EP0205995A2 - Lubrifiant et utilisation de celui-ci - Google Patents

Lubrifiant et utilisation de celui-ci Download PDF

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Publication number
EP0205995A2
EP0205995A2 EP19860107408 EP86107408A EP0205995A2 EP 0205995 A2 EP0205995 A2 EP 0205995A2 EP 19860107408 EP19860107408 EP 19860107408 EP 86107408 A EP86107408 A EP 86107408A EP 0205995 A2 EP0205995 A2 EP 0205995A2
Authority
EP
European Patent Office
Prior art keywords
lubricant
total weight
oils
amount
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19860107408
Other languages
German (de)
English (en)
Other versions
EP0205995A3 (en
EP0205995B1 (fr
Inventor
Hans Dieter Grasshoff
Vladislav Synek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wintershall Dea International AG
Original Assignee
RWE Dea AG fuer Mineraloel und Chemie
Texaco Services Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RWE Dea AG fuer Mineraloel und Chemie, Texaco Services Europe GmbH filed Critical RWE Dea AG fuer Mineraloel und Chemie
Priority to AT86107408T priority Critical patent/ATE71651T1/de
Publication of EP0205995A2 publication Critical patent/EP0205995A2/fr
Publication of EP0205995A3 publication Critical patent/EP0205995A3/de
Application granted granted Critical
Publication of EP0205995B1 publication Critical patent/EP0205995B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02Petroleum fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02Well-defined hydrocarbons
    • C10M105/06Well-defined hydrocarbons aromatic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M155/00Lubricating compositions characterised by the additive being a macromolecular compound containing atoms of elements not provided for in groups C10M143/00 - C10M153/00
    • C10M155/02Monomer containing silicon
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/008Lubricant compositions compatible with refrigerants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • C10M2203/065Well-defined aromatic compounds used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • C10M2203/1025Aliphatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
    • C10M2203/1045Aromatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • C10M2203/1065Naphthenic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
    • C10M2203/1085Residual fractions, e.g. bright stocks used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/042Metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/06Instruments or other precision apparatus, e.g. damping fluids

Definitions

  • lubricants are particularly suitable for refrigeration machines, heat pumps and related systems such as air conditioning systems. They can also be used as compressor and hydraulic oils.
  • Lubricants for refrigerating machine oils still mainly consist of highly refined mineral oils, which are dewaxed to improve the flow properties in the cold beyond what is customary for lubricating oils.
  • Pour points customary for chillers are in a range from -50 ° C to -25 ° C, depending on viscosity, and the cold pour points according to DIN 51568 are in a range between -16 ° C and -38 ° C.
  • the temperature at which flocculation of paraffin crystals occurs - important for the proper functioning of the lubricant - is also reduced by the additional dewaxing.
  • the mineral oils suitable for the production of refrigerating machine oils are obtained according to the known methods by distilling crude oils with subsequent refining (Ullmanns Encyklopadie der Technische Chemie, 4th edition, volume 20, pages 484 ff.). Depending on the origin of the crude oil, so-called paraffin-based or naphthenic-based lubricating oils are obtained.
  • Paraffin-based lubricating oils mainly contain paraffinic molecules, naphthenic-based predominantly naphthenic or cycloparaffinic molecules.
  • naphthenic oils are preferred for the production of refrigeration oils.
  • Refrigeration oils based on mineral oils usually contain no additives. Although attempts have often been made to improve the properties of the oils with the aid of additives, the success has so far been poor (ASHRAE Guide and Data Book 1969, section 23, page 281).
  • alkylbenzenes used come from the known syntheses according to Friedel-Crafts by alkylation of benzene with alkyl chlorides or olefins (Ullmann, 4th edition, volume 14, pages 672 ff.).
  • ⁇ -olefins which are produced by ethylene oligomerization or by cracking paraffins according to different processes, serve as raw material for the production of polymer oils (Ullmann, 4th edition, volume 14, pages 664 ff.).
  • these d-olefins are polymerized and hydrogenated ("Synthetic Poly- ⁇ -olefin Lubricants Today and Tomorrow", M.Campen, DFKendrick, ADMarkin, and Ullmann, 4th Edition, Volume 20, pages 505 ff.) .
  • the invention has for its object to provide lubricating oils with increased lubricating properties with improved low-temperature behavior and improved thermal stability and low foaming tendency.
  • the substituted phosphite can be, for example, a trinonylphenyl phosphite, triphenyl phosphite, dodecyl diphenyl phosphite, dioctylphenyl phosphite, tridodecyl phosphite, didecylphenyl phosphite.
  • the phosphites of medium molecular size such as, for example, dodecyl diphenyl phosphite or triphenyl phosphite are preferably used.
  • organic phosphates examples include diphenyl cresyl phosphate and other alkyl, aryl or alkylaryl derivatives of cresyl phosphate.
  • Trialkylaryl phosphates such as, for example, triisopropylphenyl phosphate or tricresyl phosphate are preferably used.
  • a methyl silicone is preferred as the silicone. It only serves to reduce foaming.
  • a coil of 0.1 mm copper wire and an approximately 15 mm long steel wire - 1.6 DIN 177-D5-1 - were inserted into glasses prepared in this way, 0.3 to 0.4 g of lubricant were weighed in and in a special device under vacuum and freezing added about the same amount of Freon refrigerant. Before the latter step, all gases were removed from the weighed oil by means of a vacuum. With the addition of nitrogen, the glasses were welded after the addition of the refrigerant. The glasses were then heated to the test temperature in a drying cabinet for a predetermined period. The test temperature was 175 ° C or 200 ° C, the test duration between 336 and 1008 hours (2 to 6 weeks).
  • alkylbenzene / mineral oil mixture (ratio 1: 1) was used as the base oil, viscosity class ISO 32, the alkylbenzene containing straight-chain C 10 -C 12 alkyls and the mineral oil component consisting of highly refined naphthenic-based oil. 1% of an isopropylated triphenyl phosphate with an average isopropyl content of 1.5 moles per mole of triphenyl phosphate and 0.005% methyl silicone was added.
  • Base oil from alkylbenzene with branched alkyl groups made from the reaction of benzene with tetrapropylene), viscosity class ISO 32, with the addition of 1% triisopropylphenyl phosphate and 0.005% methyl silicone.
  • Base oil from alkylbenzene with straight-chain alkyl groups viscosity class ISO 68, with the addition of 1% triisopropylphenyl phosphate and 0.005% methyl silicone.
  • Base oil from a mixture of poly- ⁇ -olefins, viscosity class ISO 68, with the addition of 1% triisopropylphenyl phosphate and 0.005% methyl silicone.
  • Base oil made from highly refined naphthenic mineral oil, viscosity class ISO 46, with the addition of 1% triisopropylphenyl phosphate and 0.005% methyl silicone.
  • the examples show a clear qualitative improvement in the refrigerating machine oils of the lubricants according to the invention with regard to oxidation and heat stability compared to the comparative examples.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
EP86107408A 1985-06-21 1986-05-31 Lubrifiant et utilisation de celui-ci Expired - Lifetime EP0205995B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86107408T ATE71651T1 (de) 1985-06-21 1986-05-31 Schmiermittel und anwendung desselben.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3522165 1985-06-21
DE3522165A DE3522165C1 (de) 1985-06-21 1985-06-21 Schmiermittel und ihre Verwendung

Publications (3)

Publication Number Publication Date
EP0205995A2 true EP0205995A2 (fr) 1986-12-30
EP0205995A3 EP0205995A3 (en) 1987-10-14
EP0205995B1 EP0205995B1 (fr) 1992-01-15

Family

ID=6273787

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86107408A Expired - Lifetime EP0205995B1 (fr) 1985-06-21 1986-05-31 Lubrifiant et utilisation de celui-ci

Country Status (6)

Country Link
US (1) US5049292A (fr)
EP (1) EP0205995B1 (fr)
JP (1) JPS61296093A (fr)
AT (1) ATE71651T1 (fr)
BR (1) BR8602797A (fr)
DE (2) DE3522165C1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0336171A1 (fr) * 1988-04-06 1989-10-11 Nippon Oil Co. Ltd. Utilisation de compositions d'huile lubrifiante pour réfrigérateurs
EP0384724A1 (fr) * 1989-02-22 1990-08-29 Nippon Oil Co. Ltd. Procédé de lubrification d'appareils réfrigérants
EP0693546A1 (fr) * 1994-07-19 1996-01-24 NIPPON OIL Co. Ltd. Composition d'huile et de fluide pour réfrigérateur

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JPH0645795B2 (ja) * 1986-09-05 1994-06-15 株式会社松村石油研究所 潤滑油添加剤組成物及びこれを含有する潤滑油組成物
JP2590143B2 (ja) * 1987-10-28 1997-03-12 出光興産株式会社 水素含有フロン冷媒用潤滑油組成物
KR930010525B1 (ko) * 1987-10-28 1993-10-25 이데미쓰 고산 가부시끼가이샤 수소함유 플론냉매용 윤활유와 조성물
US5185089A (en) * 1990-05-10 1993-02-09 Allied-Signal Inc. Lubricants useful with 1,1-dichloro-2,2,2-trifluoroethane
CA2060201A1 (fr) * 1990-05-17 1991-11-18 Scott T. Jolley Compositions phosphorees pour systemes de refrigeration
EP0496486B1 (fr) * 1991-01-11 1994-03-02 Mobil Oil Corporation Compositions de lubrifiant
JPH04332793A (ja) * 1991-05-07 1992-11-19 Sanyo Electric Co Ltd 冷凍機油組成物
JP3142321B2 (ja) * 1991-09-03 2001-03-07 日石三菱株式会社 冷凍機油組成物
TW203098B (fr) * 1991-09-27 1993-04-01 Mitsui Petroleum Chemicals Ind
US5518643A (en) * 1992-06-04 1996-05-21 Idemitsu Kosan Co., Ltd. Lubricating oil containing a polyvinyl ether compound for compression-type refrigerators
US5792733A (en) * 1997-08-14 1998-08-11 The Lubrizol Corporation Antiwear compositions containing phosphorus compounds and olefins
US6191078B1 (en) 1999-09-21 2001-02-20 Exxonmobil Research And Engineering Company Part-synthetic, aviation piston engine lubricant
KR100562911B1 (ko) 2004-11-24 2006-03-22 화천기공 주식회사 고속 주축 베어링 윤활 조성물
JP4809607B2 (ja) * 2005-01-11 2011-11-09 Jx日鉱日石エネルギー株式会社 組付け油、並びに冷凍空調機器の構成部品の組付け方法
EP1690920A1 (fr) * 2005-02-11 2006-08-16 JohnsonDiversey, Inc. Concentrat de lubrifiant contentant un triester phosphorique
JP7518718B2 (ja) * 2020-09-30 2024-07-18 出光興産株式会社 冷凍機油組成物、冷媒潤滑油混合組成物及び冷蔵庫

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DE2801087A1 (de) * 1977-01-14 1978-07-27 Idemitsu Kosan Co Oelzusammensetzung fuer kuehlaggregate
US4199461A (en) * 1977-02-14 1980-04-22 Chevron Research Company Refrigeration oil containing wear-inhibiting amounts of an aryl phosphate-fatty acid combination

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GB548390A (en) * 1941-04-04 1942-10-08 William Helmore Improvements in or relating to lubricating compositions
US3280031A (en) * 1963-12-31 1966-10-18 Mobil Oil Corp High temperature lubricating oils
US3459660A (en) * 1966-10-14 1969-08-05 Texaco Inc Lubricating oil composition
GB1413105A (en) * 1971-09-02 1975-11-05 Ici Ltd Hydraulic fluid compositions
US4033887A (en) * 1973-07-13 1977-07-05 Labofina S.A. Phosphoric acid ester based functional fluids
US4072027A (en) * 1977-01-19 1978-02-07 Allied Chemical Corporation Stabilized heat activated heat exchange absorption pair
US4116877A (en) * 1977-07-08 1978-09-26 Exxon Research & Engineering Co. Elastomer compatible seal swell additive for automatic transmission fluids, power transmission fluids and hydraulic steering applications
IL56876A0 (en) * 1978-05-15 1979-05-31 Stauffer Chemical Co Method for the color improvement of alkylphenyl phosphate esters
JPS57124664A (en) * 1981-01-28 1982-08-03 Hitachi Ltd Absorbing liquid for absorption type refrigerating machine
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DE2801087A1 (de) * 1977-01-14 1978-07-27 Idemitsu Kosan Co Oelzusammensetzung fuer kuehlaggregate
US4199461A (en) * 1977-02-14 1980-04-22 Chevron Research Company Refrigeration oil containing wear-inhibiting amounts of an aryl phosphate-fatty acid combination

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ASHRAE GUIDE AND DATA BOOK, 1969, Abschnitt 23, Seite 281 *
REFRIGERATING ENGINEERING, Juli 1952, Seiten 737-743,782; H.M. ELSEY et al.: "A method of evaluating refrigerator oils" *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0336171A1 (fr) * 1988-04-06 1989-10-11 Nippon Oil Co. Ltd. Utilisation de compositions d'huile lubrifiante pour réfrigérateurs
EP0384724A1 (fr) * 1989-02-22 1990-08-29 Nippon Oil Co. Ltd. Procédé de lubrification d'appareils réfrigérants
EP0693546A1 (fr) * 1994-07-19 1996-01-24 NIPPON OIL Co. Ltd. Composition d'huile et de fluide pour réfrigérateur
US6207071B1 (en) 1994-07-19 2001-03-27 Nippon Mitsubishi Oil Corporation Fluid composition comprising HFC refrigerant and alkylbenzene-based refrigerator oil

Also Published As

Publication number Publication date
BR8602797A (pt) 1987-02-10
EP0205995A3 (en) 1987-10-14
DE3522165C1 (de) 1986-10-30
DE3683409D1 (de) 1992-02-27
JPS61296093A (ja) 1986-12-26
EP0205995B1 (fr) 1992-01-15
US5049292A (en) 1991-09-17
ATE71651T1 (de) 1992-02-15

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