DE69420097T2 - Gassperrefilm und Herstellungsverfahren dafür - Google Patents
Gassperrefilm und Herstellungsverfahren dafürInfo
- Publication number
- DE69420097T2 DE69420097T2 DE69420097T DE69420097T DE69420097T2 DE 69420097 T2 DE69420097 T2 DE 69420097T2 DE 69420097 T DE69420097 T DE 69420097T DE 69420097 T DE69420097 T DE 69420097T DE 69420097 T2 DE69420097 T2 DE 69420097T2
- Authority
- DE
- Germany
- Prior art keywords
- acrylic acid
- heat treatment
- meth
- poly
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000004888 barrier function Effects 0.000 title claims description 67
- 238000004519 manufacturing process Methods 0.000 title description 6
- 238000010438 heat treatment Methods 0.000 claims description 95
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 94
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 93
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 71
- 239000001301 oxygen Substances 0.000 claims description 58
- 229910052760 oxygen Inorganic materials 0.000 claims description 58
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 57
- 230000035699 permeability Effects 0.000 claims description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 50
- 239000000203 mixture Substances 0.000 claims description 40
- 238000006386 neutralization reaction Methods 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 31
- 229920002125 Sokalan® Polymers 0.000 claims description 25
- 239000007789 gas Substances 0.000 claims description 25
- 239000004584 polyacrylic acid Substances 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 10
- 238000009835 boiling Methods 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 238000000807 solvent casting Methods 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 230000003472 neutralizing effect Effects 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 238000007127 saponification reaction Methods 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000005001 laminate film Substances 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- -1 polyethylene terephthalate Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 41
- 229910001882 dioxygen Inorganic materials 0.000 description 41
- 229920002799 BoPET Polymers 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 238000002845 discoloration Methods 0.000 description 11
- 238000002156 mixing Methods 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000011259 mixed solution Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 230000009102 absorption Effects 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 8
- 238000005259 measurement Methods 0.000 description 6
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000005022 packaging material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000005033 polyvinylidene chloride Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000012417 linear regression Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 125000004036 acetal group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 150000004291 polyenes Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000611 regression analysis Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 235000013580 sausages Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0036—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/718—Weight, e.g. weight per square meter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/02—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5262958A JP2736600B2 (ja) | 1993-09-27 | 1993-09-27 | ガスバリヤー性フィルム及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69420097D1 DE69420097D1 (de) | 1999-09-23 |
| DE69420097T2 true DE69420097T2 (de) | 1999-12-09 |
Family
ID=17382914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69420097T Expired - Lifetime DE69420097T2 (de) | 1993-09-27 | 1994-09-22 | Gassperrefilm und Herstellungsverfahren dafür |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5574096A (enExample) |
| EP (1) | EP0645428B1 (enExample) |
| JP (1) | JP2736600B2 (enExample) |
| KR (1) | KR0148854B1 (enExample) |
| CN (1) | CN1054865C (enExample) |
| AU (1) | AU676367B2 (enExample) |
| DE (1) | DE69420097T2 (enExample) |
| TW (1) | TW272947B (enExample) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2220419A1 (en) * | 1992-04-01 | 1996-11-14 | Henkel Corporation | Composition and process for treating metal |
| JP3203287B2 (ja) * | 1994-01-26 | 2001-08-27 | 呉羽化学工業株式会社 | ガスバリヤー性積層体及びその製造方法 |
| JP2832876B2 (ja) | 1994-07-27 | 1998-12-09 | 呉羽化学工業株式会社 | 複合蒸着フィルム及びその製造方法 |
| US6022913A (en) * | 1996-09-06 | 2000-02-08 | Kureha Chemical Industry Co. Ltd. | Container for retort packaging, resin composition, and gas-barrier film prepared therefrom |
| US6312641B1 (en) | 1997-10-17 | 2001-11-06 | Plastic Fabrication Technologies Llc | Method of making containers and preforms incorporating barrier materials |
| US6911255B2 (en) | 2001-05-08 | 2005-06-28 | Mitsubishi Polyester Film, Llc | Clear barrier coating and coated film |
| AU2002328087A1 (en) * | 2001-08-30 | 2003-03-10 | Hitachi Chemical Co., Ltd. | Thermosetting polyvinyl alcohol binder resin composition, slurry of electrode mix, electrode, non-aqueous electrolysis solution-containing secondary battery and use of thermosetting polyvinyl alcohol binder resin as electrode material |
| US6709735B2 (en) * | 2001-11-14 | 2004-03-23 | Mitsubishi Polyester Film, Llc | Oxygen barrier coating and coated film |
| DE10302036A1 (de) * | 2003-01-21 | 2004-07-29 | Mitsubishi Polyester Film Gmbh | Polyesterfolie mit verbesserter Sauerstoffbarriere, enthaltend Poly(m-xylol-adipinamid) und eine Barrierebeschichtung, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE10302035A1 (de) * | 2003-01-21 | 2004-07-29 | Mitsubishi Polyester Film Gmbh | Polyesterfolie mit verbesserter Sauerstoffbarriere, enthaltend Poly(m-xylol-adipinamid) sowie eine Deckschicht und eine Barrierebeschichtung, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US7435446B2 (en) | 2003-04-09 | 2008-10-14 | Toyo Ink Mfg. Co., Ltd. | Method of producing gas barrier multilayer body |
| EP1671784B1 (en) * | 2003-10-03 | 2012-08-22 | Toppan Printing Co., Ltd. | Multilayered container made by stretch forming and process for producing the same |
| US7608339B2 (en) * | 2003-10-22 | 2009-10-27 | Kureha Corporation | Multilayer film |
| WO2005037534A2 (ja) * | 2003-10-22 | 2005-04-28 | Kureha Chemical Ind Co Ltd | 積層体及びその製造方法 |
| JP4729249B2 (ja) * | 2003-10-22 | 2011-07-20 | 株式会社クレハ | 高防湿性フィルム、及びその製造方法 |
| TWI406763B (zh) * | 2005-08-31 | 2013-09-01 | Tohcello Co Ltd | Air barrier film, gas barrier layered body and manufacturing method thereof |
| JP5081416B2 (ja) | 2005-09-26 | 2012-11-28 | ユニチカ株式会社 | ガスバリア性積層体 |
| JP5092371B2 (ja) * | 2005-11-30 | 2012-12-05 | 住友化学株式会社 | 樹脂膜および積層体の製造方法 |
| US20070122557A1 (en) * | 2005-11-30 | 2007-05-31 | Sumitomo Chemical Company, Limited | Method for producing resin film and layered article |
| JP5219343B2 (ja) * | 2006-06-07 | 2013-06-26 | 日本合成化学工業株式会社 | フィルムの製造方法 |
| KR101409954B1 (ko) | 2006-08-30 | 2014-06-19 | 토요잉크Sc홀딩스주식회사 | 가스 배리어층 형성용 도료 및 가스 배리어성 적층체 |
| WO2008038839A1 (en) * | 2006-09-29 | 2008-04-03 | Sumitomo Chemical Company, Limited | Process for producing multilayer molding |
| JP4920443B2 (ja) * | 2007-02-15 | 2012-04-18 | 株式会社クラレ | 耐水性組成物 |
| US7857938B2 (en) * | 2007-04-27 | 2010-12-28 | Sumitomo Chemical Company, Limited | Method for producing a barrier container |
| JP5034782B2 (ja) * | 2007-08-29 | 2012-09-26 | 住友化学株式会社 | 樹脂混合液の製造方法 |
| CN101767448B (zh) * | 2010-01-22 | 2011-09-07 | 青岛科瑞新型环保材料有限公司 | 真空绝热板用隔气膜制作方法 |
| CN101870791B (zh) * | 2010-02-26 | 2012-02-29 | 中国科学院长春应用化学研究所 | 一种吸湿薄膜的制备方法 |
| WO2012043193A1 (ja) * | 2010-09-28 | 2012-04-05 | 株式会社クラレ | フィルムおよびその製造方法 |
| JP5523512B2 (ja) * | 2012-06-21 | 2014-06-18 | ユニチカ株式会社 | 包装材料用接着剤および包装材料 |
| JP6148500B2 (ja) * | 2013-03-01 | 2017-06-14 | 桜宮化学株式会社 | ガスバリア性塗料組成物 |
| JP6324059B2 (ja) * | 2013-12-24 | 2018-05-16 | 日本合成化学工業株式会社 | 樹脂組成物、コート層、感熱記録媒体、及び水性塗工液 |
| TWI515102B (zh) * | 2014-08-18 | 2016-01-01 | 中原大學 | 透明性阻氣複合膜及其製備方法 |
| JP7115515B2 (ja) * | 2020-06-19 | 2022-08-09 | 大日本印刷株式会社 | プリフォーム及びボトル |
| CN113248770B (zh) * | 2021-06-01 | 2022-02-11 | 中山大学 | 一种热塑性弹性体物理发泡卷材及其半连续制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2169250A (en) * | 1937-05-27 | 1939-08-15 | Du Pont | Process of forming films, threads, and the like |
| US3133865A (en) * | 1961-05-22 | 1964-05-19 | American Home Prod | Waveset composition comprising an aqueous lotion of polyvinyl alcohol and a carboxy vinyl polymer |
| CA1134977A (en) * | 1978-09-07 | 1982-11-02 | Sumitomo Chemical Co., Ltd. | Method for preparing highly absorbent polymers |
| JPS6347743A (ja) * | 1986-08-15 | 1988-02-29 | Casio Comput Co Ltd | 表示装置付カメラ |
| JPH0214376A (ja) * | 1988-03-18 | 1990-01-18 | Fuji Photo Film Co Ltd | 放射線画像読取装置 |
| JP2716464B2 (ja) * | 1988-07-18 | 1998-02-18 | 不二製油株式会社 | フレッシュチーズ様食品とその製造方法 |
| JP3340780B2 (ja) * | 1993-01-27 | 2002-11-05 | 呉羽化学工業株式会社 | ガスバリヤー性フィルム及びその製造方法 |
-
1993
- 1993-09-27 JP JP5262958A patent/JP2736600B2/ja not_active Expired - Lifetime
-
1994
- 1994-09-21 AU AU74201/94A patent/AU676367B2/en not_active Ceased
- 1994-09-22 EP EP94114948A patent/EP0645428B1/en not_active Expired - Lifetime
- 1994-09-22 US US08/310,749 patent/US5574096A/en not_active Expired - Lifetime
- 1994-09-22 DE DE69420097T patent/DE69420097T2/de not_active Expired - Lifetime
- 1994-09-23 TW TW083108780A patent/TW272947B/zh active
- 1994-09-27 CN CN94117893A patent/CN1054865C/zh not_active Expired - Lifetime
- 1994-09-27 KR KR1019940024360A patent/KR0148854B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1054865C (zh) | 2000-07-26 |
| JP2736600B2 (ja) | 1998-04-02 |
| CN1104654A (zh) | 1995-07-05 |
| AU676367B2 (en) | 1997-03-06 |
| AU7420194A (en) | 1995-04-27 |
| EP0645428A1 (en) | 1995-03-29 |
| KR950008605A (ko) | 1995-04-19 |
| EP0645428B1 (en) | 1999-08-18 |
| JPH07102083A (ja) | 1995-04-18 |
| US5574096A (en) | 1996-11-12 |
| KR0148854B1 (ko) | 1998-10-15 |
| DE69420097D1 (de) | 1999-09-23 |
| TW272947B (enExample) | 1996-03-21 |
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Owner name: KUREHA CORP., TOKYO/TOKIO, JP |