EP0205995A2 - Lubrifiant et utilisation de celui-ci - Google Patents
Lubrifiant et utilisation de celui-ci Download PDFInfo
- Publication number
- EP0205995A2 EP0205995A2 EP19860107408 EP86107408A EP0205995A2 EP 0205995 A2 EP0205995 A2 EP 0205995A2 EP 19860107408 EP19860107408 EP 19860107408 EP 86107408 A EP86107408 A EP 86107408A EP 0205995 A2 EP0205995 A2 EP 0205995A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- lubricant
- total weight
- oils
- amount
- organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000314 lubricant Substances 0.000 title claims abstract description 49
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 18
- 235000021317 phosphate Nutrition 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 15
- 239000002199 base oil Substances 0.000 claims abstract description 15
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 14
- 238000005057 refrigeration Methods 0.000 claims abstract description 13
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims abstract description 9
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 239000002480 mineral oil Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 229920013639 polyalphaolefin Polymers 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 6
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- -1 diphenylcresyl Chemical group 0.000 claims description 5
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 4
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 4
- ZMANLGWZVUUVFS-UHFFFAOYSA-N dodecyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCCCCCC)OC1=CC=CC=C1 ZMANLGWZVUUVFS-UHFFFAOYSA-N 0.000 claims description 3
- 230000001050 lubricating effect Effects 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000004378 air conditioning Methods 0.000 abstract description 4
- 230000000996 additive effect Effects 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 239000010725 compressor oil Substances 0.000 abstract description 2
- 239000010720 hydraulic oil Substances 0.000 abstract description 2
- 238000009434 installation Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 17
- 239000010452 phosphate Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000011521 glass Substances 0.000 description 9
- 150000004996 alkyl benzenes Chemical class 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000010721 machine oil Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 6
- 239000010687 lubricating oil Substances 0.000 description 6
- 230000032683 aging Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000003507 refrigerant Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 238000012430 stability testing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- BZJTUOGZUKFLQT-UHFFFAOYSA-N 1,3,5,7-tetramethylcyclooctane Chemical group CC1CC(C)CC(C)CC(C)C1 BZJTUOGZUKFLQT-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001348 alkyl chlorides Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- NMAKPIATXQEXBT-UHFFFAOYSA-N didecyl phenyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=CC=C1 NMAKPIATXQEXBT-UHFFFAOYSA-N 0.000 description 1
- MKZVQIIAAIPNGH-UHFFFAOYSA-N dioctyl phenyl phosphite Chemical compound CCCCCCCCOP(OCCCCCCCC)OC1=CC=CC=C1 MKZVQIIAAIPNGH-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000004812 organic fluorine compounds Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/02—Petroleum fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/02—Well-defined hydrocarbons
- C10M105/06—Well-defined hydrocarbons aromatic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M155/00—Lubricating compositions characterised by the additive being a macromolecular compound containing atoms of elements not provided for in groups C10M143/00 - C10M153/00
- C10M155/02—Monomer containing silicon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/008—Lubricant compositions compatible with refrigerants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
- C10M2203/065—Well-defined aromatic compounds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/104—Aromatic fractions
- C10M2203/1045—Aromatic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/108—Residual fractions, e.g. bright stocks
- C10M2203/1085—Residual fractions, e.g. bright stocks used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/041—Triaryl phosphates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/06—Instruments or other precision apparatus, e.g. damping fluids
Definitions
- lubricants are particularly suitable for refrigeration machines, heat pumps and related systems such as air conditioning systems. They can also be used as compressor and hydraulic oils.
- Lubricants for refrigerating machine oils still mainly consist of highly refined mineral oils, which are dewaxed to improve the flow properties in the cold beyond what is customary for lubricating oils.
- Pour points customary for chillers are in a range from -50 ° C to -25 ° C, depending on viscosity, and the cold pour points according to DIN 51568 are in a range between -16 ° C and -38 ° C.
- the temperature at which flocculation of paraffin crystals occurs - important for the proper functioning of the lubricant - is also reduced by the additional dewaxing.
- the mineral oils suitable for the production of refrigerating machine oils are obtained according to the known methods by distilling crude oils with subsequent refining (Ullmanns Encyklopadie der Technische Chemie, 4th edition, volume 20, pages 484 ff.). Depending on the origin of the crude oil, so-called paraffin-based or naphthenic-based lubricating oils are obtained.
- Paraffin-based lubricating oils mainly contain paraffinic molecules, naphthenic-based predominantly naphthenic or cycloparaffinic molecules.
- naphthenic oils are preferred for the production of refrigeration oils.
- Refrigeration oils based on mineral oils usually contain no additives. Although attempts have often been made to improve the properties of the oils with the aid of additives, the success has so far been poor (ASHRAE Guide and Data Book 1969, section 23, page 281).
- alkylbenzenes used come from the known syntheses according to Friedel-Crafts by alkylation of benzene with alkyl chlorides or olefins (Ullmann, 4th edition, volume 14, pages 672 ff.).
- ⁇ -olefins which are produced by ethylene oligomerization or by cracking paraffins according to different processes, serve as raw material for the production of polymer oils (Ullmann, 4th edition, volume 14, pages 664 ff.).
- these d-olefins are polymerized and hydrogenated ("Synthetic Poly- ⁇ -olefin Lubricants Today and Tomorrow", M.Campen, DFKendrick, ADMarkin, and Ullmann, 4th Edition, Volume 20, pages 505 ff.) .
- the invention has for its object to provide lubricating oils with increased lubricating properties with improved low-temperature behavior and improved thermal stability and low foaming tendency.
- the substituted phosphite can be, for example, a trinonylphenyl phosphite, triphenyl phosphite, dodecyl diphenyl phosphite, dioctylphenyl phosphite, tridodecyl phosphite, didecylphenyl phosphite.
- the phosphites of medium molecular size such as, for example, dodecyl diphenyl phosphite or triphenyl phosphite are preferably used.
- organic phosphates examples include diphenyl cresyl phosphate and other alkyl, aryl or alkylaryl derivatives of cresyl phosphate.
- Trialkylaryl phosphates such as, for example, triisopropylphenyl phosphate or tricresyl phosphate are preferably used.
- a methyl silicone is preferred as the silicone. It only serves to reduce foaming.
- a coil of 0.1 mm copper wire and an approximately 15 mm long steel wire - 1.6 DIN 177-D5-1 - were inserted into glasses prepared in this way, 0.3 to 0.4 g of lubricant were weighed in and in a special device under vacuum and freezing added about the same amount of Freon refrigerant. Before the latter step, all gases were removed from the weighed oil by means of a vacuum. With the addition of nitrogen, the glasses were welded after the addition of the refrigerant. The glasses were then heated to the test temperature in a drying cabinet for a predetermined period. The test temperature was 175 ° C or 200 ° C, the test duration between 336 and 1008 hours (2 to 6 weeks).
- alkylbenzene / mineral oil mixture (ratio 1: 1) was used as the base oil, viscosity class ISO 32, the alkylbenzene containing straight-chain C 10 -C 12 alkyls and the mineral oil component consisting of highly refined naphthenic-based oil. 1% of an isopropylated triphenyl phosphate with an average isopropyl content of 1.5 moles per mole of triphenyl phosphate and 0.005% methyl silicone was added.
- Base oil from alkylbenzene with branched alkyl groups made from the reaction of benzene with tetrapropylene), viscosity class ISO 32, with the addition of 1% triisopropylphenyl phosphate and 0.005% methyl silicone.
- Base oil from alkylbenzene with straight-chain alkyl groups viscosity class ISO 68, with the addition of 1% triisopropylphenyl phosphate and 0.005% methyl silicone.
- Base oil from a mixture of poly- ⁇ -olefins, viscosity class ISO 68, with the addition of 1% triisopropylphenyl phosphate and 0.005% methyl silicone.
- Base oil made from highly refined naphthenic mineral oil, viscosity class ISO 46, with the addition of 1% triisopropylphenyl phosphate and 0.005% methyl silicone.
- the examples show a clear qualitative improvement in the refrigerating machine oils of the lubricants according to the invention with regard to oxidation and heat stability compared to the comparative examples.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Lubricants (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT86107408T ATE71651T1 (de) | 1985-06-21 | 1986-05-31 | Schmiermittel und anwendung desselben. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3522165 | 1985-06-21 | ||
DE3522165A DE3522165C1 (de) | 1985-06-21 | 1985-06-21 | Schmiermittel und ihre Verwendung |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0205995A2 true EP0205995A2 (fr) | 1986-12-30 |
EP0205995A3 EP0205995A3 (en) | 1987-10-14 |
EP0205995B1 EP0205995B1 (fr) | 1992-01-15 |
Family
ID=6273787
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86107408A Expired - Lifetime EP0205995B1 (fr) | 1985-06-21 | 1986-05-31 | Lubrifiant et utilisation de celui-ci |
Country Status (6)
Country | Link |
---|---|
US (1) | US5049292A (fr) |
EP (1) | EP0205995B1 (fr) |
JP (1) | JPS61296093A (fr) |
AT (1) | ATE71651T1 (fr) |
BR (1) | BR8602797A (fr) |
DE (2) | DE3522165C1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0336171A1 (fr) * | 1988-04-06 | 1989-10-11 | Nippon Oil Co. Ltd. | Utilisation de compositions d'huile lubrifiante pour réfrigérateurs |
EP0384724A1 (fr) * | 1989-02-22 | 1990-08-29 | Nippon Oil Co. Ltd. | Procédé de lubrification d'appareils réfrigérants |
EP0693546A1 (fr) * | 1994-07-19 | 1996-01-24 | NIPPON OIL Co. Ltd. | Composition d'huile et de fluide pour réfrigérateur |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0645795B2 (ja) * | 1986-09-05 | 1994-06-15 | 株式会社松村石油研究所 | 潤滑油添加剤組成物及びこれを含有する潤滑油組成物 |
JP2590143B2 (ja) * | 1987-10-28 | 1997-03-12 | 出光興産株式会社 | 水素含有フロン冷媒用潤滑油組成物 |
KR930010525B1 (ko) * | 1987-10-28 | 1993-10-25 | 이데미쓰 고산 가부시끼가이샤 | 수소함유 플론냉매용 윤활유와 조성물 |
US5185089A (en) * | 1990-05-10 | 1993-02-09 | Allied-Signal Inc. | Lubricants useful with 1,1-dichloro-2,2,2-trifluoroethane |
CA2060201A1 (fr) * | 1990-05-17 | 1991-11-18 | Scott T. Jolley | Compositions phosphorees pour systemes de refrigeration |
EP0496486B1 (fr) * | 1991-01-11 | 1994-03-02 | Mobil Oil Corporation | Compositions de lubrifiant |
JPH04332793A (ja) * | 1991-05-07 | 1992-11-19 | Sanyo Electric Co Ltd | 冷凍機油組成物 |
JP3142321B2 (ja) * | 1991-09-03 | 2001-03-07 | 日石三菱株式会社 | 冷凍機油組成物 |
TW203098B (fr) * | 1991-09-27 | 1993-04-01 | Mitsui Petroleum Chemicals Ind | |
US5518643A (en) * | 1992-06-04 | 1996-05-21 | Idemitsu Kosan Co., Ltd. | Lubricating oil containing a polyvinyl ether compound for compression-type refrigerators |
US5792733A (en) * | 1997-08-14 | 1998-08-11 | The Lubrizol Corporation | Antiwear compositions containing phosphorus compounds and olefins |
US6191078B1 (en) | 1999-09-21 | 2001-02-20 | Exxonmobil Research And Engineering Company | Part-synthetic, aviation piston engine lubricant |
KR100562911B1 (ko) | 2004-11-24 | 2006-03-22 | 화천기공 주식회사 | 고속 주축 베어링 윤활 조성물 |
JP4809607B2 (ja) * | 2005-01-11 | 2011-11-09 | Jx日鉱日石エネルギー株式会社 | 組付け油、並びに冷凍空調機器の構成部品の組付け方法 |
EP1690920A1 (fr) * | 2005-02-11 | 2006-08-16 | JohnsonDiversey, Inc. | Concentrat de lubrifiant contentant un triester phosphorique |
JP7518718B2 (ja) * | 2020-09-30 | 2024-07-18 | 出光興産株式会社 | 冷凍機油組成物、冷媒潤滑油混合組成物及び冷蔵庫 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2801087A1 (de) * | 1977-01-14 | 1978-07-27 | Idemitsu Kosan Co | Oelzusammensetzung fuer kuehlaggregate |
US4199461A (en) * | 1977-02-14 | 1980-04-22 | Chevron Research Company | Refrigeration oil containing wear-inhibiting amounts of an aryl phosphate-fatty acid combination |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
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GB548390A (en) * | 1941-04-04 | 1942-10-08 | William Helmore | Improvements in or relating to lubricating compositions |
US3280031A (en) * | 1963-12-31 | 1966-10-18 | Mobil Oil Corp | High temperature lubricating oils |
US3459660A (en) * | 1966-10-14 | 1969-08-05 | Texaco Inc | Lubricating oil composition |
GB1413105A (en) * | 1971-09-02 | 1975-11-05 | Ici Ltd | Hydraulic fluid compositions |
US4033887A (en) * | 1973-07-13 | 1977-07-05 | Labofina S.A. | Phosphoric acid ester based functional fluids |
US4072027A (en) * | 1977-01-19 | 1978-02-07 | Allied Chemical Corporation | Stabilized heat activated heat exchange absorption pair |
US4116877A (en) * | 1977-07-08 | 1978-09-26 | Exxon Research & Engineering Co. | Elastomer compatible seal swell additive for automatic transmission fluids, power transmission fluids and hydraulic steering applications |
IL56876A0 (en) * | 1978-05-15 | 1979-05-31 | Stauffer Chemical Co | Method for the color improvement of alkylphenyl phosphate esters |
JPS57124664A (en) * | 1981-01-28 | 1982-08-03 | Hitachi Ltd | Absorbing liquid for absorption type refrigerating machine |
DE3265173D1 (en) * | 1981-04-07 | 1985-09-12 | Matsushita Electric Ind Co Ltd | Composition for absorption refrigeration |
-
1985
- 1985-06-21 DE DE3522165A patent/DE3522165C1/de not_active Expired
-
1986
- 1986-05-31 AT AT86107408T patent/ATE71651T1/de not_active IP Right Cessation
- 1986-05-31 DE DE8686107408T patent/DE3683409D1/de not_active Expired - Lifetime
- 1986-05-31 EP EP86107408A patent/EP0205995B1/fr not_active Expired - Lifetime
- 1986-06-16 BR BR8602797A patent/BR8602797A/pt not_active IP Right Cessation
- 1986-06-20 JP JP61143120A patent/JPS61296093A/ja active Pending
-
1989
- 1989-06-23 US US07/371,688 patent/US5049292A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2801087A1 (de) * | 1977-01-14 | 1978-07-27 | Idemitsu Kosan Co | Oelzusammensetzung fuer kuehlaggregate |
US4199461A (en) * | 1977-02-14 | 1980-04-22 | Chevron Research Company | Refrigeration oil containing wear-inhibiting amounts of an aryl phosphate-fatty acid combination |
Non-Patent Citations (2)
Title |
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ASHRAE GUIDE AND DATA BOOK, 1969, Abschnitt 23, Seite 281 * |
REFRIGERATING ENGINEERING, Juli 1952, Seiten 737-743,782; H.M. ELSEY et al.: "A method of evaluating refrigerator oils" * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0336171A1 (fr) * | 1988-04-06 | 1989-10-11 | Nippon Oil Co. Ltd. | Utilisation de compositions d'huile lubrifiante pour réfrigérateurs |
EP0384724A1 (fr) * | 1989-02-22 | 1990-08-29 | Nippon Oil Co. Ltd. | Procédé de lubrification d'appareils réfrigérants |
EP0693546A1 (fr) * | 1994-07-19 | 1996-01-24 | NIPPON OIL Co. Ltd. | Composition d'huile et de fluide pour réfrigérateur |
US6207071B1 (en) | 1994-07-19 | 2001-03-27 | Nippon Mitsubishi Oil Corporation | Fluid composition comprising HFC refrigerant and alkylbenzene-based refrigerator oil |
Also Published As
Publication number | Publication date |
---|---|
BR8602797A (pt) | 1987-02-10 |
EP0205995A3 (en) | 1987-10-14 |
DE3522165C1 (de) | 1986-10-30 |
DE3683409D1 (de) | 1992-02-27 |
JPS61296093A (ja) | 1986-12-26 |
EP0205995B1 (fr) | 1992-01-15 |
US5049292A (en) | 1991-09-17 |
ATE71651T1 (de) | 1992-02-15 |
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