DE60011814T2 - Alkylierung von aromaten - Google Patents

Alkylierung von aromaten Download PDF

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Publication number
DE60011814T2
DE60011814T2 DE60011814T DE60011814T DE60011814T2 DE 60011814 T2 DE60011814 T2 DE 60011814T2 DE 60011814 T DE60011814 T DE 60011814T DE 60011814 T DE60011814 T DE 60011814T DE 60011814 T2 DE60011814 T2 DE 60011814T2
Authority
DE
Germany
Prior art keywords
alkylation
benzene
mcm
zeolite
mww
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60011814T
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German (de)
English (en)
Other versions
DE60011814D1 (de
Inventor
John Peter VAN DEN BRINK
Avelino Corma Canos
Julius Edward CREYGHTON
Vicente Fornes Segui
Vicente Martinez Soria
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consejo Superior de Investigaciones Científicas
Universitat Politècnica de València
Original Assignee
Consejo Superior de Investigaciones Científicas
Universitat Politècnica de València
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior de Investigaciones Científicas, Universitat Politècnica de València filed Critical Consejo Superior de Investigaciones Científicas
Publication of DE60011814D1 publication Critical patent/DE60011814D1/de
Application granted granted Critical
Publication of DE60011814T2 publication Critical patent/DE60011814T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Fats And Perfumes (AREA)
DE60011814T 1999-09-20 2000-09-20 Alkylierung von aromaten Expired - Lifetime DE60011814T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP99307421 1999-09-20
EP99307421 1999-09-20
PCT/EP2000/009255 WO2001021562A1 (en) 1999-09-20 2000-09-20 Aromatics alkylation

Publications (2)

Publication Number Publication Date
DE60011814D1 DE60011814D1 (de) 2004-07-29
DE60011814T2 true DE60011814T2 (de) 2005-07-07

Family

ID=8241627

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60011814T Expired - Lifetime DE60011814T2 (de) 1999-09-20 2000-09-20 Alkylierung von aromaten

Country Status (9)

Country Link
US (1) US6855855B2 (enExample)
EP (1) EP1242343B1 (enExample)
JP (1) JP4810037B2 (enExample)
AT (1) ATE269840T1 (enExample)
AU (1) AU7779700A (enExample)
CA (1) CA2385328C (enExample)
DE (1) DE60011814T2 (enExample)
ES (1) ES2223590T3 (enExample)
WO (1) WO2001021562A1 (enExample)

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US6995295B2 (en) 2002-09-23 2006-02-07 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US7019185B2 (en) * 2002-12-06 2006-03-28 Exxonmobil Chemical Patents Inc. Aromatic alkylation process
CN100368290C (zh) * 2003-02-03 2008-02-13 昭和电工株式会社 改性层状金属硅酸盐材料及其制备方法
JP2008535941A (ja) * 2005-02-28 2008-09-04 エクソンモービル リサーチ アンド エンジニアリング カンパニー 気相芳香族アルキル化方法
US7498474B2 (en) * 2005-02-28 2009-03-03 Exxonmobil Research And Engineering Company Vapor phase aromatics alkylation process
US7525002B2 (en) * 2005-02-28 2009-04-28 Exxonmobil Research And Engineering Company Gasoline production by olefin polymerization with aromatics alkylation
US20060194998A1 (en) * 2005-02-28 2006-08-31 Umansky Benjamin S Process for making high octane gasoline with reduced benzene content
US7923589B2 (en) 2005-03-31 2011-04-12 Exxonmobil Chemical Patents Inc. Alkylaromatics production using dilute alkene
EP1866391B1 (en) 2005-03-31 2019-05-22 Badger Licensing LLC Multiphase production of ethylbenzene or cumene
US8524965B2 (en) * 2005-12-21 2013-09-03 Chevron Oronite Company Llc Method of making an alkylated aromatic using acidic ionic liquid catalyst
US7425659B2 (en) 2006-01-31 2008-09-16 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US8222468B2 (en) 2006-05-08 2012-07-17 Exxonmobil Chemical Patents Inc. Organic compound conversion process
US7501547B2 (en) 2006-05-10 2009-03-10 Exxonmobil Chemical Patents Inc. Alkylaromatics production
BRPI0712216B1 (pt) 2006-05-24 2017-04-04 Exxonmobil Chemical Patents Inc processo de produção de composto aromático monoalquilado em uma zona de reação de alquilação
BRPI0713674A2 (pt) 2006-07-28 2012-10-23 Exxonmobil Chemical Patents Inc. formulações farmarcêuticas e composições de um antagonista seletivo cxcr2 ou cxcr1 e métodos para o uso do mesmo visando o tratamento de distúrbios inflamatórios
US7959899B2 (en) 2006-07-28 2011-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions
CN101489677B (zh) * 2006-07-28 2012-12-26 埃克森美孚化学专利公司 Mcm-22家族分子筛组合物，其制造方法和用于烃转化的用途
US20080029435A1 (en) * 2006-08-02 2008-02-07 Exxonmobil Research And Engineering Company Rejuvenation process for olefin polymerization and alkylation catalyst
CA2675264C (en) 2007-02-09 2013-04-02 Exxonmobil Chemical Patents Inc. Improved alkylaromatic production process
US7790940B2 (en) * 2007-06-21 2010-09-07 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US8816145B2 (en) 2007-06-21 2014-08-26 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
EP2060550A1 (en) 2007-11-16 2009-05-20 BP p.l.c. Process for producing triptane
EP2060551A1 (en) 2007-11-16 2009-05-20 BP p.l.c. Process for producing triptane
US8101810B2 (en) * 2008-08-20 2012-01-24 Catalytic Distillation Technologies Reformate benzene reduction via alkylation
US8395006B2 (en) * 2009-03-13 2013-03-12 Exxonmobil Research And Engineering Company Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion
US9522390B2 (en) * 2010-12-10 2016-12-20 The Regents Of The University Of California Oxide materials and synthesis by fluoride/chloride anion promoted exfoliation
JP6045890B2 (ja) * 2012-11-28 2016-12-14 水澤化学工業株式会社 新規な結晶構造を有するｍｃｍ−２２型ゼオライト及び該ゼオライトからなる芳香族炭化水素精製触媒
CA2913922A1 (en) * 2013-05-31 2014-12-04 Chevron U.S.A. Inc. Delamination of borosilicate layered zeolite
WO2015066539A1 (en) * 2013-11-01 2015-05-07 Chevron U.S.A. Inc. Delaminated zeolite catalyzed aromatic alkylation
CN111099621B (zh) * 2018-10-25 2021-10-01 中国石油化工股份有限公司 Mww结构超薄纳米片分子筛的合成方法
KR102267465B1 (ko) * 2019-08-14 2021-06-22 고려대학교 산학협력단 단순 소성을 통한 나노판형 제올라이트의 제조방법과 이로부터 제조된 나노판형 제올라이트 입자
CN115872824B (zh) * 2021-09-27 2025-07-25 中国石油化工股份有限公司 一种对叔丁基乙苯的制备方法
CN115845913B (zh) * 2021-09-27 2025-03-07 中国石油化工股份有限公司 一种烷基化生产取代芳烃的方法及其催化剂和制备方法
WO2023196729A1 (en) * 2022-04-05 2023-10-12 Exxonmobil Chemical Patents Inc. Mww zeolite precursor nanoparticles having an uncondensed layer structure and methods for production thereof

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US3755483A (en) 1972-04-28 1973-08-28 Mobil Oil Vapor phase alkylation in presence of crystalline aluminosilicate catalyst
US4358395A (en) * 1978-09-11 1982-11-09 Mobil Oil Corporation Hydrogen regeneration of coke-selectivated crystalline aluminosilicate catalyst
US4393262A (en) 1978-12-14 1983-07-12 Mobil Oil Corporation Production of isopropylbenzene
US4469908A (en) 1978-12-14 1984-09-04 Mobil Oil Corporation Alkylation of aromatic hydrocarbons
DE3117135A1 (de) 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
US5421992A (en) * 1987-02-17 1995-06-06 Chevron U.S.A. Inc. Hydrocarbon conversion process using zeolite SSZ-25
US4826667A (en) 1986-01-29 1989-05-02 Chevron Research Company Zeolite SSZ-25
US5149894A (en) 1986-01-29 1992-09-22 Chevron Research And Technology Company Alkylation using zeolite SSZ-25
US4962256A (en) * 1988-10-06 1990-10-09 Mobil Oil Corp. Process for preparing long chain alkyl aromatic compounds
US4983276A (en) * 1988-10-06 1991-01-08 Mobil Oil Corp. Octane improvement in catalytic cracking and cracking catalyst composition therefor
US4954325A (en) * 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
IT1205681B (it) 1987-05-26 1989-03-31 Eniricerche Spa Materiale sintetico cristallino poroso contenente ossidi di silicio e boro
US4891458A (en) 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
AU639236B2 (en) * 1990-01-25 1993-07-22 Mobil Oil Corporation Alkylation of aromatics in the presence of a zeolite catalyst
CA2098395A1 (en) * 1991-01-11 1992-07-12 Charles Theodore Kresge Method of preparing a pillared layered oxide material
US5229341A (en) 1991-01-11 1993-07-20 Mobil Oil Corp. Crystalline oxide material
DE69225311T2 (de) 1991-01-11 1998-08-20 Mobil Oil Corp., Fairfax, Va. Schichtenförmige oxide sowie geschwollene und saeulenartige formen dieser materialien
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
WO1994029245A1 (en) 1993-06-16 1994-12-22 Mobil Oil Corporation Liquid phase ethylbenzene synthesis
US5600048A (en) * 1994-12-27 1997-02-04 Mobil Oil Corporation Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
ES2124154B1 (es) * 1995-11-08 1999-12-01 Univ Politecnica De Valencia C Metodo de preparaciion y propiedades cataliticas de un solido microporoso con alta superficie externa.
ES2105982B1 (es) 1995-11-23 1998-07-01 Consejo Superior Investigacion Zeolita itq-1

Also Published As

Publication number Publication date
ES2223590T3 (es) 2005-03-01
EP1242343B1 (en) 2004-06-23
AU7779700A (en) 2001-04-24
CA2385328C (en) 2009-10-13
WO2001021562A1 (en) 2001-03-29
DE60011814D1 (de) 2004-07-29
ATE269840T1 (de) 2004-07-15
US20030004382A1 (en) 2003-01-02
JP2003509479A (ja) 2003-03-11
US6855855B2 (en) 2005-02-15
EP1242343A1 (en) 2002-09-25
CA2385328A1 (en) 2001-03-29
JP4810037B2 (ja) 2011-11-09

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