||
JP17200089 | 1989-07-05 | ||
JP17200089 | 1989-07-05 | ||
JP17200289 | 1989-07-05 | ||
JP172002/89 | 1989-07-05 |
Related Child Applications (7)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91121100A Division-Into EP0480479B2 (de) | 1989-07-05 | 1989-10-17 | Vervendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden |
EP91121100A Division EP0480479B2 (de) | 1989-07-05 | 1989-10-17 | Vervendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden |
EP91121101A Division-Into EP0479338B1 (de) | 1989-07-05 | 1989-10-17 | Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden. |
EP92121965A Division-Into EP0536814B1 (de) | 1989-07-05 | 1989-10-17 | Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden. |
EP91121100.1 Division-Into | 1991-12-09 | ||
EP91121101.9 Division-Into | 1991-12-09 | ||
EP92121965.5 Division-Into | 1992-12-23 |
Publications (3)
Publication Number | Publication Date |
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EP0406479A1 EP0406479A1 (de) | 1991-01-09 |
EP0406479B1 EP0406479B1 (de) | 1994-04-06 |
EP0406479B2 true EP0406479B2 (de) | 2002-09-04 |
Family
ID=27323564
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89119265A Expired - Lifetime EP0406479B2 (de) | 1989-07-05 | 1989-10-17 | Kältemaschinenschmiermittel |
EP91121100A Expired - Lifetime EP0480479B2 (de) | 1989-07-05 | 1989-10-17 | Vervendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden |
EP92121965A Expired - Lifetime EP0536814B1 (de) | 1989-07-05 | 1989-10-17 | Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden. |
EP91121101A Expired - Lifetime EP0479338B1 (de) | 1989-07-05 | 1989-10-17 | Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden. |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
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EP91121100A Expired - Lifetime EP0480479B2 (de) | 1989-07-05 | 1989-10-17 | Vervendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden |
EP92121965A Expired - Lifetime EP0536814B1 (de) | 1989-07-05 | 1989-10-17 | Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden. |
EP91121101A Expired - Lifetime EP0479338B1 (de) | 1989-07-05 | 1989-10-17 | Verwendung eines Schmierstoffs für Kompressoren, die ein chlorfreies Fluorkohlenwasserstoff-Kältemittel verwenden. |
Country Status (5)
Country | Link |
---|---|
EP (4) | EP0406479B2 (de) |
KR (3) | KR950005694B1 (de) |
DE (4) | DE68914448T3 (de) |
ES (4) | ES2099120T5 (de) |
SG (2) | SG49157A1 (de) |
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- 1989-10-07 SG SG1996007058A patent/SG49157A1/en unknown
- 1989-10-17 ES ES91121100T patent/ES2099120T5/es not_active Expired - Lifetime
- 1989-10-17 EP EP89119265A patent/EP0406479B2/de not_active Expired - Lifetime
- 1989-10-17 DE DE68914448T patent/DE68914448T3/de not_active Expired - Lifetime
- 1989-10-17 EP EP91121100A patent/EP0480479B2/de not_active Expired - Lifetime
- 1989-10-17 DE DE68925537T patent/DE68925537T2/de not_active Expired - Lifetime
- 1989-10-17 ES ES91121101T patent/ES2104650T3/es not_active Expired - Lifetime
- 1989-10-17 DE DE68928281T patent/DE68928281T2/de not_active Expired - Lifetime
- 1989-10-17 ES ES92121965T patent/ES2082341T3/es not_active Expired - Lifetime
- 1989-10-17 EP EP92121965A patent/EP0536814B1/de not_active Expired - Lifetime
- 1989-10-17 EP EP91121101A patent/EP0479338B1/de not_active Expired - Lifetime
- 1989-10-17 ES ES89119265T patent/ES2051340T5/es not_active Expired - Lifetime
- 1989-10-17 DE DE68927916T patent/DE68927916T3/de not_active Expired - Lifetime
- 1989-10-17 SG SG1996007124A patent/SG49165A1/en unknown
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1996
- 1996-06-04 KR KR1019960019881A patent/KR0131017B1/ko not_active IP Right Cessation
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1997
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