DE69821511D1 - Ethylen-kopolymer-mischungen mit enger molekulargewichtsverteilung und optimierter zusammensetzung, verfahren zu ihrer herstellung und ihre verwendung - Google Patents

Ethylen-kopolymer-mischungen mit enger molekulargewichtsverteilung und optimierter zusammensetzung, verfahren zu ihrer herstellung und ihre verwendung

Info

Publication number
DE69821511D1
DE69821511D1 DE69821511T DE69821511T DE69821511D1 DE 69821511 D1 DE69821511 D1 DE 69821511D1 DE 69821511 T DE69821511 T DE 69821511T DE 69821511 T DE69821511 T DE 69821511T DE 69821511 D1 DE69821511 D1 DE 69821511D1
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DE
Germany
Prior art keywords
ethylene
production
molecular weight
weight distribution
narrow molecular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69821511T
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English (en)
Other versions
DE69821511T2 (de
Inventor
Pradeep Jain
G Hazlitt
A Degroot
W Anderson
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Dow Global Technologies LLC
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Dow Chemical Co
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Filing date
Publication date
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Publication of DE69821511D1 publication Critical patent/DE69821511D1/de
Publication of DE69821511T2 publication Critical patent/DE69821511T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00Chemical blending or stepwise polymerisation process with the same catalyst
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Bag Frames (AREA)
  • Laminated Bodies (AREA)
  • Polymerisation Methods In General (AREA)
DE69821511T 1997-09-19 1998-09-18 Ethylen-kopolymer-mischungen mit enger molekulargewichtsverteilung und optimierter zusammensetzung, verfahren zu ihrer herstellung und ihre verwendung Expired - Lifetime DE69821511T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US5955597P 1997-09-19 1997-09-19
US59555P 1997-09-19
PCT/US1998/019568 WO1999014271A1 (en) 1997-09-19 1998-09-18 Narrow mwd, compositionally optimized ethylene interpolymer composition, process for making the same and article made therefrom

Publications (2)

Publication Number Publication Date
DE69821511D1 true DE69821511D1 (de) 2004-03-11
DE69821511T2 DE69821511T2 (de) 2004-07-08

Family

ID=22023739

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69821511T Expired - Lifetime DE69821511T2 (de) 1997-09-19 1998-09-18 Ethylen-kopolymer-mischungen mit enger molekulargewichtsverteilung und optimierter zusammensetzung, verfahren zu ihrer herstellung und ihre verwendung

Country Status (20)

Country Link
US (3) US6469103B1 (de)
EP (1) EP1023390B1 (de)
JP (1) JP2003517487A (de)
KR (1) KR20010024063A (de)
CN (1) CN1270611A (de)
AR (1) AR012518A1 (de)
AT (1) ATE258958T1 (de)
AU (1) AU9571098A (de)
BR (1) BR9812478A (de)
CA (1) CA2304220C (de)
DE (1) DE69821511T2 (de)
ES (1) ES2212348T3 (de)
HU (1) HUP0004649A3 (de)
ID (1) ID24895A (de)
NO (1) NO20001408L (de)
PL (1) PL339665A1 (de)
TR (1) TR200000691T2 (de)
TW (1) TW461906B (de)
WO (1) WO1999014271A1 (de)
ZA (1) ZA988572B (de)

Families Citing this family (168)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6506866B2 (en) * 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
JPH09309926A (ja) * 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
US6812289B2 (en) * 1996-12-12 2004-11-02 Dow Global Technologies Inc. Cast stretch film of interpolymer compositions
ZA986434B (en) 1997-07-21 2000-01-20 Dow Chemical Co Broad mwd, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom.
DE69828975T2 (de) 1997-08-15 2006-01-12 Dow Global Technologies, Inc., Midland Filme aus im wesentlichen homogenen linearen olefinischen polymerzusammensetzungen
CN1270611A (zh) 1997-09-19 2000-10-18 陶氏化学公司 组成上优化的窄分子量分布的乙烯共聚物组合物及其制备方法和所得制品
GB0016153D0 (en) * 2000-06-30 2000-08-23 Borealis Tech Oy Process
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
WO2004000919A1 (en) * 2001-07-19 2003-12-31 Univation Technologies, Llc Polyethylene films with improved physical properties
JP5153989B2 (ja) * 2001-08-17 2013-02-27 ダウ グローバル テクノロジーズ エルエルシー 双峰性ポリエチレン組成物及び該組成物から製造される製品
PL203162B1 (pl) 2001-08-31 2009-08-31 Dow Global Technologies Inc Żywica polietylenowa o wielomodalnym rozkładzie ciężaru cząsteczkowego, kompozycja polimeryczna zawierająca tę żywicę i zastosowanie wielomodalnej żywicy polietylenowej
CA2411183C (en) * 2002-11-05 2011-06-14 Nova Chemicals Corporation Heterogeneous/homogeneous copolymer
JP4260501B2 (ja) * 2003-02-07 2009-04-30 株式会社プライムポリマー 二軸延伸用ポリエチレン系樹脂組成物および延伸フィルム
JP5207628B2 (ja) * 2003-12-18 2013-06-12 ダウ グローバル テクノロジーズ エルエルシー 高ひずみ速度下における優れた衝撃抵抗および改善された突発的破壊抵抗を持つフィルム
US8273826B2 (en) 2006-03-15 2012-09-25 Dow Global Technologies Llc Impact modification of thermoplastics with ethylene/α-olefin interpolymers
US8273838B2 (en) * 2004-03-17 2012-09-25 Dow Global Technologies Llc Propylene/α-olefins block interpolymers
US7714071B2 (en) * 2004-03-17 2010-05-11 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom
US7671106B2 (en) * 2004-03-17 2010-03-02 Dow Global Technologies Inc. Cap liners, closures and gaskets from multi-block polymers
US7622179B2 (en) * 2004-03-17 2009-11-24 Dow Global Technologies Inc. Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof
US7662881B2 (en) * 2004-03-17 2010-02-16 Dow Global Technologies Inc. Viscosity index improver for lubricant compositions
US7579408B2 (en) 2004-03-17 2009-08-25 Dow Global Technologies Inc. Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins
US7795321B2 (en) * 2004-03-17 2010-09-14 Dow Global Technologies Inc. Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom
CA2557870A1 (en) * 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
US7803728B2 (en) * 2004-03-17 2010-09-28 Dow Global Technologies Inc. Fibers made from copolymers of ethylene/α-olefins
US7666918B2 (en) * 2004-03-17 2010-02-23 Dow Global Technologies, Inc. Foams made from interpolymers of ethylene/α-olefins
US7622529B2 (en) * 2004-03-17 2009-11-24 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility
US7741397B2 (en) * 2004-03-17 2010-06-22 Dow Global Technologies, Inc. Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof
US7355089B2 (en) * 2004-03-17 2008-04-08 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7582716B2 (en) * 2004-03-17 2009-09-01 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack
US7608668B2 (en) * 2004-03-17 2009-10-27 Dow Global Technologies Inc. Ethylene/α-olefins block interpolymers
AR053693A1 (es) * 2004-03-17 2007-05-16 Dow Global Technologies Inc Composiciones de interpolimero de etileno/alfa-olefina multibloque adecuado para peliculas
US7863379B2 (en) * 2004-03-17 2011-01-04 Dow Global Technologies Inc. Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers
CN1976965B (zh) * 2004-03-17 2012-10-10 陶氏环球技术有限责任公司 用于形成乙烯多嵌段共聚物的包含梭移剂的催化剂组合物
US7671131B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom
US7687442B2 (en) * 2004-03-17 2010-03-30 Dow Global Technologies Inc. Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils
SG183748A1 (en) 2004-03-17 2012-09-27 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
US7897689B2 (en) * 2004-03-17 2011-03-01 Dow Global Technologies Inc. Functionalized ethylene/α-olefin interpolymer compositions
JP2008516068A (ja) 2004-10-13 2008-05-15 エクソンモービル・ケミカル・パテンツ・インク エラストマー性反応ブレンド組成物
WO2006065651A2 (en) 2004-12-17 2006-06-22 Dow Global Technologies Inc. Rheology modified polyethylene compositions
EP1674504A1 (de) * 2004-12-22 2006-06-28 Total Petrochemicals Research Feluy Geo-Membran-Anwendungen
AU2006227348A1 (en) * 2005-03-17 2006-09-28 Dow Global Technologies Inc. Adhesive and marking compositions made from interpolymers of ethylene/alpha-olefins
CA2600140A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
BRPI0609851B1 (pt) * 2005-03-17 2016-12-13 Dow Global Technologies Inc fibra obtenível de ou compreendendo um interpolímero de etileno/(alfa)-olefina, fibra obtenível de ou compreendendo pelo menos um interpolímero de etileno e uma (alfa)-olefina de c3-c20, pano, fio e método para fabricar uma fibra ou pano
US8084537B2 (en) * 2005-03-17 2011-12-27 Dow Global Technologies Llc Polymer blends from interpolymers of ethylene/α-olefin with improved compatibility
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
CA2600318A1 (en) * 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for regio-irregular multi-block copolymer formation
KR101425227B1 (ko) 2005-03-17 2014-07-31 다우 글로벌 테크놀로지스 엘엘씨 탄성 필름 및 라미네이트용의 에틸렌/α―올레핀 멀티블록혼성중합체 조성물
KR101172563B1 (ko) * 2005-06-29 2012-08-08 토요 보세키 가부시기가이샤 폴리에틸렌계 수지 적층 필름
EP1940897B1 (de) 2005-09-15 2014-05-07 Dow Global Technologies LLC Steuerung von polymerarchitektur und molekulargewichtsverteilung mit hilfe eines mehrzentrigen shuttling-mittels
US7858707B2 (en) 2005-09-15 2010-12-28 Dow Global Technologies Inc. Catalytic olefin block copolymers via polymerizable shuttling agent
EP1951511B1 (de) * 2005-10-26 2018-09-12 Dow Global Technologies LLC Mehrlägige elastische artikel
US7538173B2 (en) * 2005-11-21 2009-05-26 Equistar Chemicals Lp Polyolefin compositions
BRPI0620542A2 (pt) 2005-11-23 2011-11-16 Dow Global Technologies Inc copolìmero compreendendo etileno interpolimerizado com pelo menos uma (alfa)-olefina c3-10 e mistura de polìmeros
WO2007067965A2 (en) * 2005-12-09 2007-06-14 Dow Global Technologies Inc. Processes of controlling molecular weight distribution in ethylene/alpha-olefin compositions
US8153243B2 (en) * 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
ATE461242T1 (de) 2006-05-02 2010-04-15 Dow Global Technologies Inc Hochdichte polyethylenzusammensetzungen, verfahren zu deren herstellung, daraus hergestellte artikel und verfahren zur herstellung derartiger artikel
EP2024400B1 (de) * 2006-05-17 2012-09-12 Dow Global Technologies LLC Hocheffizientes lösungspolymerisierungsverfahren
US7456244B2 (en) 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US20080081854A1 (en) * 2006-09-06 2008-04-03 Dow Global Technologies Inc. Fibers and Knit Fabrics Comprising Olefin Block Interpolymers
ES2389876T3 (es) 2006-10-23 2012-11-02 Dow Global Technologies Inc. Método para fabricar composicones de polietileno
CN101589081A (zh) 2006-11-30 2009-11-25 陶氏环球技术公司 具有抗皱性的弹力织物和衣物
AU2007325009A1 (en) * 2006-11-30 2008-06-05 Dow Global Technologies Inc. Olefin block compositions for heavy weight stretch fabrics
CA2671259A1 (en) * 2006-11-30 2008-06-05 Dow Global Technologies Inc. Molded fabric articles of olefin block interpolymers
KR20090108598A (ko) * 2007-01-16 2009-10-15 다우 글로벌 테크놀로지스 인크. 올레핀 블록 조성물의 콘 염색사
WO2008089220A2 (en) * 2007-01-16 2008-07-24 Dow Global Technologies Inc. Colorfast fabrics and garments of olefin block compositions
CA2675099A1 (en) * 2007-01-16 2008-07-24 Dow Global Technologies Inc. Stretch fabrics and garments of olefin block polymers
EP2137244B1 (de) * 2007-04-10 2016-10-05 Dow Global Technologies LLC Polyethylenfilme und verfahren zu ihrer herstellung
ITMI20070877A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari
ITMI20070878A1 (it) 2007-05-02 2008-11-03 Dow Global Technologies Inc Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali
ATE450569T1 (de) 2007-05-02 2009-12-15 Dow Global Technologies Inc Hochdichte polyethylenzusammensetzungen, verfahren zu deren herstellung, daraus hergestellte einspritzgeformte artikel und verfahren zur herstellung derartiger artikel
ATE506406T1 (de) * 2007-06-13 2011-05-15 Dow Global Technologies Llc Polyethylenzusammensetzungen, herstellungsverfahren dafür und gegenstände daraus
JP2010533246A (ja) * 2007-07-09 2010-10-21 ダウ グローバル テクノロジーズ インコーポレイティド 繊維に適するオレフィンブロックインターポリマー組成物
WO2009042602A1 (en) * 2007-09-28 2009-04-02 Dow Global Technologies Inc Thermoplastic olefin composition with improved heat distortion temperature
EP2052857A1 (de) * 2007-10-22 2009-04-29 Dow Global Technologies Inc. Mehrschichtige Folien
EP2055720A1 (de) * 2007-11-05 2009-05-06 Total Petrochemicals Research Feluy Modell zur Vorhersage der Dichte und des Schmelzindex eines einen Kreislaufreaktor verlassenden Polymers
RU2487015C2 (ru) 2008-01-29 2013-07-10 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Полиэтиленовые композиции, способ их получения, изготовленные из них изделия и способ изготовления указанных изделий
BRPI0913169B1 (pt) 2008-08-28 2019-09-10 Dow Global Technologies Llc processo para moldar um artigo por injeção e sopro e artigo
EP2177548A1 (de) 2008-10-14 2010-04-21 Ineos Europe Limited Copolymere und Folien daraus
KR101077071B1 (ko) 2008-11-03 2011-10-26 에스케이이노베이션 주식회사 내충격성이 우수한 에틸렌 공중합체
WO2010091256A1 (en) * 2009-02-06 2010-08-12 Dow Global Technologies Inc. Ethylene-based polymers and compositions, methods of making the same, and articles prepared therefrom
BRPI0923985B1 (pt) * 2009-03-31 2019-10-08 Dow Global Technologies Llc Película multicamada e artigo fabricado
EP2246369B1 (de) * 2009-04-30 2012-09-05 Borealis AG Geradkettiges Polyethylen niedriger Dichte mit gleichmäßiger oder umgekehrter Comonomerzusammensetzungsverteilung
US20110003940A1 (en) 2009-07-01 2011-01-06 Dow Global Technologies Inc. Ethylene-based polymer compositions for use as a blend component in shrinkage film applications
KR101688253B1 (ko) 2009-07-29 2016-12-20 다우 글로벌 테크놀로지스 엘엘씨 이중- 또는 다중-헤드 사슬 이동제 및 그의 블록 공중합체의 제조에서의 용도
BR112012003539A2 (pt) 2009-08-28 2017-05-23 Dow Global Technologies Llc artigo rotomoldado e processo para fabricar um artigo
US8476366B2 (en) * 2009-10-02 2013-07-02 Dow Global Technologies, Llc Block compositions in thermoplastic vulcanizate applications
EP2483352B1 (de) 2009-10-02 2018-11-21 Dow Global Technologies LLC Blockcopolymere in weichen verbindungen
EP2483348B2 (de) 2009-10-02 2019-11-27 Dow Global Technologies LLC Blockverbundstoffe und schlagzähmodifizierte zusammensetzungen
KR101795085B1 (ko) 2009-10-02 2017-11-07 다우 글로벌 테크놀로지스 엘엘씨 열가소성 가황물 응용에서의 블록 복합체
WO2011115702A1 (en) 2010-03-19 2011-09-22 Dow Global Technologies LLC (Formerly known as Dow Global Technologies Inc.) Bicomponent fibers
BR112012032980B1 (pt) 2010-06-21 2020-08-25 Dow Global Technologies Llc composição
US8822599B2 (en) 2010-06-21 2014-09-02 Dow Global Technologies Llc Crystalline block composites as compatibilizers
EP2582749B1 (de) 2010-06-21 2019-07-24 Dow Global Technologies LLC Kristalline blockverbundstoffe als kombatibilisatoren
BR112012032686B1 (pt) 2010-06-21 2021-01-05 Dow Global Technologies Llc composição
MY163384A (en) * 2010-09-29 2017-09-15 Dow Global Technologies Llc An ethylene/alpha-olefin interpolymer suitable for use in shrinkage film applications, and articles made therefrom
US8907030B2 (en) 2010-09-29 2014-12-09 Dow Global Technologies Llc Ethylene/alpha-olefin interpolymer suitable for use in fiber applications, and fibers made therefrom
CA2814899A1 (en) 2010-10-29 2012-05-03 Dow Global Technologies Llc Polyethylene-based oriented monofilaments and strips and method for the preparation thereof
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
EP2465877A1 (de) 2010-12-20 2012-06-20 Ineos Commercial Services UK Limited Verfahren
JP6457716B2 (ja) 2011-01-14 2019-01-23 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 修飾メタロセン触媒の作成法、生成された触媒およびそれらの使用
CA2734167C (en) 2011-03-15 2018-03-27 Nova Chemicals Corporation Polyethylene film
EP2714226B1 (de) 2011-06-03 2016-04-20 Dow Global Technologies LLC Chromatographie von polymeren
DK2729525T3 (da) 2011-07-08 2020-01-02 Total Res & Technology Feluy Metallocenkatalyseret polyethylen
ES2587441T3 (es) * 2011-08-26 2016-10-24 Dow Global Technologies Llc Película de polietileno biorientada
WO2013060902A1 (es) * 2011-10-24 2013-05-02 Dow Global Technologies Llc Hilo de césped artificial
US8781154B1 (en) * 2012-01-21 2014-07-15 Google Inc. Systems and methods facilitating random number generation for hashes in video and audio applications
CA2798855C (en) 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
WO2014052173A1 (en) 2012-09-28 2014-04-03 Dow Global Technologies Llc A composition, tape and composite pipe made therefrom and a method of producing composite pipe
BR112015006917A2 (pt) 2012-09-28 2019-12-10 Dow Global Technologies Llc composição, conector e processo para melhorar a ligação entre dois ou mais meios para transportar fluidos
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
US9181369B2 (en) 2013-03-11 2015-11-10 Chevron Phillips Chemical Company Lp Polymer films having improved heat sealing properties
US9815975B2 (en) 2013-03-25 2017-11-14 Dow Global Technologies Llc Film having good barrier properties together with good physical characteristics
MY197409A (en) 2013-09-30 2023-06-16 Dow Global Technologies Llc A process for increasing the melt strength of a polyethylene resin, a masterbatch composition and a polymeric composition
EP2860031B1 (de) * 2013-10-11 2016-03-30 Borealis AG In Maschinenrichtung ausgerichtete Folien für Etiketten
US20170152377A1 (en) * 2014-06-26 2017-06-01 Dow Global Technologies Llc Breathable films and articles incorporating same
CA2864573C (en) * 2014-09-22 2021-07-06 Nova Chemicals Corporation Shrink film from single site catalyzed polyethylene
CA2868640C (en) 2014-10-21 2021-10-26 Nova Chemicals Corporation Solution polymerization process
WO2016063205A2 (en) 2014-10-21 2016-04-28 Nova Chemicals (International) S.A. Dilution index
KR101847702B1 (ko) 2015-03-26 2018-04-10 주식회사 엘지화학 올레핀계 중합체
WO2017007640A1 (en) 2015-07-08 2017-01-12 Chevron Phillips Chemical Company Lp Ziegler-natta-metallocene dual catalyst systems with activator-supports
EP3345193B1 (de) 2015-09-02 2021-04-21 Dow Global Technologies LLC Flexible vernetzte kabelisolierung und verfahren zur herstellung einer flexiblen vernetzten kabelisolierung
BR112018003282B1 (pt) 2015-09-02 2022-07-12 Dow Global Technologies Llc Composição polimérica reticulável, composição polimérica reticulada e condutor revestido
JP6832348B2 (ja) 2015-09-30 2021-02-24 ダウ グローバル テクノロジーズ エルエルシー 連鎖シャトリングに有用な多頭性または二頭性組成物、及びそれを調製するためのプロセス
US10487200B2 (en) 2015-10-29 2019-11-26 Dow Global Technologies Llc Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation
WO2018005821A1 (en) 2016-06-30 2018-01-04 Dow Global Technologies Llc Procatalyst compositions useful for low comonomer incorporation and process for preparing the same
BR112018077415B1 (pt) 2016-06-30 2023-03-14 Dow Global Technologies Llc Processo para preparar uma composição de pró-catalisador e processo de solução para polimerização de etileno e pelo menos um monômero polimerizável adicional para formar uma composição de polímero
WO2018045559A1 (en) 2016-09-09 2018-03-15 Dow Global Technologies Llc Multilayer films and laminates and articles comprising the same
KR102086056B1 (ko) * 2016-09-23 2020-03-06 주식회사 엘지화학 폴리프로필렌계 수지 조성물
KR102086055B1 (ko) * 2016-09-23 2020-03-06 주식회사 엘지화학 폴리프로필렌계 수지 조성물
KR102083001B1 (ko) 2016-09-23 2020-02-28 주식회사 엘지화학 올레핀계 공중합체 및 이의 제조 방법
US11155650B2 (en) 2016-09-29 2021-10-26 Dow Global Technologies Llc Magnesium halide-supported titanium (pro)catalysts
JP7164519B2 (ja) 2016-09-29 2022-11-01 ダウ グローバル テクノロジーズ エルエルシー オレフィンを重合する方法
BR112019005532B1 (pt) 2016-09-29 2023-04-11 Dow Global Technologies Llc Sistema e (pró)catalisador de ziegler-natta modificado
CN109963888A (zh) 2016-09-30 2019-07-02 陶氏环球技术有限责任公司 用于制备适用于链梭移的多头或双头组合物的方法
CN109937217B (zh) 2016-09-30 2021-09-14 陶氏环球技术有限责任公司 适用于链梭移的多头或双头组合物和其制备方法
CN109952324B (zh) 2016-09-30 2023-06-09 陶氏环球技术有限责任公司 适用于链梭移的封端多头或双头组合物和其制备方法
CA3041067A1 (en) 2016-10-27 2018-05-03 Univation Technologies, Llc Method of preparing a molecular catalyst
US10000594B2 (en) * 2016-11-08 2018-06-19 Chevron Phillips Chemical Company Lp Dual catalyst system for producing LLDPE copolymers with a narrow molecular weight distribution and improved processability
WO2018111638A1 (en) 2016-12-16 2018-06-21 Dow Global Technologies Llc Ethylene/ alpha-olefin interpolymer compositions
US10329412B2 (en) 2017-02-16 2019-06-25 Nova Chemicals (International) S.A. Caps and closures
WO2018170056A1 (en) 2017-03-15 2018-09-20 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
EP3596141B1 (de) 2017-03-15 2021-07-28 Dow Global Technologies LLC Katalysatorsystem für mehrblockcopolymerbildung
SG11201908307XA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
SG11201908304QA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
ES2927248T3 (es) 2017-05-31 2022-11-03 Univation Tech Llc Combinaciones de polietilenos de baja densidad lineales
US11421100B2 (en) 2017-05-31 2022-08-23 Univation Technologies, Llc. Blends of linear low density polyethylenes
CN110892016B (zh) 2017-07-28 2023-05-23 旭化成株式会社 聚乙烯组合物
US10435527B2 (en) 2017-09-26 2019-10-08 Chevron Phillips Chemical Company Lp Dual component LLDPE copolymers with improved impact and tear resistance
US10358506B2 (en) 2017-10-03 2019-07-23 Chevron Phillips Chemical Company Lp Dual catalyst system for producing LLDPE copolymers with improved processability
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
SG11202005667PA (en) 2017-12-29 2020-07-29 Dow Global Technologies Llc Dual-headed organoaluminum compositions
CN111433235B (zh) 2017-12-29 2023-06-13 陶氏环球技术有限责任公司 封端的双头有机铝组合物
KR102571139B1 (ko) * 2018-06-08 2023-08-28 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 에틸렌 중합체 혼합물과 이의 제조방법 및 이를 이용한 성형품
CN112292417B (zh) * 2018-06-15 2023-10-13 陶氏环球技术有限责任公司 包括具有高分子量高密度级分的双峰型乙烯类聚合物的吹塑膜
JP7418356B2 (ja) 2018-06-15 2024-01-19 ダウ グローバル テクノロジーズ エルエルシー 高分子量高密度画分を有するバイモーダルエチレン系ポリマーを含むキャストフィルム
CA3103013A1 (en) * 2018-06-15 2019-12-19 Dow Global Technologies Llc Bimodal ethylene-based polymers having high molecular weight high density fractions
BR112020025506B1 (pt) 2018-06-15 2024-01-23 Dow Global Technologies Llc Método de produção de polímero à base de etileno bimodal
EP3590994A1 (de) 2018-07-04 2020-01-08 SABIC Global Technologies B.V. Polymer zur herstellung von bidirektional ausgerichteten filmen
TWI839414B (zh) * 2018-11-30 2024-04-21 美商陶氏全球科技有限責任公司 具有平衡特性之基於聚合物之膜
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
US11427703B2 (en) 2019-03-25 2022-08-30 Chevran Phillips Chemical Company LP Dual component LLDPE copolymers with improved impact and tear resistance, and methods of their preparation
EP3976678A1 (de) * 2019-05-31 2022-04-06 Dow Global Technologies LLC Ziegler-natta-katalysierte polyethylenharze und folien damit
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties
US11286379B2 (en) * 2019-10-08 2022-03-29 Nova Chemicals (International) S.A. Flexible rotationally molded article
WO2024062315A1 (en) * 2022-09-23 2024-03-28 Nova Chemicals (International) S.A. Ethylene copolymer composition and film applications

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4243619A (en) 1978-03-31 1981-01-06 Union Carbide Corporation Process for making film from low density ethylene hydrocarbon copolymer
US5272236A (en) 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
US5250612A (en) 1991-10-07 1993-10-05 The Dow Chemical Company Polyethylene films exhibiting low blocking force
US5972444A (en) 1991-10-15 1999-10-26 The Dow Chemical Company Polyolefin compositions with balanced shrink properties
US5562958A (en) 1991-10-15 1996-10-08 The Dow Chemical Company Packaging and wrapping film
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
ES2095037T3 (es) 1991-12-30 1997-02-01 Dow Chemical Co Polimerizaciones de interpolimeros de etileno.
US5530065A (en) * 1992-01-07 1996-06-25 Exxon Chemical Patents Inc. Heat sealable films and articles made therefrom
US5210142A (en) 1992-02-13 1993-05-11 The Dow Chemical Company Reduction of melt fracture in linear polyethylene
EP0572034A2 (de) * 1992-05-29 1993-12-01 Idemitsu Kosan Company Limited Ethylencopolymere und Ethylencopolymerzusammensetzung
EP0575123B2 (de) 1992-06-17 2008-02-13 Mitsui Chemicals, Inc. Ethylencopolymerzusammensetzung
CA2144737C (en) 1992-09-16 2002-04-23 William John Hodgson Jr. Soft films having enhanced physical properties
ES2149262T3 (es) * 1993-01-29 2000-11-01 Dow Chemical Co Interpolimerizaciones de etileno.
KR100326775B1 (ko) 1993-04-28 2002-10-25 더 다우 케미칼 캄파니 에틸렌중합체블렌드로부터제조한성형가공품
AU690623B2 (en) 1993-12-08 1998-04-30 Dow Chemical Company, The Stretch cling film and fabrication method
NZ287207A (en) 1994-05-09 1998-10-28 Dow Chemical Co Medium modulus polyethylene film comprising interpolymer with defined melt flow ratio and molecular weight distribution; fabrication method
CA2190004A1 (en) 1994-05-09 1995-11-16 Brad A. Cobler Medium modulus film and fabrication method
US5631069A (en) 1994-05-09 1997-05-20 The Dow Chemical Company Medium modulus molded material comprising substantially linear polyethlene and fabrication method
CA2199411C (en) * 1994-09-07 2006-11-14 Shih-Yaw Lai Plastic linear low density polyethylene
US5773106A (en) 1994-10-21 1998-06-30 The Dow Chemical Company Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus
KR19990087096A (ko) 1996-02-20 1999-12-15 스티븐 에스. 그레이스 수축 필름 및 최대 열수축률을 갖는 필름의 제조 방법
CA2271482A1 (en) 1996-11-13 1998-05-22 The Dow Chemical Company Polyolefin compositions with balanced sealant properties and improved modulus and method for same
KR100478377B1 (ko) 1996-11-13 2005-03-23 다우 글로벌 테크놀로지스 인크. 잘 균형된 특성 또는 개선된 인성을 갖는 수축 필름 및 그의제조 방법
ATE223445T1 (de) 1997-07-21 2002-09-15 Dow Chemical Co Ethyleninterpolymerzusammensetzungen mit breiter molekulargewichtsverteilung und einheitlicher zusammensetzung, verfahren zu dessen herstellung und daraus hergestellte artikel
ZA986434B (en) 1997-07-21 2000-01-20 Dow Chemical Co Broad mwd, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom.
CN1270611A (zh) 1997-09-19 2000-10-18 陶氏化学公司 组成上优化的窄分子量分布的乙烯共聚物组合物及其制备方法和所得制品

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