DE69323140T2 - Verfahren zur Herstellung von Phenol, Aceton und alpha-Methylstyrol - Google Patents

Verfahren zur Herstellung von Phenol, Aceton und alpha-Methylstyrol

Info

Publication number
DE69323140T2
DE69323140T2 DE69323140T DE69323140T DE69323140T2 DE 69323140 T2 DE69323140 T2 DE 69323140T2 DE 69323140 T DE69323140 T DE 69323140T DE 69323140 T DE69323140 T DE 69323140T DE 69323140 T2 DE69323140 T2 DE 69323140T2
Authority
DE
Germany
Prior art keywords
methylstyrene
phenol
acetone
alpha
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69323140T
Other languages
English (en)
Other versions
DE69323140D1 (de
DE69323140T3 (de
Inventor
Vladimir Michailo Zakoshansky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SABIC Global Technologies BV
Illa International Ltd
Original Assignee
Illa International Ltd
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25481882&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69323140(T2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Illa International Ltd, General Electric Co filed Critical Illa International Ltd
Publication of DE69323140D1 publication Critical patent/DE69323140D1/de
Application granted granted Critical
Publication of DE69323140T2 publication Critical patent/DE69323140T2/de
Publication of DE69323140T3 publication Critical patent/DE69323140T3/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/517—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of peroxy-compounds to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69323140T 1992-09-14 1993-09-06 Verfahren zur Herstellung von Phenol, Aceton und alpha-Methylstyrol Expired - Lifetime DE69323140T3 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/944,688 US5254751A (en) 1992-09-14 1992-09-14 Method for the decomposition of cumene hydroperoxide by acidic catalyst to phenol and acetone

Publications (3)

Publication Number Publication Date
DE69323140D1 DE69323140D1 (de) 1999-03-04
DE69323140T2 true DE69323140T2 (de) 2001-03-29
DE69323140T3 DE69323140T3 (de) 2003-07-24

Family

ID=25481882

Family Applications (4)

Application Number Title Priority Date Filing Date
DE69329300T Expired - Lifetime DE69329300T2 (de) 1992-09-14 1993-09-06 Verfahren zur Spaltung von Cumolhydroperoxid
DE69331564T Expired - Lifetime DE69331564T2 (de) 1992-09-14 1993-09-06 Verfahren zur Spaltung von Cumolhydroperoxid
DE69323140T Expired - Lifetime DE69323140T3 (de) 1992-09-14 1993-09-06 Verfahren zur Herstellung von Phenol, Aceton und alpha-Methylstyrol
DE69333863T Expired - Lifetime DE69333863T2 (de) 1992-09-14 1993-09-06 Die Spaltung von Cumolhydroperoxid

Family Applications Before (2)

Application Number Title Priority Date Filing Date
DE69329300T Expired - Lifetime DE69329300T2 (de) 1992-09-14 1993-09-06 Verfahren zur Spaltung von Cumolhydroperoxid
DE69331564T Expired - Lifetime DE69331564T2 (de) 1992-09-14 1993-09-06 Verfahren zur Spaltung von Cumolhydroperoxid

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69333863T Expired - Lifetime DE69333863T2 (de) 1992-09-14 1993-09-06 Die Spaltung von Cumolhydroperoxid

Country Status (8)

Country Link
US (2) US5254751A (de)
EP (4) EP1142855B1 (de)
JP (3) JP3268082B2 (de)
KR (1) KR0161540B1 (de)
CN (3) CN1071293C (de)
CA (1) CA2105187A1 (de)
DE (4) DE69329300T2 (de)
ES (3) ES2172063T3 (de)

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US5371305A (en) * 1992-12-31 1994-12-06 Hercules Incorporated Process for producing phenol from cumene
RU2108318C1 (ru) * 1994-03-01 1998-04-10 Закошанский Владимир Михайлович СПОСОБ ПОЛУЧЕНИЯ ФЕНОЛА, АЦЕТОНА И α МЕТИЛСТИРОЛА
JP3711504B2 (ja) * 1994-03-01 2005-11-02 ゼネラル・エレクトリック・カンパニイ 工業用クメンヒドロペルオキシドのフェノール、アセトン及びα−メチルスチレンへの酸分解方法
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US5463136A (en) * 1994-12-22 1995-10-31 Shell Oil Company Cumene hydroperoxide cleavage process
JP3769050B2 (ja) * 1995-07-07 2006-04-19 三井化学株式会社 フェノールの製造方法
IN185136B (de) * 1995-09-20 2000-11-25 Gen Electric
US5672774A (en) * 1995-10-24 1997-09-30 General Electric Company Phenol tar processing method
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RU2141938C1 (ru) 1996-12-15 1999-11-27 ООО "Илла Интернешнл", Лтд. Энергосберегающий и высокоселективный способ получения фенола и ацетона (процесс иф-96)
RU2142932C1 (ru) * 1997-11-03 1999-12-20 Закошанский Владимир Михайлович Высокоселективный способ получения фенола и ацетона (процесс фан-98)
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US6201157B1 (en) * 2000-01-10 2001-03-13 Sunoco, Inc. (R&M) Method for production of phenol and acetone by decomposition of cumene hydroperoxide
DE10021482A1 (de) * 2000-05-03 2001-11-08 Phenolchemie Gmbh & Co Kg Verfahren zur thermischen Nachbehandlung von Spaltprodukt aus der säurekatalysierten Spaltung von Cumolhydroperoxid
DE10051581A1 (de) * 2000-10-18 2002-06-20 Phenolchemie Gmbh & Co Kg Verfahren zur Spaltung von Alkylarylhydroperoxiden
DE10111889A1 (de) * 2001-03-13 2002-10-02 Phenolchemie Gmbh & Co Kg Verfahren zur säurekatalysierten Spaltung von Cumolhydroperoxid
RU2231045C2 (ru) * 2002-05-20 2004-06-20 Общество с ограниченной ответственностью "Еврохим-СпбТрейдинг" Способ измерения концентрации гидропероксидов алкилароматических углеводородов в жидких промышленных потоках
US7282613B2 (en) * 2003-02-14 2007-10-16 Shell Oil Company Process for producing phenol and methyl ethyl ketone
US7312365B2 (en) * 2003-02-14 2007-12-25 Shell Oil Company Process for low temperature cleavage of an oxidation mixture comprising hydroperoxides
US7141703B2 (en) * 2003-02-14 2006-11-28 Shell Oil Company Process for producing phenol and ketone using neutralizing base
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US7109385B2 (en) * 2004-03-31 2006-09-19 General Electric Company Process for producing phenol
US7141701B1 (en) * 2005-08-19 2006-11-28 Uop Llc Decomposition of cumene hydroperoxide
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US7888537B2 (en) * 2006-12-29 2011-02-15 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
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WO2010098916A2 (en) 2009-02-26 2010-09-02 Exxonmobil Chemical Patents Inc. Process for producing phenol
US9321710B2 (en) 2010-01-25 2016-04-26 Exxonmobil Chemical Patents Inc. Process for producing phenol
US20110306800A1 (en) 2010-06-09 2011-12-15 Scott Roy Keenan Method for the decomposition of cumene hydroperoxide
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CN103052618B (zh) 2010-09-14 2015-08-05 埃克森美孚化学专利公司 生产苯酚的方法
CN103097331B (zh) 2010-09-14 2016-01-27 埃克森美孚化学专利公司 用于制备苯酚的方法
US9365474B2 (en) 2010-09-14 2016-06-14 Exxonmobil Chemical Patents Inc. Processes for producing phenol
WO2012067711A1 (en) 2010-11-16 2012-05-24 Exxonmobil Chemical Patents Inc. Process for producing phenol
CN103492072B (zh) 2011-04-19 2016-01-20 埃克森美孚化学专利公司 苯酚的制备方法
US9388102B2 (en) 2011-04-19 2016-07-12 Exxonmobil Chemical Patents Inc. Process for producing phenol
SG194025A1 (en) 2011-04-19 2013-11-29 Exxonmobil Chem Patents Inc Method for producing phenol and/or cyclohexanone
US9469589B2 (en) 2011-06-30 2016-10-18 Exxonmobil Chemical Patents Inc. Process for producing phenol and/or cyclohexanone
CN104080763B (zh) * 2011-09-19 2016-08-24 凯洛格·布朗及鲁特有限公司 联产低甲醇含量的丙酮的方法和系统
WO2013043272A1 (en) 2011-09-23 2013-03-28 Exxonmobil Chemical Patents Inc. Process for producing phenol
WO2013043271A1 (en) 2011-09-23 2013-03-28 Exxonmobil Chemical Patents Inc. Process for producing phenol
US9249078B2 (en) 2011-10-07 2016-02-02 Exxonmobil Chemical Patents Inc. Mixed metal oxide catalysts and use thereof
US8865957B2 (en) 2012-03-09 2014-10-21 Honeywell Intenational Inc. Method for producing alpha-methyl styrene from cumene
SG11201509522UA (en) 2013-06-28 2015-12-30 Exxonmobil Chem Patents Inc Process for producing phenol and/or cyclohexanone
CN106573868B (zh) 2014-04-23 2019-08-16 陶氏环球技术有限责任公司 制造苯酚时酸性催化剂的中和
CN104151144A (zh) * 2014-07-16 2014-11-19 常州大学 一种过氧化氢异丙苯分解制苯酚/丙酮的方法
RU2565764C1 (ru) 2014-08-08 2015-10-20 Общество с ограниченной ответственностью "Научно-производственное объединение ЕВРОХИМ" Способ получения фенола и ацетона
KR102040059B1 (ko) * 2016-11-14 2019-11-05 주식회사 엘지화학 페놀의 정제 방법
CN110818536A (zh) * 2019-11-13 2020-02-21 中国石油化工股份有限公司 一种采用微反应器装置催化分解过氧化氢异丙苯的方法
CN114426463B (zh) * 2020-10-13 2024-05-28 中国石油化工股份有限公司 制备间苯二酚的方法
CN114981232A (zh) 2020-12-21 2022-08-30 株式会社Lg化学 制备α-甲基苯乙烯的方法

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Also Published As

Publication number Publication date
ES2127253T5 (es) 2002-10-16
EP1142855B1 (de) 2005-08-31
DE69333863D1 (de) 2005-10-06
CN1235949A (zh) 1999-11-24
ES2148669T3 (es) 2000-10-16
DE69323140D1 (de) 1999-03-04
EP0738698A3 (de) 1997-08-27
CN1235952A (zh) 1999-11-24
KR940006977A (ko) 1994-04-26
JP2002193857A (ja) 2002-07-10
CN1089593A (zh) 1994-07-20
CN1071293C (zh) 2001-09-19
EP0589588B2 (de) 2002-03-13
DE69323140T3 (de) 2003-07-24
KR0161540B1 (ko) 1999-01-15
JPH10152449A (ja) 1998-06-09
USRE40668E1 (en) 2009-03-17
DE69331564T2 (de) 2002-10-10
EP1142855A1 (de) 2001-10-10
CA2105187A1 (en) 1994-03-15
DE69329300T2 (de) 2001-02-08
EP0873983B1 (de) 2002-02-06
US5254751A (en) 1993-10-19
ES2172063T3 (es) 2002-09-16
CN1101371C (zh) 2003-02-12
ES2127253T3 (es) 1999-04-16
DE69333863T2 (de) 2006-06-14
DE69331564D1 (de) 2002-03-21
JP3268082B2 (ja) 2002-03-25
DE69329300D1 (de) 2000-09-28
EP0738698B1 (de) 2000-08-23
JPH06293682A (ja) 1994-10-21
CN1088051C (zh) 2002-07-24
EP0589588A1 (de) 1994-03-30
EP0873983A3 (de) 1998-12-09
EP0589588B1 (de) 1999-01-20
JP3797914B2 (ja) 2006-07-19
EP0873983A2 (de) 1998-10-28
EP0738698A2 (de) 1996-10-23
JP3281587B2 (ja) 2002-05-13

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