EP0244647B1 - Utilisation de la caséine comme agent de nettoyage - Google Patents

Utilisation de la caséine comme agent de nettoyage Download PDF

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Publication number
EP0244647B1
EP0244647B1 EP87105029A EP87105029A EP0244647B1 EP 0244647 B1 EP0244647 B1 EP 0244647B1 EP 87105029 A EP87105029 A EP 87105029A EP 87105029 A EP87105029 A EP 87105029A EP 0244647 B1 EP0244647 B1 EP 0244647B1
Authority
EP
European Patent Office
Prior art keywords
casein
surfactant mixture
cleaning agent
conjunction
polyphosphates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP87105029A
Other languages
German (de)
English (en)
Other versions
EP0244647A3 (en
EP0244647A2 (fr
Inventor
Dénes Pötschke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
POETSCHKE, DENES
Original Assignee
Potschke Denes
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Potschke Denes filed Critical Potschke Denes
Priority to AT87105029T priority Critical patent/ATE61396T1/de
Publication of EP0244647A2 publication Critical patent/EP0244647A2/fr
Publication of EP0244647A3 publication Critical patent/EP0244647A3/de
Application granted granted Critical
Publication of EP0244647B1 publication Critical patent/EP0244647B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/384—Animal products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof

Definitions

  • the invention relates to the use of casein in combination with a surfactant mixture as a high-pressure and decoction cleaner.
  • Casein has long been known as an additive for soaps, so it is pointed out in "Ullmann, Encyclopedia of Industrial Chemistry", Volume 3, 1916, pages 292 to 297, in particular on page 297, that toilet soap increases by adding 10% casein solution and can be improved in quality.
  • the soap should become more delicate and durable and have greater foaming power.
  • DE-A-27 48 800, US-A-40 79 020 and EP-AI-0 013 585 it is known in the case of dishwashing detergents which are intended for manual dishwashing, casein in an amount of 0.25 to 5 % By weight to use.
  • casein there is to at least partially replace alkylbenzenesulfonates, alkylsulfonates and alkylsulfates, since these tend to adversely affect the properties of mildness and also of draining / drying under soft water conditions.
  • DE-A-26 07 656 describes a washing and cleaning agent for textiles which, in addition to phosphate building salts, also contains complexing agents, such as phosphonic acids, and protective colloids, such as casein.
  • casein in combination with a surfactant mixture is excellently suitable as a high-pressure and boil-out cleaning agent and is able to remove even strong incrustations. It is particularly advantageous to dispense with the use of polyphosphates.
  • casein As a milk protein, casein is biodegradable so that it does not pose any environmental problems. Casein is a by-product of milk processing in large quantities, for which the invention also creates a use.
  • Casein or caseinates are used according to the invention.
  • milk protein is normally present in the dry matter of the cleaning agent in amounts of more than 5 to 20% by weight, in particular 7 to 15% by weight. In special cases, however, the proportion can also be higher, especially if the cleaning agent otherwise only contains the surfactant mixture.
  • Casein is usually commercially available as a powder that is sparingly soluble in water. However, by increasing the pH, casein can be made soluble in a known manner. Solubilization using ammonium hydroxide is preferred. However, other soluble caseinates can also be used.
  • the high-pressure or decoction cleaner is preferably free of polyphosphates.
  • the use of the high-pressure or boil-out cleaning agent made of casein and surfactant mixture is preferably used for cleaning heavily soiled objects, such as machines, apparatus, boat, ship and aircraft bodies and swimming pools.
  • the special abilities of milk proteins to remove coarse dirt come into play here. It is therefore not necessary for the heavy soiling to be completely dissolved. Rather, it is sufficient to remove the dirt in the form of more or less coarse particles.
  • the cleaning agent according to the invention can be in liquid form, which is preferred if further constituents of the cleaning agent are usually used in liquid form anyway. If the cleaning agent is in liquid form, it expediently also contains a preservative in order to avoid bacterial decomposition of the milk protein.
  • milk proteins are used in the form of liquid preparations of digested milk protein which contain preservatives. These liquid preparations are used in combination with surfactant mixtures.
  • the ratio of protein solution to surfactant mixture can be in the ratio of 1: 2 to 2: 1, preferably 1: 1.
  • the protein solution preferably contains 5 to 20% by weight of soluble milk protein (caseinates) and a sufficient amount of preservative.
  • the surfactant mixture generally contains 20 to 60% by weight of wetting agent and water-soluble organic solvents. Protein solution and surfactant mixture are preferably prepared and used in the form of a common liquid mixture. Based on the solids content, this may contain about 10 to 30% by weight of casein or caseinate and about 90 to 70% by weight of surfactant mixture. Depending on the intended use, this liquid mixture is then diluted many times over.
  • the surfactant mixture mainly serves as a detergent for removing incrustations (from tar, oils, etc.), in containers, foulards, stenter frames, sieves, machines and machine parts, air conditioning systems as well as vehicle and aircraft bodies.
  • a detergent for high-pressure cleaning the mixture of protein solution and surfactant mixture is diluted, preferably in a ratio of 1: 3 to 1: 5. This lowers its viscosity so that it can be added to the heated water of the high-pressure cleaner.
  • Such a detergent is also suitable for cleaning by boiling, which can be combined with high-pressure cleaning for stubborn soiling.
  • Heavily soiled machines, apparatus, vehicles, ship, boat and aircraft bodies as well as inside and outside walls or cladding can be cleaned effectively with high-pressure cleaning agents containing milk protein, even if the dirt cannot be removed otherwise or can only be removed with environmentally harmful or aggressive chemicals can be.
  • the combination of protein solution and surfactant mixture is also effective for high-pressure cleaning of food businesses, public and private swimming pools, sewage treatment plants and containers.
  • the viscous mixture of surfactant mixture and protein solution is first diluted 3 to 5 times. About 20 to 60 l of this solution are then metered into 3000 to 5000 l of heated washing water. The protein solution and surfactant mixture are then approximately 150 to 1250 times diluted (0.08 to 1.3 g / 1 washing liquid).

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (5)

1. Utilisation de caséine conjointement avec un mélange d'agents tensio-actifs, en tant qu'agent de nettoyage sous haute pression.
2. Utilisation de caséine conjointement avec un mélange d'agents tensio-actifs pour éliminer des incrustations par ébullition dans des récipients, des foulards, des châssis-tendeurs, des tamis, des machines, des pièces de machines, des installations de climatisation, de même que des corps de véhicules et des fuselages d'avions.
3. Utilisation de caséine selon la revendication 1 ou 2 sous la forme d'un agent qui est exempt de polyphosphates.
4. Utilisation de caséine conjointement avec un mélange d'agents tensio-actifs sous la forme d'un agent qui est exempt de polyphosphates, pour l'élimination d'incrustations par ébullition.
5. Utilisation de caséine selon l'une des revendications 1 à 4, caractérisée par le fait qu'elle est mise en solution.
EP87105029A 1982-07-30 1983-07-16 Utilisation de la caséine comme agent de nettoyage Expired - Lifetime EP0244647B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT87105029T ATE61396T1 (de) 1982-07-30 1983-07-16 Verwendung von casein als reinigungsmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19823228479 DE3228479A1 (de) 1982-07-30 1982-07-30 Waschmittel fuer textilien
DE3228479 1982-07-30

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP83106984.4 Division 1983-07-16

Publications (3)

Publication Number Publication Date
EP0244647A2 EP0244647A2 (fr) 1987-11-11
EP0244647A3 EP0244647A3 (en) 1988-06-08
EP0244647B1 true EP0244647B1 (fr) 1991-03-06

Family

ID=6169707

Family Applications (2)

Application Number Title Priority Date Filing Date
EP83106984A Expired EP0110007B1 (fr) 1982-07-30 1983-07-16 Utilisation de protéines du lait comme produits auxiliaires textiles
EP87105029A Expired - Lifetime EP0244647B1 (fr) 1982-07-30 1983-07-16 Utilisation de la caséine comme agent de nettoyage

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP83106984A Expired EP0110007B1 (fr) 1982-07-30 1983-07-16 Utilisation de protéines du lait comme produits auxiliaires textiles

Country Status (5)

Country Link
US (1) US4761161A (fr)
EP (2) EP0110007B1 (fr)
JP (1) JPS5943099A (fr)
AT (2) ATE61396T1 (fr)
DE (3) DE3228479A1 (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0762157B2 (ja) * 1987-08-14 1995-07-05 文一郎 細田 石けん
DE3903362A1 (de) * 1989-02-04 1990-08-09 Basf Ag Chemisch modifizierte proteine
NZ240224A (en) * 1991-08-26 1993-07-27 Protein Tech Int Laundry detergents including a casein modified material as a soil anti-redeposition agent
US5885306A (en) * 1994-02-01 1999-03-23 Meiji Seika Kaisha, Ltd. Method for preventing redeposition of desorbed dyes to pre-dyed fabrics or its garments and dye antiredeposition agent
US5494744A (en) * 1994-10-12 1996-02-27 Kimberly-Clark Corporation Method of applying a protein coating to a substrate and article thereof
US5898024A (en) * 1995-03-01 1999-04-27 Charvid Limited Liability Non-caustic cleaning composition comprising peroxygen compound and specific silicate, and method of making the same in free-flowing, particulate form
US5663132A (en) * 1995-03-01 1997-09-02 Charvid Limited Liability Company Non-caustic composition comprising peroxygen compound and metasilicate and cleaning methods for using same
US6194367B1 (en) 1995-03-01 2001-02-27 Charvid Limited Liability Co. Non-caustic cleaning composition comprising peroxygen compound and specific silicate and method of making the same in free-flowing, particulate form
EP0815310B1 (fr) * 1995-03-14 2003-08-27 Kimberly-Clark Worldwide, Inc. Article mouillable
US5858503A (en) * 1995-10-26 1999-01-12 Kimberly-Clark Worldwide, Inc. Method of applying chemical charge modifiers to a substrate and article thereof
US5855788A (en) * 1996-02-07 1999-01-05 Kimberly-Clark Worldwide, Inc. Chemically charged-modified filter for removing particles from a liquid and method thereof
US5912194A (en) * 1996-08-30 1999-06-15 Kimberly Clark Corp. Permeable liquid flow control material
DE19942538A1 (de) * 1999-09-07 2001-03-08 Cognis Deutschland Gmbh Waschmittel
DE19944222A1 (de) * 1999-09-15 2001-03-29 Cognis Deutschland Gmbh Waschmitteltabletten
DE10061280A1 (de) * 2000-12-08 2002-06-13 Novaprot Gmbh Reinigungswirksame, grenzflächenaktive Kombination aus nachwachsenden Rohstoffen mit hoher Fettlösekraft
DE102005055495A1 (de) * 2005-11-18 2007-05-24 Henkel Kgaa Textilbehandlungsmittel mit einem Milcherzeugnis
EP1948772A1 (fr) * 2005-11-18 2008-07-30 Henkel AG & Co. KGaA Agent de traitement pour textile contenant un produit laitier
CN1865559B (zh) * 2006-06-22 2010-09-29 上海题桥纺织染纱有限公司 牛奶蛋白纤维或其长丝或其混纺织物织造和染色的方法
WO2010025452A1 (fr) * 2008-08-29 2010-03-04 Micro Pure Solutions, Llc Procédé de traitement de fluides contenant du sulfate d’hydrogène

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE516983C (de) * 1927-02-10 1931-01-29 Appreturanstalt Verfahren zur Erzeugung weisser oder gefaerbter Effekte in Stueckware beim Faerben mit Klotzanilinschwarz
US2894801A (en) * 1956-11-29 1959-07-14 United Merchants & Mfg Textile printing emulsions
BE627260A (fr) * 1962-01-29
US3287277A (en) * 1964-02-20 1966-11-22 Barbour John Henderson Liquid detergent
GB1328107A (en) * 1969-12-30 1973-08-30 Ciba Geigy Uk Ltd Dyeing process
JPS4948590A (fr) * 1972-09-14 1974-05-10
FR2264085B1 (fr) * 1974-03-15 1976-12-17 Procter & Gamble Europ
GB1536136A (en) * 1975-03-03 1978-12-20 Unilever Ltd Detergent composition
GB1562793A (en) * 1975-11-07 1980-03-19 Unilever Ltd Cleaning composition
US4079020A (en) * 1975-11-07 1978-03-14 Lever Brothers Company Cleaning composition
GB1538174A (en) * 1976-11-05 1979-01-10 Unilever Ltd Cleaning composition
DE2838274A1 (de) * 1978-09-01 1980-03-13 Bayer Ag Verfahren zum faerben und bedrucken von cellulosefasern mit reaktivfarbstoffen
NZ192549A (en) * 1979-01-12 1981-11-19 Unilever Ltd Liquid detergent comprising a copolymer of n-vinylpyrrolidone
EP0018947B1 (fr) * 1979-05-04 1984-02-01 Ciba-Geigy Ag Composition et procédé pour la teinture de tissus en polyester ou en un mélange de polyester avec du coton ou de la laine
NZ201309A (en) * 1981-07-24 1985-07-12 Unilever Plc Detergent compositions containing dialkyl sulphosuccinates and undegraded protein
FR2528459B1 (fr) * 1982-06-11 1985-07-26 Sandoz Sa Procede de teinture ou d'impression de textiles encolles

Also Published As

Publication number Publication date
EP0244647A3 (en) 1988-06-08
EP0244647A2 (fr) 1987-11-11
EP0110007A2 (fr) 1984-06-13
JPS5943099A (ja) 1984-03-09
EP0110007B1 (fr) 1988-04-27
ATE61396T1 (de) 1991-03-15
US4761161A (en) 1988-08-02
ATE33861T1 (de) 1988-05-15
DE3382198D1 (de) 1991-04-11
DE3376435D1 (en) 1988-06-01
EP0110007A3 (en) 1984-12-19
DE3228479A1 (de) 1984-02-09

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