ES2127253T5 - Procedimiento para la produccion de fenol, acetona y alfa-metilestireno. - Google Patents

Procedimiento para la produccion de fenol, acetona y alfa-metilestireno.

Info

Publication number
ES2127253T5
ES2127253T5 ES93307016T ES93307016T ES2127253T5 ES 2127253 T5 ES2127253 T5 ES 2127253T5 ES 93307016 T ES93307016 T ES 93307016T ES 93307016 T ES93307016 T ES 93307016T ES 2127253 T5 ES2127253 T5 ES 2127253T5
Authority
ES
Spain
Prior art keywords
acetone
decomposition
phenol
acid catalyst
dicumil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93307016T
Other languages
English (en)
Other versions
ES2127253T3 (es
Inventor
Vladimir Michailo Zakoshansky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Illa International Ltd
General Electric Co
Original Assignee
Illa International Ltd
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25481882&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2127253(T5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Illa International Ltd, General Electric Co filed Critical Illa International Ltd
Publication of ES2127253T3 publication Critical patent/ES2127253T3/es
Application granted granted Critical
Publication of ES2127253T5 publication Critical patent/ES2127253T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/517—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of peroxy-compounds to >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE PRESENTA UN METODO PARA MEJORAR LA DESCOMPOSICION DEL HIDROPEROXIDO DE CUMENO EN FENOL Y ACETONA MEDIANTE UN CATALIZADOR ACIDICO. EL METODO COMPRENDE LA DESCOMPOSICION DEL HIDROPEROXIDO DE CUMENO DE UNA FORMA NO ISOTERMICA EN LA PRESENCIA DE UN EXCESO DE ACETONA MEDIANTE LO CUAL LA RELACION MOLAR DE LA ACETONA CON RESPECTO AL FENOL EN EL REACTOR DE DESCOMPOSICION ES DE ENTRE 1.1:1 Y 1.5:1. TAMBIEN SE PRESENTA UN METODO PARA MEJORAR LA SELECTIVIDAD DE LA DESCOMPOSICION DEL PEROXIDO DE DICUMIL EN ALFA-METILESTIRENO, FENOL Y ACETONA EN LA PRESENCIA DE UN CATALIZADOR ACIDICO. EL METODO COMPRENDE LA REALIZACION DE LA DESCOMPOSICION A UNA TEMPERATURA ENTRE 80 (GRADOS) Y 110 (GRADOS) C. ASIMISMO SE PRESENTA UN METODO PARA PREPARAR FENOL Y ACETONA A PARTIR DE LA DESCOMPOSICION DE CHP CON UN CATALIZADOR ACIDICO, EL METODO COMPRENDE (A) LA DESCOMPOSICION DEL CHP A UNA CONCENTRACION DE CATALIZADOR ACIDICO ESPECIFICA Y UNA TEMPERATURA ADECUADA MEDIANTE LO CUAL SE FORMA UNA COMPOSICION QUE CONTIENE FENIL, ACETONA Y PEROXIDO DE DICUMIL, LA TRANSFERENCIA DEL PEROXIDO DE DICUMIL A UN REACTOR DE FLUJO EN EL QUE SE PRODUCE LA DESCOMPOSICION DEL PEROXIDO DE DICUMIL EN FENIL, ACETONA Y AMS A UNA CONCENTRACION DE CATALIZADOR ACIDICO INFERIOR Y A UNA TEMPERATURA MAYOR QUE LA CONCENTRACION DE CATALIZADOR Y LA TEMPERATURA DEL PASO (A).
ES93307016T 1992-09-14 1993-09-06 Procedimiento para la produccion de fenol, acetona y alfa-metilestireno. Expired - Lifetime ES2127253T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/944,688 US5254751A (en) 1992-09-14 1992-09-14 Method for the decomposition of cumene hydroperoxide by acidic catalyst to phenol and acetone

Publications (2)

Publication Number Publication Date
ES2127253T3 ES2127253T3 (es) 1999-04-16
ES2127253T5 true ES2127253T5 (es) 2002-10-16

Family

ID=25481882

Family Applications (3)

Application Number Title Priority Date Filing Date
ES93307016T Expired - Lifetime ES2127253T5 (es) 1992-09-14 1993-09-06 Procedimiento para la produccion de fenol, acetona y alfa-metilestireno.
ES98112218T Expired - Lifetime ES2172063T3 (es) 1992-09-14 1993-09-06 Procedimiento para la descomposicion de hidroperoxido de cumeno.
ES96202123T Expired - Lifetime ES2148669T3 (es) 1992-09-14 1993-09-06 Procedimiento para la descomposicion de hidroperoxido de cumeno.

Family Applications After (2)

Application Number Title Priority Date Filing Date
ES98112218T Expired - Lifetime ES2172063T3 (es) 1992-09-14 1993-09-06 Procedimiento para la descomposicion de hidroperoxido de cumeno.
ES96202123T Expired - Lifetime ES2148669T3 (es) 1992-09-14 1993-09-06 Procedimiento para la descomposicion de hidroperoxido de cumeno.

Country Status (8)

Country Link
US (2) US5254751A (es)
EP (4) EP0589588B2 (es)
JP (3) JP3268082B2 (es)
KR (1) KR0161540B1 (es)
CN (3) CN1071293C (es)
CA (1) CA2105187A1 (es)
DE (4) DE69331564T2 (es)
ES (3) ES2127253T5 (es)

Families Citing this family (61)

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US7166752B2 (en) * 1989-01-17 2007-01-23 Sunoco, Inc. (R&M) Decomposition of cumene oxidation product
US5371305A (en) * 1992-12-31 1994-12-06 Hercules Incorporated Process for producing phenol from cumene
JP3711504B2 (ja) * 1994-03-01 2005-11-02 ゼネラル・エレクトリック・カンパニイ 工業用クメンヒドロペルオキシドのフェノール、アセトン及びα−メチルスチレンへの酸分解方法
RU2108318C1 (ru) * 1994-03-01 1998-04-10 Закошанский Владимир Михайлович СПОСОБ ПОЛУЧЕНИЯ ФЕНОЛА, АЦЕТОНА И α МЕТИЛСТИРОЛА
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TW318174B (es) * 1994-11-04 1997-10-21 Gen Electric
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JP3769050B2 (ja) * 1995-07-07 2006-04-19 三井化学株式会社 フェノールの製造方法
IN185136B (es) * 1995-09-20 2000-11-25 Gen Electric
US5672774A (en) * 1995-10-24 1997-09-30 General Electric Company Phenol tar processing method
US5962751A (en) * 1996-04-26 1999-10-05 General Electric Company Phenol tar desalting method
RU2125038C1 (ru) * 1996-09-24 1999-01-20 Закошанский Владимир Михайлович Безотходный экономичный способ получения фенола и ацетона
RU2141938C1 (ru) 1996-12-15 1999-11-27 ООО "Илла Интернешнл", Лтд. Энергосберегающий и высокоселективный способ получения фенола и ацетона (процесс иф-96)
RU2114816C1 (ru) * 1997-02-13 1998-07-10 Открытое акционерное общество "Казаньоргсинтез" Способ разложения гидроперекиси кумола кислотным катализатором на фенол и ацетон
RU2142932C1 (ru) * 1997-11-03 1999-12-20 Закошанский Владимир Михайлович Высокоселективный способ получения фенола и ацетона (процесс фан-98)
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DE10111889A1 (de) * 2001-03-13 2002-10-02 Phenolchemie Gmbh & Co Kg Verfahren zur säurekatalysierten Spaltung von Cumolhydroperoxid
RU2231045C2 (ru) * 2002-05-20 2004-06-20 Общество с ограниченной ответственностью "Еврохим-СпбТрейдинг" Способ измерения концентрации гидропероксидов алкилароматических углеводородов в жидких промышленных потоках
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CN105732304A (zh) 2009-02-26 2016-07-06 埃克森美孚化学专利公司 苯酚的制备方法
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KR101748068B1 (ko) 2010-09-14 2017-06-15 엑손모빌 케미칼 패턴츠 인코포레이티드 페놀의 제조 방법
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WO2012067711A1 (en) 2010-11-16 2012-05-24 Exxonmobil Chemical Patents Inc. Process for producing phenol
SG194008A1 (en) 2011-04-19 2013-11-29 Exxonmobil Chem Patents Inc Process for producing phenol
JP5793793B2 (ja) 2011-04-19 2015-10-14 エクソンモービル ケミカル パテンツ インコーポレイテッド フェノール及び／又はシクロヘキサノンの製造方法
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JP6453903B2 (ja) 2014-04-23 2019-01-16 ダウ グローバル テクノロジーズ エルエルシー フェノールの生成における酸性触媒の中和
CN104151144A (zh) * 2014-07-16 2014-11-19 常州大学 一种过氧化氢异丙苯分解制苯酚/丙酮的方法
RU2565764C1 (ru) 2014-08-08 2015-10-20 Общество с ограниченной ответственностью "Научно-производственное объединение ЕВРОХИМ" Способ получения фенола и ацетона
KR102040059B1 (ko) 2016-11-14 2019-11-05 주식회사 엘지화학 페놀의 정제 방법
CN110818536A (zh) * 2019-11-13 2020-02-21 中国石油化工股份有限公司 一种采用微反应器装置催化分解过氧化氢异丙苯的方法
CN114426463B (zh) * 2020-10-13 2024-05-28 中国石油化工股份有限公司 制备间苯二酚的方法
JP7464211B2 (ja) * 2020-12-21 2024-04-09 エルジー・ケム・リミテッド α－メチルスチレンの製造方法

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DE69323140T2 (de) 2001-03-29
JPH06293682A (ja) 1994-10-21
JPH10152449A (ja) 1998-06-09
EP0589588B1 (en) 1999-01-20
US5254751A (en) 1993-10-19
DE69329300T2 (de) 2001-02-08
DE69331564T2 (de) 2002-10-10
CN1235952A (zh) 1999-11-24
JP3797914B2 (ja) 2006-07-19
EP0873983A3 (en) 1998-12-09
EP0589588B2 (en) 2002-03-13
ES2148669T3 (es) 2000-10-16
EP0738698A2 (en) 1996-10-23
EP0738698A3 (en) 1997-08-27
CN1088051C (zh) 2002-07-24
DE69333863D1 (de) 2005-10-06
JP3268082B2 (ja) 2002-03-25
CA2105187A1 (en) 1994-03-15
CN1235949A (zh) 1999-11-24
JP2002193857A (ja) 2002-07-10
JP3281587B2 (ja) 2002-05-13
EP0873983B1 (en) 2002-02-06
DE69323140T3 (de) 2003-07-24
CN1071293C (zh) 2001-09-19
EP0589588A1 (en) 1994-03-30
KR0161540B1 (ko) 1999-01-15
EP0873983A2 (en) 1998-10-28
KR940006977A (ko) 1994-04-26
DE69333863T2 (de) 2006-06-14
ES2172063T3 (es) 2002-09-16
ES2127253T3 (es) 1999-04-16
CN1101371C (zh) 2003-02-12
EP1142855B1 (en) 2005-08-31
EP1142855A1 (en) 2001-10-10
DE69331564D1 (de) 2002-03-21
EP0738698B1 (en) 2000-08-23
DE69323140D1 (de) 1999-03-04
DE69329300D1 (de) 2000-09-28
USRE40668E1 (en) 2009-03-17
CN1089593A (zh) 1994-07-20

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