DE69016895T2 - Isomerization of endocycloolefins into exocycloolefins and copolymerization of cycloolefins with ethylene. - Google Patents

Isomerization of endocycloolefins into exocycloolefins and copolymerization of cycloolefins with ethylene.

Info

Publication number
DE69016895T2
DE69016895T2 DE69016895T DE69016895T DE69016895T2 DE 69016895 T2 DE69016895 T2 DE 69016895T2 DE 69016895 T DE69016895 T DE 69016895T DE 69016895 T DE69016895 T DE 69016895T DE 69016895 T2 DE69016895 T2 DE 69016895T2
Authority
DE
Germany
Prior art keywords
isomerization
ethylene
exocycloolefins
endocycloolefins
cycloolefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69016895T
Other languages
German (de)
Other versions
DE69016895D1 (en
Inventor
Toshihiro Sagane
Hideaki C O Mitsui P Yamaguchi
Shuji C O Mitsui Petroc Minami
Akira Mizuno
Hiroo Wamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP1244494A external-priority patent/JPH03106909A/en
Priority claimed from JP1244493A external-priority patent/JPH03106832A/en
Priority claimed from JP27571589A external-priority patent/JP2795486B2/en
Priority claimed from JP1275714A external-priority patent/JP2848869B2/en
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Publication of DE69016895D1 publication Critical patent/DE69016895D1/en
Application granted granted Critical
Publication of DE69016895T2 publication Critical patent/DE69016895T2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F232/08—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2213—Catalytic processes not covered by C07C5/23 - C07C5/31 with metal oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2226—Catalytic processes not covered by C07C5/23 - C07C5/31 with inorganic acids; with salt or anhydrides of acids
    • C07C5/2233—Acids of sulfur; Salts thereof; Sulfur oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2266—Catalytic processes not covered by C07C5/23 - C07C5/31 with hydrides or organic compounds
    • C07C5/2273—Catalytic processes not covered by C07C5/23 - C07C5/31 with hydrides or organic compounds with ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
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    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C07C2523/22—Vanadium
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
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    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/043—Sulfides with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/04—Sulfides
    • C07C2527/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins
    • C07C2531/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/90—Ring systems containing bridged rings containing more than four rings
    • C07C2603/91—Polycyclopentadienes; Hydrogenated polycyclopentadienes

Abstract

This invention is to provide a novel process for the isomerization of a cycloolefin having an endo form to a cycloolefin having an exo form. The resulting isomer mixture has a novel composition, and a random copolymer produced from the above compositionally novel isomer mixture and ethylene has an excellent heat resistance and mechanical strength.
DE69016895T 1989-08-15 1990-08-13 Isomerization of endocycloolefins into exocycloolefins and copolymerization of cycloolefins with ethylene. Expired - Fee Related DE69016895T2 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP21044989 1989-08-15
JP21044889 1989-08-15
JP1244494A JPH03106909A (en) 1989-09-20 1989-09-20 Cycloolefin random copolymer and its production
JP1244493A JPH03106832A (en) 1989-09-20 1989-09-20 Isomerization of endo isomer of pentacyclopentadecene to exo isomer, mixture of pentacyclopentadecene isomers and production thereof
JP27571589A JP2795486B2 (en) 1989-08-15 1989-10-23 Cyclic olefin random copolymer and method for producing the same
JP1275714A JP2848869B2 (en) 1989-08-15 1989-10-23 Method for Isomerizing Tetracyclododecene Endo Form into Exo Form, Tetracyclododecene Isomer Mixture, and Method for Producing the Same

Publications (2)

Publication Number Publication Date
DE69016895D1 DE69016895D1 (en) 1995-03-23
DE69016895T2 true DE69016895T2 (en) 1995-07-20

Family

ID=27553867

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69016895T Expired - Fee Related DE69016895T2 (en) 1989-08-15 1990-08-13 Isomerization of endocycloolefins into exocycloolefins and copolymerization of cycloolefins with ethylene.

Country Status (7)

Country Link
US (2) US5106931A (en)
EP (1) EP0417489B1 (en)
KR (1) KR930003691B1 (en)
CN (1) CN1073122C (en)
AT (1) ATE118472T1 (en)
CA (1) CA2023214C (en)
DE (1) DE69016895T2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2061003C (en) * 1991-02-12 1999-02-09 Mitsui Chemicals, Inc. Process for isomerizing endo-form of aromatic group-containing norbornenes to exo-form thereof, isomer mixture of aromatic group-containing norbornenes and process for preparing same, and ethylene/aromatic group-contain ng norbornene copolymer and process for preparing same
DE69200228T2 (en) * 1991-11-11 1994-10-20 Mitsui Petrochemical Ind Process for the preparation of a cycloolefin statistical copolymer.
KR100336114B1 (en) * 1999-11-16 2002-05-08 박찬구 Isomerization of isolated double bonds in cyclioolefin
US6260505B1 (en) 1999-12-03 2001-07-17 Midwest Pontoon Covers, Inc. Pontoon boat cover system

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3381046A (en) * 1966-08-15 1968-04-30 Exxon Research Engineering Co Jet and rocket fuel
US4288644A (en) * 1978-11-20 1981-09-08 Suntech, Inc. Process for isomerization of tetrahydrodimethyldicyclopentadiene
US4614778A (en) * 1984-02-03 1986-09-30 Hirokazu Kajiura Random copolymer
US4689380A (en) * 1984-11-16 1987-08-25 Hercules Incorporated Cycloolefin copolymerization method, feed composition and product
JPS62132998A (en) * 1985-12-05 1987-06-16 Nippon Oil Co Ltd High-density fuel oil
JPS63305111A (en) * 1987-06-08 1988-12-13 Nippon Oil Co Ltd Random copolymer and manufacture thereof
WO1989001950A1 (en) * 1987-08-26 1989-03-09 Showa Denko Kabushiki Kaisha Ethylene/polycyclic monomer copolymer and process for its preparation
JPH0751609B2 (en) * 1988-01-20 1995-06-05 日本石油株式会社 Random copolymer and method for producing the same

Also Published As

Publication number Publication date
EP0417489A1 (en) 1991-03-20
KR930003691B1 (en) 1993-05-08
CA2023214C (en) 1996-10-15
DE69016895D1 (en) 1995-03-23
US5106931A (en) 1992-04-21
CA2023214A1 (en) 1991-02-16
CN1073122C (en) 2001-10-17
ATE118472T1 (en) 1995-03-15
KR910004682A (en) 1991-03-29
US5310931A (en) 1994-05-10
EP0417489B1 (en) 1995-02-15
CN1051045A (en) 1991-05-01

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Legal Events

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8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: MITSUI CHEMICALS, INC., TOKIO/TOKYO, JP

8339 Ceased/non-payment of the annual fee