DE69712409D1 - Hexagonales, schichtförmiges Lithiummanganat als aktives Material für die positive Elektrode einer Lithiumbatterie, Verfahren zu dessen Herstellung, und dieses enthaltende Lithiumbatterie - Google Patents

Hexagonales, schichtförmiges Lithiummanganat als aktives Material für die positive Elektrode einer Lithiumbatterie, Verfahren zu dessen Herstellung, und dieses enthaltende Lithiumbatterie

Info

Publication number
DE69712409D1
DE69712409D1 DE69712409T DE69712409T DE69712409D1 DE 69712409 D1 DE69712409 D1 DE 69712409D1 DE 69712409 T DE69712409 T DE 69712409T DE 69712409 T DE69712409 T DE 69712409T DE 69712409 D1 DE69712409 D1 DE 69712409D1
Authority
DE
Germany
Prior art keywords
lithium battery
hexagonal
production
positive electrode
active material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69712409T
Other languages
English (en)
Other versions
DE69712409T2 (de
Inventor
Khalil Amine
Hideo Yasuda
Yuko Fujita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Storage Battery Co Ltd
Original Assignee
Japan Storage Battery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Japan Storage Battery Co Ltd filed Critical Japan Storage Battery Co Ltd
Publication of DE69712409D1 publication Critical patent/DE69712409D1/de
Application granted granted Critical
Publication of DE69712409T2 publication Critical patent/DE69712409T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14—Methods for preparing oxides or hydroxides in general
    • C01B13/36—Methods for preparing oxides or hydroxides in general by precipitation reactions in aqueous solutions
    • C01B13/366—Methods for preparing oxides or hydroxides in general by precipitation reactions in aqueous solutions by hydrothermal processing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1228—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [MnO2]n-, e.g. LiMnO2, Li[MxMn1-x]O2
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
DE69712409T 1996-06-13 1997-06-12 Hexagonales, schichtförmiges Lithiummanganat als aktives Material für die positive Elektrode einer Lithiumbatterie, Verfahren zu dessen Herstellung, und dieses enthaltende Lithiumbatterie Expired - Fee Related DE69712409T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17423296A JP3846601B2 (ja) 1996-06-13 1996-06-13 リチウム電池用正極活物質およびその製造方法ならびに前記活物質を備えた電池

Publications (2)

Publication Number Publication Date
DE69712409D1 true DE69712409D1 (de) 2002-06-13
DE69712409T2 DE69712409T2 (de) 2003-04-03

Family

ID=15975038

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69712409T Expired - Fee Related DE69712409T2 (de) 1996-06-13 1997-06-12 Hexagonales, schichtförmiges Lithiummanganat als aktives Material für die positive Elektrode einer Lithiumbatterie, Verfahren zu dessen Herstellung, und dieses enthaltende Lithiumbatterie

Country Status (5)

Country Link
US (1) US5981106A (de)
EP (1) EP0813256B1 (de)
JP (1) JP3846601B2 (de)
CN (1) CN1131571C (de)
DE (1) DE69712409T2 (de)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6348182B1 (en) * 1996-06-27 2002-02-19 The Honjo Chemical Corporation Process for producing lithium manganese oxide with spinel structure
JP2001508391A (ja) 1996-12-30 2001-06-26 リーデル−デ ハーエン アクチェンゲゼルシャフト 酸化リチウムマンガンの調製方法
KR100565923B1 (ko) * 1997-08-18 2006-03-30 고교기쥬쯔잉초가다이효스루니혼고쿠 리튬망간 복합산화물 입자상 조성물의 제조와 이것의 리튬이온 2차전지에의 이용
JPH11180717A (ja) * 1997-12-22 1999-07-06 Ishihara Sangyo Kaisha Ltd マンガン酸リチウム及びその製造方法ならびにそれを用いてなるリチウム電池
JP3624088B2 (ja) * 1998-01-30 2005-02-23 キヤノン株式会社 粉末材料、電極構造体、それらの製造方法、及びリチウム二次電池
KR100268749B1 (ko) * 1998-02-26 2000-10-16 이 병 길 리튬 이차전지 양극재료용 층상 결정구조 이산화 망간 및 이의 합성 방법
US6306542B1 (en) 1998-05-22 2001-10-23 Kabushiki Kaisha Toyota Chuo Kenkyusho Lithium manganese composite oxide for lithium secondary battery cathode active material, manufacturing method thereof, and lithium secondary battery using the composite oxide as cathode active material
EP0963952A3 (de) * 1998-06-12 2001-08-29 Japan Storage Battery Company Limited Verfahren zur Herstellung einer Lithium enthaltenden Nickelverbindung
JP3482424B2 (ja) * 1998-10-02 2003-12-22 シャープ株式会社 非水系二次電池用正極活物質の製造方法及び非水系二次電池
KR20010002210A (ko) * 1999-06-12 2001-01-05 김순택 리튬 이차 전지용 양극 활물질 및 그의 제조 방법
JP4941692B2 (ja) * 2000-05-16 2012-05-30 株式会社豊田中央研究所 リチウム二次電池正極活物質用リチウムマンガン複合酸化物およびその製造方法
JP4080337B2 (ja) 2001-03-22 2008-04-23 松下電器産業株式会社 正極活物質およびこれを含む非水電解質二次電池
US6964828B2 (en) 2001-04-27 2005-11-15 3M Innovative Properties Company Cathode compositions for lithium-ion batteries
JP4510331B2 (ja) 2001-06-27 2010-07-21 パナソニック株式会社 非水電解質二次電池
US20030108793A1 (en) * 2001-08-07 2003-06-12 3M Innovative Properties Company Cathode compositions for lithium ion batteries
JP4836371B2 (ja) * 2001-09-13 2011-12-14 パナソニック株式会社 正極活物質およびこれを含む非水電解質二次電池
JP3827545B2 (ja) 2001-09-13 2006-09-27 松下電器産業株式会社 正極活物質、その製造方法および非水電解質二次電池
US8658125B2 (en) 2001-10-25 2014-02-25 Panasonic Corporation Positive electrode active material and non-aqueous electrolyte secondary battery containing the same
US9391325B2 (en) 2002-03-01 2016-07-12 Panasonic Corporation Positive electrode active material, production method thereof and non-aqueous electrolyte secondary battery
JP4197237B2 (ja) 2002-03-01 2008-12-17 パナソニック株式会社 正極活物質の製造方法
JP4594605B2 (ja) * 2002-08-05 2010-12-08 パナソニック株式会社 正極活物質およびこれを含む非水電解質二次電池
US20040121234A1 (en) * 2002-12-23 2004-06-24 3M Innovative Properties Company Cathode composition for rechargeable lithium battery
JP4554911B2 (ja) 2003-11-07 2010-09-29 パナソニック株式会社 非水電解質二次電池
US7211237B2 (en) * 2003-11-26 2007-05-01 3M Innovative Properties Company Solid state synthesis of lithium ion battery cathode material
US7611549B2 (en) * 2003-12-22 2009-11-03 Cardiac Pacemakers, Inc. Magnetic stacking fixture for stacking electrodes
US7238450B2 (en) * 2003-12-23 2007-07-03 Tronox Llc High voltage laminar cathode materials for lithium rechargeable batteries, and process for making the same
CN1322607C (zh) * 2005-04-27 2007-06-20 吉林大学 锂二次电池正极材料－正交晶系LiMnO2的制备方法
WO2007041209A2 (en) * 2005-09-29 2007-04-12 Massachusetts Institute Of Technology Oxides having high energy densities
US7696126B2 (en) 2006-02-14 2010-04-13 Honda Motor Co., Ltd. Method of producing oxidation catalyst for cleaning exhaust gas
JP5014218B2 (ja) * 2007-03-22 2012-08-29 三洋電機株式会社 非水電解質二次電池
KR101280319B1 (ko) * 2010-05-04 2013-07-01 한국세라믹기술원 수열합성법을 이용하여 리튬망간복합산화물을 합성하는 방법, 이에 의하여 제조된 리튬망간복합산화물 및 이를 사용하는 전기화학소자
WO2012067675A1 (en) * 2010-11-17 2012-05-24 Uchicago Argonne, Llc, Operator Of Argonne National Laboratory Electrode structures and surfaces for li batteries
CN102205989A (zh) * 2011-03-25 2011-10-05 江苏国泰锂宝新材料有限公司 电池正极材料LiMn2O4的制备方法
CN102299314A (zh) * 2011-07-14 2011-12-28 上海微纳科技有限公司 尖晶石LiMn2O4锂离子电池正极材料的制备方法
JP5826653B2 (ja) * 2012-02-01 2015-12-02 株式会社Ｇｓユアサ 非水電解質二次電池用正極活物質およびそれを用いた非水電解質二次電池
JP2014002849A (ja) * 2012-06-15 2014-01-09 Toyota Motor Corp リチウムマンガン含有酸化物とその製造方法、リチウムイオン二次電池の正極活物質、およびリチウムイオン二次電池
JP5895730B2 (ja) * 2012-06-18 2016-03-30 トヨタ自動車株式会社 リチウムマンガン含有酸化物とその製造方法、リチウムイオン二次電池の正極活物質、およびリチウムイオン二次電池
KR101297385B1 (ko) * 2012-07-09 2013-08-19 성신여자대학교 산학협력단 리튬 이차 전지용 양극 활물질 제조방법
CN103078106B (zh) * 2013-02-07 2015-05-13 湖南信达新材料有限公司 锂离子电池锰酸锂正极材料的制备方法
JP6283743B2 (ja) 2013-07-09 2018-02-21 ダウ グローバル テクノロジーズ エルエルシー カソードを形成する方法
CN105612123B (zh) 2013-10-24 2018-06-08 陶氏环球技术有限责任公司 改善的锂金属氧化物正极材料及制备其的方法
US10069143B2 (en) 2013-12-23 2018-09-04 Uchicago Argonne, Llc Cobalt-stabilized lithium metal oxide electrodes for lithium batteries
US11205776B2 (en) 2014-05-27 2021-12-21 Dow Global Technologies Llc Lithium metal oxide cathode materials and method to make them
WO2016095177A1 (en) 2014-12-18 2016-06-23 Dow Global Technologies Llc Lithium ion battery having improved thermal stability
US10305103B2 (en) 2015-08-11 2019-05-28 Uchicago Argonne, Llc Stabilized electrodes for lithium batteries
JP7043076B2 (ja) * 2016-08-30 2022-03-29 国立研究開発法人産業技術総合研究所 リチウムニッケル系複合酸化物及びその製造方法
US10741839B2 (en) 2017-03-02 2020-08-11 Uchicago Argonne, Llc Surface treatment for lithium battery electrode materials
KR20200128673A (ko) * 2018-03-07 2020-11-16 히타치 긴조쿠 가부시키가이샤 리튬 이온 이차 전지용 정극 활물질 및 리튬 이온 이차 전지
CN109585824A (zh) * 2018-11-23 2019-04-05 安徽工业大学 一种球形中空多孔锰酸锂正极材料的制备方法
CN110615480A (zh) * 2019-08-30 2019-12-27 浙江工业大学 一种动态水热法制备层状锰酸锂材料的方法
CN113594445A (zh) * 2020-04-30 2021-11-02 湖南杉杉能源科技股份有限公司 一种多金属复合氧化物包覆改性锰酸锂正极材料及其制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2234233B (en) * 1989-07-28 1993-02-17 Csir Lithium manganese oxide
US5316875A (en) * 1991-07-19 1994-05-31 Matsushita Electric Industrial Co., Ltd. Secondary battery with nonaqueous electrolyte and method of manufacturing same
JPH05299092A (ja) * 1992-01-17 1993-11-12 Matsushita Electric Ind Co Ltd 非水電解質リチウム二次電池及びその製造方法
JP2847663B2 (ja) * 1992-10-06 1999-01-20 日本電信電話株式会社 非水電解質電池
US5418090A (en) * 1993-02-17 1995-05-23 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
CA2096264A1 (en) * 1993-05-14 1994-11-15 Jeffrey Raymond Dahn Novel method for preparing solid solution materials for secondary non-aqueous batteries
JPH0710541A (ja) * 1993-06-30 1995-01-13 Tosoh Corp リチウムマンガン複合酸化物
JPH07101728A (ja) * 1993-10-01 1995-04-18 Tosoh Corp リチウムマンガン酸化物及びその製造方法並びにその用途
JPH087883A (ja) * 1994-06-23 1996-01-12 Sony Corp 非水電解液二次電池
JP3067531B2 (ja) * 1994-07-13 2000-07-17 松下電器産業株式会社 非水電解液二次電池の正極活物質およびそれを用いた電池

Also Published As

Publication number Publication date
EP0813256A3 (de) 1998-09-16
US5981106A (en) 1999-11-09
EP0813256B1 (de) 2002-05-08
JP3846601B2 (ja) 2006-11-15
JPH103921A (ja) 1998-01-06
EP0813256A2 (de) 1997-12-17
CN1171638A (zh) 1998-01-28
CN1131571C (zh) 2003-12-17
DE69712409T2 (de) 2003-04-03

Similar Documents

Publication Publication Date Title
DE69712409T2 (de) Hexagonales, schichtförmiges Lithiummanganat als aktives Material für die positive Elektrode einer Lithiumbatterie, Verfahren zu dessen Herstellung, und dieses enthaltende Lithiumbatterie
DE69907660D1 (de) Aktives material einer positiven elektrode für nichtwässrige elektrodensekundärbatterie und verfahren zu dessen herstellung und nichtwässrige sekundärbatterie, die dieses verwendet
DE69409352T2 (de) Nichtwässrige Sekundärbatterie, aktives Material für positive Elektrode und Verfahren zu dessen Herstellung
DE69620154T2 (de) Lithium-nickel-verbundoxid, verfahren zu seiner herstellung und positives aktives material für sekundäre batterie
DE69408179T2 (de) Sekundäre Batterie mit nichtwässrigem Elektrolyten und Verfahren zu ihrer Herstellung
DE69309332D1 (de) Positives, aktives Elektrodenmaterial für eine Lithium-Sekundärzelle mit nichtwässrigem Elektrolyt und Verfahren zu seiner Herstellung
DE69716021D1 (de) Positivelektrodematerial für alkalische Speicherbatterie, Herstellungsverfahren, und alkalische Speicherbatterie die dieses Material verwendet
DE60036843D1 (de) Negatives Elektrodenmaterial für nichtwässrige Lithium-Sekundärbatterie, Verfahren zu dessen Herstellung und nichtwässrige Lithium-Sekundärbatterie enthaltend dieses Material
DE69404602D1 (de) Herstellungsverfahren eines Separators für eine Lithium-Sekundärbatterie und eine Lithium-Sekundärbatterie mit organischem Elektrolyt, die einen solchen Separator verwendet
DE69416930D1 (de) Elektrode für Sammlerbatterie und Verfahren zu ihrer Herstellung
DE69314088T2 (de) Positivelektrode für Lithium-Sekundärbatterie und Verfahren zu seiner Herstellung und eine nichtwässrige Elektrolyte Lithium-Sekundärbatterie unter Verwendung derselben
DE69710073D1 (de) Kohlenstoffmaterial für negative elektrode einer sekundären li-batterie, verfahren zu deren herstellung und damit hergstellte sekundäre li-batterie
DE69407526D1 (de) Kohlenstoffhaltiges Elektrodenmaterial für Sekundärbatterie, sowie Verfahren zu seiner Herstellung
DE69837744D1 (de) Sekundärbatterie mit nichtwässrigem Elektrolyten und Verfahren zu ihrer Herstellung
DE69408223D1 (de) Wiederaufladebarer Lithiumenthaltender elektrochemischer Stromgenerator und Verfahren zu ihrer Herstellung
DE69614444T2 (de) Kohlenstofffaser für Sekundärbatterie-Elektrode und Verfahren zu ihrer Herstellung
DE69704042T2 (de) An der Oberfläche graphitiertes Kohlenstoffmaterial, Verfahren zu seiner Herstellung und dieses verwendende Negativelektrode für Lithium-Ionen-Sekundärbatterie
DE69416640T2 (de) Lithiumsekundärzelle mit organischem elektrolyten, aktives material für positive elektrode einer li-sekundärzelle und verfahren zur herstellung des aktiven materials
DE69510977T2 (de) Negative Elektrode für Lithium Akkumulator und Verfahren zu deren Herstellung
DE69418933T2 (de) Elektrode für eine wiederaufladbare Batterie mit nichtwässrigem Elektrolyten und Verfahren zu ihrer Herstellung
AU6354196A (en) A wound electrochemical cell, a method for the manufacture thereof, and the use of such electrochemical cells
DE69512182D1 (de) Kathode für Lithium Sekundärbatterie und Verfahren zu ihrer Herstellung
DE69908123D1 (de) Nickelelektrode für alkalispeicherbatterien, verfahren zu deren herstellung und alkalispeicherbatterie
DE69711776D1 (de) Amorphes Lithiumnickelat als positives Aktivmaterial, Herstellungsverfahren dafür und dieses Aktivmaterial enthaltende Lithiumbatterie
DE69511003T2 (de) Elektrode für alkalische Speicherbatterie und Verfahren zu dessen Herstellung

Legal Events

Date Code Title Description
8332 No legal effect for de
8370 Indication of lapse of patent is to be deleted
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee