DE69804845T2 - Talkum enthaltende polypropylenzusammensetzungen - Google Patents
Talkum enthaltende polypropylenzusammensetzungenInfo
- Publication number
- DE69804845T2 DE69804845T2 DE69804845T DE69804845T DE69804845T2 DE 69804845 T2 DE69804845 T2 DE 69804845T2 DE 69804845 T DE69804845 T DE 69804845T DE 69804845 T DE69804845 T DE 69804845T DE 69804845 T2 DE69804845 T2 DE 69804845T2
- Authority
- DE
- Germany
- Prior art keywords
- polymer
- propylene
- polymer composition
- initiated
- talc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 74
- -1 POLYPROPYLENE Polymers 0.000 title claims abstract description 50
- 239000000454 talc Substances 0.000 title claims abstract description 47
- 229910052623 talc Inorganic materials 0.000 title claims abstract description 47
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 45
- 239000004743 Polypropylene Substances 0.000 title description 24
- 235000012222 talc Nutrition 0.000 title 1
- 229920000642 polymer Polymers 0.000 claims abstract description 58
- 238000000034 method Methods 0.000 claims abstract description 19
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 15
- 239000002667 nucleating agent Substances 0.000 claims abstract description 11
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 60
- 229920001577 copolymer Polymers 0.000 claims description 40
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 28
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 10
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 7
- 238000000071 blow moulding Methods 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000001746 injection moulding Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 238000003856 thermoforming Methods 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 229920001384 propylene homopolymer Polymers 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- FXSUTKNIHXGZFF-UHFFFAOYSA-N 1-ethenyl-2-methylcyclohexane Chemical compound CC1CCCCC1C=C FXSUTKNIHXGZFF-UHFFFAOYSA-N 0.000 claims description 2
- OLGHJTHQWQKJQQ-UHFFFAOYSA-N 3-ethylhex-1-ene Chemical group CCCC(CC)C=C OLGHJTHQWQKJQQ-UHFFFAOYSA-N 0.000 claims description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 2
- UNUVUYPEOAILGM-UHFFFAOYSA-N 4-ethenylbicyclo[2.2.1]heptane Chemical compound C1CC2CCC1(C=C)C2 UNUVUYPEOAILGM-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 239000013307 optical fiber Substances 0.000 claims description 2
- 239000010865 sewage Substances 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 description 44
- 239000007789 gas Substances 0.000 description 20
- 238000006116 polymerization reaction Methods 0.000 description 20
- 238000002425 crystallisation Methods 0.000 description 19
- 230000008025 crystallization Effects 0.000 description 19
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 17
- 239000000047 product Substances 0.000 description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
- 239000005977 Ethylene Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 9
- 229910001629 magnesium chloride Inorganic materials 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 229920001971 elastomer Polymers 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000000806 elastomer Substances 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 229910010062 TiCl3 Inorganic materials 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 5
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 150000003609 titanium compounds Chemical class 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 description 3
- 229910003074 TiCl4 Inorganic materials 0.000 description 3
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminum chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 229910052732 germanium Chemical group 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- 150000005309 metal halides Chemical class 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Chemical group 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000012041 precatalyst Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011345 viscous material Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- OEGQMCQKZSQYBV-UHFFFAOYSA-N 2-nonan-4-yloxycarbonylbenzoic acid Chemical compound CCCCCC(CCC)OC(=O)C1=CC=CC=C1C(O)=O OEGQMCQKZSQYBV-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 241001251094 Formica Species 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 241000282485 Vulpes vulpes Species 0.000 description 1
- NDJMNNSJDIFFTH-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].CC1=CC(C(=CC=C2)C=3C=CC=CC=3)=C2C1[Zr+2]([SiH](C)C)C1C(C)=CC2=C1C=CC=C2C1=CC=CC=C1 NDJMNNSJDIFFTH-UHFFFAOYSA-L 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- OANIYCQMEVXZCJ-UHFFFAOYSA-N ditert-butyl(dimethoxy)silane Chemical compound CO[Si](OC)(C(C)(C)C)C(C)(C)C OANIYCQMEVXZCJ-UHFFFAOYSA-N 0.000 description 1
- DISZQMPRUTYNJL-UHFFFAOYSA-N ditetradecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCCC DISZQMPRUTYNJL-UHFFFAOYSA-N 0.000 description 1
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 1
- QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- RTAKQLTYPVIOBZ-UHFFFAOYSA-N tritert-butylalumane Chemical compound CC(C)(C)[Al](C(C)(C)C)C(C)(C)C RTAKQLTYPVIOBZ-UHFFFAOYSA-N 0.000 description 1
- 150000003658 tungsten compounds Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/005—Modified block copolymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Lubrication Of Internal Combustion Engines (AREA)
- Measuring Fluid Pressure (AREA)
- Measurement Of Length, Angles, Or The Like Using Electric Or Magnetic Means (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI974178A FI974178A0 (fi) | 1997-11-07 | 1997-11-07 | Polypropensammansaettningar |
| PCT/EP1998/007216 WO1999024501A1 (en) | 1997-11-07 | 1998-11-09 | Talc containing polypropylene compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69804845D1 DE69804845D1 (de) | 2002-05-16 |
| DE69804845T2 true DE69804845T2 (de) | 2002-11-14 |
Family
ID=8549900
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69804845T Expired - Lifetime DE69804845T2 (de) | 1997-11-07 | 1998-11-09 | Talkum enthaltende polypropylenzusammensetzungen |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6683125B1 (https=) |
| EP (1) | EP1030876B1 (https=) |
| JP (1) | JP2001522916A (https=) |
| KR (1) | KR100495371B1 (https=) |
| CN (1) | CN100369961C (https=) |
| AT (1) | ATE215978T1 (https=) |
| AU (1) | AU744407B2 (https=) |
| BR (1) | BR9813984A (https=) |
| CA (1) | CA2308393A1 (https=) |
| DE (1) | DE69804845T2 (https=) |
| DK (1) | DK1030876T3 (https=) |
| ES (1) | ES2175837T3 (https=) |
| FI (1) | FI974178A0 (https=) |
| WO (1) | WO1999024501A1 (https=) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US7622523B2 (en) | 2002-08-12 | 2009-11-24 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
| CN100345896C (zh) | 2002-08-12 | 2007-10-31 | 埃克森美孚化学专利公司 | 增塑聚烯烃组合物 |
| US8119725B2 (en) * | 2005-05-17 | 2012-02-21 | Exxonmobil Chemical Patents Inc. | Fiber reinforced polypropylene composite interior trim cover panels |
| US7482402B2 (en) * | 2005-05-17 | 2009-01-27 | Exxonmobil Research And Engineering Company | Fiber reinforced polypropylene compositions |
| ATE435243T1 (de) | 2005-05-20 | 2009-07-15 | Borealis Tech Oy | Polymer mit hohem schmelzfluss und verbesserter beständigkeit für röhrenanwendungen |
| US7445827B2 (en) * | 2005-12-02 | 2008-11-04 | Fina Technology, Inc. | Polymer compositions for reduced shrinkage |
| DE602005018243D1 (de) * | 2005-12-22 | 2010-01-21 | Borealis Tech Oy | Polypropylenzusammensetzung enthaltend ein Propylenhomopolymer |
| EP1818365A1 (en) | 2006-02-14 | 2007-08-15 | Borealis Technology Oy | Polypropylene compositions |
| EP1923200A1 (en) * | 2006-11-20 | 2008-05-21 | Borealis Technology Oy | Article |
| EP1935938A1 (en) | 2006-12-18 | 2008-06-25 | Borealis Technology Oy | Improved high melt flow heterophasic polypropylene copolymers |
| CN101790446B (zh) | 2007-08-27 | 2013-08-07 | 博里利斯技术有限公司 | 生产聚合物粒料的设备和方法 |
| BRPI0816523B1 (pt) | 2007-10-22 | 2018-12-11 | Dow Global Technologies Inc | composição polimérica e processo para fabricar um artigo moldado |
| EP2067794A1 (en) | 2007-12-06 | 2009-06-10 | Borealis Technology OY | Use of a Ziegler-Natta procatalyst containing a trans-esterification product of a lower alcohol and a phthalic ester for the production of reactor grade thermoplastic polyolefins with improved paintability |
| WO2009153213A1 (en) | 2008-06-16 | 2009-12-23 | Borealis Ag | Thermoplastic polyolefins with high flowability and excellent surface quality produced by a multistage process |
| ATE523558T1 (de) | 2009-07-01 | 2011-09-15 | Borealis Ag | Polypropylenzusammensetzung mit hohem durchfluss |
| EP2338657A1 (en) | 2009-12-23 | 2011-06-29 | Borealis AG | Heterophasic polypropylene with improved balance between stiffness and transparency |
| EP2338656A1 (en) | 2009-12-23 | 2011-06-29 | Borealis AG | Heterophasic polypropylene with improved balance between stiffness and transparency |
| CN102206377B (zh) * | 2010-03-31 | 2015-03-11 | 上海金发科技发展有限公司 | 一种高光泽易成型聚丙烯复合材料及其制备方法 |
| PL2471858T3 (pl) | 2010-12-06 | 2017-08-31 | Borealis Ag | Polipropylen heterofazowy o zwiększonej sztywności i przezroczystości oraz odpowiedniej wytrzymałości na uderzenie |
| EP2514770B1 (en) * | 2011-04-21 | 2014-02-26 | Borealis AG | Polypropylene homopolymers with high heat deflection temperature, high stiffness and flowability |
| EP2535372B1 (en) * | 2011-06-15 | 2016-09-14 | Borealis AG | In-situ reactor blend of a Ziegler-Natta catalysed, nucleated polypropylene and a metallocene catalysed polypropylene |
| US9657155B2 (en) * | 2013-04-12 | 2017-05-23 | Printpack Illinois, Inc. | Containers and materials with improved punctureability |
| US9057857B2 (en) | 2013-06-28 | 2015-06-16 | Corning Optical Communications LLC | Fiber optic assembly for optical cable |
| JP2017522918A (ja) | 2014-06-10 | 2017-08-17 | プリントパック イリノイ インコーポレイテッド | 改善された穴開け容易性（ｐｕｎｃｔｕｒｅａｂｉｌｉｔｙ）を有する容器 |
| EP3015504A1 (en) | 2014-10-27 | 2016-05-04 | Borealis AG | Heterophasic polypropylene with improved puncture respectively impact strength/stiffness balance |
| EP3015503A1 (en) | 2014-10-27 | 2016-05-04 | Borealis AG | Heterophasic polypropylene with improved stiffness/impact balance |
| CA2964654C (en) | 2014-10-27 | 2019-03-12 | Borealis Ag | Heterophasic polypropylene with improved impact strength/stiffness balance, improved powder flowability, reduced emissions and low shrinkage |
| CN107207802B (zh) | 2014-12-22 | 2020-10-09 | Sabic环球技术有限责任公司 | 聚丙烯组合物 |
| ES2637434T5 (es) | 2015-07-08 | 2020-07-06 | Borealis Ag | Tubo elaborado de una composición de polipropileno heterofásico |
| TR201811902T4 (tr) | 2015-07-08 | 2018-09-21 | Borealis Ag | Geliştirilmiş toz akışkanlığı, azaltılmış emisyonları ve düşük küçülme özellikli heterofazik polipropilen. |
| US10450491B2 (en) | 2016-08-08 | 2019-10-22 | Ticona Llc | Thermally conductive polymer composition for a heat sink |
| US11990859B2 (en) * | 2018-05-28 | 2024-05-21 | Borealis Ag | Devices for a photovoltaic (PV) module |
| MY197103A (en) * | 2018-09-12 | 2023-05-25 | Borealis Ag | Polypropylene composition with excellent stiffness and impact strength |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2736792A1 (de) | 1977-08-16 | 1979-03-01 | Basf Ag | Polypropylen-formmasse |
| US4436863A (en) | 1981-05-01 | 1984-03-13 | Allied Corporation | Use of ethylene-vinyl acetate copolymers and oxidized high density polyethylene homopolymers as processing aids for talc filled polypropylene compounds |
| JPS60139428A (ja) * | 1983-12-27 | 1985-07-24 | Sumitomo Chem Co Ltd | ポリプロピレン延伸フイルム |
| JPS60139731A (ja) * | 1983-12-27 | 1985-07-24 | Sumitomo Chem Co Ltd | 結晶性プロピレン重合体組成物 |
| JPS60139710A (ja) * | 1984-11-15 | 1985-07-24 | Sumitomo Chem Co Ltd | プロピレン共重合体の製造方法 |
| EP0152701B1 (en) * | 1983-12-27 | 1988-06-08 | Sumitomo Chemical Company, Limited | Process for producing propylene copolymer |
| JPS6395252A (ja) * | 1986-10-13 | 1988-04-26 | Mitsui Toatsu Chem Inc | ポリプロピレン樹脂組成物 |
| JPH01204947A (ja) * | 1988-02-12 | 1989-08-17 | Nissan Motor Co Ltd | 自動車外装部品用熱可塑性樹脂組成物 |
| JP2679147B2 (ja) * | 1988-09-08 | 1997-11-19 | 住友化学工業株式会社 | 樹脂組成物 |
| CA2002200A1 (en) | 1988-11-04 | 1990-05-04 | Masahiro Kakugo | Crystalline polypropylene and crystalline polypropylene composition |
| EP0417319B1 (en) | 1989-03-29 | 1996-10-02 | Mitsubishi Chemical Corporation | Blown polypropylene resin container |
| DE3921358A1 (de) | 1989-06-29 | 1991-01-10 | Hoechst Ag | Biaxial orientierte polypropylenfolie mit hoher mechanischer festigkeit |
| JPH03163145A (ja) * | 1989-11-22 | 1991-07-15 | Mitsubishi Kasei Corp | ポリプロピレン樹脂製ブロー成形容器 |
| FI88047C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner |
| FI88048C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator |
| JPH0657057A (ja) | 1992-08-11 | 1994-03-01 | Sumitomo Chem Co Ltd | ポリプロピレン組成物及びそのフィルム |
| JPH06228345A (ja) * | 1992-12-08 | 1994-08-16 | Sumitomo Chem Co Ltd | プロピレン系樹脂組成物成形品の表面処理方法及び塗装方法 |
| FI95387C (fi) | 1992-12-29 | 1996-01-25 | Borealis As | Menetelmä -olefiinien polymeroimiseksi sekä esipolymeroitu katalyyttikompositio ja menetelmä tämän valmistamiseksi |
| BR9301831A (pt) | 1993-05-13 | 1994-11-29 | Polibrasil S A Ind E Comercio | Polipropileno de elevada resistência em fusão, artigo moldado e processo contínuo para produção de polipropileno de elevada resistência em fusão. |
| FI96615C (fi) | 1993-06-04 | 1996-07-25 | Neste Oy | Menetelmä C4-C40- -olefiinien polymeroimiseksi tai kopolymeroimiseksi muiden -olefiinien kanssa |
| CA2143429C (en) * | 1993-06-30 | 1999-01-26 | Takao Nomura | Polypropylene composition |
| FI96866C (fi) | 1993-11-05 | 1996-09-10 | Borealis As | Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö |
| AU693917B2 (en) * | 1994-09-08 | 1998-07-09 | Showa Denko Kabushiki Kaisha | Propylene block copolymer, process for producing the same and resin composition comprising the same |
| JPH1036584A (ja) * | 1996-07-23 | 1998-02-10 | Tonen Corp | ポリプロピレン系樹脂組成物 |
| FI963707A0 (fi) | 1996-09-19 | 1996-09-19 | Borealis Polymers Oy | Foerfarande foer polymerisering av alfa-olefiner, vid polymerisering anvaendbar katalysator och foerfarande foer framstaellning av densamma |
| FI974175A7 (fi) * | 1997-11-07 | 1999-05-08 | Borealis As | Menetelmä polypropeenin valmistamiseksi |
| FI980342A0 (fi) * | 1997-11-07 | 1998-02-13 | Borealis As | Polymerroer och -roerkopplingar |
-
1997
- 1997-11-07 FI FI974178A patent/FI974178A0/fi not_active Application Discontinuation
-
1998
- 1998-11-09 DK DK98963443T patent/DK1030876T3/da active
- 1998-11-09 DE DE69804845T patent/DE69804845T2/de not_active Expired - Lifetime
- 1998-11-09 AU AU18721/99A patent/AU744407B2/en not_active Ceased
- 1998-11-09 CN CNB988129167A patent/CN100369961C/zh not_active Expired - Lifetime
- 1998-11-09 WO PCT/EP1998/007216 patent/WO1999024501A1/en not_active Ceased
- 1998-11-09 BR BR9813984-3A patent/BR9813984A/pt not_active IP Right Cessation
- 1998-11-09 EP EP98963443A patent/EP1030876B1/en not_active Expired - Lifetime
- 1998-11-09 KR KR10-2000-7004977A patent/KR100495371B1/ko not_active Expired - Lifetime
- 1998-11-09 AT AT98963443T patent/ATE215978T1/de active
- 1998-11-09 ES ES98963443T patent/ES2175837T3/es not_active Expired - Lifetime
- 1998-11-09 US US09/530,797 patent/US6683125B1/en not_active Expired - Lifetime
- 1998-11-09 CA CA002308393A patent/CA2308393A1/en not_active Abandoned
- 1998-11-09 JP JP2000520503A patent/JP2001522916A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE69804845D1 (de) | 2002-05-16 |
| US6683125B1 (en) | 2004-01-27 |
| CN1284978A (zh) | 2001-02-21 |
| FI974178A0 (fi) | 1997-11-07 |
| EP1030876A1 (en) | 2000-08-30 |
| KR20010024595A (ko) | 2001-03-26 |
| AU1872199A (en) | 1999-05-31 |
| BR9813984A (pt) | 2000-09-26 |
| CA2308393A1 (en) | 1999-05-20 |
| CN100369961C (zh) | 2008-02-20 |
| AU744407B2 (en) | 2002-02-21 |
| DK1030876T3 (da) | 2002-08-05 |
| ATE215978T1 (de) | 2002-04-15 |
| JP2001522916A (ja) | 2001-11-20 |
| ES2175837T3 (es) | 2002-11-16 |
| KR100495371B1 (ko) | 2005-06-14 |
| EP1030876B1 (en) | 2002-04-10 |
| WO1999024501A1 (en) | 1999-05-20 |
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