DE69016895T2 - Isomerisierung von Endocycloolefinen in Exocycloolefine sowie Copolymerisation von Cycloolefinen mit Ethylen. - Google Patents

Isomerisierung von Endocycloolefinen in Exocycloolefine sowie Copolymerisation von Cycloolefinen mit Ethylen.

Info

Publication number
DE69016895T2
DE69016895T2 DE69016895T DE69016895T DE69016895T2 DE 69016895 T2 DE69016895 T2 DE 69016895T2 DE 69016895 T DE69016895 T DE 69016895T DE 69016895 T DE69016895 T DE 69016895T DE 69016895 T2 DE69016895 T2 DE 69016895T2
Authority
DE
Germany
Prior art keywords
isomerization
ethylene
exocycloolefins
endocycloolefins
cycloolefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69016895T
Other languages
English (en)
Other versions
DE69016895D1 (de
Inventor
Toshihiro Sagane
Hideaki C O Mitsui P Yamaguchi
Shuji C O Mitsui Petroc Minami
Akira Mizuno
Hiroo Wamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP1244494A external-priority patent/JPH03106909A/ja
Priority claimed from JP1244493A external-priority patent/JPH03106832A/ja
Priority claimed from JP1275714A external-priority patent/JP2848869B2/ja
Priority claimed from JP27571589A external-priority patent/JP2795486B2/ja
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Application granted granted Critical
Publication of DE69016895D1 publication Critical patent/DE69016895D1/de
Publication of DE69016895T2 publication Critical patent/DE69016895T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F232/08—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2213—Catalytic processes not covered by C07C5/23 - C07C5/31 with metal oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2226—Catalytic processes not covered by C07C5/23 - C07C5/31 with inorganic acids; with salt or anhydrides of acids
    • C07C5/2233—Acids of sulfur; Salts thereof; Sulfur oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2266—Catalytic processes not covered by C07C5/23 - C07C5/31 with hydrides or organic compounds
    • C07C5/2273—Catalytic processes not covered by C07C5/23 - C07C5/31 with hydrides or organic compounds with ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C07C2523/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/043—Sulfides with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins
    • C07C2531/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/90—Ring systems containing bridged rings containing more than four rings
    • C07C2603/91—Polycyclopentadienes; Hydrogenated polycyclopentadienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69016895T 1989-08-15 1990-08-13 Isomerisierung von Endocycloolefinen in Exocycloolefine sowie Copolymerisation von Cycloolefinen mit Ethylen. Expired - Fee Related DE69016895T2 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP21044989 1989-08-15
JP21044889 1989-08-15
JP1244494A JPH03106909A (ja) 1989-09-20 1989-09-20 環状オレフィン系ランダム共重合体およびその製造方法
JP1244493A JPH03106832A (ja) 1989-09-20 1989-09-20 ペンタシクロペンタデセン類エンド体のエキソ体への異性化方法およびペンタシクロペンタデセン類異性体混合物ならびにその製造方法
JP1275714A JP2848869B2 (ja) 1989-08-15 1989-10-23 テトラシクロドデセン類エンド体のエキソ体への異性化方法およびテトラシクロドデセン類異性体混合物ならびにその製造方法
JP27571589A JP2795486B2 (ja) 1989-08-15 1989-10-23 環状オレフィン系ランダム共重合体およびその製造方法

Publications (2)

Publication Number Publication Date
DE69016895D1 DE69016895D1 (de) 1995-03-23
DE69016895T2 true DE69016895T2 (de) 1995-07-20

Family

ID=27553867

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69016895T Expired - Fee Related DE69016895T2 (de) 1989-08-15 1990-08-13 Isomerisierung von Endocycloolefinen in Exocycloolefine sowie Copolymerisation von Cycloolefinen mit Ethylen.

Country Status (7)

Country Link
US (2) US5106931A (de)
EP (1) EP0417489B1 (de)
KR (1) KR930003691B1 (de)
CN (1) CN1073122C (de)
AT (1) ATE118472T1 (de)
CA (1) CA2023214C (de)
DE (1) DE69016895T2 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2061003C (en) * 1991-02-12 1999-02-09 Mitsui Chemicals, Inc. Process for isomerizing endo-form of aromatic group-containing norbornenes to exo-form thereof, isomer mixture of aromatic group-containing norbornenes and process for preparing same, and ethylene/aromatic group-contain ng norbornene copolymer and process for preparing same
EP0542488B1 (de) * 1991-11-11 1994-07-06 Mitsui Petrochemical Industries, Ltd. Verfahren zur Herstellung eines statistischen Cycloolefincopolymers
KR100336114B1 (ko) * 1999-11-16 2002-05-08 박찬구 비공액 이중결합을 가지는 사이클로올레핀의 이성질화방법
US6260505B1 (en) 1999-12-03 2001-07-17 Midwest Pontoon Covers, Inc. Pontoon boat cover system

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3381046A (en) * 1966-08-15 1968-04-30 Exxon Research Engineering Co Jet and rocket fuel
US4288644A (en) * 1978-11-20 1981-09-08 Suntech, Inc. Process for isomerization of tetrahydrodimethyldicyclopentadiene
US4614778A (en) * 1984-02-03 1986-09-30 Hirokazu Kajiura Random copolymer
US4689380A (en) * 1984-11-16 1987-08-25 Hercules Incorporated Cycloolefin copolymerization method, feed composition and product
JPS62132998A (ja) * 1985-12-05 1987-06-16 Nippon Oil Co Ltd 高密度燃料油
JPS63305111A (ja) * 1987-06-08 1988-12-13 Nippon Oil Co Ltd ランダム共重合体及びその製造法
WO1989001950A1 (en) * 1987-08-26 1989-03-09 Showa Denko Kabushiki Kaisha Ethylene/polycyclic monomer copolymer and process for its preparation
JPH0751609B2 (ja) * 1988-01-20 1995-06-05 日本石油株式会社 ランダム共重合体及びその製造法

Also Published As

Publication number Publication date
KR930003691B1 (ko) 1993-05-08
CA2023214C (en) 1996-10-15
CN1051045A (zh) 1991-05-01
EP0417489B1 (de) 1995-02-15
KR910004682A (ko) 1991-03-29
CA2023214A1 (en) 1991-02-16
ATE118472T1 (de) 1995-03-15
US5106931A (en) 1992-04-21
DE69016895D1 (de) 1995-03-23
US5310931A (en) 1994-05-10
EP0417489A1 (de) 1991-03-20
CN1073122C (zh) 2001-10-17

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8327 Change in the person/name/address of the patent owner

Owner name: MITSUI CHEMICALS, INC., TOKIO/TOKYO, JP

8339 Ceased/non-payment of the annual fee