DE59406591D1 - Verfahren zur Herstellung von kornorientierten Elektroblechen mit verbesserten Ummagnetisierungsverlusten - Google Patents
Verfahren zur Herstellung von kornorientierten Elektroblechen mit verbesserten UmmagnetisierungsverlustenInfo
- Publication number
- DE59406591D1 DE59406591D1 DE59406591T DE59406591T DE59406591D1 DE 59406591 D1 DE59406591 D1 DE 59406591D1 DE 59406591 T DE59406591 T DE 59406591T DE 59406591 T DE59406591 T DE 59406591T DE 59406591 D1 DE59406591 D1 DE 59406591D1
- Authority
- DE
- Germany
- Prior art keywords
- strip
- temperature
- hot
- final
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 238000000137 annealing Methods 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 2
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 238000005096 rolling process Methods 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000005097 cold rolling Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000005261 decarburization Methods 0.000 abstract 1
- 230000001419 dependent effect Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 238000001953 recrystallisation Methods 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular fabrication or treatment of ingot or slab
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1222—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1261—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D3/00—Diffusion processes for extraction of non-metals; Furnaces therefor
- C21D3/02—Extraction of non-metals
- C21D3/04—Decarburising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
- C21D8/1233—Cold rolling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Electromagnetism (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing Of Steel Electrode Plates (AREA)
- Soft Magnetic Materials (AREA)
- Manufacturing Of Magnetic Record Carriers (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Insulating Of Coils (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4311151A DE4311151C1 (de) | 1993-04-05 | 1993-04-05 | Verfahren zur Herstellung von kornorientierten Elektroblechen mit verbesserten Ummagnetisierungsverlusten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE59406591D1 true DE59406591D1 (de) | 1998-09-10 |
Family
ID=6484784
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4311151A Expired - Fee Related DE4311151C1 (de) | 1993-04-05 | 1993-04-05 | Verfahren zur Herstellung von kornorientierten Elektroblechen mit verbesserten Ummagnetisierungsverlusten |
| DE59406591T Expired - Lifetime DE59406591D1 (de) | 1993-04-05 | 1994-03-14 | Verfahren zur Herstellung von kornorientierten Elektroblechen mit verbesserten Ummagnetisierungsverlusten |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4311151A Expired - Fee Related DE4311151C1 (de) | 1993-04-05 | 1993-04-05 | Verfahren zur Herstellung von kornorientierten Elektroblechen mit verbesserten Ummagnetisierungsverlusten |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US5711825A (de) |
| EP (1) | EP0619376B1 (de) |
| JP (1) | JP2728112B2 (de) |
| KR (1) | KR100247598B1 (de) |
| CN (1) | CN1040998C (de) |
| AT (1) | ATE169346T1 (de) |
| AU (1) | AU673720B2 (de) |
| BR (1) | BR9401398A (de) |
| CA (1) | CA2120438C (de) |
| CZ (1) | CZ282649B6 (de) |
| DE (2) | DE4311151C1 (de) |
| ES (1) | ES2121590T3 (de) |
| HU (1) | HU216760B (de) |
| PL (1) | PL173284B1 (de) |
| RO (1) | RO114637B1 (de) |
| RU (1) | RU2126452C1 (de) |
| SK (1) | SK281614B6 (de) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0709470B1 (de) * | 1993-11-09 | 2001-10-04 | Pohang Iron & Steel Co., Ltd. | Verfahren zur herstellung von stahlblech mit gerichteter magnetisierung unterverwendung von niedrigen brammenaufheiztemperaturen. |
| FR2731713B1 (fr) * | 1995-03-14 | 1997-04-11 | Ugine Sa | Procede de fabrication d'une tole d'acier electrique a grains orientes pour la realisation notamment de circuits magnetiques de transformateurs |
| DE19628136C1 (de) * | 1996-07-12 | 1997-04-24 | Thyssen Stahl Ag | Verfahren zur Herstellung von kornorientiertem Elektroblech |
| DE19628137C1 (de) * | 1996-07-12 | 1997-04-10 | Thyssen Stahl Ag | Verfahren zur Herstellung von kornorientiertem Elektroblech |
| IT1284268B1 (it) * | 1996-08-30 | 1998-05-14 | Acciai Speciali Terni Spa | Procedimento per la produzione di lamierino magnetico a grano orientato, con elevate caratteristiche magnetiche, a partire da |
| IT1285153B1 (it) * | 1996-09-05 | 1998-06-03 | Acciai Speciali Terni Spa | Procedimento per la produzione di lamierino magnetico a grano orientato, a partire da bramma sottile. |
| IT1290173B1 (it) * | 1996-12-24 | 1998-10-19 | Acciai Speciali Terni Spa | Procedimento per la produzione di lamierino di acciaio al silicio a grano orientato |
| IT1290171B1 (it) * | 1996-12-24 | 1998-10-19 | Acciai Speciali Terni Spa | Procedimento per il trattamento di acciaio al silicio, a grano orientato. |
| IT1290977B1 (it) * | 1997-03-14 | 1998-12-14 | Acciai Speciali Terni Spa | Procedimento per il controllo dell'inibizione nella produzione di lamierino magnetico a grano orientato |
| IT1290978B1 (it) * | 1997-03-14 | 1998-12-14 | Acciai Speciali Terni Spa | Procedimento per il controllo dell'inibizione nella produzione di lamierino magnetico a grano orientato |
| FR2761081B1 (fr) * | 1997-03-21 | 1999-04-30 | Usinor | Procede de fabrication d'une tole d'acier electrique a grains orientes pour la fabrication notamment de circuits magnetiques de transformateurs |
| WO1998046802A1 (en) * | 1997-04-16 | 1998-10-22 | Acciai Speciali Terni S.P.A. | New process for the production of grain oriented electrical steel from thin slabs |
| AU2698097A (en) * | 1997-04-16 | 1998-11-11 | Acciai Speciali Terni S.P.A. | New process for the production at low temperature of grain oriented electrical steel |
| AU2701197A (en) * | 1997-04-24 | 1998-12-11 | Acciai Speciali Terni S.P.A. | New process for the production of high-permeability electrical steel fr om thin slabs |
| DE19735062A1 (de) * | 1997-08-13 | 1999-02-18 | Thyssen Stahl Ag | Verfahren zur Herstellung von kornorientiertem Elektroblech und Verwendung eines Stahls für Elektroblech |
| DE19745445C1 (de) * | 1997-10-15 | 1999-07-08 | Thyssenkrupp Stahl Ag | Verfahren zur Herstellung von kornorientiertem Elektroblech mit geringem Ummagnetisierungsverlust und hoher Polarisation |
| IT1299137B1 (it) * | 1998-03-10 | 2000-02-29 | Acciai Speciali Terni Spa | Processo per il controllo e la regolazione della ricristallizzazione secondaria nella produzione di lamierini magnetici a grano orientato |
| EP0947597B2 (de) * | 1998-03-30 | 2015-06-10 | Nippon Steel & Sumitomo Metal Corporation | Verfahren zur Herstellung eines kornorientierten Elektrobleches mit ausgezeichneten magnetischen Eigenschaften |
| DE19816158A1 (de) * | 1998-04-09 | 1999-10-14 | G K Steel Trading Gmbh | Verfahren zur Herstellung von korn-orientierten anisotropen, elektrotechnischen Stahlblechen |
| KR100482208B1 (ko) * | 2000-11-17 | 2005-04-21 | 주식회사 포스코 | 침질처리에 의한 용접구조용 강재의 제조방법 |
| RU2199595C1 (ru) * | 2002-06-25 | 2003-02-27 | Открытое акционерное общество "Новолипецкий металлургический комбинат" | Способ производства холоднокатаной электротехнической анизотропной стали |
| RU2414513C1 (ru) * | 2007-04-05 | 2011-03-20 | Ниппон Стил Корпорейшн | Способ непрерывного отжига полосовой стали, имеющей точку кюри, и устройство для непрерывного отжига такой стали |
| ITRM20070218A1 (it) * | 2007-04-18 | 2008-10-19 | Ct Sviluppo Materiali Spa | Procedimento per la produzione di lamierino magnetico a grano orientato |
| CN101545072B (zh) * | 2008-03-25 | 2012-07-04 | 宝山钢铁股份有限公司 | 一种高电磁性能取向硅钢的生产方法 |
| CN101348851B (zh) * | 2008-09-05 | 2010-12-01 | 首钢总公司 | 一种低温铸坯加热生产普通取向电工钢的方法 |
| RU2465348C1 (ru) * | 2008-09-10 | 2012-10-27 | Ниппон Стил Корпорейшн | Способ производства листа из электротехнической стали с ориентированным зерном |
| AT507475B1 (de) * | 2008-10-17 | 2010-08-15 | Siemens Vai Metals Tech Gmbh | Verfahren und vorrichtung zur herstellung von warmband-walzgut aus siliziumstahl |
| IT1396714B1 (it) * | 2008-11-18 | 2012-12-14 | Ct Sviluppo Materiali Spa | Procedimento per la produzione di lamierino magnetico a grano orientato a partire da bramma sottile. |
| CN101603148B (zh) * | 2009-07-28 | 2011-01-05 | 首钢总公司 | 一种生产经济的低温加热取向电工钢的方法 |
| CA2781916C (en) * | 2009-11-25 | 2014-01-28 | Tata Steel Ijmuiden B.V. | Process to manufacture grain-oriented electrical steel strip and grain-oriented electrical steel produced thereby |
| CN102199696A (zh) * | 2010-03-25 | 2011-09-28 | 宁波宝新不锈钢有限公司 | 一种特殊合金钢的预热保温生产方法 |
| EP2578706B1 (de) * | 2010-05-25 | 2016-06-08 | Nippon Steel & Sumitomo Metal Corporation | Verfahren zur herstellung eines kornorientierten elektrostahlblechs |
| DE102011054004A1 (de) * | 2011-09-28 | 2013-03-28 | Thyssenkrupp Electrical Steel Gmbh | Verfahren zum Herstellen eines kornorientierten, für elektrotechnische Anwendungen bestimmten Elektrobands oder -blechs |
| CN102382963B (zh) * | 2011-11-08 | 2013-11-27 | 北京科技大学 | 一种提高高硅电工钢室温塑性的热处理方法 |
| WO2014020369A1 (en) * | 2012-07-31 | 2014-02-06 | Arcelormittal Investigación Y Desarrollo Sl | Method of production of grain-oriented silicon steel sheet grain oriented electrical steel sheet and use thereof |
| CN103834856B (zh) | 2012-11-26 | 2016-06-29 | 宝山钢铁股份有限公司 | 取向硅钢及其制造方法 |
| WO2014132354A1 (ja) * | 2013-02-27 | 2014-09-04 | Ｊｆｅスチール株式会社 | 方向性電磁鋼板の製造方法 |
| CN103484643B (zh) * | 2013-08-23 | 2015-04-15 | 安阳钢铁股份有限公司 | 一种防止取向硅钢热轧边裂的方法 |
| CN110869531B (zh) * | 2017-07-13 | 2022-06-03 | 日本制铁株式会社 | 方向性电磁钢板及方向性电磁钢板的制造方法 |
| JP6946848B2 (ja) * | 2017-08-17 | 2021-10-13 | 日本製鉄株式会社 | 方向性電磁鋼板の製造方法 |
| CN110218850B (zh) * | 2019-06-24 | 2021-04-02 | 鞍钢股份有限公司 | 一种降低取向硅钢高温退火边部粘结缺陷的隔离剂 |
| CN114540714B (zh) * | 2022-02-28 | 2022-12-27 | 西北工业大学 | 一种改善含铜取向硅钢磁性能的方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE790798A (fr) * | 1971-11-04 | 1973-02-15 | Armco Steel Corp | Procédé de fabrication de fer au silicium à orientation cube-sur-arete à partir de brames coulées |
| JPS5037009B2 (de) * | 1972-04-05 | 1975-11-29 | ||
| US3855018A (en) * | 1972-09-28 | 1974-12-17 | Allegheny Ludlum Ind Inc | Method for producing grain oriented silicon steel comprising copper |
| US3855019A (en) * | 1973-05-07 | 1974-12-17 | Allegheny Ludlum Ind Inc | Processing for high permeability silicon steel comprising copper |
| US3976517A (en) * | 1975-07-15 | 1976-08-24 | Allegheny Ludlum Industries, Inc. | Processing for grain-oriented silicon steel |
| JPS6037172B2 (ja) * | 1978-03-11 | 1985-08-24 | 新日本製鐵株式会社 | 一方向性珪素鋼板の製造法 |
| JPS5948934B2 (ja) * | 1981-05-30 | 1984-11-29 | 新日本製鐵株式会社 | 高磁束密度一方向性電磁鋼板の製造方法 |
| JPS6048886B2 (ja) * | 1981-08-05 | 1985-10-30 | 新日本製鐵株式会社 | 鉄損の優れた高磁束密度一方向性電磁鋼板及びその製造方法 |
| US4615760A (en) * | 1983-01-12 | 1986-10-07 | Dressler Robert F | Suppression or control of liquid convection in float zones in a zero-gravity environment by viscous gas shear |
| JPS59208020A (ja) * | 1983-05-12 | 1984-11-26 | Nippon Steel Corp | 低鉄損一方向性電磁鋼板の製造方法 |
| JPS60197819A (ja) * | 1984-03-22 | 1985-10-07 | Nippon Steel Corp | 薄手高磁束密度方向性電磁鋼板の製造方法 |
| JPS60218426A (ja) * | 1984-04-14 | 1985-11-01 | Nippon Steel Corp | 鉄損の優れた高磁束密度一方向性電磁鋼板の製造方法 |
| JPS61117215A (ja) * | 1984-10-31 | 1986-06-04 | Nippon Steel Corp | 鉄損の少ない一方向性電磁鋼板の製造方法 |
| JPS6240315A (ja) * | 1985-08-15 | 1987-02-21 | Nippon Steel Corp | 磁束密度の高い一方向性珪素鋼板の製造方法 |
| EP0321695B1 (de) * | 1987-11-20 | 1993-07-21 | Nippon Steel Corporation | Verfahren zur Herstellung von kornorientierten Elektrostahlblechen mit hoher Flussdichte |
| JPH0717961B2 (ja) * | 1988-04-25 | 1995-03-01 | 新日本製鐵株式会社 | 磁気特性、皮膜特性ともに優れた一方向性電磁鋼板の製造方法 |
| EP0390142B2 (de) * | 1989-03-30 | 1999-04-28 | Nippon Steel Corporation | Verfahren zum Herstellen kornorientierter Elektrobleche mit hoher magnetischer Flussdichte |
| JP2782086B2 (ja) * | 1989-05-29 | 1998-07-30 | 新日本製鐵株式会社 | 磁気特性、皮膜特性ともに優れた一方向性電磁鋼板の製造方法 |
| DE4116240A1 (de) * | 1991-05-17 | 1992-11-19 | Thyssen Stahl Ag | Verfahren zur herstellung von kornorientierten elektroblechen |
-
1993
- 1993-04-05 DE DE4311151A patent/DE4311151C1/de not_active Expired - Fee Related
-
1994
- 1994-03-14 DE DE59406591T patent/DE59406591D1/de not_active Expired - Lifetime
- 1994-03-14 AT AT94103908T patent/ATE169346T1/de active
- 1994-03-14 EP EP94103908A patent/EP0619376B1/de not_active Expired - Lifetime
- 1994-03-14 ES ES94103908T patent/ES2121590T3/es not_active Expired - Lifetime
- 1994-03-21 RU RU94009842A patent/RU2126452C1/ru not_active IP Right Cessation
- 1994-03-23 HU HU9400843A patent/HU216760B/hu not_active IP Right Cessation
- 1994-03-23 CZ CZ94671A patent/CZ282649B6/cs not_active IP Right Cessation
- 1994-03-29 PL PL94302832A patent/PL173284B1/pl not_active IP Right Cessation
- 1994-03-30 RO RO94-00529A patent/RO114637B1/ro unknown
- 1994-03-31 SK SK388-94A patent/SK281614B6/sk not_active IP Right Cessation
- 1994-03-31 CA CA002120438A patent/CA2120438C/en not_active Expired - Fee Related
- 1994-03-31 AU AU59243/94A patent/AU673720B2/en not_active Ceased
- 1994-04-04 KR KR1019940007070A patent/KR100247598B1/ko not_active IP Right Cessation
- 1994-04-04 US US08/222,627 patent/US5711825A/en not_active Expired - Lifetime
- 1994-04-05 BR BR9401398A patent/BR9401398A/pt not_active IP Right Cessation
- 1994-04-05 JP JP6067472A patent/JP2728112B2/ja not_active Expired - Fee Related
- 1994-04-05 CN CN94105439A patent/CN1040998C/zh not_active Expired - Fee Related
-
1996
- 1996-10-23 US US08/735,896 patent/US5759294A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2728112B2 (ja) | 1998-03-18 |
| US5711825A (en) | 1998-01-27 |
| RU94009842A (ru) | 1996-06-27 |
| EP0619376A1 (de) | 1994-10-12 |
| BR9401398A (pt) | 1994-10-18 |
| JPH06322443A (ja) | 1994-11-22 |
| HU216760B (hu) | 1999-08-30 |
| CA2120438A1 (en) | 1994-10-06 |
| CN1040998C (zh) | 1998-12-02 |
| CZ282649B6 (cs) | 1997-08-13 |
| CA2120438C (en) | 2006-06-13 |
| ATE169346T1 (de) | 1998-08-15 |
| HUT70224A (en) | 1995-09-28 |
| EP0619376B1 (de) | 1998-08-05 |
| SK38894A3 (en) | 1994-11-09 |
| HU9400843D0 (en) | 1994-06-28 |
| ES2121590T3 (es) | 1998-12-01 |
| KR100247598B1 (ko) | 2000-04-01 |
| AU673720B2 (en) | 1996-11-21 |
| RU2126452C1 (ru) | 1999-02-20 |
| SK281614B6 (sk) | 2001-05-10 |
| RO114637B1 (ro) | 1999-06-30 |
| PL173284B1 (pl) | 1998-02-27 |
| AU5924394A (en) | 1994-10-27 |
| DE4311151C1 (de) | 1994-07-28 |
| CZ67194A3 (en) | 1994-12-15 |
| CN1098440A (zh) | 1995-02-08 |
| US5759294A (en) | 1998-06-02 |
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