DE69812901T2 - Katalytische herstellung von pentafluorpropenen - Google Patents

Katalytische herstellung von pentafluorpropenen

Info

Publication number
DE69812901T2
DE69812901T2 DE69812901T DE69812901T DE69812901T2 DE 69812901 T2 DE69812901 T2 DE 69812901T2 DE 69812901 T DE69812901 T DE 69812901T DE 69812901 T DE69812901 T DE 69812901T DE 69812901 T2 DE69812901 T2 DE 69812901T2
Authority
DE
Germany
Prior art keywords
catalyst
magnesium
zinc
aluminum
fluorides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69812901T
Other languages
German (de)
English (en)
Other versions
DE69812901D1 (de
Inventor
Joseph Nappa
N. Rao
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of DE69812901D1 publication Critical patent/DE69812901D1/de
Publication of DE69812901T2 publication Critical patent/DE69812901T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/084—Decomposition of carbon-containing compounds into carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69812901T 1997-01-31 1998-01-07 Katalytische herstellung von pentafluorpropenen Expired - Lifetime DE69812901T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3632797P 1997-01-31 1997-01-31
PCT/US1998/000429 WO1998033755A1 (en) 1997-01-31 1998-01-07 The catalytic manufacture of pentafluoropropenes

Publications (2)

Publication Number Publication Date
DE69812901D1 DE69812901D1 (de) 2003-05-08
DE69812901T2 true DE69812901T2 (de) 2003-11-06

Family

ID=21887975

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69812901T Expired - Lifetime DE69812901T2 (de) 1997-01-31 1998-01-07 Katalytische herstellung von pentafluorpropenen

Country Status (5)

Country Link
US (1) US6369284B1 (enExample)
EP (1) EP0958265B1 (enExample)
JP (1) JP4031052B2 (enExample)
DE (1) DE69812901T2 (enExample)
WO (1) WO1998033755A1 (enExample)

Families Citing this family (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4001926B2 (ja) 1996-11-21 2007-10-31 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フッ化ビニルの接触製造
BR0012650A (pt) * 1999-07-21 2002-04-09 Halocarbon Prod Corp Produção de fluorocarbonos alifáticos
US8033120B2 (en) * 2002-10-25 2011-10-11 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
US7279451B2 (en) 2002-10-25 2007-10-09 Honeywell International Inc. Compositions containing fluorine substituted olefins
US7230146B2 (en) * 2003-10-27 2007-06-12 Honeywell International Inc. Process for producing fluoropropenes
US20040089839A1 (en) * 2002-10-25 2004-05-13 Honeywell International, Inc. Fluorinated alkene refrigerant compositions
US9255046B2 (en) 2003-07-25 2016-02-09 Honeywell International Inc. Manufacturing process for HFO-1234ze
US7880040B2 (en) * 2004-04-29 2011-02-01 Honeywell International Inc. Method for producing fluorinated organic compounds
US8530708B2 (en) * 2003-07-25 2013-09-10 Honeywell International Inc. Processes for selective dehydrohalogenation of halogenated alkanes
US7091388B2 (en) * 2003-09-26 2006-08-15 Honeywell International Inc. Method of making 1,1,3,3,3-pentafluoropropene
US7655610B2 (en) * 2004-04-29 2010-02-02 Honeywell International Inc. Blowing agent compositions comprising fluorinated olefins and carbon dioxide
US9308199B2 (en) * 2004-04-29 2016-04-12 Honeywell International Inc. Medicament formulations
US9499729B2 (en) 2006-06-26 2016-11-22 Honeywell International Inc. Compositions and methods containing fluorine substituted olefins
ES2528181T7 (es) * 2004-04-29 2020-03-30 Honeywell Int Inc Procedimientos para la síntesis de 1,3,3,3-tetrafluoropropeno y 2,3,3,3-tetrafluoropropeno
CN1972887B (zh) * 2004-04-29 2010-10-13 霍尼韦尔国际公司 1,3,3,3-四氟丙烯的合成方法
US8383867B2 (en) 2004-04-29 2013-02-26 Honeywell International Inc. Method for producing fluorinated organic compounds
US8084653B2 (en) * 2004-04-29 2011-12-27 Honeywell International, Inc. Method for producing fluorinated organic compounds
US7674939B2 (en) * 2004-04-29 2010-03-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US7659434B2 (en) * 2004-04-29 2010-02-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US9102579B2 (en) * 2004-04-29 2015-08-11 Honeywell International Inc. Method for producing fluorinated organic compounds
US7951982B2 (en) * 2004-04-29 2011-05-31 Honeywell International Inc. Method for producing fluorinated organic compounds
US9024092B2 (en) * 2006-01-03 2015-05-05 Honeywell International Inc. Method for producing fluorinated organic compounds
US20060116538A1 (en) * 2004-10-29 2006-06-01 Ralph Newton Miller Azeotrope compositions comprising 1,1,3,3,3-pentafluoropropene and hydrogen fluoride and uses thereof
US7897823B2 (en) * 2004-10-29 2011-03-01 E. I. Du Pont De Nemours And Company Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
US20060094911A1 (en) * 2004-10-29 2006-05-04 Rao Velliyur N M Noncatalytic manufacture of 1,1,3,3,3-pentafluoropropene from 1,1,1,3,3,3-hexafluoropropane
AU2016200229B2 (en) * 2005-03-04 2017-03-09 The Chemours Company Fc, Llc. Compositions comprising a fluoroolefin
US20220389297A1 (en) 2005-03-04 2022-12-08 The Chemours Company Fc, Llc Compositions comprising a fluoroolefin
US7569170B2 (en) 2005-03-04 2009-08-04 E.I. Du Pont De Nemours And Company Compositions comprising a fluoroolefin
JP4627045B2 (ja) * 2005-04-27 2011-02-09 セントラル硝子株式会社 金属製造保護ガス
US8574451B2 (en) * 2005-06-24 2013-11-05 Honeywell International Inc. Trans-chloro-3,3,3-trifluoropropene for use in chiller applications
US7476771B2 (en) 2005-11-01 2009-01-13 E.I. Du Pont De Nemours + Company Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
US7388117B2 (en) * 2005-11-01 2008-06-17 E.I. Du Pont De Nemours And Company Azeotrope compositions comprising 1,2,3,3,3-pentafluoropropene and hydrogen fluoride and uses thereof
US7902410B2 (en) * 2005-11-03 2011-03-08 Honeywell International Inc. Process for the manufacture of fluorinated alkanes
US7560602B2 (en) 2005-11-03 2009-07-14 Honeywell International Inc. Process for manufacture of fluorinated olefins
JP5710103B2 (ja) * 2006-01-03 2015-04-30 ハネウェル・インターナショナル・インコーポレーテッド フッ化有機化合物の製造方法
EP2001828B1 (en) * 2006-03-31 2012-08-22 E.I. Du Pont De Nemours And Company Coproduction of hydrofluoroolefins
US20090005616A1 (en) * 2006-03-31 2009-01-01 Ralph Newton Miller Purification of 1,2,3,3,3-Pentafluoropropene by Extractive Distillation
CN103396288B (zh) * 2006-06-27 2016-12-28 纳幕尔杜邦公司 1,2,3,3,3-五氟丙烯制备方法
RU2444508C2 (ru) * 2006-06-27 2012-03-10 Е. И. Дюпон Де Немур Энд Компани Способ производства тетрафторпропена
WO2008002500A1 (en) 2006-06-27 2008-01-03 E. I. Du Pont De Nemours And Company Tetrafluoropropene production processes
US20100242677A1 (en) * 2006-07-03 2010-09-30 Honeywell International Inc. Non-ferrous metal cover gases
US20080003127A1 (en) * 2006-07-03 2008-01-03 Honeywell International Inc. Non-Ferrous Metal Cover Gases
US8044252B2 (en) 2006-07-13 2011-10-25 E.I. Du Pont De Nemours And Company Catalytic isomerization between E and Z isomers of 1,2,3,3,3-pentafluoropropene
US8067650B2 (en) * 2006-08-24 2011-11-29 Honeywell International Inc. Process for the production of HFO trans-1234ze from HFC-245fa
US8273928B2 (en) * 2006-08-24 2012-09-25 E I Du Pont De Nemours And Company Processes for separation of fluoroolefins from hydrogen fluoride by azeotropic distillation
US8053613B2 (en) 2006-09-05 2011-11-08 E.I. Du Pont De Nemours And Company Processes for producing 1,2,3,3,3-pentafluoropropene and precursors thereof
WO2008030441A1 (en) * 2006-09-05 2008-03-13 E. I. Du Pont De Nemours And Company 1,2,3,3,3-pentafluoropropene production processes
WO2008030615A2 (en) * 2006-09-08 2008-03-13 E. I. Du Pont De Nemours And Company Azeotrope compositions comprising 1,1,1,2,3-pentafluoropropene and hydrogen fluoride and uses thereof
CN101522597B (zh) 2006-10-03 2013-05-29 墨西哥化学阿玛科股份有限公司 通过脱卤化氢制备c3-c6(氢)氟烯烃的方法
US8013194B2 (en) 2008-03-14 2011-09-06 Honeywell International Inc. Process for the manufacture of fluorinated olefins
TW200831446A (en) * 2006-11-15 2008-08-01 Du Pont Processes for producing pentafluoropropenes and certain azeotropes comprising HF and certain halopropenes of the formula C3HCIF4
JP2010531897A (ja) * 2007-06-27 2010-09-30 アーケマ・インコーポレイテッド ヒドロフルオロオレフィンを製造する２段階法
TW200920721A (en) * 2007-07-13 2009-05-16 Solvay Fluor Gmbh Preparation of halogen and hydrogen containing alkenes over metal fluoride catalysts
US8058491B2 (en) 2007-08-16 2011-11-15 E. I. Du Pont De Nemours And Company Catalytic isomerization between E and Z isomers of 1,2,3,3,3-pentafluoropropene using aluminum catalyst
JP2010536777A (ja) * 2007-08-16 2010-12-02 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー アルミニウム触媒を用いた１，２，３，３，３−ペンタフルオロプロペンのｅ異性体とｚ異性体間での触媒異性化
US7700815B2 (en) 2007-09-28 2010-04-20 Honeywell International Inc Method for producing fluorinated organic compounds
CA2712616A1 (en) 2008-02-21 2009-08-27 E. I. Du Pont De Nemours And Company Processes for separation of 1,3,3,3-tetrafluoropropene from hydrogen fluoride by azeotropic distillation
US8710282B2 (en) 2008-03-14 2014-04-29 Honeywell International Inc. Integrated process for the manufacture of fluorinated olefins
FR2929272B1 (fr) * 2008-03-28 2010-04-09 Arkema France Procede pour la preparation du 2,3,3,3-tetrafluoro-1-propene
FR2929273B1 (fr) * 2008-03-28 2017-05-26 Arkema France Procede de preparation de composes fluores.
CA3262933A1 (en) 2008-05-07 2025-02-28 The Chemours Company Fc, Llc COMPOSITIONS CONTAINING 1,1,1,2,3-PENTAFLUOROPROPANE OR 2,3,3,3-TETRAFLUOROPROPENE
GB0808836D0 (en) 2008-05-15 2008-06-18 Ineos Fluor Ltd Process
FR2933691B1 (fr) * 2008-07-10 2012-11-09 Arkema France Hydro(chloro)fluoroolefines et leur procede de preparation
US8129574B2 (en) 2009-08-31 2012-03-06 Honeywell International Inc. Hydrogenation process for fluorocarbons
SI3812360T1 (sl) 2009-09-09 2024-02-29 Honeywell International Inc. Monoklorotrifluoropropenske spojine in sestavki ter postopki, ki jih uporabljajo
US20110269999A1 (en) * 2010-04-29 2011-11-03 Honeywell International Inc. Process for dehydrohalogenation of halogenated alkanes
US9012702B2 (en) 2011-02-21 2015-04-21 E. I. Du Pont De Nemours And Company Catalytic dehydrochlorination of hydrochlorofluorocarbons
JP6182989B2 (ja) 2012-06-28 2017-08-23 セントラル硝子株式会社 １，３，３，３−テトラフルオロプロペンの製造方法
JP6119757B2 (ja) * 2012-09-21 2017-04-26 セントラル硝子株式会社 １，２−ジクロロ−３，３，３−トリフルオロプロペンの製造方法
JP2017114766A (ja) * 2014-04-28 2017-06-29 旭硝子株式会社 （ｅ）−１−クロロ−３，３，３−トリフルオロプロペンの製造方法
US10738001B2 (en) 2015-06-05 2020-08-11 3M Innovative Properties Company Hydrofluoroolefins and methods of using same
CN114375287B (zh) * 2019-09-12 2024-07-30 关东电化工业株式会社 具有＝cf2或＝chf的结构的氟烯烃的精制方法、以及高纯度氟烯烃及其制造方法
TW202430495A (zh) 2022-10-03 2024-08-01 日商關東電化工業股份有限公司 氟烯烴之製造方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2599631A (en) 1945-12-06 1952-06-10 Du Pont Preparation of vinyl fluoride
US2478933A (en) 1947-04-02 1949-08-16 Allied Chem & Dye Corp Manufacture of 1, 1-chlorofluoroethylenes
FR1330146A (fr) 1961-12-22 1963-06-21 Stauffer Chemical Co Procédé amélioré de préparation de composés organiques fluorés par pyrolyse
US3607955A (en) 1968-04-08 1971-09-21 Phillips Petroleum Co Hydrofluorination and dehydrofluorination and catalysts therefor
DE3676804D1 (de) * 1986-01-22 1991-02-14 Atochem North America Verfahren zur umwandlung eines 1,1,1-trifluoralkans in ein 1,1-difluoralken.
SU1706690A1 (ru) 1988-04-19 1992-01-23 Всесоюзный Научно-Исследовательский Институт Технического Углерода Пористый углеродный материал
CA2019913A1 (en) 1990-06-08 1991-12-08 Michael S. Bolmer Production of vinylidene fluoride from 1,1-difluoroethane
US5136113A (en) 1991-07-23 1992-08-04 E. I. Du Pont De Nemours And Company Catalytic hydrogenolysis
KR950701896A (ko) * 1992-06-05 1995-05-17 이노우에 노리유키 1,1,1,2,3-펜타플루오로프로펜의 제조방법 및 1,1,1,2,3-펜타플루오로프로판의 제조방법
US5396000A (en) * 1993-05-24 1995-03-07 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,2,3,-pentafluoropropane
US5559069A (en) 1994-05-26 1996-09-24 E. I. Du Pont De Nemours And Company Catalysts for halogenated hydrocarbon processing, their precursors and their preparation and use
JPH0967281A (ja) * 1995-09-01 1997-03-11 Daikin Ind Ltd １，１，１，３，３−ペンタフルオロプロペンの製造方法及び１，１，１，３，３−ペンタフルオロプロパンの製造方法
JP4001926B2 (ja) 1996-11-21 2007-10-31 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー フッ化ビニルの接触製造
US5945573A (en) * 1997-01-31 1999-08-31 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,3,3-pentafluoropropane

Also Published As

Publication number Publication date
EP0958265B1 (en) 2003-04-02
DE69812901D1 (de) 2003-05-08
US6369284B1 (en) 2002-04-09
JP4031052B2 (ja) 2008-01-09
WO1998033755A1 (en) 1998-08-06
EP0958265A1 (en) 1999-11-24
JP2001509803A (ja) 2001-07-24

Similar Documents

Publication Publication Date Title
DE69801489T2 (de) Verfahren zur herstellung von 1,1,1,3,3-pentafluorpropan
DE3887625T2 (de) Verfahren zur Herstellung von 1,1,1-Trifluorodichlorethan und von 1,1,1,2-Tetrafluorchlorethan.
DE69415748T2 (de) Auf Chrom basierter Fluorierungskatalysator, Verfahren zur Herstellung dieses Katalysators und Fluorierungsverfahren mittels dieses Katalysators
DE68906524T2 (de) Verfahren zur Isomerisierung von gesättigten Fluorkohlenwasserstoffen.
DE69105924T2 (de) Verfahren zur Herstellung von 1,1,1,2-Tetrafluorethan.
DE69512250T2 (de) Verfahren zur herstellung von 1,1,1,3,3,3- hexafluorpropan
DE69406525T2 (de) Fluorierung in der Gasphase mittels kristallisierter Katalysatoren
DE69518645T2 (de) Herstellung von 1,2-dihydro und 2,2-dihydro hexafluorpropanen und ihre azeotrope mit hf
DE69407870T2 (de) Fluorierungskatalysator und Fluorierungsverfahren
US6369284B1 (en) Catalytic manufacture of pentafluoropropenes
DE69006951T2 (de) Verfahren zur Herstellung von 1,1,1,2-Tetrafluorethan.
DE3874231T2 (de) Katalysator und verfahren zur herstellung von 1,1,1,2-tetrafluoraethan in der dampfphase.
DE69228242T2 (de) Verfahren zur herstellung von pentafluorethan
DE68907754T2 (de) Verfahren zur Fluorierung in der Gasphase.
DE69400034T2 (de) Verfahren zur Fluorierung von Perchlorethylen oder Pentachlorethan.
DE69723063T2 (de) Verfahren zur herstellung von endständiges fluor enthaltenden halogierten propanen
DE69023759T3 (de) Verfahren zur herstellung von 1,1,1,2-tetrafluoroäthan.
DE69400036T2 (de) Reinigung von Pentafluorethan.
DE69633985T2 (de) Behandlung von Chromoxid und dessen Verwendung in der katalytischen Herstellung von Vinylfluorid
DE69211837T2 (de) Verfahren zur herstellung von 2,2-dichlor-1,1,1-trifluorethan, 2-chlor-1,1,1,2-tetrafluorethan und pentafluorethan
DE69431853T2 (de) Verfahren zur Herstellung von 1,1,3,3,3-Pentafluorpropen
DE69010171T2 (de) Mehrstufenverfahren zur Herstellung von Hexafluoropropylen.
DE69212306T2 (de) Verfahren zur herstellung von 2-chlor-1,1,1,2-tetrafluorethan und pentafluorethan
DE69510223T2 (de) Herstellung von 2-chlor-2-hydrohexafluorpropan und ihre azeotropen mit hf
DE1937110A1 (de) Auf Aluminiumfluorid basierender Katalysator fuer die Fluorierung von Kohlenwasserstoffen in der Gasphase

Legal Events

Date Code Title Description
8364 No opposition during term of opposition