DE602004013365T2 - Verfahren zur modifizierung eines fluorpolymersubstrats und dadurch erhaltene verbundgegenstände - Google Patents
Verfahren zur modifizierung eines fluorpolymersubstrats und dadurch erhaltene verbundgegenstände Download PDFInfo
- Publication number
- DE602004013365T2 DE602004013365T2 DE602004013365T DE602004013365T DE602004013365T2 DE 602004013365 T2 DE602004013365 T2 DE 602004013365T2 DE 602004013365 T DE602004013365 T DE 602004013365T DE 602004013365 T DE602004013365 T DE 602004013365T DE 602004013365 T2 DE602004013365 T2 DE 602004013365T2
- Authority
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- Germany
- Prior art keywords
- carbon atoms
- group
- fluoropolymer
- sub
- substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000758 substrate Substances 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims abstract description 38
- 229920002313 fluoropolymer Polymers 0.000 title claims description 94
- 239000004811 fluoropolymer Substances 0.000 title claims description 92
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 51
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 17
- 125000003118 aryl group Chemical group 0.000 claims abstract description 17
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 9
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 8
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 8
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 8
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 8
- 239000001257 hydrogen Substances 0.000 claims abstract description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 8
- 230000005855 radiation Effects 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 37
- 239000003607 modifier Substances 0.000 claims description 29
- 239000002131 composite material Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 5
- 238000010030 laminating Methods 0.000 claims description 2
- 238000005304 joining Methods 0.000 claims 3
- 238000004026 adhesive bonding Methods 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 7
- 229920000642 polymer Polymers 0.000 description 28
- 229920001577 copolymer Polymers 0.000 description 24
- 239000000178 monomer Substances 0.000 description 20
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- 238000012986 modification Methods 0.000 description 16
- 230000004048 modification Effects 0.000 description 16
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- 230000000052 comparative effect Effects 0.000 description 13
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- 230000003068 static effect Effects 0.000 description 8
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 8
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- 238000000576 coating method Methods 0.000 description 7
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- 229920001343 polytetrafluoroethylene Polymers 0.000 description 7
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- 238000004458 analytical method Methods 0.000 description 5
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- 239000011248 coating agent Substances 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical compound CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
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- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 4
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- 229920006254 polymer film Polymers 0.000 description 4
- 229920000307 polymer substrate Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
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- 229920002981 polyvinylidene fluoride Polymers 0.000 description 4
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- TUMNHQRORINJKE-UHFFFAOYSA-N 1,1-diethylurea Chemical compound CCN(CC)C(N)=O TUMNHQRORINJKE-UHFFFAOYSA-N 0.000 description 3
- YBBLOADPFWKNGS-UHFFFAOYSA-N 1,1-dimethylurea Chemical compound CN(C)C(N)=O YBBLOADPFWKNGS-UHFFFAOYSA-N 0.000 description 3
- AGRIQBHIKABLPJ-UHFFFAOYSA-N 1-Pyrrolidinecarboxaldehyde Chemical compound O=CN1CCCC1 AGRIQBHIKABLPJ-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229920003313 Bynel® Polymers 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
- 229920000299 Nylon 12 Polymers 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- LINDOXZENKYESA-UHFFFAOYSA-N TMG Natural products CNC(N)=NC LINDOXZENKYESA-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000002070 germicidal effect Effects 0.000 description 3
- 229920002681 hypalon Polymers 0.000 description 3
- UNBDDZDKBWPHAX-UHFFFAOYSA-N n,n-di(propan-2-yl)formamide Chemical compound CC(C)N(C=O)C(C)C UNBDDZDKBWPHAX-UHFFFAOYSA-N 0.000 description 3
- NZMAJUHVSZBJHL-UHFFFAOYSA-N n,n-dibutylformamide Chemical compound CCCCN(C=O)CCCC NZMAJUHVSZBJHL-UHFFFAOYSA-N 0.000 description 3
- SKECXRFZFFAANN-UHFFFAOYSA-N n,n-dimethylmethanethioamide Chemical compound CN(C)C=S SKECXRFZFFAANN-UHFFFAOYSA-N 0.000 description 3
- MBHINSULENHCMF-UHFFFAOYSA-N n,n-dimethylpropanamide Chemical compound CCC(=O)N(C)C MBHINSULENHCMF-UHFFFAOYSA-N 0.000 description 3
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 description 3
- JIKUXBYRTXDNIY-UHFFFAOYSA-N n-methyl-n-phenylformamide Chemical compound O=CN(C)C1=CC=CC=C1 JIKUXBYRTXDNIY-UHFFFAOYSA-N 0.000 description 3
- 229920006120 non-fluorinated polymer Polymers 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N 1,1-dimethylguanidine Chemical compound CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- ARXKVVRQIIOZGF-UHFFFAOYSA-N 1,2,4-butanetriol Chemical compound OCCC(O)CO ARXKVVRQIIOZGF-UHFFFAOYSA-N 0.000 description 2
- CJKFVHIAEZFRKY-UHFFFAOYSA-N 1,3-diethyl-1,3-dimethylurea Chemical compound CCN(C)C(=O)N(C)CC CJKFVHIAEZFRKY-UHFFFAOYSA-N 0.000 description 2
- KDISMIMTGUMORD-UHFFFAOYSA-N 1-acetylpiperidine Chemical compound CC(=O)N1CCCCC1 KDISMIMTGUMORD-UHFFFAOYSA-N 0.000 description 2
- CJAOGUFAAWZWNI-UHFFFAOYSA-N 1-n,1-n,4-n,4-n-tetramethylbenzene-1,4-diamine Chemical compound CN(C)C1=CC=C(N(C)C)C=C1 CJAOGUFAAWZWNI-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
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- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
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- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical class C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
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- 230000008859 change Effects 0.000 description 2
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- 150000001875 compounds Chemical class 0.000 description 2
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- 150000002009 diols Chemical class 0.000 description 2
- 230000005670 electromagnetic radiation Effects 0.000 description 2
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- 238000007429 general method Methods 0.000 description 2
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- 238000002844 melting Methods 0.000 description 2
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- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- LGPPATCNSOSOQH-UHFFFAOYSA-N 1,1,2,3,4,4-hexafluorobuta-1,3-diene Chemical compound FC(F)=C(F)C(F)=C(F)F LGPPATCNSOSOQH-UHFFFAOYSA-N 0.000 description 1
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
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- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 description 1
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- 229940057054 1,3-dimethylurea Drugs 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 1
- NYUNHMRXBVASOA-UHFFFAOYSA-N 1,7-dioxacyclotridecane-8,13-dione Chemical compound O=C1CCCCC(=O)OCCCCCO1 NYUNHMRXBVASOA-UHFFFAOYSA-N 0.000 description 1
- KPIPMYXCQUYZFG-UHFFFAOYSA-N 1-butyl-3-hexyl-1,3-diazinan-2-one Chemical compound CCCCCCN1CCCN(CCCC)C1=O KPIPMYXCQUYZFG-UHFFFAOYSA-N 0.000 description 1
- ZBLHYRKOUDNVGQ-UHFFFAOYSA-N 1-ethyl-3-hexyl-1,3-diazinan-2-one Chemical compound CCCCCCN1CCCN(CC)C1=O ZBLHYRKOUDNVGQ-UHFFFAOYSA-N 0.000 description 1
- GWCFTYITFDWLAY-UHFFFAOYSA-N 1-ethylazepan-2-one Chemical compound CCN1CCCCCC1=O GWCFTYITFDWLAY-UHFFFAOYSA-N 0.000 description 1
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- JQFZLWIGUBJIMU-UHFFFAOYSA-N 1-hexyl-3-phenyl-1,3-diazinan-2-one Chemical compound O=C1N(CCCCCC)CCCN1C1=CC=CC=C1 JQFZLWIGUBJIMU-UHFFFAOYSA-N 0.000 description 1
- NNRJZQLYYRFJBA-UHFFFAOYSA-N 1-methyl-1-octadecyl-3,3-dipropylurea Chemical compound CCCCCCCCCCCCCCCCCCN(C)C(=O)N(CCC)CCC NNRJZQLYYRFJBA-UHFFFAOYSA-N 0.000 description 1
- GGYVTHJIUNGKFZ-UHFFFAOYSA-N 1-methylpiperidin-2-one Chemical compound CN1CCCCC1=O GGYVTHJIUNGKFZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US702393 | 2000-10-31 | ||
| US10/702,393 US7273531B2 (en) | 2003-11-05 | 2003-11-05 | Method of modifying a fluoropolymeric substrate and composite articles thereby |
| PCT/US2004/030654 WO2005047373A1 (en) | 2003-11-05 | 2004-09-20 | Method of modifying a fluoropolymeric substrate and composite articles thereby |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE602004013365D1 DE602004013365D1 (de) | 2008-06-05 |
| DE602004013365T2 true DE602004013365T2 (de) | 2009-07-02 |
Family
ID=34551665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE602004013365T Expired - Lifetime DE602004013365T2 (de) | 2003-11-05 | 2004-09-20 | Verfahren zur modifizierung eines fluorpolymersubstrats und dadurch erhaltene verbundgegenstände |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7273531B2 (https=) |
| EP (1) | EP1694748B1 (https=) |
| JP (1) | JP4891084B2 (https=) |
| KR (1) | KR101135846B1 (https=) |
| CN (1) | CN100441614C (https=) |
| AT (1) | ATE393187T1 (https=) |
| DE (1) | DE602004013365T2 (https=) |
| WO (1) | WO2005047373A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7241817B2 (en) * | 2003-06-06 | 2007-07-10 | Arkema France | Process for grafting a fluoropolymer and multilayer structures comprising this grafted polymer |
| US7589140B2 (en) * | 2005-09-29 | 2009-09-15 | 3M Innovative Properties Company | Fluoropolymer bonding compositions |
| US9662869B2 (en) * | 2007-02-08 | 2017-05-30 | Meissner Filtration Products, Inc. | Multilayer film, method of making the same and containers formed from the same |
| FR2944982B1 (fr) * | 2009-04-30 | 2011-10-14 | Commissariat Energie Atomique | Procede de preparation d'un substrat metallise,ledit substrat et ses utilisations |
| CN102190287B (zh) * | 2011-03-24 | 2013-10-16 | 大连理工大学 | 一种提高注塑成型pmma微流控芯片热压键合率的方法 |
| JP6294504B2 (ja) * | 2014-10-31 | 2018-03-14 | 株式会社Shindo | 積層シートおよびその製造方法 |
| JP7005844B1 (ja) * | 2020-12-11 | 2022-01-24 | グンゼ株式会社 | フッ素樹脂フィルム及びフッ素樹脂フィルムの製造方法 |
| CN115806634A (zh) * | 2021-09-13 | 2023-03-17 | 北京化工大学 | 含氟聚合物的表面亲水化改性方法 |
| JP2025045999A (ja) * | 2023-09-21 | 2025-04-02 | 日立グローバルライフソリューションズ株式会社 | 家電製品、冷蔵庫、電気掃除機 |
Family Cites Families (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US414463A (en) * | 1889-11-05 | Pencil-sharpener | ||
| US2789063A (en) | 1954-03-26 | 1957-04-16 | Minnesota Mining & Mfg | Method of activating the surface of perfluorocarbon polymers and resultant article |
| US3254561A (en) | 1961-06-19 | 1966-06-07 | Polaroid Corp | Process for polarizing ultraviolet light utilizing oriented, iodide stained film |
| US3376278A (en) | 1964-11-06 | 1968-04-02 | Minnesota Mining & Mfg | Process for the chemical modification of the solid surface of a polymer |
| US3563871A (en) | 1969-11-14 | 1971-02-16 | Ford Motor Co | Process for reducing the surface friction of an elastomer using radiation and an oxygen free atmosphere |
| CA1053994A (en) | 1974-07-03 | 1979-05-08 | Amp Incorporated | Sensitization of polyimide polymer for electroless metal deposition |
| US4164463A (en) | 1975-05-20 | 1979-08-14 | E. I. Du Pont De Nemours And Company | Hydrophilic fluoropolymers |
| US4186084A (en) | 1975-05-20 | 1980-01-29 | E. I. Du Pont De Nemours And Company | Hydrophilic fluoropolymers |
| US4261800A (en) | 1977-08-15 | 1981-04-14 | Western Electric Co., Inc. | Method of selectively depositing a metal on a surface of a substrate |
| US4192764A (en) | 1977-11-03 | 1980-03-11 | Western Electric Company, Inc. | Stabilizing composition for a metal deposition process |
| US4233421A (en) | 1979-02-26 | 1980-11-11 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition containing sulfonium curing agents |
| DE3024450A1 (de) | 1980-06-28 | 1982-01-28 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von waessrigen, kolloidalen dispersionen von copolymerisaten des typs tetrafluorethylen-ethylen |
| US5086123A (en) | 1984-02-27 | 1992-02-04 | Minnesota Mining And Manufacturing Company | Fluoroelastomer compositions containing fluoroaliphatic sulfonamides as curing agents |
| US4567241A (en) | 1984-06-11 | 1986-01-28 | The Dow Chemical Company | Modification of polymer surfaces |
| US4613653A (en) | 1984-06-11 | 1986-09-23 | The Dow Chemical Company | Modification of polymers |
| US4775449A (en) | 1986-12-29 | 1988-10-04 | General Electric Company | Treatment of a polyimide surface to improve the adhesion of metal deposited thereon |
| US4824692A (en) | 1987-07-27 | 1989-04-25 | The Goodyear Tire & Rubber Company | Process for the surface treatment of unsaturated rubber by photochemical modification with alkyl halides |
| US4912171A (en) | 1988-04-01 | 1990-03-27 | Minnesota Mining And Manufacturing Company | Fluoroelastomer curing process with phosphonium compound |
| US5478652A (en) | 1989-06-22 | 1995-12-26 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with improved bonding properties |
| US5284611A (en) | 1989-06-22 | 1994-02-08 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with improved bonding properties |
| US5051312A (en) | 1990-03-29 | 1991-09-24 | E. I. Du Pont De Nemours And Company | Modification of polymer surfaces |
| US5075427A (en) | 1990-11-19 | 1991-12-24 | W. R. Grace & Co.-Conn. | Polymer surface modification using aqueous stable diazo solution |
| US5135297A (en) * | 1990-11-27 | 1992-08-04 | Bausch & Lomb Incorporated | Surface coating of polymer objects |
| US5320789A (en) | 1991-11-06 | 1994-06-14 | Japan Atomic Energy Research Institute | Surface modification of fluorine resin with laser light |
| JPH05339536A (ja) | 1992-06-11 | 1993-12-21 | Minnesota Mining & Mfg Co <3M> | フッ素ゴム塗布用組成物 |
| US5262490A (en) | 1992-08-24 | 1993-11-16 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition with organo-onium compounds |
| JPH075773B2 (ja) | 1992-12-22 | 1995-01-25 | 工業技術院長 | 紫外レーザーを用いたフッ素系高分子成形品の表面改質方法 |
| US5419968A (en) | 1993-02-16 | 1995-05-30 | Gunze Limited | Surface-hydrophilized fluororesin moldings and method of producing same |
| DE69432966T2 (de) | 1993-03-23 | 2004-07-15 | Tokai University | Verfahren und vorrichtung zur modifizierung fester oberflächen |
| US5285002A (en) | 1993-03-23 | 1994-02-08 | Minnesota Mining And Manufacturing Company | Fluorine-containing polymers and preparation and use thereof |
| JP2612404B2 (ja) | 1993-03-29 | 1997-05-21 | 浜松ホトニクス株式会社 | フッ素樹脂の表面改質方法及びその装置 |
| MY120404A (en) | 1993-10-15 | 2005-10-31 | Kuraishiki Boseki Kabushiki Kaisha | Process for modifying the surfaces of the molded materials made of fluorine resins |
| JP3211532B2 (ja) | 1993-12-21 | 2001-09-25 | ウシオ電機株式会社 | プラスチックス表面改質方法 |
| JP3390763B2 (ja) | 1993-12-24 | 2003-03-31 | オリンパス光学工業株式会社 | 樹脂製チューブの表面改質方法 |
| JPH07330920A (ja) * | 1994-06-10 | 1995-12-19 | Tokai Univ | フッ素樹脂多孔膜と樹脂成形体との接着物 |
| JP3206310B2 (ja) * | 1994-07-01 | 2001-09-10 | ダイキン工業株式会社 | 表面改質されたフッ素樹脂成形品 |
| CN1082440C (zh) | 1994-08-19 | 2002-04-10 | 美国3M公司 | 含有含氟聚合物层的多层组合物 |
| US5656121A (en) | 1994-08-19 | 1997-08-12 | Minnesota Mining And Manufacturing Company | Method of making multi-layer composites having a fluoropolymer layer |
| CN1059155C (zh) * | 1994-08-19 | 2000-12-06 | 美国3M公司 | 具有氟聚合物层的层压制品 |
| JPH08259716A (ja) * | 1995-03-22 | 1996-10-08 | Japan Atom Energy Res Inst | 脂肪族アミンとの光照射によるフッ素系高分子の表面改質方法 |
| US5955556A (en) | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
| US5734085A (en) | 1995-12-21 | 1998-03-31 | Minnesota Mining And Manufacturing Company | Fluorinated phosphonium salts |
| JP3437361B2 (ja) | 1996-01-24 | 2003-08-18 | 独立行政法人産業技術総合研究所 | 樹脂成形用金型 |
| US5859086A (en) | 1996-08-07 | 1999-01-12 | Competitive Technologies Of Pa, Inc. | Light directed modification fluoropolymers |
| US5882466A (en) | 1996-08-08 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Aqueous bonding composition |
| JP3608406B2 (ja) * | 1998-11-25 | 2005-01-12 | 日立電線株式会社 | 改質ふっ素樹脂成形体の製造方法 |
| WO2000052084A1 (en) | 1999-03-02 | 2000-09-08 | 3M Innovative Properties Company | Compositions for fluoropolymer bonding to non-fluorinated polymers |
| JP4357024B2 (ja) | 1999-03-09 | 2009-11-04 | 静岡県 | フッ素樹脂線状体の表面処理方法 |
| US6346600B1 (en) * | 1999-04-22 | 2002-02-12 | Nippon Shokubai Co., Ltd. | Vinylpyrrolidone polymer and its stabilization and preservation processes |
| US6410667B1 (en) * | 1999-11-04 | 2002-06-25 | 3M Innovative Properties Company | Initiator/amidine complexes, systems comprising the complexes, and polymerized compositions made therewith |
| US6685793B2 (en) * | 2001-05-21 | 2004-02-03 | 3M Innovative Properties Company | Fluoropolymer bonding composition and method |
| US6630047B2 (en) * | 2001-05-21 | 2003-10-07 | 3M Innovative Properties Company | Fluoropolymer bonding composition and method |
| US6753087B2 (en) | 2001-05-21 | 2004-06-22 | 3M Innovative Properties Company | Fluoropolymer bonding |
| US6752894B2 (en) | 2001-12-14 | 2004-06-22 | 3M Innovative Properties Company | Process for modifying a polymeric surface |
| US6844030B2 (en) | 2001-12-14 | 2005-01-18 | 3M Innovative Properties Company | Process for modifying a polymeric surface |
-
2003
- 2003-11-05 US US10/702,393 patent/US7273531B2/en not_active Expired - Fee Related
-
2004
- 2004-09-20 DE DE602004013365T patent/DE602004013365T2/de not_active Expired - Lifetime
- 2004-09-20 EP EP04788833A patent/EP1694748B1/en not_active Expired - Lifetime
- 2004-09-20 KR KR1020067010840A patent/KR101135846B1/ko not_active Expired - Fee Related
- 2004-09-20 WO PCT/US2004/030654 patent/WO2005047373A1/en not_active Ceased
- 2004-09-20 AT AT04788833T patent/ATE393187T1/de not_active IP Right Cessation
- 2004-09-20 JP JP2006537990A patent/JP4891084B2/ja not_active Expired - Fee Related
- 2004-09-20 CN CNB2004800328862A patent/CN100441614C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1694748A1 (en) | 2006-08-30 |
| EP1694748B1 (en) | 2008-04-23 |
| WO2005047373A1 (en) | 2005-05-26 |
| KR101135846B1 (ko) | 2012-04-16 |
| KR20060117964A (ko) | 2006-11-17 |
| JP4891084B2 (ja) | 2012-03-07 |
| JP2007527333A (ja) | 2007-09-27 |
| CN100441614C (zh) | 2008-12-10 |
| CN1878825A (zh) | 2006-12-13 |
| ATE393187T1 (de) | 2008-05-15 |
| US20050092429A1 (en) | 2005-05-05 |
| US7273531B2 (en) | 2007-09-25 |
| DE602004013365D1 (de) | 2008-06-05 |
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