EP0205995A3 - Lubricant and its use - Google Patents

Lubricant and its use Download PDF

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Publication number
EP0205995A3
EP0205995A3 EP86107408A EP86107408A EP0205995A3 EP 0205995 A3 EP0205995 A3 EP 0205995A3 EP 86107408 A EP86107408 A EP 86107408A EP 86107408 A EP86107408 A EP 86107408A EP 0205995 A3 EP0205995 A3 EP 0205995A3
Authority
EP
European Patent Office
Prior art keywords
oils
stability
organic
heat
silicones
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86107408A
Other languages
German (de)
Other versions
EP0205995B1 (en
EP0205995A2 (en
Inventor
Hans Dieter Grasshoff
Vladislav Synek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wintershall Dea International AG
Original Assignee
Texaco Technology Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Technology Europe GmbH filed Critical Texaco Technology Europe GmbH
Priority to AT86107408T priority Critical patent/ATE71651T1/en
Publication of EP0205995A2 publication Critical patent/EP0205995A2/en
Publication of EP0205995A3 publication Critical patent/EP0205995A3/en
Application granted granted Critical
Publication of EP0205995B1 publication Critical patent/EP0205995B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02Petroleum fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02Well-defined hydrocarbons
    • C10M105/06Well-defined hydrocarbons aromatic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M155/00Lubricating compositions characterised by the additive being a macromolecular compound containing atoms of elements not provided for in groups C10M143/00 - C10M153/00
    • C10M155/02Monomer containing silicon
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/008Lubricant compositions compatible with refrigerants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06Well-defined aromatic compounds
    • C10M2203/065Well-defined aromatic compounds used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • C10M2203/1025Aliphatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
    • C10M2203/1045Aromatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • C10M2203/1065Naphthenic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
    • C10M2203/1085Residual fractions, e.g. bright stocks used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/041Triaryl phosphates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/042Metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/06Instruments or other precision apparatus, e.g. damping fluids

Abstract

Base oils can be substantially improved with respect to their oxidation stability and heat stability by the addition of additive combinations consisting of organic phosphates and organic phosphites as well as, if appropriate, silicones. <??>These lubricants are particularly suitable for refrigeration machines, heat pumps and similar installations, such as air-conditioning units. They can also be used as compressor oils and hydraulic oils.
EP86107408A 1985-06-21 1986-05-31 Lubricant and its use Expired - Lifetime EP0205995B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86107408T ATE71651T1 (en) 1985-06-21 1986-05-31 LUBRICANTS AND APPLICATION OF SAME.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3522165A DE3522165C1 (en) 1985-06-21 1985-06-21 Lubricants and their use
DE3522165 1985-06-21

Publications (3)

Publication Number Publication Date
EP0205995A2 EP0205995A2 (en) 1986-12-30
EP0205995A3 true EP0205995A3 (en) 1987-10-14
EP0205995B1 EP0205995B1 (en) 1992-01-15

Family

ID=6273787

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86107408A Expired - Lifetime EP0205995B1 (en) 1985-06-21 1986-05-31 Lubricant and its use

Country Status (6)

Country Link
US (1) US5049292A (en)
EP (1) EP0205995B1 (en)
JP (1) JPS61296093A (en)
AT (1) ATE71651T1 (en)
BR (1) BR8602797A (en)
DE (2) DE3522165C1 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0645795B2 (en) * 1986-09-05 1994-06-15 株式会社松村石油研究所 Lubricating oil additive composition and lubricating oil composition containing the same
KR930010525B1 (en) * 1987-10-28 1993-10-25 이데미쓰 고산 가부시끼가이샤 Lubricating oil composition for hydrogen-containing fluorocarbon refrigerant
JP2590143B2 (en) * 1987-10-28 1997-03-12 出光興産株式会社 Lubricating oil composition for hydrogen-containing Freon refrigerant
ES2058368T3 (en) * 1988-04-06 1994-11-01 Nippon Oil Co Ltd LUBRICATING OIL COMPOSITIONS FOR REFRIGERATORS.
JP2588287B2 (en) * 1989-02-22 1997-03-05 日本石油株式会社 Refrigeration oil composition
US5185089A (en) * 1990-05-10 1993-02-09 Allied-Signal Inc. Lubricants useful with 1,1-dichloro-2,2,2-trifluoroethane
AU656895B2 (en) * 1990-05-17 1995-02-23 Lubrizol Corporation, The Phosphorus-containing compositions for refrigeration systems
EP0496486B1 (en) * 1991-01-11 1994-03-02 Mobil Oil Corporation Lubricant compositions
JPH04332793A (en) * 1991-05-07 1992-11-19 Sanyo Electric Co Ltd Refrigerating machine oil composition
JP3142321B2 (en) * 1991-09-03 2001-03-07 日石三菱株式会社 Refrigeration oil composition
TW203098B (en) * 1991-09-27 1993-04-01 Mitsui Petroleum Chemicals Ind
US5518643A (en) * 1992-06-04 1996-05-21 Idemitsu Kosan Co., Ltd. Lubricating oil containing a polyvinyl ether compound for compression-type refrigerators
CA2154109C (en) * 1994-07-19 2004-06-29 Katsuya Takigawa Fluid compositon comprising hfc refrigerant and alkylbenzene-based refrigerator oil
US5792733A (en) * 1997-08-14 1998-08-11 The Lubrizol Corporation Antiwear compositions containing phosphorus compounds and olefins
US6191078B1 (en) 1999-09-21 2001-02-20 Exxonmobil Research And Engineering Company Part-synthetic, aviation piston engine lubricant
KR100562911B1 (en) 2004-11-24 2006-03-22 화천기공 주식회사 Lubricant composition for high speed spindle bearing
JP4809607B2 (en) * 2005-01-11 2011-11-09 Jx日鉱日石エネルギー株式会社 Assembly oil and method of assembling components of refrigeration and air conditioning equipment
EP1690920A1 (en) * 2005-02-11 2006-08-16 JohnsonDiversey, Inc. Lubricant concentrate containing a phosphate triester
JP2022057190A (en) * 2020-09-30 2022-04-11 出光興産株式会社 Refrigerating machine oil composition, refrigerant lubricating oil-mixed composition, and refrigerator

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2801087A1 (en) * 1977-01-14 1978-07-27 Idemitsu Kosan Co Oil compsn. for cooling systems contg. phosphite tri-ester - preventing carbon deposits on valves in systems having compressor and reducing corrosion (NL 18.7.78)
US4199461A (en) * 1977-02-14 1980-04-22 Chevron Research Company Refrigeration oil containing wear-inhibiting amounts of an aryl phosphate-fatty acid combination

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB548390A (en) * 1941-04-04 1942-10-08 William Helmore Improvements in or relating to lubricating compositions
US3280031A (en) * 1963-12-31 1966-10-18 Mobil Oil Corp High temperature lubricating oils
US3459660A (en) * 1966-10-14 1969-08-05 Texaco Inc Lubricating oil composition
GB1413105A (en) * 1971-09-02 1975-11-05 Ici Ltd Hydraulic fluid compositions
US4033887A (en) * 1973-07-13 1977-07-05 Labofina S.A. Phosphoric acid ester based functional fluids
US4072027A (en) * 1977-01-19 1978-02-07 Allied Chemical Corporation Stabilized heat activated heat exchange absorption pair
US4116877A (en) * 1977-07-08 1978-09-26 Exxon Research & Engineering Co. Elastomer compatible seal swell additive for automatic transmission fluids, power transmission fluids and hydraulic steering applications
IL56876A0 (en) * 1978-05-15 1979-05-31 Stauffer Chemical Co Method for the color improvement of alkylphenyl phosphate esters
JPS57124664A (en) * 1981-01-28 1982-08-03 Hitachi Ltd Absorbing liquid for absorption type refrigerating machine
DE3265173D1 (en) * 1981-04-07 1985-09-12 Matsushita Electric Ind Co Ltd Composition for absorption refrigeration

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2801087A1 (en) * 1977-01-14 1978-07-27 Idemitsu Kosan Co Oil compsn. for cooling systems contg. phosphite tri-ester - preventing carbon deposits on valves in systems having compressor and reducing corrosion (NL 18.7.78)
US4199461A (en) * 1977-02-14 1980-04-22 Chevron Research Company Refrigeration oil containing wear-inhibiting amounts of an aryl phosphate-fatty acid combination

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ASHRAE GUIDE AND DATA BOOK, 1969, Abschnitt 23, Seite 281 *
REFRIGERATING ENGINEERING, Juli 1952, Seiten 737-743,782; H.M. ELSEY et al.: "A method of evaluating refrigerator oils" *

Also Published As

Publication number Publication date
ATE71651T1 (en) 1992-02-15
DE3522165C1 (en) 1986-10-30
EP0205995B1 (en) 1992-01-15
BR8602797A (en) 1987-02-10
US5049292A (en) 1991-09-17
EP0205995A2 (en) 1986-12-30
DE3683409D1 (en) 1992-02-27
JPS61296093A (en) 1986-12-26

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