EP0110007A2 - Utilisation de protéines du lait comme produits auxiliaires textiles - Google Patents

Utilisation de protéines du lait comme produits auxiliaires textiles Download PDF

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Publication number
EP0110007A2
EP0110007A2 EP83106984A EP83106984A EP0110007A2 EP 0110007 A2 EP0110007 A2 EP 0110007A2 EP 83106984 A EP83106984 A EP 83106984A EP 83106984 A EP83106984 A EP 83106984A EP 0110007 A2 EP0110007 A2 EP 0110007A2
Authority
EP
European Patent Office
Prior art keywords
weight
detergent
percent
milk protein
milk
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP83106984A
Other languages
German (de)
English (en)
Other versions
EP0110007B1 (fr
EP0110007A3 (en
Inventor
Dénes Pötschke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to AT83106984T priority Critical patent/ATE33861T1/de
Publication of EP0110007A2 publication Critical patent/EP0110007A2/fr
Publication of EP0110007A3 publication Critical patent/EP0110007A3/de
Application granted granted Critical
Publication of EP0110007B1 publication Critical patent/EP0110007B1/fr
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/384—Animal products
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof

Definitions

  • the invention relates to a cleaning agent, in particular for textiles.
  • the detergents used for textiles today contain polyphosphates.
  • large amounts of polyphosphates end up in rivers, which is now a serious environmental problem.
  • Considerable efforts have therefore been made for a long time to find suitable substitutes for polyphosphates.
  • a satisfactory result has not yet been achieved.
  • the invention is therefore based on the object of creating a treatment agent, in particular for textiles, or of providing an additive for such treatment agents with the aim of reducing the polyphosphate content of the conventional treatment agents or even being able to dispense entirely with polyphosphates and other phosphorus compounds.
  • the invention consists in the fact that the cleaning or treatment agent contains milk protein. It has surprisingly been found that milk protein (also called milk protein) is able due to its structure to take over the effect of the phosphates previously used in conjunction with other conventional treatment or cleaning agent components. In contrast to polyphosphates, milk protein is degradable, so there are no environmental problems. Milk protein is a by-product of milk utilization in large quantities, for which the invention also creates a use.
  • milk protein also called milk protein
  • Casein or caseinates are preferred. Casein has long been known as an additive for soaps, so it is pointed out in "Ullmann, Encyclopedia of Technical Chemistry", Volume 3, 1916, pages 292 to 297, in particular on page 297, that toilet soap is increased by adding 10% casein solution and can be improved in quality. The soap should become more delicate and durable and have greater foaming power. Furthermore, in the case of a dishwashing detergent which is intended in particular for manual dishwashing, it is known to use casein in an amount of 0.25 to 5 percent by weight.
  • the milk protein is normally present in the dry matter of a detergent in amounts of more than 5 to 20 percent by weight, in particular 7 to 15 percent by weight. In special cases, however, the proportion may also be higher, especially if the detergent is otherwise only the main components normally used, such as surfactants and the like. Like. Contains. It has proven to be advantageous if the detergent additionally contains at least one softening agent, with phosphate-free softening agents being preferred. Such hardeners are, for example, sodium aluminum silicates, such as zeolites, and complexing agents, such as ethylenediaminetetraacetic acid, nitriloacetic acids and the like. Such softening agents or chelating agents are preferably contained in the detergent according to the invention, because this has the full effect of casein as a substitute for tripolyphosphate.
  • milk protein especially casein
  • casein is usually commercially available as a powder that is sparingly soluble in water.
  • casein can be made soluble in a known manner. Solubilization using ammonium hydroxide is preferred.
  • other soluble caseinates can also be used.
  • the detergent according to the invention normally contains 5 to 20 percent by weight alkylbenzenesulfonate, 20 to 35 percent by weight sodium percarbonate and / or sodium perborate, 3 to 15 percent by weight alkali silicate and 5 to 30 percent by weight Casein, an addition of 5 to 15 percent by weight of at least one softening agent being preferred.
  • the detergent according to the invention can contain other conventional constituents, such as cellulose derivatives, fatty alcohol oxyethylates, sodium sulfate and further additional washing aids, such as sodium soaps as foam suppressants.
  • the cleaning or treatment agent is preferably free of phosphorus compounds.
  • the cleaning agent according to the invention is particularly suitable as a detergent for textiles and in turn as a detergent which can be used both at 60 ° and at 90 ° C laundry. All that is required is a main wash cycle. H. there is no need for a pre-wash and a soft wash. This is due to the special dirt-dissolving and dirt-carrying properties of the milk protein. Furthermore, sodium sulfate can be dispensed with as an additive in the detergent, which further reduces the salt load in the waste water.
  • the detergent is suitable for use in washing machines and not only in the household, but also for large laundries, hospitals and the like. The like. It shows no dirt reduction position.
  • the cleaning agent according to the invention can also be used in other fields, for example as a textile auxiliary or as an additive, for example.
  • B. for washing or cleaning textile goods before dyeing, during dyeing and after dyeing.
  • the milk protein is particularly valuable in its use when leveling stained goods. It has been shown that stains and other discoloration can be removed in a washing process with the help of the cleaning agent according to the invention even where there are all commercially available chemicals, such as.
  • the cleaning agent according to the invention is also suitable for cleaning heavily soiled objects, such as machines, apparatus; Boats, ships and aircraft bodies, swimming pools, it is preferably used as part of a high pressure cleaning.
  • the special abilities of milk proteins to remove coarse dirt come into play here. It is therefore not necessary for the heavy soiling to be completely dissolved. It is sufficient to remove the dirt in the form of more or less coarse particles.
  • the cleaning agent according to the invention is to be used as a detergent for textiles, then it is normally in a dry form, e.g. B. as a free-flowing powder.
  • detergent amounts of, for example, 200 g are sufficient for a washing process in comparison to the otherwise usual 250 g, which are required for known detergents for prewash and main wash.
  • the lower weight quantity alone reduces the pollution of the waste water.
  • there is the good biodegradability of the milk proteins. Saving a pre-wash and a soft wash also saves water and energy. Due to the good dirt-bearing properties of the milk proteins, both a good detachment of the dirt and a softening of the textile fibers are achieved.
  • the tear strength of the textiles is not reduced by the detergent according to the invention.
  • the cleaning agent according to the invention can also be in liquid form, which is preferred if further constituents of the cleaning agent are usually used in liquid form anyway. This is special when used as a textile aid. If the cleaning agent is in liquid form, it expediently also contains a preservative in order to avoid bacterial decomposition of the milk protein.
  • TPP pentasodium triphosphate
  • a detergent suitable for washing at 60 ° C has the following composition:
  • the advantage of the invention is particularly clear, since the heavy-duty detergents in particular - especially for use at 60 ° C. - normally have a very high phosphate content.
  • This example shows further compositions of phosphate-free detergents.
  • Examples 5 to 10 below show the use of milk proteins in the form of liquid preparations of digested milk protein which contain preservatives. These liquid preparations are preferably used in combination with surfactants or surfactant mixtures. When used as a dyeing aid, the solution of the milk protein can be called an equalizer and the solution of the surfactants can be called a corrector.
  • the equalizer can be used on its own in the textile industry, e.g. B. as a leveling agent.
  • the leveler milk protein
  • the ratio of leveler to corrector can be in the ratio of 1: 2 to 2: 1, preferably 1: 1.
  • the leveler preferably contains 5 to 20 percent by weight soluble milk protein (caseinates) and a sufficient amount of preservative.
  • the corrector usually contains 20 to 60 percent by weight of wetting agent and water-soluble organic solvents.
  • the leveler and corrector are preferably prepared and used in the form of a common liquid mixture.
  • this may contain about 10 to 30 percent by weight casein or caseinate and about 90 to 70 percent by weight surfactant mixture. Depending on the intended use, this liquid mixture is then diluted many times over.
  • the corrector is mainly used for stained, reactive and direct stains on cellulose goods with the possibility of refinishing in the decoction bath, as well as for lightening too dark reactive stains on cellulose, furthermore for removing oligomers in polyester stains, as detergent for removing incrustations (from tar , oil etc.), for containers, foulards, stenter frames, screens, machines and machine parts, air conditioning systems as well as vehicle and aircraft bodies.
  • the mixture of leveler and corrector is diluted, preferably in a ratio of 1: 3 to 1: 5. This lowers its viscosity so that it can be added to the heated water of the high-pressure cleaner.
  • a detergent is also suitable for cleaning by boiling, which can be combined with high-pressure cleaning for stubborn soiling.
  • milk protein is used as a leveling agent for cotton dyeing, especially of knitted cotton fabrics using substantive and reactive dyes after the pull-out process.
  • the leveling agent is added to the dye liquor prophylactically to prevent color irregularity.
  • liquid leveler per liter of liquor 0.05 to 0.35 g casein per liter of liquor
  • Equalizer and corrector which preferably consists of a mixture of non-ionic emulsifiers, detergents and cleaning enhancers, in combination remove color stains and dirt stains from cotton stains that cannot otherwise be cleaned if they have been dyed with substantive and reactive dyes.
  • the coloring remains unimportant.
  • the color tone becomes a maximum of 10% lighter.
  • Color nuance using milk protein and a surfactant mixture in a hot dye bath Color nuance using milk protein and a surfactant mixture in a hot dye bath.
  • the special leveling and cleaning effect is due to the milk protein, especially casein and caseinate.
  • the other chemicals or the corrector have a supporting effect.
  • the remaining components of the detergent or the corrector can be replaced by equivalent substances.
  • leveler and corrector are also effective for high-pressure cleaning of food businesses, public and private swimming pools, sewage treatment plants and containers.
  • the viscous mixture of corrector and leveler is first diluted 3 to 5 times. About 20 to 60 l of this solution are then metered into 3000 to 5000 l of heated washing water. The leveler and corrector are then approximately 150 to 1250 times diluted (0.08 to 1.3 g / 1 washing liquid).
  • this high-pressure cleaning agent was also able to remove sticky and hardened impurities with great success.

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Zoology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
EP83106984A 1982-07-30 1983-07-16 Utilisation de protéines du lait comme produits auxiliaires textiles Expired EP0110007B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT83106984T ATE33861T1 (de) 1982-07-30 1983-07-16 Verwendung von milchprotein als textilhilfsmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19823228479 DE3228479A1 (de) 1982-07-30 1982-07-30 Waschmittel fuer textilien
DE3228479 1982-07-30

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP87105029.0 Division-Into 1987-04-04

Publications (3)

Publication Number Publication Date
EP0110007A2 true EP0110007A2 (fr) 1984-06-13
EP0110007A3 EP0110007A3 (en) 1984-12-19
EP0110007B1 EP0110007B1 (fr) 1988-04-27

Family

ID=6169707

Family Applications (2)

Application Number Title Priority Date Filing Date
EP83106984A Expired EP0110007B1 (fr) 1982-07-30 1983-07-16 Utilisation de protéines du lait comme produits auxiliaires textiles
EP87105029A Expired - Lifetime EP0244647B1 (fr) 1982-07-30 1983-07-16 Utilisation de la caséine comme agent de nettoyage

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP87105029A Expired - Lifetime EP0244647B1 (fr) 1982-07-30 1983-07-16 Utilisation de la caséine comme agent de nettoyage

Country Status (5)

Country Link
US (1) US4761161A (fr)
EP (2) EP0110007B1 (fr)
JP (1) JPS5943099A (fr)
AT (2) ATE61396T1 (fr)
DE (3) DE3228479A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0530418A1 (fr) * 1991-08-26 1993-03-10 Protein Technologies International, Inc. Méthode et produits pour améliorer les qualités anti-redéposition de salissures de détergents
EP1083215A1 (fr) * 1999-09-07 2001-03-14 Cognis Deutschland GmbH Composition détergente
WO2001019952A1 (fr) * 1999-09-15 2001-03-22 Cognis Deutschland Gmbh & Co. Kg Detergent en pastilles

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0762157B2 (ja) * 1987-08-14 1995-07-05 文一郎 細田 石けん
DE3903362A1 (de) * 1989-02-04 1990-08-09 Basf Ag Chemisch modifizierte proteine
US5885306A (en) * 1994-02-01 1999-03-23 Meiji Seika Kaisha, Ltd. Method for preventing redeposition of desorbed dyes to pre-dyed fabrics or its garments and dye antiredeposition agent
US5494744A (en) * 1994-10-12 1996-02-27 Kimberly-Clark Corporation Method of applying a protein coating to a substrate and article thereof
US6194367B1 (en) 1995-03-01 2001-02-27 Charvid Limited Liability Co. Non-caustic cleaning composition comprising peroxygen compound and specific silicate and method of making the same in free-flowing, particulate form
US5898024A (en) * 1995-03-01 1999-04-27 Charvid Limited Liability Non-caustic cleaning composition comprising peroxygen compound and specific silicate, and method of making the same in free-flowing, particulate form
US5663132A (en) * 1995-03-01 1997-09-02 Charvid Limited Liability Company Non-caustic composition comprising peroxygen compound and metasilicate and cleaning methods for using same
BR9607204A (pt) * 1995-03-14 1997-11-11 Kimberly Clark Co Artigo umedecivel
US5858503A (en) * 1995-10-26 1999-01-12 Kimberly-Clark Worldwide, Inc. Method of applying chemical charge modifiers to a substrate and article thereof
US5855788A (en) * 1996-02-07 1999-01-05 Kimberly-Clark Worldwide, Inc. Chemically charged-modified filter for removing particles from a liquid and method thereof
US5912194A (en) * 1996-08-30 1999-06-15 Kimberly Clark Corp. Permeable liquid flow control material
DE10061280A1 (de) * 2000-12-08 2002-06-13 Novaprot Gmbh Reinigungswirksame, grenzflächenaktive Kombination aus nachwachsenden Rohstoffen mit hoher Fettlösekraft
DE102005055495A1 (de) * 2005-11-18 2007-05-24 Henkel Kgaa Textilbehandlungsmittel mit einem Milcherzeugnis
WO2007057080A1 (fr) * 2005-11-18 2007-05-24 Henkel Ag & Co. Kgaa Agent de traitement pour textile contenant un produit laitier
CN1865559B (zh) * 2006-06-22 2010-09-29 上海题桥纺织染纱有限公司 牛奶蛋白纤维或其长丝或其混纺织物织造和染色的方法
WO2010025452A1 (fr) * 2008-08-29 2010-03-04 Micro Pure Solutions, Llc Procédé de traitement de fluides contenant du sulfate d’hydrogène

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE627260A (fr) * 1962-01-29
DE516983C (de) * 1927-02-10 1931-01-29 Appreturanstalt Verfahren zur Erzeugung weisser oder gefaerbter Effekte in Stueckware beim Faerben mit Klotzanilinschwarz
GB1004442A (en) * 1964-02-20 1965-09-15 John Henderson Barbour Improvements in or relating to detergents and methods of manufacturing same
GB1328107A (en) * 1969-12-30 1973-08-30 Ciba Geigy Uk Ltd Dyeing process
FR2264085A1 (fr) * 1974-03-15 1975-10-10 Procter & Gamble Europ
FR2303074A1 (fr) * 1975-03-03 1976-10-01 Unilever Nv Compositions detergentes ayant un pouvoir anti-jaunissant et antimineralisant accru
US4079020A (en) * 1975-11-07 1978-03-14 Lever Brothers Company Cleaning composition
DE2748800A1 (de) * 1976-11-05 1978-05-11 Unilever Nv Reinigungsmittel
EP0071413A2 (fr) * 1981-07-24 1983-02-09 Unilever Plc Compositions détergentes

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2894801A (en) * 1956-11-29 1959-07-14 United Merchants & Mfg Textile printing emulsions
JPS4948590A (fr) * 1972-09-14 1974-05-10
GB1562793A (en) * 1975-11-07 1980-03-19 Unilever Ltd Cleaning composition
DE2838274A1 (de) * 1978-09-01 1980-03-13 Bayer Ag Verfahren zum faerben und bedrucken von cellulosefasern mit reaktivfarbstoffen
NZ192549A (en) * 1979-01-12 1981-11-19 Unilever Ltd Liquid detergent comprising a copolymer of n-vinylpyrrolidone
EP0018947B1 (fr) * 1979-05-04 1984-02-01 Ciba-Geigy Ag Composition et procédé pour la teinture de tissus en polyester ou en un mélange de polyester avec du coton ou de la laine
FR2528459B1 (fr) * 1982-06-11 1985-07-26 Sandoz Sa Procede de teinture ou d'impression de textiles encolles

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE516983C (de) * 1927-02-10 1931-01-29 Appreturanstalt Verfahren zur Erzeugung weisser oder gefaerbter Effekte in Stueckware beim Faerben mit Klotzanilinschwarz
BE627260A (fr) * 1962-01-29
GB1004442A (en) * 1964-02-20 1965-09-15 John Henderson Barbour Improvements in or relating to detergents and methods of manufacturing same
GB1328107A (en) * 1969-12-30 1973-08-30 Ciba Geigy Uk Ltd Dyeing process
FR2264085A1 (fr) * 1974-03-15 1975-10-10 Procter & Gamble Europ
FR2303074A1 (fr) * 1975-03-03 1976-10-01 Unilever Nv Compositions detergentes ayant un pouvoir anti-jaunissant et antimineralisant accru
US4079020A (en) * 1975-11-07 1978-03-14 Lever Brothers Company Cleaning composition
DE2748800A1 (de) * 1976-11-05 1978-05-11 Unilever Nv Reinigungsmittel
EP0071413A2 (fr) * 1981-07-24 1983-02-09 Unilever Plc Compositions détergentes

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0530418A1 (fr) * 1991-08-26 1993-03-10 Protein Technologies International, Inc. Méthode et produits pour améliorer les qualités anti-redéposition de salissures de détergents
EP1083215A1 (fr) * 1999-09-07 2001-03-14 Cognis Deutschland GmbH Composition détergente
WO2001019952A1 (fr) * 1999-09-15 2001-03-22 Cognis Deutschland Gmbh & Co. Kg Detergent en pastilles

Also Published As

Publication number Publication date
DE3376435D1 (en) 1988-06-01
DE3382198D1 (de) 1991-04-11
US4761161A (en) 1988-08-02
EP0244647A2 (fr) 1987-11-11
EP0110007B1 (fr) 1988-04-27
ATE61396T1 (de) 1991-03-15
JPS5943099A (ja) 1984-03-09
EP0244647B1 (fr) 1991-03-06
EP0244647A3 (en) 1988-06-08
ATE33861T1 (de) 1988-05-15
EP0110007A3 (en) 1984-12-19
DE3228479A1 (de) 1984-02-09

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